• Proceedings of the Korean Biophysical Society Conference
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• 2003.06a
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• pp.74-74
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• 2003

We report here the results on N-acetyl-N'-methylamide of oxazolidine (Ac-Oxa-NHMe) calculated using the ab initio molecular orbital method with the self-consistent reaction field (SCRF) theory at the HF level of theory with the 6-3l+G(d) basis set. The displacement of the $\square$-CH$_2$ group in proline ring by oxygen atom has affected the structure of proline, cis$\^$∼/ trans equilibrium, and rotational barrier. The up-puckered structure is found to be prevalent for the trans conformers of the Oxa amide. The higher cis populations of the Oxa amide can be interpreted due to the longer distance between the acetyl methyl group and the 5-methylene group of the ring for the trans conformer of the Oxa amide than that of the Pro amide. The changes in charge of the prolyl nitrogen and the decrease in electron overlap of the C$\^$∼/ N bond for TS structures seem to play a role in lowering rotational barriers of the Oxa amide compared to that of the Pro amide. The calculated preferences for cis conformers in the order of Oxa > Pro amides and for trans-to-cis rotational barriers in the order of Pro > Oxa amide in water are consistent with experimental results on Oxa-containing peptides. The pertinent distance between the prolyl nitrogen and the N$\^$∼/ H amide group to form a hydrogen bond might indicate that this intramolecular hydrogen bond could contribute in stabilizing the TS structures of Oxa and Pro amides and play a role in prolyl isomerization.

• Journal of Powder Materials
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• v.24 no.4
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• pp.302-307
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• 2017

In this study, Fe-Cu-C alloy is sintered by spark plasma sintering (SPS). The sintering conditions are 60 MPa pressure with heating rates of 30, 60 and $9^{\circ}C/min$ to determine the influence of heating rate on the mechanical and microstructure properties of the sintered alloys. The microstructure and mechanical properties of the sintered Fe-Cu-C alloy is investigated by X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM). The temperature of shrinkage displacement is changed at $450^{\circ}C$ with heating rates 30, 60, and $90^{\circ}C/min$. The temperature of the shrinkage displacement is finished at $650^{\circ}C$ when heating rate $30^{\circ}C/min$, at $700^{\circ}C$ when heating rate $60^{\circ}C/min$ and at $800^{\circ}C$ when heating rate $90^{\circ}C/min$. For the sintered alloy at heating rates of 30, 60, and $90^{\circ}C/min$, the apparent porosity is calculated to be 3.7%, 5.2%, and 7.7%, respectively. The hardness of the sintered alloys is investigated using Rockwell hardness measurements. The objective of this study is to investigate the densification behavior, porosity, and mechanical properties of the sintered Fe-Cu-C alloys depending on the heating rate.

• Steel and Composite Structures
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• v.39 no.2
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• pp.215-228
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• 2021

This paper investigates the effect of micromechanical models on the bending behavior of bidirectional functionally graded (BDFG) beams subjected to different mechanical loading. The material properties of the beam are considered to be graded in both axial and thickness directions according to a power law. The beam's behavior is modeled by the mean of quasi 3D displacement field that contain undetermined integral terms and involves a reduced unknown functions. Navier's method is employed to determine and compute the displacements and stress for a simply supported beam. Different homogenization schemes such as Voigt, Reus, and Mori-Tanaka are employed to analyze the response of the BDFG beam subjected to linear, uniform, exponential and sinusoidal distributed loading. The results obtained by the present method are compared with available results in the literature and a good agreement was found. Several numerical results are presented in tabular form and in figures to examine the effects of the material gradation, micromechanical models and types of loading on the bending response of BDFG beams. It can be concluded that the present theory is not only accurate but also simple in predicting the bending response of BDFG beam subjected to different static loads.

• Advances in concrete construction
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• v.14 no.3
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• pp.169-183
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• 2022

In this article, vibrational behavior and wave propagation characteristics in (FG) functionally graded plates resting on Kerr foundation with three parameters is studied using a 2D dimensional (HSDT) higher shear deformation theory. The new 2D higher shear deformation theory has only four variables in field's displacement, which means has few numbers of unknowns compared with others theories. The shape function used in this theory satisfies the nullity conditions of the shear stresses on the two surfaces of the FG plate without using shear correction factors. The FG plates are considered to rest on the Kerr layer, which is interconnected with a Pasternak-Kerr shear layer. The FG plate is materially inhomogeneous. The material properties are supposed to vary smoothly according to the thickness of the plate by a Voigt's power mixing law of the volume fraction. The equations of motion due to the dynamics of the plate resting on a three-parameter foundation are derived using the principle of minimization of energies; which are then solved analytically by the Navier technique to find the vibratory characteristics of a simply supported plate, and the wave propagation results are derived by using the dispersion relations. Perceivable numerical results are fulfilled to evaluate the vibratory and the wave propagation characteristics in functionally graded plates and some parameters such wave number, thickness ratio, power index and foundation parameters are discussed in detail.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.25 no.5
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• pp.413-420
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• 2012

