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Optical Properties of Cdlnsub 2Ssub 4 and Cdlnsub 2Ssub 4 : $CdIn_2S_4$$CdIn_2S_4 : Co^{2+}$Single Crystals ($CdIn_2S_4$$CdIn_2S_4 : Co^{2+}$ 단결정의 광학적 특성)

  • Choe, Seong-Hyu;Bang, Tae-Hwan;Kim, Hyeong-Gon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.5
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    • pp.296-302
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    • 1999
  • $CdIn_2S_4 and CdIn_2S_4 : Co^{2+}$ singlecrystals of thenormal spinel structure were grown by the C.T.R. method. The optical energy band structure of these compounds had a indirect band gap at the fundamental optical absorption band edge. The direct and the indirect energy gaps are found to be 2.325 and2.179eV for $Cdln_2S_4$ , and 2.303 and 2.169eV for $CdIn_2S_4 and CdIn_2S_4 : Co^{2+}$ at 5K, respectivly. The fundamental absorption band edge of these single crystals shift to a shorter wavelength region with decreasing temperature, and the temperature dependence of the optical energy gaps in these compounds satisfy Varshni equation. The Varshni constants$\alpha and \beta$ of the direct energy gap are given by $13.39{\times}10_{-4}eV/K$ and 509 K for $Cdln_2S_4$ and $29.73{\times}10_{-4} eV/K$ and 1398K for $CdIn_2S_4 and CdIn_2S_4 : Co^{2+}$. The Varshni constants ${\alpha}and {\beta}$ of the indirect energy gap are given by 9.68${\times}10^{-4}$ eV/K 308K for $Cdln_2S_4$ and $13.33{\times}10_{-4}eV/K$ and 440K for $CdIn_2S_4 : Co^{2+}$ respectivly. The impurity optical absorption peaks due to cobalt dopant are observed in $CdIn_2S_4 : Co^{2+}$ single crystal. These impurity optical absorption peaks can be attributed to the electronic transitions between the split energy levels of $Co_{2+}$ ions located at $T_d$ symmetry site of $Cdln_2S_4$ host lattece.

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Effect of Microstructures and Sintering Additives on the Mechanical Properties of Si$_3$N$_4$ (질화규소의 기계적 특성에 미치는 미세구조 및 소결조제의 영향)

  • Park, Hye-Ryeon;Lee, O-Sang;Park, Hui-Dong;Lee, Jae-Do
    • Korean Journal of Materials Research
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    • v.2 no.5
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    • pp.330-336
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    • 1992
  • Four distinctive hot pressed and heat treated S${i_3}{N_4}$ceramics, S${i_3}{N_4}$-8%${Y_2}{O_3}$, S${i_3}{N_4}$-6% ${Y_2}{O_3}$-2% $A{l_2}{O_3}$, S${i_3}{N_4}$-4% ${Y_2}{O_3}$-3% $A{l_2}{O_3}$, 그리고 S${i_3}{N_4}$-1% MgO-1% Si$O_2$(in wt%), were prepared and characterized by X-ray diffraction, scanning electron microscopy, image analysis and mechanical tests. The fracture toughness of S${i_3}{N_4}$-8% ${Y_2}{O_3}$specimens containing large elongated grains showed the highest value of about 9.8MPa$m^{1/2}$. Two out of four S${i_3}{N_4}$, ceramics(S${i_3}{N_4}$-6% ${Y_2}{O_3}$-2% $A{l_2}{O_3}$and S${i_3}{N_4}$-4% ${Y_2}{O_3}$-3% $A{l_2}{O_3}$) heat treated at 200 $0^{\circ}C$retained the fracture strength of over 900MPa and fracture toughness of over 8.0MPa$m^{1/2}$. Large ${\beta}$-S${i_3}{N_4}$grains having a diameter larger than 1${\mu}$m appeared to contribute to increase in fracture toughness.

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Study on the Residual Tobacco poison to Cocoon Crops according to the Tobacco Cultivation of the Mulching System (개양 Mulching 담배 재배에 따른 잔류독성 기간에 관한 연구)

