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Preparation of Cu2(btc)3-AAO Hybrid Membrane by Layer-by-layer Technique (Layer-by-layer 기법을 통한 Cu2(btc)3-AAO 하이브리드 분리막의 제조)

  • Yoo, Hyeonseok;Choi, Jinsub
    • Journal of the Korean institute of surface engineering
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    • v.51 no.1
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    • pp.21-26
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    • 2018
  • The $Cu_2(btc)_3$ metal-organic frameworks (MOF) coated anodic aluminum oxide (AAO) membrane was successfully prepared by layer-by-layer technique using hand spray method. It was confirmed that the $Cu_2(btc)_3$ layer, which has the pore sized in 2-3 nm, on surface of AAO exhibited the polycrystalline thin film structure by XRD analysis. More than 100 repetitive spray cycles were required to obtain more robust and thick MOFs on AAO and it was possible to uniformly coat both the top and bottom surfaces of the AAO. It should be noted that the MOFs also could be coated on surface of pores resulting in reduce the size of pore from 52 nm to 32 nm.

Numerical simulation of the effect of bedding layer geometrical properties on the shear failure mechanism using PFC3D

  • Haeri, Hadi;Sarfarazi, Vahab;Zhu, Zheming;Marji, Mohammad Fatehi
    • Smart Structures and Systems
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    • v.22 no.5
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    • pp.611-620
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    • 2018
  • In this research the effect of bedding layer angle and bedding layer thickness on the shear failure mechanism of concrete has been investigated using PFC3D. For this purpose, firstly calibration of PFC3d was performed using Brazilian tensile strength. Secondly shear test was performed on the bedding layer. Thickness of layers were 5 mm, 10 mm and 20 mm. in each thickness layer, layer angles changes from $0^{\circ}$ to $90^{\circ}$ with increment of $25^{\circ}$. Totally 15 model were simulated and tested by loading rate of 0.016 mm/s. The results shows that when layer angle is less than $50^{\circ}$, tensile cracks initiates between the layers and propagate till coalesce with model boundary. Its trace is too high. With increasing the layer angle, less layer mobilize in failure process. Also the failure trace is very short. It's to be note that number of cracks decrease with increasing the layer thickness. The minimum shear test strength was occurred when layer angle is more than $50^{\circ}$. The maximum value occurred in $0^{\circ}$. Also, the shear test tensile strength was increased by increasing the layer thickness.

Numerical simulation of the effect of bedding layer geometrical properties on the punch shear test using PFC3D

  • Haeri, Hadi;Sarfarazi, Vahab;Zhu, Zheming
    • Structural Engineering and Mechanics
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    • v.68 no.4
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    • pp.507-517
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    • 2018
  • In this research the effect of bedding layer angle and bedding layer thickness on the shear failure mechanism of concrete has been investigated using PFC3D. For this purpose, firstly calibration of PFC3d was performed using Brazilian tensile strength. Secondly punch shear test was performed on the bedding layer. Thickness of layers were 5 mm, 10 mm and 20 mm. in each thickness layer, layer angles changes from $0^{\circ}$ to $90^{\circ}$ with increment of $25^{\circ}$. Totally 15 model were simulated and tested by loading rate of 0.016 mm/s. The results show that when layer angle is less than $50^{\circ}$, tensile cracks initiates between the layers and propagate till coalesce with model boundary. Its trace is too high. With increasing the layer angle, less layer mobilizes in failure process. Also, the failure trace is very short. It's to be note that number of cracks decrease with increasing the layer thickness. The minimum shear punch test strength was occurred when layer angle is more than $50^{\circ}$. The maximum value occurred in $0^{\circ}$. Also, the shear punch test tensile strength was increased by increasing the layer thickness.

Electrical and optical characterizations of OSCs based on polymer/fullerene BHJ structures with LiF inter-layer (Polymer/fullerene/LiF inter-layer BHJ 유기태양전지의 광학 및 전기적 특성에 대한 연구)

