• Bulletin of the Korean Chemical Society
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• v.18 no.8
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• pp.831-840
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• 1997

Core/shell structured composite metal oxides of Fe2O3/MgO were prepared by thermal decomposition of Fe(acac)3 adsorbed on the surface of MgO cores. The morphology of the composites conformed to that of the MgO used as the cores. Broad powder X-ray diffraction peaks shifted toward larger d, large BET surface area (∼350 m2/g), and the size of crystalline domains in nano range (4 nm), all corroborate to the nanocrystallinity of the Fe2O3/MgO composite which was prepared by using nanocrystalline MgO as the core. By use of microcrystalline MgO as the core, microcrystalline Fe2O3/MgO composite was prepared, and it had small BET surface area of less than 35 m2/g. AFM measurements on nanocrystalline Fe2O3/MgO showed a collection of spherical aggregates (∼80 nm dia) with a very rough surface. On the contrary, microcrystalline Fe2O3/MgO was a collection of plate-like flat crystallites with a smooth surface. The nitrogen adsorption-desorption behavior indicated that microcrystalline Fe2O3/MgO was nonporous, whereas nanocrystalline Fe2O3/MgO was mesoporous. Bimodal distribution of the pore size became unimodal as the layer of Fe2O3 was applied to nanocrystalline MgO. The macropores in a wide distribution which the nanocrystalline MgO had were absent in the nanocrystalline Fe2O3/MgO. The decomposition of CCl4 was largily enhanced by the overlayer of Fe2O3 on nanocrystalline MgO making the reaction between nanocrystalline Fe2O3/MgO and CCl4 be nearly stoichiometric. The reaction products were environmentally benign MgCl2 and CO2. Such an enhancement was not attainable with the microcrystalline samples. Even for the nanocrystalline MgO, the enhancement was not attained, if not with the Fe2O3 layer. Without the layer of Fe2O3, it was observed that the nanocrystalline domain of the MgO transformed into microcrystalline one as the decomposition of CCl4 proceeded on its surface. It appeared that the layer of Fe2O3 on the particles of nanocrystalline Fe2O3/MgO blocked the transformation of the nanocrystalline domain into microcrystalline one. Therefore, in order to attain stoichiometric reaction between CCl4 and Fe2O3/MgO core/shell structured composite metal oxide, the morphology of the core MgO has to be nanocrystalline, and also the nanocrystalline domains has to be sustained until the core was exhausted into MgCl2.

• Journal of Hydrogen and New Energy
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• v.23 no.6
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• pp.581-587
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• 2012

Thermal aging effect on NSR kinetics was studied over Pt/Co/Fe/Ba/$Al_2O_3$ catalyst. The amount of $NO_x$ uptake over Pt/Co/Fe/Ba/$Al_2O_3$ calcined at $400^{\circ}C$ increased with increasing NSR temperature from $200^{\circ}C$ to $400^{\circ}C$, where amount of $NO_x$ uptake is the highest at $400^{\circ}C$ with mol ratio of $NO_x$/Ba = 0.5. Thereafter, the amount of $NO_x$ uptake at $400^{\circ}C$ decreased with the higher calcination temperature, where Pt/Co/Fe/Ba/$Al_2O_3$ catalyst calcined at $700^{\circ}C$ showed an amount of $NO_x$ uptake with the mol ratio of $NO_x$/Ba=0.062. Result of XRD and NSR showed that Fe addition into Pt/Co/Fe/Ba/$Al_2O_3$ suppressed sintering of Pt crystallites and make $NO_x$ uptake larger, compared to no addition of Fe into Pt/Co/Fe/Ba/$Al_2O_3$ catalyst. From BET result, it was found that the change of specific surface area was relatively small by the thermal aging process. Therefore, it was found that the sintering of Pt crystallites caused the decrease of $NO_x$ uptake during NSR reaction and Fe played a role to suppress the sintering process of Pt crystallites caused by thermal aging.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.30 no.5 s.248
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• pp.568-575
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• 2006