In this study, the Kernel integration scheme for 2D linear elastic direct boundary element method has been discussed on the basis of subparametric element. Usually, the isoparametric based boundary element uses same polynomial order in the both basis function and mapping function. On the other hand, the order of mapping function is lower than the order of basis function to define displacement field when the subparametric concept is used. While the logarithmic numerical integration is generally used to calculate Kernel integration as well as Cauchy principal value approach, new formulation has been derived to improve the accuracy of numerical solution by algebraic modification. The subparametric based direct boundary element has been applied to 2D elliptical partial differential equation, especially for plane stress/strain problems, to demonstrate whether the proposed algebraic expression for integration of singular Kernel function is robust and accurate. The problems including cantilever beam and square plate with a cutout have been tested since those are typical examples of simple connected and multi connected region cases. It is noted that the number of DOFs has been drastically reduced to keep same degree of accuracy in comparison with the conventional isoparametric based BEM. It is expected that the subparametric based BEM associated with singular Kernel function integration scheme may be extended to not only subparametric high order boundary element but also subparametric high order dual boundary element.

• Geomechanics and Engineering
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• v.12 no.3
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• pp.541-560
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• 2017

In this research, experimental and numerical simulations were adopted to investigate the effects of ligament angle on compressive strength and failure mode of rock-like material specimens containing two non-coplanar filled fissures under uniaxial compression. The experimental results show that with the increase of ligament angle, the compressive strength decreases to a nadir at the ligament angle of $60^{\circ}$, before increasing to the maximum at the ligament angle of $120^{\circ}$, while the elastic modulus is not obviously related to the ligament angle. The shear coalescence type easily occurred when ${\alpha}$ < ${\beta}$, although having the same degree difference between the angle of ligament and fissure. Numerical simulations using $PFC^{2D}$ were performed for flawed specimens under uniaxial compression, and the results are in good consistency with the experimental results. By analyzing the crack evolution process and parallel bond force field of rock-like material specimen containing two non-coplanar filled fissures, we can conclude that the coalescence and propagation of crack are mainly derived from parallel bond force, and the crack initiation and propagation also affect the distribution of parallel bond force. Finally, the displacement vectors in ligament region were used to identify the type of coalescence, and the results coincided with that obtained by analyzing parallel bond force field. These experimental and numerical results are expected to improve the understanding of the mechanism of flawed rock engineering structures.

• Steel and Composite Structures
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• v.47 no.5
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• pp.551-568
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• 2023

In this research, a new two-dimensional (2D) and quasi three-dimensional (quasi-3D) higher order shear deformation theory is devised to address the bending problem of functionally graded plates resting on an elastic foundation. The displacement field of the suggested theories takes into account a parabolic transverse shear deformation shape function and satisfies shear stress free boundary conditions on the plate surfaces. It is expressed as a combination of trigonometric and exponential shear shape functions. The Pasternak mathematical model is considered for the elastic foundation. The material properties vary constantly across the FG plate thickness using different distributions as power-law, exponential and Mori-Tanaka model. By using the virtual works principle and Navier's technique, the governing equations of FG plates exposed to sinusoidal and evenly distributed loads are developed. The effects of material composition, geometrical parameters, stretching effect and foundation parameters on deflection, axial displacements and stresses are discussed in detail in this work. The obtained results are compared with those reported in earlier works to show the precision and simplicity of the current formulations. A very good agreement is found between the predicted results and the available solutions of other higher order theories. Future mechanical analyses of three-dimensionally FG plate structures can use the study's findings as benchmarks.

