• Korean Chemical Engineering Research
• /
• v.43 no.5
• /
• pp.637-640
• /
• 2005

The density of polar-nonpolar liquid mixtures composed of methyl tert-butyl ether(MTBE) and 2,2,4-trimethylpentane, and methyl ethyl ketone (MEK) and 2,2,4-trimethylpentane, and the density of polar-polar liquid mixture of MTBE and MEK were measured by densitometer at 278.15 K, 288.15 K and 298.15 K, respectively. The excess molar volume of the binary systems calculated from the measured density was shown good agreement with the calculated one by the cubic Peng-Robinson- Stryjek-Vera (PRSV) equation of state together with Huron-Vidal mixing rule and it confirmed that the cubic PRSV equation of state could be used in the molar volume calculation of polar mixture.

• Proceedings of the KSME Conference
• /
• 2001.11b
• /
• pp.205-210
• /
• 2001

Cubic equations of state with two temperature dependent parameters are suggested and optimized using ASHRAE data for methane, propane, carbon dioxide, R-32 and R-134a. Appropriate simple functional forms are assumed for the temperature dependent parameters. The equations tested are Martin, Fuller, Harmens-Knapp, Schmidt-Wenzel. Among them modified Schmidt-Wenzel equation of state appears to be the choice for calculation of saturation properties such as vapor pressures, saturated liquid volumes, and saturated vapor volumes with an average absolute deviation of about one percent over the entire region excluding; the near cirtical.

• The Korean Journal of Rheology
• /
• v.5 no.2
• /
• pp.109-124
• /
• 1993

본 연구의 목표는 임의의 3차원 사출성형 금형 공간내에서 단섬유 강화 플라스틱의 충전 공정에서의 과도기적 섬유방향성을 예측하는 수치해석 프로그램의 개발에 있다. Hele-Shaw 방정식에 단섬유에 의해서 추가된 응력을 고려한 Dinh-Armstrong의 모델을 도 입함으로써 새로운 충전과정의 압력 지배 방정식이 유도되었다. 새로운 압력지배 방정식은 단섬유에 의한 응력 때문에 몇 개의 새로운 항들을 포함하고 있다. 충전 과정의 해석은 새 로운 압력지배방정식과 에너지 방정식을 유한효소법과 유한 차분법을 이용하여 풀고 동시에 배향텐서(roientation tensor)의 변화 방정식을 4차 Runge-Kutta 방법을 이용하여 풀었다. 단섬유 배향 텐서를 텐서의 변환 법칙을 이용하여 임의의 3차원 금형 공간내의 모든유한요 소의 중심에서 두께방향의 모든유한 차분 격자를 따라 계산하였다. 이러한 방법으로 임의의 3차원 사출성형 금형 공간내에서 비등온 충전유동과 과도기적 3차원 섬유배향상태를 서로의 상호작용을 고려하여 수치 모사하여 다양한 유동 형태에 따른 단섬유 배향 상태의 변화에 대하여 알아보고자 한다.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.19 no.2
• /
• pp.608-616
• /
• 2018

If a general nonlinear system is linearized by the successive multiplication of the 1st and 2nd order systems, then there are four types of poles in this linearized system: the pole of the 1st order system and the equal poles, two distinct real poles, and complex conjugate pair of poles of the 2nd order system. Linear Quadratic (LQ) control is a method of designing a control law that minimizes the quadratic performance index. It has the advantage of ensuring the stability of the system and the pole placement of the root of the system by weighted matrix adjustment. LQ control by the weighted matrix can move the position of the pole of the system arbitrarily, but it is difficult to set the weighting matrix by the trial and error method. This problem can be solved using the characteristic equations of the Hamiltonian system, and if the control weighting matrix is a symmetric matrix of constants, it is possible to move several poles of the system to the desired closed loop poles by applying the control law repeatedly. The paper presents a method of calculating the state weighting matrix and the control law for moving the equal poles with Jordan blocks to two real poles using the characteristic equation of the Hamiltonian system. We express this characteristic equation with a state weighting matrix by means of a trigonometric function, and we derive the relation function (${\rho},\;{\theta}$) between the equal poles and the state weighting matrix under the condition that the two real poles are the roots of the characteristic equation. Then, we obtain the moving-range of the two real poles under the condition that the state weighting matrix becomes a positive semi-finite matrix. We calculate the state weighting matrix and the control law by substituting the two real roots selected in the moving-range into the relational function. As an example, we apply the proposed method to a simple example 3rd order system.

• Transactions of the Korean hydrogen and new energy society
• /
• v.30 no.5
• /
• pp.385-394
• /
• 2019

The analysis of temperature behavior of a hydrogen tank during refueling is of significance to clarify the safety of the compressed hydrogen storage in vehicles since the temperature at a tank rises with inflow of hydrogen. A mass balance and an energy balance were combined to obtain analytical model for temperature change during the hydrogen refueling. The equation was coupled to Peng-Robinson-Gasem (PRG) equation of state (EOS) for hydrogen. The PRG EOS was adopted after comparison with other four different cubic EOSs. A parameter of the model was determined to fit data from experiments of various inlet flow rates and temperatures. The temperature and pressure change with refueling time were obtained by the developed model. The calculation results revealed that the extent of precooling was more effective than the flow rate control.

