• 제목/요약/키워드: 2DE

검색결과 4,750건 처리시간 0.034초

Performance of carbon fiber added to anodes of conductive cement-graphite pastes used in electrochemical chloride extraction in concretes

  • Pellegrini-Cervantes, M.J.;Barrios-Durstewitz, C.P.;Nunez-Jaquez, R.E.;Baldenebro-Lopez, F.J.;Corral-Higuera, R.;Arredondo-Rea, S.P.;Rodriguez-Rodriguez, M.;Llanes-Cardenas, O.;Beltran-Chacon, R.
    • Carbon letters
    • /
    • 제26권
    • /
    • pp.18-24
    • /
    • 2018
  • Pollution of chloride ion-reinforced concrete can trigger active corrosion processes that reduce the useful life of structures. Multifunctional materials used as a counter-electrode by electrochemical techniques have been used to rehabilitate contaminated concrete. Cement-based pastes added to carbonaceous material, fibers or dust, have been used as an anode in the non-destructive Electrochemical Chloride Extraction (ECE) technique. We studied the performance of the addition of Carbon Fiber (CF) in a cement-graphite powder base paste used as an anode in ECE of concretes contaminated with chlorides from the preparation of the mixture. The experimental parameters were: 2.3% of free chlorides, 21 days of ECE application, a Carbon Fiber Volume Fraction (CFVF) of 0.1, 0.3, 0.6, 0.9%, a lithium borate alkaline electrolyte, a current density of $4.0A/m^2$ and a cement/graphite ratio of 1.0 for the paste. The efficiency of the ECE in the traditional technique using metal mesh as an anode was 77.6% and for CFVF of 0.9% it was 90.4%, with a tendency to increase to higher percentages of the CFVF in the conductive cement-graphite paste, keeping the pH stable and achieving a homogeneous ECE in the mass of the concrete contaminated with chlorides.

Synthesis and Characterization of Dense Ceramic Membranes for Methane Conversion - Part II

  • Santos, A.;Fontes, V.A.;Fontes, F.A.Oliveira;De Sousa, J.F.;De Souza, C.P.
    • 한국분말야금학회:학술대회논문집
    • /
    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
    • /
    • pp.1112-1113
    • /
    • 2006
  • The perovskite- type oxide $(ABO_3)$ containing transition metals on the B-site show mixed (electronic/ionic) conductivity. These mixed-conductivity oxides are promising materials for oxygen permeating membranes. The main objective of this research work is to synthesize and characterization ceramic powders of the Sr-Co-Fe-O system for methane conversion using membrane reactor. SCFO powders were synthesized from the route was based on the complex method of combination of acid EDTA and citrate and shown be available by control efficient of synthesis to performed $SrCo_{0.8}Fe_{0.2}O_{3-\delta$, moreover, it presented easy implementation, reproducibility and operation. Powder ceramic was characterized by XRD, microscopic optic, SEM and TG-DTA.

  • PDF

Factors Associated With the Illness of Nursing Professionals Caused by COVID-19 in Three University Hospitals in Brazil

  • de Oliveira, Larissa Bertacchini;de Souza, Luana Mendes;de Lima, Fabia Maria;Fhon, Jack Roberto Silva;Puschel, Vilanice Alves de Araujo;Carbogim, Fabio da Costa
    • Safety and Health at Work
    • /
    • 제13권2호
    • /
    • pp.255-260
    • /
    • 2022
  • Background: The coronavirus disease 2019 (COVID-19) pandemic has demonstrated the importance of implementing strategic management that prioritizes the safety of frontline nurse professionals. In this sense, this research was aimed at identifying factors associated with the illness of nursing professionals caused by COVID-19 according to socio-demographic, clinical, and labor variables. Methods: A cross-sectional study was conducted in three Brazilian university hospitals with 859 nursing professionals, which include nurses, technicians, and nursing assistants, between November 2020 and February 2021. We present data using absolute and relative frequency. We used Chi-square test for hypothesis testing and multiple logistic regression for predictive analysis and chances of occurrence. Results: The rate of nursing professionals affected by COVID-19 was 41.8%, and the factors associated with contamination were the number of people in the same household with COVID-19 and obesity. Being a nurse was a protective factor when the entire nursing team was considered. The model is significant, and its variables represent 56.61% of the occurrence of COVID-19 in nursing professionals. Conclusion: Obesity and living in the same household as other people affected by COVID-19 increases the risk of contamination by this new coronavirus.

ESSENTIAL SPECTRUM OF A WEIGHTED GEOMETRIC REALIZATION

  • Hatim, Khalid;Baalal, Azeddine
    • Nonlinear Functional Analysis and Applications
    • /
    • 제26권4호
    • /
    • pp.701-716
    • /
    • 2021
  • In this present article, we construct a new framework that's we call the weighted geometric realization of 2 and 3-simplexes. On this new weighted framework, we construct a nonself-adjoint 2-simplex Laplacian L and a self-adjoint 2-simplex Laplacian N. We propose general conditions to ensure sectoriality for our new nonself-adjoint 2-simplex Laplacian L. We show the relation between the essential spectra of L and N. Finally, we prove the absence of the essential spectrum for our 2-simplex Laplacians L and N.