• Geomechanics and Engineering
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• v.34 no.4
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• pp.397-408
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• 2023

Pipe pile walls are commonly used as retaining structures for excavation projects, particularly in densely populated coastal cities such as Hong Kong. Pipe pile walls are preferred in reclaimed land due to their cost-effectiveness and convenience for installation. However, the pre-bored piling techniques used to install pipe piles can cause significant ground disturbance, posing risks to nearby sensitive structures. This study reports a well-documented case history in a reclamation site, and it was found that pipe piling could induce ground settlement of up to 100 mm. Statutory design submissions in Hong Kong typically specify a ground settlement alarm level of 10 mm, which is significantly lower than the actual settlement observed in this study. In addition, lateral soil movement of approximately 70 mm was detected in the marine deposit. The lateral soil displacement in the marine deposit was found to be up to 3.4 and 3.1 times that of sand fill and CDG, respectively, mainly due to the relatively low stiffness of the marine deposit. Based on the monitoring data and site-investigation data, a 3D numerical analysis was established to back-analyze soil movements due to the installation of the pipe pile wall. The comparison between measured and computed results indicates that the equivalent ground loss ratio is 20%, 40%, and 20% for the fill, marine deposit and CDG, respectively. The maximum ground settlement increases with an increase in the ground loss ratio of the marine deposit, whereas the associated influence radius remains stationary at 1.2 times the pipe pile wall depth (H). The maximum ground settlement increases rapidly when the thickness of marine deposit is less than 0.32H, particularly for the ground loss ratio of larger than 40%. This study provides new insights into the pipe piling construction in reclamation sites.

• Journal of Biosystems Engineering
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• v.34 no.5
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• pp.315-324
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• 2009

Various types of vibration are transmitted to operators of agricultural tractors while working in the field. Most harmful vibration to human body is ride vibrations with low frequency ranging from 1 to 10 Hz, caused by rough terrain. These ride vibration has vertical and rotational components. This study was conducted to develop an active seat suspension system with two degrees of freedoms, enabling effectively reduce vibrations in vertical and pitch motions. Therefore, a mechanism for the active seat suspension was developed, and an electro-hydraulic servo system and a controller to drive the active seat suspension system were also developed in this study. A simulation model was developed to evaluate how the active seat suspension system effectively reduce the vibrations transmitted to the base of seat. Active seat suspension was optimized to enhance the performance using the developed simulation model. The performance of the seat suspension system was evaluated according to the test codes described in EEC78/764 in order to investigate the feasibility of application to agricultural tractors. The result showed that the developed active seat suspension system could reduce the magnitude of vertical vibration up to 80% for the input vibrations according to the test codes described in EEC78/764. The system could reduce the rotational displacement of ${\pm}\;2.5$ degrees up to 50% for the pitch vibration on the average in the frequency range of 1 to 2 Hz.

• Restorative Dentistry and Endodontics
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• v.26 no.2
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• pp.134-140
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• 2001

The polymerization shrinkage of composite resins is an important drawback although the composites have many advantages-more esthetic and conservative than metallic restoratives etc. The purposes of this research were to develop a new measurement method and to manufacture an instrument that can measure the initial dynamic volumetric shrinkage of composite resins during polymerization. The instrument was basically an electromagnetic balance that constructed with a force transducer using position sensitive photo detector(PSPD) and a negative feedback servo amplifier of proportional-derivative(PD) controller. The volumetric change of composites during polymerization was detected continuously as buoyancy change in distilled water by means of Archimedes's principle. It was converted to continuous electrical voltage signal in real time. The signal was properly conditioned and filtered and then it was stored in computer by a data acquisition(DAQ) board. By using this electronic instrument. the dynamic patterns of the polymerization shrinkage of eight commercial(Z-100, DenFil, AeliteFil, Z-250, P-60, SureFil, Synergy compact, and Tetric ceram) composite resins were measured and compared. The results were as follows. 1. From this project of developing instrument, the ability has been achieved that can acquire and process data of electrical signal transformed from various physical phenomenon by using temperature, displacement. photo. and force transducer. As a consequence, the instrumentation and measurement system used to analyze the physical characteristics of various dental materials in dental research field can be designed, manufactured and implemented in lab. 2. This instrument has some advantages. It was insensible to temperature change and could measure true dynamic volumetric shrinkage in real time without complicated process. It showed accuracy and high precision results with small standard deviation. 3. The polymerization shrinkage of composites was significantly different between brands and ranged from 2.47％ to 3.89％, The order of polymerization shrinkage was as follows, in order of increasing shrinkage, SureFil, P60, Z250, Z100, Synergy compact. DenFil, Tetric ceram, and AeliteFil. 4. The polymerization shrinkage rate per unit time, dVol％/dt, showed that the instrument can provide an indirect research method for polymerization reaction kinetics.