• 제목/요약/키워드: 2b-site

검색결과 1,256건 처리시간 0.027초

Mössbauer Study of the Dynamics in BaFe12O19 Single Crystals

  • Choi, J.W.;Sur, J.C.;Lim, Jung-Tae;Kim, Chin-Mo;Kim, Chul-Sung
    • Journal of Magnetics
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    • 제17권1호
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    • pp.6-8
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    • 2012
  • M$\ddot{o}$ssbauer spectra of hexagonal $BaFe_{12}O_{19}$ single crystals were studied at various temperatures (4-300 K). It was found that the spin states in Fe atoms were parallel to the ${\gamma}$-ray's direction into a single crystal along the caxis. The location of the Fe ion in the 2b site is unusual in an oxide structure and has strong anisotropic lattice vibrations. Moreover, at room temperature, the zero absorption lines of the Fe ions at the 2b site were observed due to fast diffusion motion in a double well atomic potential. The two Fe ions of the single crystal mainly enter into the sites in the mirror plane of the trigonalbipyramidal structure.

AC2B 알루미늄 주조합금의 정량적 응고균열 강도 평가 (Quantitative Evaluation of Solidification Crack Strength of AC2B Aluminum Casting Alloy)

  • 김헌주
    • 한국주조공학회지
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    • 제34권4호
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    • pp.136-142
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    • 2014
  • Numerical solution of thermal stress by CAE analysis could be an effective method in product development stage of castings to predict and treat the problem of solidification cracking of castings. Quantitative stress-strain data are necessary, in this case. Tension type apparatus of a solidification crack test which can measure stress-strain relationship quantitatively was developed and the test procedure was established by this research. Solidification crack strength obtained from the following test procedure could be utilized to evaluate it in terms of effect factors on thermo-plastic characteristic of solidifying alloy such as grain size of solid, grain morphology, distribution of solid grain, etc. Proposed test procedure is as follow: Prediction of temperature at the failure site of solidification cracked specimen by computer simulation of solidification, Calculation of solid fraction of the failure site from thermodynamic solution of solidification under Scheil condition.

질소산화물의 촉매반응에 의한 저감기술에 관한 연구 (A Stud on the Catalytic Removal of Nitric Oxide)

  • 홍성수;박종원;정덕영;박대원;조경목;오광중
    • 한국대기환경학회지
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    • 제14권1호
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    • pp.25-33
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    • 1998
  • We have studied the reduction of NO by propane over perovskite-type oxides prepared by malic acid method. The catalysts were modified to enhance the activity by substitution by substitution of metal into A or B site of perovskite oxides. In addition, the reaction conditions, such as temperature, $O_2$ concentration, space velocity have been studed. In the $LaCoO_3$ type catalyst, the partial substitution of Ba, Sr into A site enhanced the catalytic activity in the reduction of NO. In the $La_{0.6}Sr_{0.4}Co_{1-x}Fe_xO_3(x=0 \sim 1.9)$ catalyst, the partial substitution of Fe into B site enhanced the conversion of NO, but excess amount of Fe decreased the conversion of NO. The surface area and catalytic activity of perovskite catalysts prepared by malic acid method showed higher values than those of solid reaction method. In the $La_{0.6}Sr_{0.4}Co_{1-x}Fe_xO_3$ catalyst, the conversion of NO increased with increasing $O_2$ concentration and contact time. The introduction of water into reactant feed decreased the catalytic activity.

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리기다소나무 임분에서 산림관리작업이 토양의 물리성 및 산림의 수질정화기능에 미치는 영향 (Influence of Forest Practices on Soil Physical Properties and Facility of Purifying Water Quality in Pinus rigida Stands)

  • 박재현
    • 한국환경복원기술학회지
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    • 제10권2호
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    • pp.61-70
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    • 2007
  • This study aims to clarify the effect of forest management practices(thinning and pruning) on soil physical properties and water quality to get the fundamental information on the facility of purifying water quality after forestry practices. Rainfall, throughfall, stemflow, soil and stream water were sampled at the study site which consists of Pinus rigida in Jinju National University Experimental Forest for 4 years from Mar. 1, 2002 to Nov. 30, 2006. Averaged tree height of the management site increased by 1.6m, compared to the value of the non-management site in Pinus rigida. Increment of averaged D. B. H. at the management site showed 4.2cm more in Pinus rigida compared with that at non-management sites. Mesopore ratios (pF2.7) and total porosities of A layer soil at the management site increased more than those at the non-management sites in both stands. Otherwise, soil bulk density resulted in being reversely. Water qualities of throughfall, stemflow and buffered soil water were influenced more positively by the management practice. The average electrical conductivity of stream water was $32.9{\mu}S/cm$ within the range of non-polluted stream water.

