• 제목/요약/키워드: 2D crystals

검색결과 247건 처리시간 0.026초

융제법에 의한 Sapphire 단결정 성장에 관한 연구 (Single Crystal Growth of Sapphire by Flux Method)

  • 조병곤;주경;오근호;최종건;김대웅;강원호
    • 한국세라믹학회지
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    • 제25권2호
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    • pp.95-100
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    • 1988
  • Single crystals of sapphire were grown from solution by slow cooling method using B2O3 and PbO as flux agents. The morphology of grown crystals was tube, rhombohedral, or hexagonal-plate. It was found that the morphology and the size of grown crystal were highly dependent on the amount of fluxes in the solution, the ratio of B2O3 vs. PbO, and cooling rate.

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Isolation of a New Phenylpropanoid from Codonopsis ussuriensis

  • Lee, Ihn-Rhan;Seo, Eun-Kyong
    • Archives of Pharmacal Research
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    • 제13권4호
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    • pp.365-366
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    • 1990
  • A new phenylpropanoid was isolated from the roots of Codonopsis ussuriensis (Rupr. et Maxim) Hemsley. It was coloress crystals, mp. 140-142.deg.C and was elucidated as 4-(3-ethoxy-1-propenyl)-2, 6-dimethoxyphenyl-$\beta$-D-glucopyranoside on basis of spectral data analysis.

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2차원 광결정 제작에 패턴 특성을 향상시키기 위한 공정 기술 (Fabrication Technology for Improving Pattern Quality in Two-Dimensional Photonic Crystal Structure)

  • 김해성;신동훈;김순구;이진구;이범석;김혜원;이재은;한영수;최영호
    • 한국전기전자재료학회논문지
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    • 제16권6호
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    • pp.515-521
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    • 2003
  • There are now many theoretical investigations and real manufactures for numerous applications of photonic crystals (PCs) associated with photonic band gap and photonic integrated circuits. However, there are some difficulties to design and fabricate the desired pattern quality. It is not easy to satisfy accurate critical dimension (CD) for patterns with arbitrary shapes and pitch sizes aligned in various directions. In this work, we report the optimum conditions to better fabricate and design, and greatly improve pattern quality in delineating two-dimensional (2D) PCs in the nanometer range using single- step e-beam lithography system with conventional exposure mode.

Fast(submillisecond) Switching of Nematic Liquid Crystals and Effects of Dielectric Dispersion; Theory and Experiment

  • Shiyanovskii, Sergij V.;Golovin, Andrii B.;Yin, Ye;Lavrentovich, Oleg D.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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    • pp.181-186
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    • 2005
  • We demonstrate that the finite rate of dielectric relaxation in liquid crystals which has been ignored previously causes profound effects in the fast dielectric reorientation of the director. The phenomenon is relevant for submillisecond switching of the director when the switching rate approaches the rate of dielectric relaxation through the reorientation of the molecular dipoles. A submillisecond switching ($15-400\;{\mu}s$ for an optical retardation shift $0.3-2.2\;{\mu}m$ in $10-15\;{\mu}m$ thick cells) is demonstrated for dual frequency nematic cells with high pretilt that maximizes the dielectric torque acting on the director. We propose the theory of dielectric response in which the electric displacement depends not only on the present (as in the standard theory) but also on the past values of electric field and director. We design an experiment in which the standard "instantaneous" model and our model predict effects of opposite signs; the experimental data support the latter model.

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자동차 브레이크 마찰재용 비침상형 육티탄산칼륨의 합성 연구 (Synthesis of Potassium Hexatitanate with Non-Fibrous Shape as a Raw Material for Friction Material in Brake System)

  • 이정주;이나리;피재환;김종영;김정주
    • 한국재료학회지
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    • 제27권3호
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    • pp.132-136
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    • 2017
  • We synthesized potassium hexatitanate, ($K_2Ti_6O_{13}$, PT6), with a non-fibrous shape, by acid leaching and subsequent thermal treatment of potassium tetratitanate ($K_2Ti_4O_9$, PT4), with layered crystal structure. By controlling nucleation and growth of PT4 crystals, we obtained splinter-type crystals of PT6 with increased width and reduced thickness. The optimal holding temperature for the layered PT4 was found to be ${\sim}920^{\circ}C$. The length and width of the PT4 crystals were increased when the nucleation and growth time were increased. After a proton exchange reaction using aqueous 0.3 M HCl solution, and subsequent heat treatment at $850^{\circ}C$, the PT4 crystal transformed into splinter-type PT6 crystals. The frictional characteristics of the friction materials show that as the particle size of PT6 increases, the coefficient of friction (COF) and wear amounts of both the friction materials and counter disc increase.