• Korean Chemical Engineering Research
• /
• v.61 no.4
• /
• pp.550-554
• /
• 2023

Fossil energy sources are limited in their sustainable use and expansion due to global warming caused by carbon dioxide emissions. Hydrogen is considered as a promising alternative to traditional fossil fuels. To ensure the stable long-term storage, it is necessary to accurately predict its thermodynamic properties at cryogenic temperatures. Therefore, this study aimed to investigate thermodynamic properties, such as saturated vapor pressure and density, enthalpy, and entropy of liquid and gas, using cubic equations of state that demonstrate relatively simple relationships. Among the three types of equations of state (Redlich-Kwong (RK), Soave-Redlich-Kwong (SRK), and Peng-Robinson (PR)), the SRK model exhibited relatively accurate prediction results for various physical properties.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.21 no.1
• /
• pp.20-27
• /
• 2020

In general, a nonlinear system is linearized in the form of a multiplication of the 1st and 2nd order system. This paper reports a design method of a weighting matrix and control law of LQ control to move the double poles that have a Jordan block to a pair of complex conjugate poles. This method has the advantages of pole placement and the guarantee of stability, but this method cannot position the poles correctly, and the matrix is chosen using a trial and error method. Therefore, a relation function (𝜌, 𝜃) between the poles and the matrix was derived under the condition that the poles are the roots of the characteristic equation of the Hamiltonian system. In addition, the Pole's Moving-range was obtained under the condition that the state weighting matrix becomes a positive semi-definite matrix. This paper presents examples of how the matrix and control law is calculated.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2021.06a
• /
• pp.105-105
• /
• 2021

본 연구에서는 2차원 비선형 천수모형과 수심평균된 스칼라 이송모형을 해석하는 수치모형에 대해 기술하였다. 수치모형의 정확성을 보장함과 동시에 안정성을 높이기 위해 유한체적법, 플럭스 재구성 및 minmod 제한자를 사용하였다. 비선형 천수방정식의 이송항과 바닥 경사항은 계산된 수심의 양수 보존과 흐름의 정상 상태를 보장하기 위한 second order well-balanced positivity preserving central-upwind method를 이용하여 수치적으로 이산화되었다. 마찬가지로, 이송-확산 방정식 내 이송항은 동일한 2차 풍상차분법을 통해 수치적으로 풀이하였다. 격자점 경계면에서의 불연속으로 인한 수치진동을 방지하기 위해 이송항의 계산에 포함된 보존항의 차이로 인해 발생하는 스칼라의 수치확산을 최소화하기 위해 무차원의 비소산함수를 도입하였다. 또한, 확산항은 유한차분법을 이용하여 이산화하였다. 제안된 수치모형은 시간미분항의 계산을 위해 오일러 기법을 적용하여 계산된 수심 및 스칼라의 양수 보존여부와 함께 정지된 흐름의 정상 상태의 보존여부를 확인하였다. 제안된 수치모형의 해석 정확성을 평가하기 위해 1, 2차원 공간 내 다양한 흐름 조건에서의 해석해를 이용한 3개의 벤치마크 테스트를 수행하였다. 평균 제곱근 오차(Root Mean Squared Error, RMSE)를 산정하여 수치모형의 성능을 정량적으로 평가하였으며, 비소산함수를 적용함에 따라 스칼라의 수치확산이 감소하게 되었음을 확인하였다. 또한, 세 차례의 벤치마크 테스트 결과는 공통적으로 수치모형에 의해 계산된 결과값이 비소산함수를 고려함에 따라 해석해와 잘 일치함을 확인하였다.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.14 no.3
• /
• pp.329-337
• /
• 2001

In this study a compound planetary gear combined with three planet gears, which is used for continuously variable transmission, is modeled that consider variable nonlinear gear mesh stiffness and damping when gear rotates, and thus equation of motion of compound planetary gear is derived. Locus of sun gear center causing noise and vibration is being determined from performing derived state equation with numerical analysis in fourth order Runge-Kutta method.

• Journal of Industrial Technology
• /
• v.19
• /
• pp.253-260
• /
• 1999

Two thermodynamic models were used to predict the partial molar volumes of solutes in supercritical carbon dioxide at infinite dilution: (1) the Peng-Robinson equation of state with various mixing rules including those based on $EOS/G^E$ (2) the Kirkwood Buff fluctuation integral with the hard sphere expansion (HSE) method. The Kirkwood-Buff fluctuation integral method, in which an equation of state for pure component and molecular parameters are required, produced better results especially near the critical point than the Peng-Robinson equation of state with the several mixing rules based an $EOS/G^E$. When the $EOS/G^E$ mixing rules were used, poorer results were obtained compared with the classical mixing rule and Kirkwood-Buff model.