The present paper provides plastic limit load solutions of axial and circumferential through-wall cracked pipes based on detailed three-dimensional (3-D) finite element (FE) limit analysis using elastic-perfectly-plastic behavior. As a loading condition, axial tension, global bending moment, internal pressure, combined tension and bending and combined internal pressure and bending are considered for circumferential through-wall cracked pipes, while only internal pressure is considered for axial through-wall cracked pipes. Especially, more emphasis is given for through-wall cracked pipes subject to combined loading. Comparisons with existing solutions show a large discrepancy in short through-wall crack (both axial and circumferential) for internal pressure. In the case of combined loading, the FE limit analyses results show thickness effect on limit load solutions. Furthermore, the plastic limit load solution for circumferential through-wall cracked pipes under bending is applied to derive plastic $\eta\;and\;{\gamma}$-factor of testing circumferential through-wall cracked pipes to estimate fracture toughness. Being based on detailed 3-D FE limit analysis, the present solutions are believed to be meaningful fur structural integrity assessment of through-wall cracked pipes.

• Special Issue of the Society of Naval Architects of Korea
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• 2007.09a
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• pp.99-106
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• 2007

The IACS Common Structural Rules are to be applied for double hull tanker of more than 150m length with contracted after 1 April 2006. The objectives of the rules are to make more robust, safer ship and to ensure transparency of the technical background. In compliance of CSR, we had carried out prescriptive rules scantling determination and 3-D hold FE analysis of AFRAMAX TANKER. Prescriptive rules scantling determines the minimum required scantling, hull-girder longitudinal bending and shear strength, hull girder ultimate strength, local strength of plate and stiffener, strength of primary supporting member and fatigue assessment of the longitudinal stiffener end connections to the transverse bulkhead. 3-D hold FE analysis assesses the structural adequacy of the vessel's primary hull structure and major supporting members using yielding and buckling failure modes. So we could verify the strength assessment of AFRAMAX TANKER applied CSR.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.3D
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• pp.435-444
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• 2006

This paper investigates the effect of 3-dimensional FE models to evaluation results of jointed concrete pavements which is back-calculated by AREA method. Sensitivity of 3-dimensional FE models developed to simulate the behavior of real jointed concrete pavement are analyzed after compared with 2-dimensional FE models using ILLISLAB. In comparison with 2-dimensional models, influence of concrete contraction under loading plate and base layer on surface deflections is more than that of loading configuration. Deflections at 3-dimensional model between linear and nonlinear temperature distribution under same temperature difference are similar, but noticeable differences are investigated in low elastic modulus of foundations. Dynamic deflections under loading plate are larger than static deflections in high elastic modulus of foundation, but smaller in low elastic modulus. Lower dynamic modulus of subgrade reactions are backcalculated by dynamic deflections than by static deflections. But reverse trend is investigated in the backcalculated elastic modulus of concrete which describes trends of the field backcalculation values calculated from AREA method.

• Steel and Composite Structures
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• v.39 no.3
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• pp.291-306
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• 2021

Based on Reissner's mixed variational theorem (RMVT), the authors develop a semi-analytical finite element (FE) method for a three-dimensional (3D) bending analysis of nonhomogeneous orthotropic, complete and incomplete toroidal shells subjected to uniformly-distributed loads. In this formulation, the toroidal shell is divided into several finite annular prisms (FAPs) with quadrilateral cross-sections, where trigonometric functions and serendipity polynomials are used to interpolate the circumferential direction and meridian-radial surface variations in the primary field variables of each individual prism, respectively. The material properties of the toroidal shell are considered to be nonhomogeneous orthotropic over the meridianradial surface, such that homogeneous isotropic toroidal shells, laminated cross-ply toroidal shells, and single- and bi-directional functionally graded toroidal shells can be included as special cases in this work. Implementation of the current FAP methods shows that their solutions converge rapidly, and the convergent FAP solutions closely agree with the 3D elasticity solutions available in the literature.

