• Proceedings of the Materials Research Society of Korea Conference
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• 2011.10a
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• pp.33.2-33.2
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• 2011

고온형 SOFC의 개발에 있어 스택의 신뢰성을 확보하는데 가장 중요한 핵심기술은 스택 구성요소 사이를 접합하는데 필요한 고온형 밀봉재의 개발이다. SOFC 스택에서의 밀봉재는 고체전해질과 접속자 사이에서 음극에 공급되는 연료가스와 양극에 공급되는 공기가 서로 혼합되는 것을 방지하는 역할은 물론 기계적으로 취약한 단전지의 보호 및 스택전체 구조물의 구조적 일체성(Structural integrity)을 부여하는데 주목적이 있다. 현재 기체 기밀성을 유지하기 위한 밀봉재는 크게 유리 및 결정화 유리계, mica및 mica/유리복합재료, 유리/충전재 복합재료 등이 사용되고 있으나 다수의 단위전지로 구성되는 스택 구성에서 스택의 열기계적 안정성 및 장기수명을 보장하기 위해서는 본 연구에서 개발하고자 하는 복합밀봉재가 가장 적합할 것으로 예상되고 있다. 본 연구에서는 $SiO_2-B_2O_3-RO$계에 BaO, SrO를 일정비율로 첨가하여 제작된 유리 frit을 열처리하여 물리화학적 물성변화를 검토하였으며, $700^{\circ}C$ 이하의 연화점을 갖는 유리를 기지상으로 하고 세라믹 보강재를 첨가한 고온형 복합밀봉재를 개발하고 그 물리화학적 안정성, 열기계적 안정성 및 밀봉 특성을 평가하였다.

• Composites Research
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• v.29 no.5
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• pp.231-235
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• 2016

In this study, integrated co-bonded panels with the same configuration of hat stiffeners were fabricated and measured for ply waviness phenomenon. Total specimens consisted of 2 types; 1) the general co-bonded panel and 2) the co-bonded panel with caul plate made of carbon epoxy composite materials. The first general co-bonded panel specimen exhibited that laminate thickness on the stiffener location area was much thicker than the non-stiffener area and, there was ply waviness with 0.61 mm height and 3.29 mm length. In the second co-bonded panel specimen, the reduced waviness with 0.22 mm height and 1.37 length resulted in more than 50% improvements, which is due to the uniform pressure distribution of co-bonded interface by caul plate.

• Proceedings of the Materials Research Society of Korea Conference
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• 2012.05a
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• pp.95.2-95.2
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• 2012

고온형 SOFC의 개발에 있어 스택의 신뢰성을 확보하는데 가장 중요한 핵심기술은 스택 구성요소 사이를 접합하는데 필요한 고온형 밀봉재의 개발이다. SOFC 스택에서의 밀봉재는 고체전해질과 접속자 사이에서 음극에 공급되는 연료가스와 양극에 공급되는 공기가 서로 혼합되는 것을 방지하는 역할은 물론 기계적으로 취약한 단전지의 보호 및 스택전체 구조물의 구조적 일체성(Structural integrity)을 부여하는데 주목적이 있다. 현재 기체 기밀성을 유지하기 위한 밀봉재는 크게 유리 및 결정화 유리계, mica및 mica/유리복합재료, 유리/충전재 복합재료 등이 사용되고 있으나 다수의 단위전지로 구성되는 스택 구성에서 스택의 열기계적 안정성 및 장기수명을 보장하기 위해서는 본 연구에서 개발하고자 하는 복합밀봉재가 가장 적합할 것으로 예상되고 있다. 본 연구에서는 SiO-B2O3-RO계에 BaO, SrO를 일정비율로 첨가하여 제작된 유리 frit을 열처리하여 물리화학적 물성변화를 검토하였으며, $750^{\circ}C$ 이하의 연화점을 갖는 유리를 기지상으로 하고 세라믹 보강재를 첨가한 고온형 복합밀봉재를 개발하고 그 물리화학적 안정성, 열기계적 안정성 및 밀봉 특성을 평가하였다.

• Korean Journal of Materials Research
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• v.11 no.7
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• pp.585-589
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• 2001

Many experimental results have revealed that the development of cavitaition during tensile deformation is limited by the Presence of liquid phases. However, the presence of liquid phases does not always lead to high-strain-rate superplasticity, because too much liquid causes intergranular decohesion at grain boundaries/interfaces in metal-matrix composites. Thus, it is important to examine the nature of interfaces of superplastic composites in order to understand the origin of superplastic flow related to liquid grain boundaries during high-strain-rate superplastic deformation. This study shows that a large elongation is obtained at the temperature, that is close to the onset temperature for partial melting in the superplastic composites, but the elongation significantly decreases at slightly higher temperatures, which are close to the end temperature fur partial melting. This indicates that there is an optimum amount of the liquid phase for obtaining high-strain-rate superplasticity in these materials.