Ahcyl2 upregulates NBCe1-B via multiple serine residues of the PEST domain-mediated association

  • Park, Pil Whan;Ahn, Jeong Yeal;Yang, Dongki
    • The Korean Journal of Physiology and Pharmacology
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    • 제20권4호
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    • pp.433-440
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    • 2016
  • Inositol-1,4,5-triphosphate [$IP_3$] receptors binding protein released with $IP_3$ (IRBIT) was previously reported as an activator of NBCe1-B. Recent studies have characterized IRBIT homologue S-Adenosylhomocysteine hydrolase-like 2 (AHCYL2). AHCYL2 is highly homologous to IRBIT (88%) and heteromerizes with IRBIT. The two important domains in the N-terminus of AHCYL2 are a PEST domain and a coiled-coil domain which are highly comparable to those in IRBIT. Therefore, in this study, we tried to identify the role of those domains in mouse AHCYL2 (Ahcyl2), and we succeeded in identifying PEST domain of Ahcyl2 as a regulation region for NBCe1-B activity. Site directed mutagenesis and coimmunoprecipitation assay showed that NBCe1-B binds to the N-terminal Ahcyl2-PEST domain, and its binding is determined by the phosphorylation of 4 critical serine residues (Ser151, Ser154, Ser157, and Ser160) in Ahcyl2 PEST domain. Also we revealed that 4 critical serine residues in Ahcyl2 PEST domain are indispensable for the activation of NBCe1-B using measurement of intracellular pH experiment. Thus, these results suggested that the NBCe1-B is interacted with 4 critical serine residues in Ahcyl2 PEST domain, which play an important role in intracellular pH regulation through NBCe1-B.

초·중등과학 지질단원의 학습을 위한 자은도의 지역화 자료 개발 사례 (Development Case of Regional Materials for Learning of Geology Units, Primary and Middle School Science at Jaeundo)

  • 김해경
    • 대한지구과학교육학회지
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    • 제13권1호
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    • pp.110-120
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    • 2020
  • 과학교과의 지질단원 학습은 야외학습과 지역의 자료를 활용한 수업이 학습 동기를 유발하고 학습에 긍정적인 영향을 미치는 것으로 알려졌다. 이 연구에서는 전라남도 자은도를 중심으로 과학교과 지질단원 학습을 위한 지역화 자료를 개발하고 그 사례를 제시하였다. 연구결과는 다음과 같다. 연구지역의 3개 장소(남진 선착장 부근, 양산 해변 지역, 둔장 해변 지역)를 중심으로 지질관련 지역화 자료를 개발하였다. 남진선착장 부근지역에는 해식애, 모래해안, 갯벌이 분포하고 있다. 해식애 노두에서는 퇴적암인 역암, 사암, 이암이 분포하며, 암석의 풍화 현상 그리고 끊어진 지층 및 휘어진 지층을 관찰할 수 있다. 양산 해변 지역에서는 약 1.5km 길이의 모래해안과 해식애가 발달하며 역암, 사암, 이암의 퇴적암과 화성암인 유문암 그리고 풍화에 의한 풍화혈이 발달한다. 둔장 해변 지역에선 약 2km 길이의 모래해안과 해식애 그리고 퇴적암과 다양한 지층이 분포하고 있다. 또한 해식동굴이 긴 시간의 침식으로 인해 변화해 가는 과정을 이해할 수 있는 시스택이 분포하고 있다. 3개의 장소에 분포하는 지형 및 지질현상은 자은도에 분포하는 독특한 현상으로 과학 교과서의 지질단원에 제시된 지질현상을 이해할 수 있는 지역화 자료로 활용할 수 있다. 이러한 지역화 자료는 사진으로 제작하여 교과서 사진과 비교하여 학습에 이용할 수 있으며 더 나아가 야외지질학습장으로서 활용할 만하다.

Vertical Distribution and Potential Risk of Particulate Polycyclic Aromatic Hydrocarbons in High Buildings of Bangkok, Thailand

