• Title/Summary/Keyword: 3D FE

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Energy Level Calculation of Fe3+ Paramagnetic Impurity Ion in a LiTaO3 Single Crystal (LiTaO3 단결정 내의 Fe3+ 상자성 불순물 이온에 대한 에너지 준위 계산)

  • Yeom, Tae Ho;Yoon, Dal Hoo;Lee, Soo Hyung
    • Journal of the Korean Magnetics Society
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    • v.24 no.3
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    • pp.71-75
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    • 2014
  • Ground state energy levels of the $Fe^{3+}$ paramagnetic impurity ion in stoichiometric $LiTaO_3$ and in congruent $LiTaO_3$ single crystals were calculated with electron paramagnetic resonance constants. Energy levels between six energy levels were obtained with spectroscopic splitting parameter g and zero field splitting constant D for $Fe^{3+}$ ion. The energy diagrams of $Fe^{3+}$ ion were different from different magnetic field directions ([100], [001], [111]) when magnetic field increases. The calculated ZFS energies of $Fe^{3+}$ ion in stoichiometric and congruent $LiTaO_3$ single crystals for ${\mid}{\pm}5/2$ > ${\leftrightarrow}{\mid}{\pm}3/2$ > and ${\mid}{\pm}3/2$ > ${\leftrightarrow}{\mid}{\pm}1/2$ > transitions were 12.300 GHz and 6.150 GHz, and 59.358 GHz and 29.679 GHz, respectively. It turns out that energy levels of $Fe^{3+}$ paramagnetic impurity in $LiTaO_3$ crystal are different from different crystal growing condition.

Effect of Cathode Materials (MS2, M=Fe, Ni, Co) on Electrochemical Properties of Thermal Batteries (열전지용(MS2, M=Fe, Ni, Co)계 양극의 전기화학적 특성 연구)

  • Lee, Jungmin;Im, Chae-Nam;Yoon, Hyun-Ki;Cheong, Hae-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.9
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    • pp.583-588
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    • 2017
  • Thermal batteries are used in military power sources that require robustness and long storage life for applications in missiles and torpedoes. $FeS_2$ powder is currently used as a cathode material because of its high specific energy density, environmental non-toxicity, and low cost. $MS_2$ (M = Fe, Ni, Co) cathodes have been explored as novel candidates for thermal batteries in many studies; however, the discharge characteristics (1, 2, 3 plateau) of single cells in thermal batteries with different cathodes have not been elucidated in detail. In this study, we independently analyzed the discharge voltage and calculated the total polarizations of single cells using $MS_2$ cathodes. Based on the results of this study, we propose $NiS_2$ as a potential cathode material for use in thermal batteries.

Compaction Properties of Fe Powder Fabricated by Warm Compaction (온간성형법으로 제조된 Fe 분말의 성형특성)

  • Kim, Se-Hoon;Lee, Young-Jung;Lee, Jea-Sung;Kim, Young-Do
    • Journal of Powder Materials
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    • v.14 no.3 s.62
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    • pp.185-189
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    • 2007
  • Various approaches have been proposed to increase the green density. Warm compaction method has been used for the reduction of residual stress, the improvement of magnetic properties and the higher densities. In this work, the effect of warm compaction on green density of Fe powder was investigated. After ball-milling of Fe oxide powder for 30 hours, Fe oxide powder was reduced through the hydrogen reduction process. The pure Fe powder and polymer binder were mixed by 3-D tubular mixer. And then the mixed powder was warm-compacted with various compaction pressure and binder contents. The green density of specimen was added polyvinyl binder was higher than any other specimens.

3D FE modeling considering shear connectors representation and number in CBGB

  • Abbu, Muthanna A.;Ekmekyapar, Talha A.;Ozakca, Mustafa A.
    • Steel and Composite Structures
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    • v.17 no.3
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    • pp.237-252
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    • 2014
  • The use of composite structures is increasingly present in civil building works. Composite Box Girder Bridges (CBGB), particularly, are study of effect of shear connector's numbers and distribution on the behavior of CBGBs is submitted. A Predicti structures consisting of two materials, both connected by metal devices known as shear connectors. The main functions of these connectors are to allow for the joint behavior of the girder-deck, to restrict longitudinal slipping and uplifting at the element's interface and to take shear forces. This paper presents 3D numerical models of CBGBs to simulate their actual structural behavior, with emphasis on the girder-deck interface. Additionally, a Prediction of several FE models is assessed against the results acquired from a field test. A number of factors are considered, and confirmed through experiments, especially full shear connections, which are obviously essential in composite box girder. A good representation for shear connectors by suitable element type is considered. Numerical predictions of vertical displacements at critical sections fit fairly well with those evaluated experimentally. The agreement between the FE models and the experimental models show that the FE model can aid engineers in design practices of box girder bridges. Preliminary results indicate that number of shear studs can be significantly reduced to facilitate adoption of a new arrangement in modeling CBGBs with full composition. However, a further feasibility study to investigate the practical and economic aspects of such a remedy is recommended, and it may represent partial composition in such modeling.