• Korean Journal of Materials Research
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• v.9 no.1
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• pp.104-107
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• 1999

We investigated the effects of cooling condition on deep levels and iron precipitate formation in iron-contaminated p-type silicon by DLTS(Deep Level Transient Spectroscopy) and preferential etching technique. Dependency of cooling condition on Bulk Micro-Defect (BMD) and four different iron-related deep traps were observed. For normal cooling condition, T1, T2, T3, T4 traps that related to Fe\ulcorner or Fe-O complex were obtained. However, the trap with activation energy, 0.4 eV was observed for slow cooling condition. The trap caused by the $\textrm{Fe}^{+}\textrm{}^{-}$ pair (H4:0.56eV) were detected only at the case of $\textrm{LN}_{2}$ quenching condition.

• Journal of Electrochemical Science and Technology
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• v.9 no.3
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• pp.202-211
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• 2018

In this work, Fe-Pd alloy films have been electrodeposited on different substrates using an electrolyte containing $[Pd(NH_3)_4]^{2+}$ (0.02 M) and $[Fe-Citrate]^{2+}$ (0.2 M). The influences of substrate and overpotential on chemical composition, nucleation and growth kinetics as well as the electrodeposited films morphology have been investigated using energy dispersive X-ray spectroscopy (EDS), current-time transients, scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray diffraction (XRD) patterns. In all substrates - brass, copper and sputtered fluorine doped tin oxide on glass (FTO/glass) - Fe content of the electrodeposited alloys increases by increasing the overpotential. Also the cathodic current efficiency is low due to high rate of $H_2$ co-reduction. Regarding the chronoamperometry current-time transients, it has been demonstrated that the nucleation mechanism is instantaneous with a typical three dimensional (3D) diffusion-controlled growth in the case of brass and copper substrates; while for FTO, the growth mode changes to 3D progressive. At a constant overpotential, the calculated number of active nucleation sites for metallic substrates is much higher than that of FTO/glass; however by increasing the overpotential, the number of active nucleation sites increases. The SEM micrographs as well as the XRD patterns reveal the formation of Fe-Pd alloy thin films with nanostructure arrangement and ultra-fine grains.

• Journal of the Society of Disaster Information
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• v.11 no.1
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• pp.1-8
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• 2015

This paper presents finite element (FE) analyses to clarify the effects of external pressure on the residual stresses in a girth-welded steel pipe. At first, FE simulation of the girth welding process is carried out to obtain the weld-induced residual stresses employing sequentially coupled three-dimensional (3-D) thermo-mechanical FE formulation. Then, 3-D elastic-plastic FE analyses incorporating the residual stresses and plastic strains obtained from the preceding FE simulation are performed to investigate the residual stress behavior in the girth-welded pipe under external pressure. The FE analysis results show that the hoop compressive stresses induced by the external pressure significantly alter the hoop residual stresses in the course of the mechanical loading.

• Nano
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• v.13 no.11
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• pp.1850125.1-1850125.12
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• 2018

To reduce the imbalance of impedance matching between the magnetic metal nanowires and free space, $Fe/TiO_2$ core/shell nanowire arrays with different diameters were fabricated in the templates of anodic aluminum oxide membranes by electrodeposition. The influences of the microstructure on the microwave absorption properties of the $Fe/TiO_2/Al_2O_3$ composites were studied by the transmission/reflection waveguide method. It was demonstrated experimentally that both the interfacial polarization and the diameter of the $Fe/TiO_2$ core/shell nanowires have critical effects on the microwave absorption properties. We also investigated the angle dependence of the microwave absorption properties. Due to the interfacial polarization and associated relaxation, the $Fe/TiO_2/Al_2O_3$ composites exhibited optimal microwave absorption properties when microwave propagation direction was accordant with the axis of the nanowires. Finally, we managed to obtain an optimal reflection loss of below -10 dB (90% absorption) over 10.2-14.8 GHz, with a thickness of 3.0 mm and the minimum value of -39.4 dB at 11.7 GHz.