Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis of Tripod-shaped Liquid Crystals with sp3 Nitrogen at the Apex

  • Jung, Hyun-Chul (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Lee, Seng-Kue (Department of Organic and Polymeric Materials, Tokyo Institute of Technology) ;
  • Lee, Guk-Sik (Department of Organic and Polymeric Materials, Tokyo Institute of Technology) ;
  • Shin, Hwa-Jin (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Park, Song-Ju (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Lee, Jong-Gun (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Watanabe, Junji (Department of Organic and Polymeric Materials, Tokyo Institute of Technology) ;
  • Takezoe, Hideo (Department of Organic and Polymeric Materials, Tokyo Institute of Technology) ;
  • Kang, Kyung-Tae (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University)
  • Published : 2009.09.20
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Abstract

Tripod-shaped liquid crystals with $sp^3$ nigrogen at the apex were prepared from triethanolamine. Their physical properties were investigated by using optical microscopy, differential scanning calorimetry, and X-ray diffraction measurements. The XRD study suggests that the tripod-shaped molecules show the 2D-ordered phase of either the frustrated smectic layer structure or discotic columnar phases.

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References

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