• Title/Summary/Keyword: 3-5족

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Electrochemical study on the Lanthanide-Alizarin Complexone Complexes (란탄족원소-ALC 착물의 전기화학적 연구)

  • Son, Byeong-Chan;Kim, Jae-Gyun;Park, Jong-Min
    • The Journal of Natural Sciences
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    • v.7
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    • pp.37-46
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    • 1995
  • Electrochemical behavior of $Ln^{3+},$-ALC complexes($Gd^{3+},$ $Tb^{3+},$ $Dy^{3+},$ $Ho^{3+},$ $Er^{3+},$ $Yb^{3+}$ and $Lu^{3+}$-alizarin complex-one) has been investgated by d.c polarography, differential pulse polarography and cyclic voltammetry. The reduction mechanism of ALC comes to the conclusion that the two electron make one step of reversible processes, and that there is few adsorption in the electrode reaction. The new complex is made from one lanthanide ion and one ALC. This complex is proven to make an adsorptive complex wave, by the experiments of differential pulse polarography and cyclic voltammetry. The reduction potential of complex wave($P_2$)turns up more negatively than ligand wave($P_1$) does. Linear calibration curves of the decreasing P1 and increasing $P_2$ is obtained when the lanthanide concentration varys from $2.5X10^5$M to $1X10^4M$.

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Arthroscopic Management for the Treatment of Ankle Gutter Syndrome (족 관절 구 증후군에 시행한 관절경적 치료)

  • Choi Chong Hyuk;Park Jin-Oh;Ogilvie-Harris D. J.
    • Journal of the Korean Arthroscopy Society
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    • v.4 no.1
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    • pp.54-60
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    • 2000
  • Purpose : The purpose of this study was to evaluate the gutter pathologies and the clinical results of arthroscopic treatment for ankle gutter syndrome. Materials and Methods : Seventy six patients(77 ankles) who had lesions in the ankle gutter were treated by arthroscopy. The gutter pathology could be divided into 3 categories; hypertrophic scar tissue, loose bodies and bone spurs. Fifty two patients were evaluated subjectively and functionally with authors' criteria. The follow-up period averaged 44 months(range, 2.9 year-8.5 year). Results : The incidence of the gutter lesion was $21\%$(77 ankles) among 366 ankles undergoing arthroscopy. The most common pathology was hypertrophic scar tissue. In 31 ankles$(40\%)$, the lesions were found only in gutter, and 46 ankles$(60\%)$ were associated with pathologies in other areas. All of parameters for subjective and functional evaluation were improved with statistical significance(p<0.001). Seventeen patients$(33\%)$ could returned to competitive or contact sports activity with same level of premorbid period. Conclusion : Ankle gutter is an important site of pathologies which cause chronic ankle pain, and should be explored in ankle arthroscopy. The ankle arthroscopy is a very effective treatment method fur the removal of pathologies in ankle gutter syndrome.

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The Study on Effect of Exhaust Gas Characteristics according to Aromatic compound Content in Diesel (경유의 방향족 함량 변화가 배출가스에 미치는 영향 연구)

  • Kim, Shin;Min, Kyong-Il;Yim, Eui-Soon;Ha, Jong-Han;Na, Byung-Ki
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.549-561
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    • 2014
  • According to reports in EU and USA, Aromatic ingredient in diesel estimated the causative agent of air pollution. Because reduction of total aromatic and Poly-aromatic compound content are decreasing environmentally harmful emissions HC, NOx, PM. It is necessary to investigate correlationship between automotive technology and fuel quality in Korea. This study examines emission effect of two representative domestic vehicles(2.2 L for emission of Euro 4, 5) and five kinds of domestic diesel fuel (total aromatic compound content 26, 28, 30 wt% and poly-aromatic compound content 3, 5 wt%). Finally, Environmental impact assessment was studied between vehicle and diesel fuel.

A Study on Attitude angle control of Quadruped Walking Robot (4족 보행로봇의 자세각 제어에 관한 연구)

  • Eom Han-Sung
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.9 no.8
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    • pp.1722-1729
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    • 2005
  • In this paper, we used the quadruped walking robot Titan-VIII in order to carry out this simulation of sway compensation trajectory. The attitude angle ${\phi}_r$ and ${\phi}_p$ is obtained from 3-D motion sensor that is attached at the center of robot body and the attitude control carried out at every 10[ms] for stable gait of robot. Duty factor, that is fixed at 0.5. When we change period T into 1.5, 2.0, 3.0[sec] each and moving distance per period is changed into 0.2, 0.3(m), we sim띠ate several walking experiment of robot. and then we analyze the experiment results if there are any difference between the imaginary ZMP and actual ZMP of robot and the stable gait of robot is realized.