  • 이상풍;김정배;홍기원;마영일
    • Journal of Sericultural and Entomological Science
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    • v.16 no.1
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    • pp.77-84
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    • 1974
  • In autumn season residual period of nicotine is observed in the larval duration, weight of molting larvae at the various stages, percentage of delayed molting larvae, and survival rate up to the 3rd stage from the 1st season to the 3rd season and up to the stage for four seasons, respectively. Mulberry tree is planted in pot from June 18, 1973 to August 4, 1973 and placed every other row between tobacco variety of Hicks cultivated in mulching system and control is prepared in the Sericultural Experiment Station, placing in the every ridge of mulberry field with the four seasons ; 5 day isolation (1st season), 15 day isolation (2nd season), 25 day isolation (3rd season), and 50 day isolation (4th season). 1) 1st and 3nd instar larvae fed with the tobacco stained mulberry leaf has longer larval duration for the four seasons, as compared with those of the control, increasing 12% in index with 28 hours, 17% in index with 37 hours, 23% in index with 50 hours, 17% in index with 43 hours from the 1st season to the fourth season and the 3rd to the 4th instar larvae, increasing 18% in index with 55 hours. 2) 2nd instar molting larvae, 3rd instar molting larvae from the 1st to the 4th season and 4th instar molting larvae at the 4th season decrease their larval weight respectively, as compared with the control. 3) Percentage of delayed molting larvae from the 3rd stage to the 4th stage goes up higher than that of the control in the End larval stage at the 3rd to the 4th season, in the 3rd larval stage at the 1st, the End, and the 4th season, and in the 4th larval stage at the 4th season, respectively. 4) Survival rates in the 2nd larval stage at the 2nd season to the 4th season, in the 3rd larval stage at the 1st to the 4th season, and in the 4th larval stage at the 4th season respectively are higher than that in the control.

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Characteristics of Hydrolysis Reaction Using Unsupported Catalyst at High Concentration of NaBH4 Solutions (고농도 NaBH4 수용액에서 비담지 촉매의 가수분해 반응 특성)

  • Lee, Hye-Ri;Na, Il-Chai;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.54 no.5
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    • pp.587-592
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    • 2016
  • Sodium borohydride, $NaBH_4$, shows a number of advantages as hydrogen source for portable proton exchange membrane fuel cells (PEMFCs). Properties of $NaBH_4$ hydrolysis reaction using unsupported Co-P-B Co-B, catalyst at high concentration $NaBH_4$ solution were studied. In order to enhance the hydrogen generation yield at high concentration of $NaBH_4$, the effect of catalyst type, $NaBH_4$ concentration and recovery of condensing water on the hydrogen yield were measured. The yield of hydrogen evolution increased as the boron ratio increased in preparation process of Co-P-B catalyst. The hydrogen yield decreased as the concentration increased from 20 wt% to 25 wt% in $NaBH_4$ solution during hydrolysis reaction using 1:5 Co-P-B catalyst. Maximum hydrogen yield of 96.4% obtained by recovery of condensing water and thinning of catalyst pack thickness in reactor using Co-P-B with Co-B catalyst and 25 wt% $NaBH_4$ solution.

Review of a novel disease entity, immunoglobulin G4-related disease

  • Maehara, Takashi;Moriyama, Masafumi;Nakamura, Seiji
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.46 no.1
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    • pp.3-11
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    • 2020
  • Immunoglobulin G4 (IgG4)-related dacryoadenitis and sialoadenitis (IgG4-DS) are part of a multiorgan fibroinflammatory condition of unknown etiology termed IgG4-related disease (IgG4-RD), which has been recognized as a single diagnostic entity for less than 15 years. Histopathologic examination is critical for diagnosis of IgG4-RD. CD4+ T and B cells, including IgG4-expressing plasma cells, constitute the major inflammatory cell populations in IgG4-RD and are thought to cause organ damage and tissue fibrosis. Patients with IgG4-RD who have active, untreated disease exhibit significant increase of IgG4-secreting plasmablasts in the blood. Considerable insight into the immunologic mechanisms of IgG4-RD has been achieved in the last decade using novel molecular biology approaches, including next-generation and single-cell RNA sequencing. Exploring the interactions between CD4+ T cells and B lineage cells is critical for understanding the pathophysiology of IgG4-RD. Establishment of pathogenic T cell clones and identification of antigens specific to these clones constitutes the first steps in determining the pathogenesis of the disease. Herein, the clinical features and mechanistic insights regarding pathogenesis of IgG4-RD were reviewed.

Synthesis of Li4/3Mn5/3O4 by Sol-Gel Process and its Electrochemical Properties (졸-겔법에 의한 Li4/3Mn5/3O4의 합성 및 전기화학적 특성)

  • Lee, Jin-Sik;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.80-84
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    • 1999
  • $Li_{4/3}Mn_{5/3}O_4$ having a defect structure was prepared by sol-gel process using lithium acetate and manganese acetate as starting materials, and their electrode characteristics in the lithium secondary battery was investigated. The reaction mole ratio was determined as $AA/Mn(OAc)_2$ of 0.2 and $NH_4OH/Mn(OAc)_2$ to $H_2O/Mn(OAc)_2$ of 0.4. The product was obtained through heat treatment at $350^{\circ}C$ for 12hrs after 1'st heat treatment at $150^{\circ}C$ of xerogel under oxygen atmosphere. When the charge and discharge cycles were performed between 2.0 V and 3.2 V, $Li/Li_{4/3}Mn_{5/3}O_4$ cell showed the dicharge capacity of 84.23 mAh/g and the good cycleability was obtained in the plateau region.

