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Equilibrium Kinetics and Thermodynamic Parameters Studies for Eosin Yellow Adsorption by Activated Carbon (활성탄에 의한 Eosin Yellow의 흡착에 대한 평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong Jib
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.5
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    • pp.3319-3326
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    • 2014
  • Eosin yellow is used a dye and colorant but it is harmful toxic substance. In this paper, batch adsorption studies were carried out for equilibrium, kinetics and thermodynamic parameters for eosin yellow adsorption by activated carbon with varying the operating variables like pH, initial concentration, contact time. Equilibrium adsorption data were fitted into Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms. By estimated Langmuir constant value, $R_L$=0.067-0.083, and Freundlich constant value, $\frac{1}{n}=0.237-0.267$, this process could be employed as effective treatment for removal of eosin yellow. From calculated Temkin constant, value, B=1.868-2.855 J/mol, and Dubinin-Radushkevich constant, value, E=5.345-5.735 kJ/mol, this adsorption process is physical adsorption. From kinetic experiments, the adsorption process were found to confirm to the pseudo second order model with good correlation coefficient($r^2$=0.995-0.998). The mechanism of the adsorption process was determined two step like as boundary and intraparticle diffusion.

Patent Application Research Analysis on Domestic Smart Factory Technology Through SNA (SNA를 통한 국내 스마트공장 기술에 관한 특허 출원 조사 분석)

  • Jae-Hyo Hwang;Ki-Jung Kim
    • The Journal of the Korea institute of electronic communication sciences
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    • v.19 no.1
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    • pp.267-274
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    • 2024
  • In this paper, we investigated the number of domestic patent applications by year, the number of domestic patent disclosures by year, and the number of domestic registrations by year regarding smart factories. The number of patent applications by applicant type was investigated. Based on the patents studied, it was found that the IPC appearing in the most patents was G05B 19/418. In addition, through social network analysis of smart factory patented IPCs, it was found that G05B 19/418 was the IPC with the highest degree of centrality. From the above, if the IPC of the core technology of the patent submitted for smart factory is G05B 19/418, the technology combined with G05B 23/02, that is, the technology combining "factory control" and "monitoring" is the most patented. When the IPC of the core technology was G06Q 50/04, it was confirmed that the technology combined with G06Q 50/10, that is, the technology combining "manufacturing" and "service" was the most applied for patents. Through this, it was found that in order to apply for a patent for a smart factory, it would be necessary to file a patent application that takes into account the connectivity between IPCs.

분말과 고정화 $TiO_2$를 이용한 Rhodamin B의 색도 제거 비교

  • 박영식
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.05a
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    • pp.267-270
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    • 2003
  • 수용성 양이온 안료인 RhB를 대상으로 분말 $TiO_2$와 고정화 $TiO_2$를 이용하여 색도제거실험을 수행한 결과 다음과 같은 결론을 얻었다. 1) 분말 $TiO_2$의 최적 투입량은 0.2 g/L였으며, 대부분 광촉매 반응에 의하여 제거되었다. 고정화 $TiO_2$의 최적 투입량은 210.7 g/L이었고, 광촉매와 흡착에 의해 제거되었다. Langmuir - Hinshelwood 식으로 표현되지 못하였다. 2) 고정화 $TiO_2$를 이용하여 Rhodamine B를 제거할 경우 광촉매 분리 문제는 해결할 수 있으며, 광 투과율을 증가시킬 수 있으나 같은 제거율을 얻기 위해 투입량이 분말에 비해 매우 높은 것이 문제점으로 나타났다.

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Deuteromethylactin B from a Freshwater-derived Streptomyces sp.

  • Shaikh, Anam F.;Elfeki, Maryam;Landolfa, Samantha;Tanouye, Urszula;Green, Stefan J.;Murphy, Brian T.
    • Natural Product Sciences
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    • v.21 no.4
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    • pp.261-267
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    • 2015
  • Compared to their terrestrial and marine counterparts, little is known about the capacity of freshwater-derived actinomycete bacteria to produce novel secondary metabolites. In the current study, we highlight the disparities that exist between cultivation-independent and -dependent analyses of actinomycete communities from four locations in Lake Michigan sediment. Furthermore, through phylogenetic analysis of strains isolated from these locations, we identified a Streptomyces sp., strain B025, as being distinct from other Streptomyces spp. isolated from sediment. Upon fermentation this strain produced a rare class of eight-membered lactone secondary metabolites, which have been for their antitumor properties. We used spectroscopic and chemical derivitization techniques to characterize octalactin B (1) in addition to its corresponding novel, unnatural degradation product (2).

Nutritional Status and Requirements of Protein and Energy in Female Korean College Students Maintaining Their Usual and Activity(2) : Nitrogen Intake and Balance (자유로운 식이와 활동을 유지하는 한국 여대생의 에너지와 단백질대사에 대한 연구(2) : 질소섭취와 평형)

  • 김주연
    • Journal of Nutrition and Health
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    • v.28 no.4
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    • pp.259-267
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    • 1995
  • A study was conducted to investigate nitrogen balance and to estimate daily nitrogen requirement in 43 Korean female college students students maintaining their usual diet and activity levels. Nitrogen intake and excretion were measured in two separate peroids about one month apart, each period lasting for 3 days. Nitrogen intake was assessed by duplicate portion analysis of diet, and N excretion in faces and urine were measured during the study period. Mean daily nitrogen intake level was 129.3mg/kg B.W and the apparent digestibility of nitrogen was 76%. Mean daily urinary nitrogen excretion was 113.5mg/kg BW. 895 of total nitrogen intake. Mean daily nitrogen balance of subjects was -14.5mg/kg BW. Mean daily requirements of nitrogen for 0 balance, calculated by regression analysis of N balance and energy-adjusted N intake. were 1) 197.mg/kg B.W with the present energy intake level of the study subjects. 2) 157mg/kg B.W when energy intake is sufficient to maintain energy balance, and 30 130mg/kg B.W. when energy intake is Korean RDA level for moderate activity. When energy intake level is sufficient to meet their requirement, daily protein requirement for 0 balance is about 1.0g/kg B.W. The results of this study indicate that nitrogen intake level of young female college students is not sufficient to meet their requirements, and they should increase protein intake together with increase in energy intake.