New Engineering J and COD Estimation Methods for Axial Through-Wall Cracked Pipes (축방향 관통균열 배관의 새로운 탄소성 J-적분 및 COD 계산식)

  • Huh, Nam-Su;Park, Young-Jae;Kim, Yun-Jae;Kim, Young-Jin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.2
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    • pp.239-246
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    • 2003
  • This paper proposes engineering estimation equations of elastic-plastic J and COD fur axial through-wall cracked pipes under internal pressure. Based on detailed 3-D FE results based on deformation plasticity, the plastic influence functions for fully plastic J and COD solutions are tabulated as a function of the mean radius-to-thickness ratio, the normalized crack length. and the strain hardening. Based on these results, the GE/EPRI-type J and COD estimation equations are proposed and validated against the 3-D FE results based on deformation plasticity. For more general application to general stress-strain laws or to complex loading, the developed GE/EPRI-type solutions are re-formulated based on the reference stress concept. Such a reformulation provides simpler equations for J and COD, which are then further extended to combined internal pressure and bending. The proposed reference stress based J and COD estimation equations are compared with elastic-plastic 3-D FE results using actual stress-strain data for Type 316 stainless steels. The FE results for both internal pressure cases and combined internal pressure and bending cases compare very well with the proposed J and COD estimations.

Real-time Observation and Analysis of Solidification Sequence of Fe-Rich Al-Si-Cu Casting Alloy by Synchrotron X-ray Radiography (가속 방사광을 활용한 Fe함유 Al-Si-Cu 주조용 합금의 응고과정 실시간 관찰 및 분석)

  • Kim, Bong-Hwan;Lee, Sang-Hwan;Yasuda, Hideyuki;Lee, Sang-Mok
    • Journal of Korea Foundry Society
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    • v.30 no.3
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    • pp.100-110
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    • 2010
  • The solidification sequence and formation of intermetallic phase of Fe-rich Al-Si-Cu alloy were investigated by using real-time imaging of synchrotron X-ray radiation. Effects of cooling rate during uni-directional solidification on the resultant solidification behavior was also studied in a specially constructed vacuum chamber in the SPring-8 facility. The series of radiographic images were complementarily analyzed with conventional analysis of OM and SEM/EDX for phase identification. Detailed solidification sequence and formation mechanisms of various phases were discussed based on real-time image analysis. The growth rates of $\alpha$-AlFeMnSi and ${\beta}-Al_5FeSi$ were measured in order to understand the growth behavior of each phase. It is suggested that real-time imaging technique can be a powerful tool for the precise understanding of solidification behavior of various industrial materials.

THE EVOLUTION OF THE GALACTIC GLOBULAR CLUSTERS.: I. METAL ABUNDANCE CALIBRATIONS

  • Lee, See-Woo;Park, Nam-Kyu
    • Journal of The Korean Astronomical Society
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    • v.17 no.2
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    • pp.69-103
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    • 1984
  • Five different calibrations of metal abundances of globular clusters are examined and these are compared with metallicity ranking parameters such as $(Sp)_c$, . Q39 and IR-indices. Except for the calibration $[Fe/H]_H$ by the high dispersion echelle analysis. the other calibration scales are correlated with the morphological parameters of red giant branch. In the $[Fe/H]_H$-scale. the clusters later than ${\sim}F8$ have nearly a constant metal abundance. $[Fe/H]_H{\simeq}-1.05$, regradless of morphological characteristics of horizontal branch and red giant branch. By the two fundamental calibration scales of $[Fe/H]_L$ (derived by the low dispersion analysis) and $[Fe/H]_{{\Delta}s}$ (derived by the spectral analysis of RR Lyrae stars). the globular clusters are divided into the halo clusters with [Fe/H]<-1.0 and the disk clusters confined within the galactocentric distance ${\tau}_G=10\;kpc$ and galactic plane distance |z|=3 kpc. In this case the abundance gradient is given by d[Fe/H]/$dr_G{\approx}-0.05\;kpc^{-1}$ and d[Fe/H]/$d|z|{\simeq}-0.08\;kpc^{-1}$ within ${\tau}_G=20\;kpc$ and |z|=10 kpc, respectively. According to these characteristics of the spatial distribution of globular clusters. the chemical evolution of the galactic globular clusters can be accounted for by the two-zone (disk-halo) slow collapse model when the $[Fe/H]_L$-or $[Fe/H]_{{\Delta}s}$-scale is applied. In the case of $[Fe/H]_H$-scale, the one-zone fast collapse model is preferred for the evolution of globular clusters.

