• Bulletin of the Korean Chemical Society
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• v.21 no.1
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• pp.39-43
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• 2000

New coordination polymers of general form, $$[CoL_2X_2]_n$$ (L = 3,3'-oxybis(pyridine) (obp), 1,4-bis(3-pyri-doxy) benzene (bpob); X = Cl, NCS), have been prepared via a slow diffusion method. The reaction of the present linkers with cobalt(II) ion affords infinite 2-dimensional sheet products. For $[Co(obp) $_2Cl_2]_n$$, the local geometry of the cobalt center is an octahedral arrangement with four nitrogen donors and two chlorine ions in trans positions. $$[Co(bpob)_2(NCS)_2]_n$$ has provided a similar structure: the local geometry of the cobalt atom is an octahedral arrangement with four pyridine units and two NCS groups in transpositions. The obp and bpob linkers connect two cobalt(II) ions defining the edges of 40- and 60-membered $[Co(II)]_4$ ring, respectively. Thermal analyses of the coordination polymers show significant thermal behavior associated with the characteristic structures.

• The KSFM Journal of Fluid Machinery
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• v.9 no.2 s.35
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• pp.30-38
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• 2006

An aerodynamic design for centrifugal compressor which was applied to medium speed diesel engine has been done. First of all, exact compressor specifications must be defined by accurate engine system matching. This matching program has been developed. Using the meanline prediction method, geometric design and performance curves for compressor were established and verified by comparing three dimensional viscous CFD results. The deviation at the design point was about 2.3%. Combustor has been designed and manufactured for the performance test of medium speed diesel engine turbocharger. Fuel nozzle of combustor was designed and its characteristics was analyzed by PIV and PDPA test equipment. Through these results, spray characteristics were studied and flow coefficient equation was deduced.

• Current Optics and Photonics
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• v.6 no.6
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• pp.619-626
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• 2022

In this study, we develop a three-dimensional (3D) terahertz time-of-flight (THz-TOF) imaging technique with a large depth range, based on asynchronous optical sampling (ASOPS) methods. THz-TOF imaging with the ASOPS technique enables rapid scanning with a time-delay span of 10 ns. This means that a depth range of 1.5 m is possible in principle, whereas in practice it is limited by the focus depth determined by the optical geometry, such as the focal length of the scan lens. We characterize the spatial resolution of objects at different vertical positions with a focal length of 5 cm. The lateral resolution varies from 0.8-1.8 mm within the vertical range of 50 mm. We obtain THz-TOF images for samples with multiple reflection layers; the horizontal and vertical locations of the objects are successfully determined from the 2D cross-sectional images, or from reconstructed 3D images. For instance, we can identify metallic objects embedded in insulating enclosures having a vertical depth range greater than 30 mm. For feasible practical use, we employ the proposed technique to locate a metallic object within a thick chocolate bar, which is not accessible via conventional transmission geometry.

• The Journal of the Acoustical Society of Korea
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• v.43 no.1
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• pp.103-111
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• 2024

Axial-flow fans are used to transport fluids in relatively low-pressure flow regimes, and a variety of design variables are employed. The tip geometry of an axial fan plays a dominant role in its flow and noise performance, and two of the most prominent flow phenomena are the tip vortex and the tip leakage vortex that occur at the tip of the blade. Various studies have been conducted to control these three-dimensional flow structures, and winglet geometries have been developed in the aircraft field to suppress wingtip vortices and increase efficiency. In this study, a numerical and experimental study was conducted to analyze the effect of winglet geometry applied to an axial fan blade for an air conditioner outdoor unit. The unsteady Reynolds-Averaged Navier-Stokes (RANS) equation and the FfocwsWilliams and Hawkings (FW-H) equation were numerically solved based on computational fluid dynamics techniques to analyze the three-dimensional flow structure and flow noise numerically, and the validity of the numerical method was verified by comparison with experimental results. The differences in the formation of tip vortex and tip leakage vortex depending on the winglet geometry were compared through a three-dimensional flow field, and the resulting aerodynamic performance was quantitatively compared. In addition, the effect of winglet geometry on flow noise was evaluated by numerically simulating noise based on the predicted flow field. A prototype of the target fan model was built, and flow and noise experiments were conducted to evaluate the actual performance quantitatively.

• Bulletin of the Korean Chemical Society
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• v.29 no.3
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• pp.546-550
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• 2008

The title compound of nicotinato lead(II) complex [Pb$(C_5H_4NCOO)_2$] has been optimized at B3LYP/LANL2DZ and HF/LANL2DZ levels of theory. The calculated results show that the lead(II) ion adopts 2- coordinate geometry, which is the same as its crystal structure and different from the 4-coordinate geometry of isonicotinato lead(II) complex. Atomic charge distributions indicate that during forming the title compound, each nicotinic acid ion transfers their negative charges to central lead(II) ion. The electronic spectra calculated by B3LYP/LANL2DZ level show that there exist two absorption bands, which have some red shifts compared with those of isonicotinato lead(II) complex and the electronic transitions are mainly derived from intraligand $\pi$ -$\pi$ transition and ligand-to-metal charge transfer (LMCT) transition. CIS-HF method is not suitable for the system studied here. The thermodynamic properties of the title compound at different temperatures have been calculated and corresponding relations between the properties and temperature have also been obtained. The second order optical nonlinearity was calculated, and the molecular hyperpolarizability was $1.147754{\times}10^{-30}$ esu.