Surgical Treatment of Ganglions in Foot and Ankle (족부 및 족관절부 결절종의 수술적 치료)

  • Choi, Ik-Su;Roh, Su-In;Kwak, Cheol-Ho;Kim, Sang-Eun;Lee, Chan-Woo
    • Journal of Korean Foot and Ankle Society
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    • v.8 no.1
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    • pp.97-100
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    • 2004
  • Purpose: To evaluate the results of surgical treatment and relationship between the recurrence and characteristics of ganglions in foot and ankle. Materials and Methods: Seventeen cases of ganglions located in foot and ankle, excised at St. Benedict Hospital from Mar. 1993 to Apr. 2003, were included in the study. All of cases were analyzed retrospectively in terms of age, sex of the patients, location and size of the ganglion, symptom, operative method as well as recurrence rate were evaluated. The mean follow up was 1.8 years (11 months${\sim}$6.5 years). Results: The size of ganglion ranged from 0.5 cm to 5.0 cm with mean size of 2.5 cm. The most common area of ganglion was the dorsum of foot and pain was the primary chief complain. The recurrence was found in 4 cases (23.5%): 1 of them occurred among 8 cases the diameter of which was less than 2.5 cm and other 3 occurred among 9 cases larger than 2.5 cm. 12 cases were completely excised mass with no recurrence. But 5 cases were incompletely excised & ligated stalk of mass and 4 cases of them were recurred. A correlation was only observed between complete excision and low recurrence rate. Conclusion: Recurrence rate of ganglions in foot and ankle was high and the correlation was obtained between complete excision and low recurrence rate.

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Microbial Degradation of Aromatic Compounds in Industrial Wastewater (방향족화합물이 함유된 폐수의 생물학적 처리)

  • 박춘호;김용기;오평수
    • Microbiology and Biotechnology Letters
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    • v.19 no.6
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    • pp.631-636
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    • 1991
  • The bacteria which can biodegrade aromatic compounds were screened from soil and wastewater. The isolated Pseudomonas sp. HC107 had high removal rate of COD and phenol. And also this strain grew on m-cresol, salicylate, toluene, 2, 4-D and benzene. When the strain culture (2 ml/day) was treated on continuous reactor at mixed wastewater from chemical, pharmaceutical and dye industry, the treatment rate of COD, BOD and phenol was to be about 92.5%, 95.3% and 93.5%, respectively.

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Evaluation of Petroleum Oil Degrading Mixed Microorganism Agent for the Bioremediation of Petroleum Oil Spilled in Marine Environments (해양유류오염정화를 위한 유류분해 미생물제제의 평가)

  • Sohn, Jae-Hak
    • Journal of Life Science
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    • v.21 no.11
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    • pp.1599-1606
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    • 2011
  • To evaluate the effects of microorganism agents on oil biodegradation, treatability and microcosm studies were conducted. Petroleum oil degrading bacteria were isolated from enriched cultures of oil-contaminated sediment samples using a mineral salts medium (MSM) containing 0.5% Arabian heavy crude oil as the sole carbon source. After a 5 day-incubation period using MSM, mixed microorganisms of three species (strains BS1, BS2 and BS4) degraded 48.4% of aliphatic hydrocarbons and 30.5% of aromatic hydrocarbons. Treatability and microcosm tests were performed in the three different treatment conditions (AO: Arabian heavy crude oil, AO+IN: Arabian heavy crude oil+inorganic nutrient, AO+IN+MM: Arabian heavy crude oil+inorganic nutrient+mixed microorganism agents). Among these, significantly enhanced biodegradation of aliphatic hydrocarbons were observed in AO+IN and AO+IN+MM conditions, without showing any different biodegradation rates in either condition. However, the degradation rates of aromatic hydrocarbons in an AO+IN+MM condition were increased by 50% in the treatability test and by 13% in the microcosm test compared to those in an AO+IN condition. Taken together, it can be concluded that mixed microorganism agents enhance the biodegradation of aliphatic and aromatic hydrocarbons in laboratory, a treatability test, and a microcosm test. This agent could especially be a useful tool in the application of bioremediation for removal of aromatic hydrocarbons.