  • Pongpiachan, Siwatt
    • Asian Pacific Journal of Cancer Prevention
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    • 제14권3호
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    • pp.1865-1877
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    • 2013
  • Vertical variations of polycyclic aromatic hydrocarbon (PAH) concentrations in $PM_{10}$ were investigated in order to assess the factors controlling their behavior in the urban atmosphere of Bangkok City, Thailand. Air samples were collected every three hours for three days at three different levels at Bai-Yok Suit Hotel (site-1 and site-2) and Bai-Yok Sky Hotel (site-3) in February $18^{th}-21^{st}$, 2008. The B[a]P concentration showed a value 0.54 fold, lower than the United Kingdom Expert Panel on Air Quality Standard (UK-EPAQS; i.e. 250 pg $m^{-3}$) at the top level. In contrast, the B[a]P concentrations exhibited, at the ground and middle level, values 1.50 and 1.43 times higher than the UK-EPAQS standard respectively. PAHs displayed a diurnal variation with maximums at night time because of the traffic rush hour coupled with lower nocturnal mixing layer, and the decreased wind speed, which consequently stabilized nocturnal boundary layer and thus enhanced the PAH contents around midnight. By applying Nielsen's technique, the estimated traffic contributions at Site-3 were higher than those of Site-1: about 10% and 22% for Method 1 and Method 2 respectively. These results reflect the more complicated emission sources of PAHs at ground level in comparison with those of higher altitudes. The average values of incremental individual lifetime cancer risk (ILCR) for all sampling sites fell within the range of $10^{-7}-10^{-6}$, being close to the acceptable risk level ($10^{-6}$) but much lower than the priority risk level ($10^{-4}$).

지하수 오염 가능성 평가 -수리지질 및 부지특성 조사와 경험적 평가 방법을 이용한 지하수 요염 가능성- (An Assessment of Groundwater Pollution Potential of a Proposed Petrochemical Plant Site in Ulsan, South Korea Hydrogeologic and site characterization and groundwater pollution potential by utilizing several empirical assessment methodologies)

  • 한정상;한규상;이영동;유대호
    • 자원환경지질
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    • 제23권4호
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    • pp.425-452
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    • 1990
  • 지하수 환경의 오염 가능성에 대한 정량적인 전산분석을 실시하기 이전 단계로 경험적인 평가방법을 이용하여 조사대상 지역 지하수환경의 오염 가능성을 광범위한 수리지질 및 수리분산 실험을 실시하여 평가하였다. 그 결과 최상위 대수층은 포화 비고결 퇴적물과 풍화대 및 수리적으로 연결성이 양호한 상부 파쇄암으로 구성되어 있다. 최상위 대수층의 대표적인 수리전도도는 $2.88{\times}10^{-6}m/s$, 저유계수(비산출률)은 0.09, 지하수의 주흐름 경로에서 다시 안 유속은 0.011m/d, 비반응 오염 용질의 공극유속은 0.12m/d, 지하수의 동수구배는 4.6%이다. 취득한 제반 수리지질 자료를 이용하여 조사대상 지역의 자하수환경 오염 가능성을 경험적인 평가법으로 평가한 바, 1) DRASTIC 분석 결과에 의하면, 본 지역은 "지하수 오염 가능성에 취약성이 희박하거나, 오염에 민감하지 않은 지역"으로 나타났으며, 2) Legrand 수치법 분석법을 이용하여 입지 적합성과 오염 가능성을 평가한 바, 본 지역은 "B" grade에 해당하는 "오염 가능성이 없기 때문에 대체적으로 입지로 적합하나, 부분적으로 적합지 않을 수도 있는 지역"으로 분류되었고, 3) 폐기물-토양 입지 연관성 행열 평가법에 의하면, 본 부지는 8군에 속하는 것으로 평가되었다.

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NiZn 페라이트의 저온 소결 특성에 관한 연구 (A Study on Properties of Low Temperature Sintering in the NiZn Ferrite System)

  • 고상기;김병호;김경용
    • 한국세라믹학회지
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    • 제34권10호
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    • pp.1074-1082
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    • 1997
  • Microstructure and permeability as a function of sintering temperature and composition were studied on the Ni$\delta$Cu0.4-$\delta$Zn0.6Fe2O4 ($\delta$=0, 0.1, 0.2, 0.3, 0.4) which was prepared by Cu2+ substitution for Ni2+ in Ni.0.4Zn0.6Fe2O4, then followed by 8 wt% CuO and 1wt% Bi2O3 as sintering aids. It was found that NiCuZn ferrite in which Cu2+ is substituted for Ni2+ is more effective in reduction of sintering temperature than Ni.0.4Zn0.6Fe2O4, containing CuO as a sintering aid. The specimen $\delta$=0.2 sintered at 90$0^{\circ}C$ for 2hr exhibited the highest initial permeability value ($\mu$o=280 at 1Mhz), but the real permeability decreased at the frequency under 10 MHz. EPMA analysis showed that Ni$\delta$Cu0.4-$\delta$Zn0.6Fe2O4 ($\delta$=0.4), sintered at 95$0^{\circ}C$ for 2hrs consisted of three phase regions of Ni.0.3Cu0.1Zn0.6Fe2O4 region, Cu and Bi liquid existed at the 3-point boundary, although the stabilization energy of Ni2+ is higher than that of Cu2+ in B site.

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