• Journal of the Korean Institute of Telematics and Electronics A
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• v.32A no.8
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• pp.107-118
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• 1995

Three-dimensional simulator for thermal oxidation process is developed. The simulator is consisted by two individual module, one is analytic-model module and the other is numerical-model module. The analytic-model which uses simple complementary-error function guarantees fast calculation in prediction of multi-dimensional oxidation process. The numerical-model which is based on boundary element method (BEM), has a good accuracy and suitable for various process conditions. The results of this study show that oxide growth is retarded at the corner of hole structure and enhanced at the corner of island structure. These effects are reson of different distribution of oxidant diffusion and mask stress. The utility of models and simulator developed in this study is demonstrated by using it to predict not only traditional shape of LOCOS but also process effects in small geometry.

• Smart Media Journal
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• v.3 no.4
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• pp.22-27
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• 2014

Three-dimensional image reconstruction allows us to represent real objects in the virtual space and observe the objects at arbitrary view points. This technique can be used in various application areas such as education, culture, and art. In this paper, we propose an implementation method of the high-quality three-dimensional object using multiple Kinect cameras released from Microsoft. First, We acquire color and depth images from triple Kinect cameras; Kinect cameras are placed in front of the object as a convergence form. Because original depth image includes some areas where have no depth values, we employ joint bilateral filter to refine these areas. In addition to the depth image problem, there is an color mismatch problem in color images of multiview system. In order to solve it, we exploit an color correction method using three-dimensional geometry. Through the experimental results, we found that three-dimensional object which is used the proposed method is more naturally represented than the original three-dimensional object in terms of the color and shape.

• Journal of Powder Materials
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• v.3 no.2
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• pp.104-111
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• 1996

In order to obtain homogeneous and high quality products in powder compaction forging process, it is very important to control stress, strain, density and density distributions. Therefore, it is necessary to understand quantitatively the elasto-plastic deformation and densification behaviors of porous metals and metal powders. In this study, elasto-plastic finite element method using Lee-Kim's pressure dependent porous material yield function has been used for the analysis of three dimensional indenting process. The analysis predicts deformed geometry, stress, strain and density distribution and load. The calculated load is in good agreement with experimental one. The calculated results do not show axisymmetric distributions because of the edge effect. The core part which is in contact with the indentor and the outer diagonal edge part are in compressive stress states and the middle part is in tensile stress state. As a results, it can be concluded that three dimensional analysis is more realistic than axisymmetric assumption approach.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.7
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• pp.916-923
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• 2000

Numerical study of three-dimensional turbulent flow in a forward curved centrifugal fan is presented. Standard $k-{\varepsilon}$ turbulence model and non-orthogonal curvilinear coordinates arc used to consider the turbulent flow field and complex geometry. Finite Volume approach is adopted for discretization scheme and structured grid system is used to help convergence. Multiblock grid system is used for flow field and divided into five domains that are inlet, outlet, impeller, tip clearance and scroll. It is assumed that the flow field is steady and incompressible. These numerical results are compared with the experimental data inside a rotor and at the fan outlet. Most important flow features are captured through this numerical approach. Finally details of flow field inside a fan are described and analyzed.

• The Journal of the Acoustical Society of Korea
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• v.21 no.4
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• pp.339-438
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• 2002

This paper presents a method to simulate noise propagation by a computer for outdoor environment. Sound propagated in 3 dimensional space generates reflected waves whenever it hits boundary surfaces. If a receiver is away from a sound source, it receives multiple sound waves which are reflected from various boundary surfaces in space. The algorithm being developed in this paper is based on a ray sound theory. If we get 3 dimensional geometry input as well as sound sources, we can compute sound effects all over the boundary surfaces. In this paper, we present two approaches to compute sound: the first approach, called forward tracing, traces sounds forwards from sound sources. while the second approach, called geometry based computation, computes possible propagation routes between sources and receivers. We compare two approaches and suggest the geometry based sound computation for outdoor simulation. Also this approach is very efficient in the sense we can save computational time compared to the forward sound tracing. Sound due to impulse-response is governed by physical environments. When a sound source waveform and numerically computed impulse in time is convoluted, the result generates a synthetic sound. This technique can be easily generalized to synthesize realistic stereo sounds for virtual reality, while the simulation result is visualized using VRML.