Comparison of Mathematical Models Applied to F1 Dairy Sheep Lactations in Organic Farm and Environmental Factors Affecting Lactation Curve Parameter

  • Angeles-Hernandez, J.C.;Albarran-Portillo, B.;Gomez Gonzalez, A.V.;Pescador Salas, N.;Gonzalez-Ronquillo, M.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • 제26권8호
    • /
    • pp.1119-1126
    • /
    • 2013
  • The objective of this study was to compare the goodness of fit of four lactation curve models: Wood's Gamma model (WD), Wilmink (WL), and Pollott's multiplicative two (POL2) and three parameters (POL3) and to determine the environmental factors affecting the complete lactation curve of F1 dairy sheep under organic management. A total of 5,382 weekly milk yields records from 150 ewes, under organic management were used. Residual mean square (RMS), determination coefficients ($R^2$), and correlation (r) analysis were used as an indicator of goodness of fit for each model. WL model best fitted the lactation curves as indicated by the lower RMS values (0.019), followed by WD (0.023), POL2 (0.025) and POL3 (0.029). The four models provided total milk yield (TMY) estimations that were highly correlated (0.93 to 0.97) with observed TMY (89.9 kg). The four models under estimated peak yield (PY), whereas POL2 and POL3 gave nearer peak time lactation estimations. Ewes lambing in autumn had higher TMY and showed a typical curve shape. Higher TMY were recorded in second and third lambing. Season of lambing, number of lambing and type of lambing had a great influenced over TMY shaping the complete lactation curve of F1 dairy sheep. In general terms WL model showed the best fit to the F1 dairy sheep lactation curve under organic management.

Metal Biosorption by Surface-Layer Proteins from Bacillus Species

  • Allievi, Mariana Claudia;Florencia, Sabbione;Mariano, Prado-Acosta;Mercedes, Palomino Maria;Ruzal, Sandra M.;Carmen, Sanchez-Rivas
    • Journal of Microbiology and Biotechnology
    • /
    • 제21권2호
    • /
    • pp.147-153
    • /
    • 2011
  • Bacillus species have been involved in metal association as biosorbents, but there is not a clear understanding of this chelating property. In order to evaluate this metal chelating capacity, cultures and spores from Grampositive bacteria of species either able or unable to produce surface layer proteins (S-layers) were analyzed for their capacity of copper biosorption. Only those endowed of S-layers, like Bacillus sphaericus and B. thuringiensis, showed a significant biosorption capacity. This capacity (nearly 50%) was retained after heating of cultures, thus supporting that structural elements of the envelopes are responsible for such activity. Purified S-layers from two Bacillus sphaericus strains had the ability to biosorb copper. Copper biosorption parameters were determined for strain B. sphaericus 2362, and after analyses by means of the Langmuir model, the affinity and capacity were shown to be comparable to other bacterial biosorbents. A competitive effect of $Ca^{2+}$ and $Zn^{2+}$, but not of $Cd^{2+}$, was also observed, thus indicating that other cations may be biosorbed by this protein. Spores that have been shown to be proficient for copper biosorption were further analyzed for the presence of S-layer content. The retention of S-layers by these spores was clearly observed, and after extensive treatment to eliminate the S-layers, the biosorption capacity of these spores was significantly reduced. For the first time, a direct correlation between S-layer protein content and metal biosorption capacity is shown. This capacity is linked to the retention of S-layer proteins attached to Bacillus spores and cells.

Lessons from Yeast on Emerging Roles of the ATAD2 Protein Family in Gene Regulation and Genome Organization

  • Cattaneo, Matteo;Morozumi, Yuichi;Perazza, Daniel;Boussouar, Faycal;Jamshidikia, Mahya;Rousseaux, Sophie;Verdel, Andre;Khochbin, Saadi
    • Molecules and Cells
    • /
    • 제37권12호
    • /
    • pp.851-856
    • /
    • 2014
  • ATAD2, a remarkably conserved, yet poorly characterized factor is found upregulated and associated with poor prognosis in a variety of independent cancers in human. Studies conducted on the yeast Saccharomyces cerevisiae ATAD2 homologue, Yta7, are now indicating that the members of this family may primarily be regulators of chromatin dynamics and that their action on gene expression could only be one facet of their general activity. In this review, we present an overview of the literature on Yta7 and discuss the possibility of translating these findings into other organisms to further define the involvement of ATAD2 and other members of its family in regulating chromatin structure and function both in normal and pathological situations.