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Optical properties of $YVO_{4}$ and Nd:$YVO_{4}$ single crystals grown by developed EFG method (Developed EFG법으로 성장시킨 $YVO_{4}$ 및 Nd:$YVO_{4}$ 단결정의 광학적 특성)

  • ;;M.A. Ivanov;V.V. Kochurikhin
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.4
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    • pp.180-183
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    • 2001
  • $YVO_{4}$ and Nd:$YVO_{4}$ single crystals have been grown developed Edge-defined film-fed growth (EFG) method and the crystals were measured on optical properties. $YVO_{4}$ and Nd:$YVO_{4}$ single crystal were transparent, high quality due to homogeneity of surface temperature of the melt and stability of meniscus during crystal growth. In transmittance and absorption spectra, Nd:$YVO_{4}$ single crystals had absorption peaks at wavelengths of 532, 593, 753, 808, 888 though $YVO_{4}$ single crystal had a broad transmittance at wavelength ranging from 340 to 1000nm. Also, Nd:$YVO_{4}$ single crystals had emissions of energy at range of 800~900 nm in photoluminescence (PL) spectrum.

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Luminescence Characteristics and Crystal Structure of CaWO4-Li2WO4-Eu2O3 Phosphors (CaWO4-Li2WO4-Eu2O3계 형광체의 PL 특성과 결정구조)

  • Kim, Jeong-Seog;Choi, Jin-Ho;Jeong, Bong-Man;Kang, Hyun-Ju
    • Journal of the Korean Ceramic Society
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    • v.43 no.1 s.284
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    • pp.10-15
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    • 2006
  • Photoluminescence (PL) and crystal structures of the $(l-x)CaWO_4-xLi_2WO_4$ binary system added with $Eu_2O_3$ activator have been characterized. The $CaWO_4\;and\;Li_2WO_4$ have the scheelite and phenakite structures respectively. The $CaWO_4-Li_2WO_4-Eu_2O_3$ phosphors show the red luminescence of 613 nm peak wavelength. The wavelength range of excitation spectral band is $380\~470$ nm with the peak wavelength of 397 nm. The $0.88(0.5CaWO_4-0.5Li_2WO_4)-0.12Eu_2O_3$ showed the most superior luminescence characteristics. The effect of co-doping elements such as $Al_2O_3$ and rare-earth oxides on PL has been characterized. The co-doping elements deteriorated the luminescence intensity except the $Al_2O_3$ and $Gd_2O_3$. The PL characteristics of $CaWO_4-Li_2WO_4-Eu_2O_3$ phosphors have been compared to those of the alkali europium double molybdates (tungstates) of scheelite-related structure such as $LiEu(MoO_4)_2$ and $CsEu(MoO_4)_2$. The crystal structures of $(l-y)[(l-x)CaWO_4-xLi_2WO_4]-yEu_2O_3$ phosphors have been characterized using XRD data and rietveld refinement.

Application of Zn2TiO4 for nucleation and control of willemite crystalline glaze (아연결정유약의 결정 생성 및 제어를 위한 Zn2TiO4 활용 연구)

  • Lee, Hyun-Soo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.4
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    • pp.154-161
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    • 2017
  • $Zn_2TiO_4$, which is a progenitor of zinc crystallization, plays a significant role in controlling the crystallization of willemite ($Zn_2SiO_4$) in forming glaze at low temperatures. Thus, $Zn_2TiO_4$ was used to formulate stable willemite and to gain structural control. When synthesized 15 wt% of $Zn_2TiO_4$ is added to engobe and then applied, it can manipulate its crystallization and location. Additionally, when colorant is added to $Zn_2TiO_4$ and then applied to engobe, the mixture's colorant effect can be shown at crystallization. Certain characteristics of synthesized $Zn_2TiO_4$ enable various engobes to be applied to clay bodies. With a single glazing, the crystallization, location, and color of the crystals can be discretionarily regulated.

The Effectiveness of Cognitive Monitoring Skills of Elementary Students on Science (초등학생의 과학에 대한 인지모니터링 기능의 효율성 분석)

  • Ko, Kawng-Byung;Ko, Se-Hwan;Kim, Beom-Ki;Choi, Kwan-Soon
    • Journal of The Korean Association For Science Education
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    • v.24 no.6
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    • pp.1173-1180
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    • 2004
  • The purpose of this study was to investigate the effectiveness of cognitive monitoring skills of elementary students on science by the grade and sex. The subject of this study was 1001 elementary students of $2{\sim}6$ grade from 5 schools. The instrument of study, TSCM I (Test of Science Cognitive Monitoring I ) for $2{\sim}4$ grade and TSCM II for $4{\sim}6$ grade were developed. The results of this study showed that the effectiveness of cognitive monitoring skills was 63.4% for $2{\sim}4$ grade and 57.4% for $4{\sim}6$ grade. The effectiveness of cognitive monitoring skills of 3 and 4 graders was significantly higher than 2, while 5 and 6 was higher than 4 graders. Girls were higher than boys for 2 and 3 grade, but 4${\sim}$6 graders were not significantly different by the sex.