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Application of a Dynamic-Nanoindentation Method to Analyze the Local Structure of an Fe-18 at.% Gd Cast Alloy

  • Choi, Yong;Baik, Youl;Moon, Byung M.;Sohn, Dong-Seong
    • Nuclear Engineering and Technology
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    • v.49 no.3
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    • pp.576-580
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    • 2017
  • A dynamic nanoindentation method was applied to study an Fe-18 at.% Gd alloy as a neutron-absorbing material prepared by vacuum arc-melting and cast in a mold. The Fe-18 at.% Gd cast alloy had a microstructure with matrix phases and an Fe-rich primary dendrite of $Fe_9Gd$. Rietveld refinement of the X-ray spectra showed that the Fe-18 at.% Gd cast alloy consisted of 35.84 at.% $Fe_3Gd$, 6.58 at.% $Fe_5Gd$, 16.22 at.% $Fe_9Gd$, 1.87 at.% $Fe_2Gd$, and 39.49 at.% ${\beta}-Fe_{17}Gd_2$. The average nanohardness of the primary dendrite phase and the matrix phases were 8.7 GPa and 9.3 GPa, respectively. The fatigue limit of the matrix phase was approximately 37% higher than that of the primary dendrite phase. The dynamic nanoindentation method is useful for identifying local phases and for analyzing local mechanical properties.

MICROSTRUCTURE AND MECHANICAL PROPERTIES OF HOT-DEFORMED AlMg4 ALLOYS WITH THE VARIATIONS OF Mn, Fe, AND Si CONTENTS

  • DA B. LEE;BONG H. KIM;KWEON H. CHOI;SEUNG Y. YANG;NAM S. KIM;SEONG H. HA;YOUNG O. YOON;HYUN K. LIM;SHAE KIM;SOONG K. HYUN
    • Archives of Metallurgy and Materials
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    • v.65 no.4
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    • pp.1255-1259
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    • 2020
  • This paper aims to investigate the microstructural evolution and mechanical properties of hot-deformed AlMg4 alloys with Mn, Fe, and Si as the main impurities. For this purpose, solidification behavior and microstructural evolution during hot-rolling and heat-treatment processes are investigated by using theoretical calculations and experimental characterization. The crystallization and morphological transformation of intermetallic Al3Fe, Al6Mn, and Mg2Si phases are revealed and discussed in terms of the variation in chemical composition. Following a homogenization heat-treatment, the effect of heat treatment on the intermetallic compounds is also investigated after hot-rolling. It was revealed that the Mg2Si phase can be broken into small particles and spherodized more easily than the Al3Fe intermetallic phase during the hot-rolling process. For the Mn containing alloys, both yield and ultimate tensile strength of the hot-rolled alloys increased from 270 to 296 MPa while elongation decreased from 17 to 13%, which can be attributed to Mn-containing intermetallic as well as dispersoid.

Scientific Analysis of National Registered Cultural Heritage 666, Korea's First Fighters used during the Korean War (F-51D) (등록문화재 제666호 F-51D 무스탕 전투기 과학적 분석)

  • Kang, Hyunsam;Jang, Hanul;Kim, Soochul;Lee, Uicheon
    • Conservation Science in Museum
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    • v.23
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    • pp.71-90
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    • 2020
  • The scientific analysis of a 'F-51D Mustang Fighter'(Registered Cultural Heritage 666), one of the War Memorial of Korean collections, was carried out. The paint layer and canopy were discolored due to a constant outdoor exhibit. The results obtained through the scientific survey and analysis processes were intended to be used as basic data for the future dismantling and restoration of the fighter. The analysis results for the pigment components have confirmed red oxide of iron, Fe2O3 organic pigments, such as Cobalt Blue, phthalocyanine blue, etc., yellow PbCrO4, white TiO2, black Fe3O4, and gray Fe3O4 + TiO2. It has been also confirmed that Alkyd resin was mainly used for painting. The fighter's canopy was Poly methyl methacrylate(PMMA), and Al was detected as the main component of the fighter body, wings, and tails.