  • Song, Yoon-Seog;Kim, Seung-Ju;Ryu, S.O.
    • Journal of the Semiconductor & Display Technology
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    • v.10 no.1
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    • pp.27-32
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    • 2011
  • In this study, we have investigated the power conversion efficiency of organic solar cells utilizing conjugated polymer/fullerene bulk-hetero junction(BHJ) device structures. We have fabricated poly(3-hexylthiophene)(P3HT), poly[2methoxy-5-(3',7'-dimethyloctyl-oxy)-1-4-phenylenevinylene] as an electron donor, [6,6]-phenyl $C_{61}$ butyric acid methylester(PCBM-$C_{61}$)as an electron acceptor, and poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)(PEDOT:PSS) used as a hole injection layer(HIL), after fabricated active layer, between active layer and metal cathode(Al) deposited LiF interlayer(5 nm). The properties of fabricated organic solar cell(OSC) devices have been analyzed as a function of different thickness. The electrical characteristics of the fabricated devices were investigated by means J-V, fill factor(FF) and power conversion efficiency(PCE). We observed the highest PCEs of 0.628%(MDMO-PPV:PCBM-$C_{61}$) and 2.3%(P3HT:PCBM-$C_{61}$) with LiF inter-layer at the highest thick active layer, which is 1.3times better than the device without LiF inter-layer.

Plasma Resistance of YAS (Y2O3-Al2O3-SiO2) Coating Layer with YAG Phase Contents (YAG 상함량에 따른 YAS (Y2O3-Al2O3-SiO2)계 코팅층의 내플라즈마 특성)

  • Park, Eui Keun;Lee, Hyun-Kwuon
    • Korean Journal of Materials Research
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    • v.30 no.11
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    • pp.621-626
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    • 2020
  • This study is aimed at preparing and evaluating the plasma resistance of YAS (Y2O3-Al2O3-SiO2) coating layer with crystalline YAG phase contents. For this purpose, YAS frits with controlled phase contents are prepared and melt-coated on sintered Al2O3 ceramics. Then, the results of phase analysis of crystalline YAS coating layer are compared to that of YAS frits, and discussed with regard to the plasma resistance of the YAS coating layer. The phase contents of the YAS frit change in a manner different from that of the prepared YAS coating layer, presumably owing to the composition change of YAS frit during the melt-coating process. The plasma resistance of the YAS coating layer is shown to increase with the YAG phase contents in the coating layer. Comparing the weight loss of YAS coating layer with those of commercial Y2O3, Al2O3, and quartz ceramics, the plasma resistance of the prepared YAS coating layer is 8 times higher than that of quartz and 3 times higher than that of Al2O3; this layer shows 70 % of the resistance of Y2O3.

Efficient Signal Integrity Verification in Complicated Multi-Layer VLSI Interconnects (복잡한 다층 VLSI 배선구조에서의 효율적인 신호 무결성 검증 방법)

  • Jin, U-Jin;Eo, Yun-Seon;Sim, Jong-In
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.39 no.3
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    • pp.73-84
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    • 2002
  • Fast and accurate new capacitance determination methodology for non-uniform complicated multi-layer VLSI interconnects is presented. Since a capacitance determination of intricate multi-layer interconnects using 3-dimensional field-solver is not practical, quasi-3-dimensional methodology is presented. Interconnects with discontinuity (i.e., bend structure and different spacing between lines, etc.) are partitioned. Then, each partial capacitance of divided parts is extracted by using 2-dimensional extraction methodology. For a multi-layer interconnects with shielding layer, the system can be simplified by investigating a distribution of charge in it. Thereby, quasi-3-dimensional capacitance for multi-layer interconnects can be determined by combining solid-ground based 2-dimensional capacitance and shielding effect which is independently determined with layout dimensions. This methodology for complicated multi-layer interconnects is more accurate and cost-efficient than conventional 3-dimensional methodology It is shown that the quasi-3-dimensional capacitance methodology has excellent agreement with 3-dimensional field- solver-based results within 5% error.

3D video coding for e-AG using spatio-temporal scalability (e-AG를 위한 시공간적 계위를 이용한 3차원 비디오 압축)

  • 오세찬;이영호;우운택
    • Proceedings of the IEEK Conference
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    • 2003.11a
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    • pp.199-202
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    • 2003
  • In this paper, we propose a new 3D coding method for heterogeneous systems over enhanced Access Grid (e-AG) with 3D display using spatio-temporal scalability. The proposed encoder produces four bit-streams: one base layer and enhancement layer l, 2 and 3. The base layer represents a video sequence for left eye with lower spatial resolution. An enhancement layer l provides additional bit-stream needed for reproduction of frames produced in base layer with full resolution. Similarly, the enhancement layer 2 represents a video sequence for right eye with lower spatial resolution and an enhancement layer 3 provides additional bit-stream needed for reproduction of its reference pictures with full resolution. In this system, temporal resolution reduction is obtained by dropping B-frames in the receiver according to network condition. The receiver system can select the spatial and temporal resolution of video sequence with its display condition by properly combining bit-streams.