A study on dose attenuation in bone density when TBI using diode detector and TLD (전신방사선조사(TBI)시 다이오드 측정기(Diode detector) 및 열형광선량계(TLD)를 이용한 골조직 선량감쇄에 대한 고찰)

  • IM Hyun Sil;Lee Jung Jin;Jang Ahn Ki;Kim Wan Seon
    • The Journal of Korean Society for Radiation Therapy
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    • v.15 no.1
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    • pp.67-77
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    • 2003
  • I. Purpose Uniform dose distribution of the whole body is essential factor for the total body irradiation(TBI). In order to achieved this goal, we used to compensation filter to compensate body contour irregularity and thickness differences. But we can not compensate components of body, namely lung or bone. The purpose of this study is evaluation of dose attenuation in bone tissue when TBI using diode detectors and TLD system. II. Materials and Methods The object of this study were 5 patients who undergo TBI at our hospital. Dosimetry system were diode detectors and TLD system. Treatment method was bilateral and delivered 10MV X-ray from linear accelerator. Measurement points were head, neck, pelvis, knees and ankles. TLD used two patients and diode detectors used three patients. III. Results Results are as followed. All measured dose value were normalized skin dose. TLD dosimetry : Measured skin dose of head, neck, pelvis, knees and ankles were $92.78{\pm}3.3,\;104.34{\pm}2.3,\;98.03{\pm}1.4,\;99.9{\pm}2.53,\;98.17{\pm}0.56$ respectably. Measured mid-depth dose of pelvis, knees and ankles were $86{\pm}1.82,\;93.24{\pm}2.53,\;91.50{\pm}2.84$ respectably. There were $6.67\%{\sim}11.65\%$ dose attenuation at mid-depth in pelvis, knees and ankles. Diode detector : Measured skin dose of head, neck, pelvis, knees and ankles were $95.23{\pm}1.18,\;98.33{\pm}0.6,\;93.5{\pm}1.5,\;87.3{\pm}1.5,\;86.90{\pm}1.16$ respectably. There were $4.53\%{\sim}12.6\%$ dose attenuation at mid-depth in pelvis, knees and ankles. IV. Conclusion We concluded that dose measurement with TLD or diode detector was inevitable when TBI treatment. Considered dose attenuation in bone tissue, We must have adequately deduction of compensator thickness that body portion involved bone tissue.

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Electrochemical Studies on the Heavy Lanthanide Complexes (무거운 란탄족 이온 착물의 전기화학적 연구)

  • Pak, Chong Min;Kim, Chae Kyun;Son, Byung Chan
    • Analytical Science and Technology
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    • v.5 no.3
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    • pp.249-261
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    • 1992
  • Electrochemical behavior of the heavy lanthanide complexes of alizarin red S(ARS) has been investigated by d. c. polarography, differential pulse polarography and cyclic voltammetry. The reduction mechanism at a mercury electrode of alizarin red S as a complexing ligand showed a one step of two-electron transfer and the electron process is found to be reversible. Alizarin red S forms a 3:1 adsorptive complexes with lanthanides and the complexes are reduced via one step of two-elctron. The reduction potential of complex wave($P_2$) shifted more negatively than the ligand wave($P_1$). The linear calibration curves of the decreacing $P_1$ and increasing $P_2$ is obtained when the lanthanide concentration varies from $2.0{\times}10^{-6}M$ to $6.4{\times}10^{-5}M$ under the condition of pH 9.5, 0.1M LiCl and $1{\times}10^{-3}M$ ARS.

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Ruthenium Catalyzed Synthesis of N-Substituted Perhydroazepine Derivatives (루테늄 촉매를 이용한 N-치환 과수소아제핀 유도체의 합성)

  • Sim, Sang Cheol;Do, Chil Hun;Lee, Seung Yeop;Jo, Wan Ho;Heo, Geun Tae
    • Journal of the Korean Chemical Society
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    • v.34 no.6
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    • pp.652-657
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    • 1990
  • Primary amines react with 1,6-hexanediol at 180$^{\circ}C$ for 5 h under argon atmosphere in the presence of both $RuCl_3{\cdot}3H_2$O and $PR_3$ to give N-substituted perhydroazepine derivatives in good yields. For aromatic amines such as anilines, $RuCl_3{\cdot}3H_2$O combined with $PPh_3$ showed the highest catalytic activity. On the other hand, in the reaction of aliphatic amines, $RuCl_3{\cdot}3H_2$O combined with $PBu_3$ showed the highest catalytic activity. These differences may be attributed to the difference in the basicity of these amines. Less basic aromatic amines may require less basic phosphines, while more basic aliphatic amines may require more basic phosphines as the ligands.

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