Analyzing corrosion rates of TiO2 nanotubes/titanium separation passive layer under surface and crystallization changes

  • Torres, I. Zamudio;Dominguez, A. Sosa;Bueno, J.J. Perez;Meas, Y.;Lopez, M.L. Mendoza;Dector, A.
    • Advances in nano research
    • /
    • 제10권3호
    • /
    • pp.211-219
    • /
    • 2021
  • The evaluation of the corrosion resistance of titanium with a TiO2 nanotubes top layer was carried out (TiO2 NT). These nanostructures were evolved into anatase nanoparticles without heat treatment in an aqueous medium, which is a novel phenomenon. This work analyzes the layer between the nanotube bottom and the substrate, which is thin and still susceptible to corrosion. The bottom of TiO2 nanotubes having Fluor resulting from the synthesis process changed between amorphous to crystalline anatase with a crystallite size of about 4 nm, which influenced the corrosion rates. Four kinds of samples were evaluated. A) NT by Ti anodizing; B) NTSB for Ti plates, either modifying its surface or anodizing the modified surface; C) NT-480 for anodized Ti and heat-treated (480℃) for reaching the anatase phase; D) NTSB-480 for Ti plates, first, modifying its surface using sandblast, after that, anodizing the modified surface, and finally, heat-treated to 480℃ to compare with samples having induced crystallization and passivation. Four electrochemical techniques were used to evaluate the corrosion rates. The surfaces having TiO2 nanotubes with a sandblast pre-treatment had the highest resistance to corrosion.

POSITIVE RADIAL SOLUTIONS FOR A CLASS OF ELLIPTIC SYSTEMS CONCENTRATING ON SPHERES WITH POTENTIAL DECAY

  • Carriao, Paulo Cesar;Lisboa, Narciso Horta;Miyagaki, Olimpio Hiroshi
    • 대한수학회보
    • /
    • 제50권3호
    • /
    • pp.839-865
    • /
    • 2013
  • We deal with the existence of positive radial solutions concentrating on spheres for the following class of elliptic system $$\large(S) \hfill{400} \{\array{-{\varepsilon}^2{\Delta}u+V_1(x)u=K(x)Q_u(u,v)\;in\;\mathbb{R}^N,\\-{\varepsilon}^2{\Delta}v+V_2(x)v=K(x)Q_v(u,v)\;in\;\mathbb{R}^N,\\u,v{\in}W^{1,2}(\mathbb{R}^N),\;u,v&gt;0\;in\;\mathbb{R}^N,}$$ where ${\varepsilon}$ is a small positive parameter; $V_1$, $V_2{\in}C^0(\mathbb{R}^N,[0,{\infty}))$ and $K{\in}C^0(\mathbb{R}^N,[0,{\infty}))$ are radially symmetric potentials; Q is a $(p+1)$-homogeneous function and p is subcritical, that is, 1 < $p$ < $2^*-1$, where $2^*=2N/(N-2)$ is the critical Sobolev exponent for $N{\geq}3$.

Insights into Systems for Iron-Sulfur Cluster Biosynthesis in Acidophilic Microorganisms

  • Myriam, Perez;Braulio, Paillavil;Javiera, Rivera-Araya;Claudia, Munoz-Villagran;Omar, Orellana;Renato, Chavez;Gloria, Levican
    • Journal of Microbiology and Biotechnology
    • /
    • 제32권9호
    • /
    • pp.1110-1119
    • /
    • 2022
  • Fe-S clusters are versatile and essential cofactors that participate in multiple and fundamental biological processes. In Escherichia coli, the biogenesis of these cofactors requires either the housekeeping Isc pathway, or the stress-induced Suf pathway which plays a general role under conditions of oxidative stress or iron limitation. In the present work, the Fe-S cluster assembly Isc and Suf systems of acidophilic Bacteria and Archaea, which thrive in highly oxidative environments, were studied. This analysis revealed that acidophilic microorganisms have a complete set of genes encoding for a single system (either Suf or Isc). In acidophilic Proteobacteria and Nitrospirae, a complete set of isc genes (iscRSUAX-hscBA-fdx), but not genes coding for the Suf system, was detected. The activity of the Isc system was studied in Leptospirillum sp. CF-1 (Nitrospirae). RT-PCR experiments showed that eight candidate genes were co-transcribed and conform the isc operon in this strain. Additionally, RT-qPCR assays showed that the expression of the iscS gene was significantly up-regulated in cells exposed to oxidative stress imposed by 260 mM Fe2(SO4)3 for 1 h or iron starvation for 3 h. The activity of cysteine desulfurase (IscS) in CF-1 cell extracts was also upregulated under such conditions. Thus, the Isc system from Leptospirillum sp. CF-1 seems to play an active role in stressful environments. These results contribute to a better understanding of the distribution and role of Fe-S cluster protein biogenesis systems in organisms that thrive in extreme environmental conditions.