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3D Mesh Compression Based on Layer of Mesh and Operation Code (메쉬의 계층 및 연산코드 기반 3차원 메쉬 압축)

  • 이민정;권용무;김창헌
    • Proceedings of the Korean Information Science Society Conference
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    • 2002.10d
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    • pp.415-417
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    • 2002
  • 날로 커져가는 3D 모델을 효율적으로 사용하기 위한 노력으로 압축처리 방법들이 연구되고 있다. 본 논문에서는 3D 모델의 메쉬를 Layer로 분할하여 Vertex Layer와 Triangle Layer를 생성 후, 삼각형들을 몇가지 연산코드로 분류하여 압축(compression)하는 방법을 제안한다. Triangle Layer는 기본 정점으로부터 연결된 선분의 정점들로 이루어진 Vertex Layer의 쌍을 이용하여 만들어진다. 이 Triangle Layer에 해당 되는 삼각형들의 연결 정보를 제안한 연산코드로 분류하고, 이것을 엔트로피 코딩하여 3D 모델을 압축한다. 이 기법은 삼각형의 형태를 기준으로 한 개나 두 개의 삼각형을 하나의 연산코드로 분류하거나 삼각형의 연결 상황에 따라 하나의 연산코드로 분류하여 연결정보를 표현한다. 복원(decompression)시에는 연산 코드를 이용하여 삼각형의 연결정보를 뽑아내면 원 상태의 3D 모델을 획득할 수 있다. 이 방법은 연결 정보를 무손실 압축하는 방법으로, 지금까지 제안된 압축기법과 비교할 때, 간단하면서도 월등한 압축 효과를 볼 수 있다.

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Characterization of Sol-gel Coated Pb(ZrTi)O3 Thin film for Piezoelectric Vibration MEMS Energy Harvester (압전 MEMS 진동에너지 수집소자를 위한 졸겔 공법기반의 Pb(ZrTi)O3 박막의 특성 분석 및 평가)

  • Park, Jong-C.;Park, Jae-Y.
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1240_1241
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    • 2009
  • In this paper, sol-gel-spin coated $Pb(ZrTi)O_3$ thin film with $ZrO_2$ buffer-layer and $PbTiO_3$ seed-layer was investigated for vibration MEMS energy harvester to scavenge power from ambient vibration via d33 piezoelectric mode. Piezoelectric thin film deposition techniques on insulating layer is the important key for $d_{33}$ mode of piezoelectric vibration energy harvester. $ZrO_2$ buff-layer was utilized as an insulating layer. $PbTIO_3$ seed-layer was applied as an inter-layer between PZT and $ZrO_2$ layer to improve the crystalline of PZT thin film. The fabricated PZT thin film had a remanent polarization of 5.3uC/$cm^2$ and the coercive field of 60kV/cm. The fabricated energy harvester using PZT thin film with PTO seed-layer generated 1.1uW of electrical power to $2.2M{\Omega}$ of load with $4.4V_{pvp}$ from vibration of 0.39g at 528Hz.

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EL Properties of the Organic Light-Emitting-Diode with various Thickness and Cathode Electrode (유기발광소자의 막두께 및 음극전극의 변호에 따른 발광특성)

  • 김형권;이덕출
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.10
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    • pp.897-902
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    • 1998
  • We prepared Organic LED with a two layer structure by vacuum evaporation. The diode consisted of hole transfer layer (thickness of 30, 50, 70 nm) and electron transfer layer (thickness of 70, 50, 30 nm) material, which was N, N'-diphenyl- N, N'-bis-(3-methyl phenyl)-1,1'-diphenyl-4,4'-diamine)(TPD) and tris(8-hydroxy quinoline) aluminum(Alq3), respectively. We investigated EL properties of the LED with various thickness and cathode electrode. The best results were obtained when thickness of the electron layer is equal to that of emission layer and when AlLi alloy was used as a cathode. The EL intensity, luminance and efficiency of organic LED with equal of layer thick were improved seven, three and two times, respectively. Alq3 was ionized by carrier injection from cathode and could produce exitons. After electron-hole pairs were formed by combination of the electrons and holes at the emission layer, Alq3 layer emitted light.

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