Synthesis of Tripod-shaped Liquid Crystals with sp3 Nitrogen at the Apex

  • Jung, Hyun-Chul;Lee, Seng-Kue;Lee, Guk-Sik;Shin, Hwa-Jin;Park, Song-Ju;Lee, Jong-Gun;Watanabe, Junji;Takezoe, Hideo;Kang, Kyung-Tae
    • Bulletin of the Korean Chemical Society
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    • 제30권9호
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    • pp.1946-1950
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    • 2009
  • Tripod-shaped liquid crystals with $sp^3$ nigrogen at the apex were prepared from triethanolamine. Their physical properties were investigated by using optical microscopy, differential scanning calorimetry, and X-ray diffraction measurements. The XRD study suggests that the tripod-shaped molecules show the 2D-ordered phase of either the frustrated smectic layer structure or discotic columnar phases.

$MgIn_2Se_4 및 MgIn_2Se_4 : Ni^{2+}$ 단결정 성장의 광학적 특성에 관한 연구 (Optical Properties of Undoped and $Ni^{2+}$ -doped $MgIn_2Se_4$ Single Crystals)

  • 김형곤;김병철;신석두;김덕태;최영일;김남오
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제48권1호
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    • pp.12-17
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    • 1999
  • $MgIn_2Se_4 and MgIn_2Se_4 : Ni^{2+}$ single crystals were grown in the rhombohedral structure by the chemical transport reaction (C.T.R.) method using iodine as a transport agent. The optical absorption measured near the fundamental band edge showed that the optical energy band structure of these compounds had a direct band gap. The fundamental absorption band edge of these single crystals shift to a shorter wavelength region by decreasing temperature and the temperature dependence of the optical energy gaps in these compounds satisfy Varshni equation. The impurity optical absorption peaks due to nickel are observed in $MgIn_2Se_4 and MgIn_2Se_4 : Ni^{2+}$ single crystal. These impurity optical absorption peaks can be attributed to the electronic transitions between the split energy levels of $Ni_{2+}$ ions located at $T_d$ symmetry site of $MgIn_2Se_4$ host lattice. In the hotoluminescence spectrum of the single crystal at 10 K, a blue emission with a peak at 687nm and a green emission with a peak at 815nm for the $MgIn_2Se_4$ single crystal were observed.

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$Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}$$Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}$:$Co^{2+}$ 단결정의 광학적 특성과 열역학 함수 추정 (Optical Properties and Thermodynamic Function Properties of Undoped and Co-Doped $Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}$ Single Crystals)

  • 현승철;박현;박광호;오석균;김형곤;김남오
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제52권7호
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    • pp.275-281
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    • 2003
  • $Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}$ and $Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}$:$Co^{2+}$ single crystals were grown by CTR method. The grown single crystals have defect chalcopyrite structure with lattice constant a=5.5966$\AA$, c=10.8042$\AA$ for the pure, a=5.6543$\AA$, c=10.8205$\AA$ for the Co-doped single crystal, respectively. The optical energy band gap was given as indirect band gap. The optical energy band gap was decreased according to add of Co-impurity Temperature dependence of optical energy band gap was fitted well to the Varshni equation. From this relation, we can deduced the entropy, enthalpy and heat capacity. Also, we can observed the Co-impurity optical absorption peaks assigned to the $Co^{2+}$ ion sited at the $T_{d}$ symmetry lattice and we consider that they were attributed to the electron transitions between energy levels of ions.

Dynamic Structure of Bacteriorhodopsin Revealed by $^{13}C$ Solid-state NMR

  • Saito, Hazime;Yamaguchi, Satoru;Tuzi, Satoru
    • Journal of Photoscience
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    • 제9권2호
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    • pp.110-113
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    • 2002
  • We demonstrate here a dynamic structure of bacteriorhodopsin (bR) as revealed by $^{13}$ C NMR studies on [3_$^{13}$ C]_,[1-$^{13}$ C]Ala- and/or Val-labeled wild type and a variety of site-directed mutants at ambient temperature. For this purpose, well-resolved (up to twelve) I$^{13}$ C NMR peaks were assigned with reference to the displacement of peaks due to the conformation-dependent I$^{13}$ C chemical shifts and reduced peak-intensities due to site-directed mutations. Revealed bR structure was not rigid as anticipated from 2D crystals of hexagonal array but a dynamically heterogeneous, undergoing a variety of local fluctuations depending upon specific site with frequency range of 10$^2$ -10$^{8}$ Hz. In particular, dynamics- dependent suppression of peaks turned out to be very sensitive to the motion of 10$^{-4}$ s and 10$^{-5}$ s interfered with frequency of magic angle spinning and proton decoupling, respectively. It is also noteworthy that such dynamic feature is strongly dependent upon the manner of 2D crystalline packing: $^{13}$ C NMR peaks of monomeric bR yielded either highly broadened or completely suppressed signals, depending upon the type of $^{13}$ C-labeled amino-acid residues.

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