• Applied Chemistry for Engineering
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• v.3 no.3
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• pp.430-439
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• 1992

To improve the adhesion of interface and dispersion of glass beads in the composite, HDPE filled with glass brads, we encapsulated the g1ass beads with polymer by phase separation method using complex coacervation in organic solvent. EMAA and EAA were used as the polymeric wall materials. The microencapsulation efficiency and morphology were observed by thermogravimetric analysis and SEM, respectively. And also we investigated the physical and dynamic mechanical properties of the composite as the function of the beads contents and microencapsulation efficiency. Compared with the composite containing non-treated glass beads, the decrease in tensile strengthe of the composites containing the encapsulated glass beads become markedly small, and about 30~40% Increase in tensile modulus was observed. From the results of the dynamic mechanical analysis, it was found that the adhesion of interface and dispersion could be improved upon encapsulation.

• Composites Research
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• v.21 no.6
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• pp.23-30
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• 2008

In this paper, the effect of the natural aging on the strength distribution and structural service life of a Filament Wound (FW) composite pressure vessel was studied. The fiber failure strain, which is varied significantly, was considered as the design random variable and the strength analysis was carried out by probabilistic numerical approach. The progressive failure analysis technique and the First Order Reliability Method (FORM) were embedded in this numerical model. As the calculation results, the probability of failure was obtained for each aging time steps and it is found that the strength degradation in FW composite pressure vessel, due to the natural aging, appears within 10 year-aging-time. As an example of the life prediction under natural aging using arbitrary laminated model, the service lifetime of 13 years was predicted based on the probability of failure of 2.5% and the design pressure of 3,250 psi.

• Transactions of the Korean Society of Automotive Engineers
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• v.4 no.2
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• pp.173-182
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• 1996

An analytical model has been developed to predict the elastic properties of a filled resin reinforced by chopped fibers, a three-phase composite such as a filled sheet molding compound(SMC). In the model the matrix material and fillers form an effective matrix. The effective matrix is then considered to be reinforced with long fibers lying in the sheet plane but randomly oriented in the plane. Expressions for the resulting transversely isotropic composite properties are explicitly presented. Using this model, the Young's and shear moduli are calculated for the SMC sample with filler weight fraction of 35% and fiber content of 30%. The same properties are also determined experimentally. The agreement between the calculated and measured elastic moduli is found to be very good for the in-plane properties. However, the out-of-plane properties show a large difference because the effect of voids is not taken into account in the model.

• Composites Research
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• v.36 no.6
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• pp.435-440
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• 2023

This study aimed to enhance the thermal conductivity of B₄C/Al composite materials, commonly used in transport/storage containers for spent nuclear fuel, by incorporating both boron carbide (B₄C) and cubic boron nitride(cBN) as reinforcing agents in an aluminum (Al) matrix. The composite materials were successfully manufactured through a stir casting process and practical neutron-absorbing materials were obtained by rolling the fabricated composite ingot. The evaluation of the thermal conductivity of the fabricated composites was carried out because thermal conductivity is critical for neutron absorbing materials. The thermal conductivity measurement results indicated an approximately 3% increase in thermal conductivity under the same volume fraction when compared to composite materials using only B₄C particles. Through neutron absorption cross-sectional area calculations, it was confirmed that the neutron absorption capability decreased to a negligible level. Based on the findings of this study, new design approaches for neutron absorption materials are proposed, contributing to the development of high-performance transport/storage containers.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.31 no.4
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• pp.159-165
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• 2021

The fiber composites have been investigated as lightweight structure material platforms for aerospace applications because their strength can be enhanced by adding reinforcement without a significant increase in weight. In this study, the fabrication and characterization of carbon nanotube (CNT) reinforced glass fiber composites are demonstrated to enhance the tensile strength of longitudinal direction along the glass fibers. Due to the reinforcement of CNT in epoxy layers, the yield strength of fiber/epoxy composites is enhanced by about 10 %. Furthermore, using scanning electron microscopy, analysis of fracture surfaces shows that mixed CNT in epoxy layers acts as necking agents between fractured surfaces of fiber/epoxy; thereby, initiation and evolution of crack across fiber composite can be suppressed by CNT necking between fractured surfaces.

• Transactions of the Korean Society of Mechanical Engineers
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• v.12 no.6
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• pp.1207-1216
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• 1988

The most 3-Dimensional problems of composite materials, especially three-dimensional stress or strain distribution on jointed boundary in composite materials remains unsolved due to the limitations of analytic techniques. The purpose of this paper is to apply the Embedded Grid Method to model development to measure the three-dimensional strain distribution along the jointed boundary of composite materials which consist of two different materials. It was confirmed that the Embedded Grid Method was very useful in model development and measuring the three-dimensional strain distribution in a local region near the jointed boundary.