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Evaluation of Portable Slipmeter using Human Perception (인간의 인지적 감각을 이용한 휴대용 미끄럼 측정기의 성능평가)

  • Choi, Hyung Jin;Kim, Jung Soo
    • Journal of the Korea Safety Management & Science
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    • v.16 no.3
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    • pp.267-271
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    • 2014
  • The objectives of this study were to evaluate the safe criteria of portable slipmeter using human perception onto the several different floor surfaces under contaminated conditions. It was difficult to find why many different slipmeters took there's own safe criteria. It is still unclear how thres hold values established in many literatures. Two different subjective slippery evaluating methods, AHP(Analytic Hierarchy Process) and Friedman test,were used to evaluate the perception of slipperiness of seven different floor surfaces under the contaminated condition with detergent solution. Twelve subjects worn same footwear and walked with self-selected step and cadence along the test floors. The SCOF(Static Coefficient of Friction) obtained for same test conditions with BOT-3000 was compared to perception of slipperiness to establish as a safe criteria. The very high significant correlation(r=0.97) was found between AHP and Friedman test. Also, The high significant correlation(r=0.96) was found between AHP and SCOF obtained with BOT-3000. The results suggested that the SCOF should be greater than 0.63 for safer walking. Perception rating obtained with AHP showed a high correlation with Friedman test and the SCOF obtained with BOT-3000 except for polished tile floor. The safe criteria obtained through this study were similar to ANSI/NFSIB101.1.

A Delta-Sigma Fractional-N Frequency Synthesizer for Quad-Band Multi-Standard Mobile Broadcasting Tuners in 0.18-μm CMOS

  • Shin, Jae-Wook;Kim, Jong-Sik;Kim, Seung-Soo;Shin, Hyun-Chol
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.7 no.4
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    • pp.267-273
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    • 2007
  • A fractional-N frequency synthesizer supports quadruple bands and multiple standards for mobile broadcasting systems. A novel linearized coarse tuned VCO adopting a pseudo-exponential capacitor bank structure is proposed to cover the wide bandwidth of 65%. The proposed technique successfully reduces the variations of KVCO and per-code frequency step by 3.2 and 2.7 times, respectively. For the divider and prescaler circuits, TSPC (true single-phase clock) logic is extensively utilized for high speed operation, low power consumption, and small silicon area. Implemented in $0.18-{\mu}m$ CMOS, the PLL covers $154{\sim}303$ MHz (VHF-III), $462{\sim}911$ MHz (UHF), and $1441{\sim}1887$ MHz (L1, L2) with two VCO's while dissipating 23 mA from 1.8 V supply. The integrated phase noise is 0.598 and 0.812 degree for the integer-N and fractional-N modes, respectively, at 750 MHz output frequency. The in-band noise at 10 kHz offset is -96 dBc/Hz for the integer-N mode and degraded only by 3 dB for the fractional-N mode.

Ultrasonics and electromagnetics for a wireless corrosion sensing system embedded in structural concrete

  • Hietpas, K.;Ervin, B.;Banasiak, J.;Pointer, D.;Kuchma, D.A.;Reis, H.;Bernhard, J.T.
    • Smart Structures and Systems
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    • v.1 no.3
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    • pp.267-282
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    • 2005
  • This work describes ongoing development of an embedded sensor system for the early detection and prevention of deterioration of reinforcing steel tendons within reinforced concrete. These devices will evaluate the condition of the steel tendon using ultrasonic techniques and then wirelessly transmit this data to the outside world without human intervention. The ultrasonic transducers and the interpretation of the sensed signals that allow detection and prognosis of tendon condition are detailed. Electrical characterization of concrete mixtures used in bridge construction is conducted and a wideband microstrip antenna is designed and fabricated to operate between 2.4 and 2.5 GHz when embedded in such a medium. Simulations and measurements of the embedded antenna element are presented. Transceiver selection and implementation are discussed as well as future work in operational protocols, sensor networking, and power sources. By implementing commercially available off-the-shelf components whenever possible, these devices have the potential to save millions of dollars a year in evaluation, repair and replacement of reinforced concrete.

Terminal Care Stress, Job Satisfaction and Terminal Care Performance for Nurses in Internal Medicine Wards (내과병동 간호사의 임종간호 스트레스, 직무만족도 및 임종간호수행)

  • Baek, Eu Kyoung;Choi, Eun Joung
    • Journal of Hospice and Palliative Care
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    • v.18 no.4
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    • pp.267-275
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    • 2015
  • Purpose: This study is aimed to investigate the relationship among terminal care stress, job satisfaction and terminal care performance nurses in internal medicine wards and to provide a basis to improve terminal care performance. Methods: This is a descriptive study performed with 201 nurses who have at least one year of experience and are stationed at the internal medicine department of three general hospitals and three university hospitals in P city of a metropolitan city B. The nurses also had an experience with a dying patient. Data were collected from March 1 through March 31, 2014. The study was approved by the Institutional Review Board of Kosin University. Results: Job satisfaction was negatively correlated with stress in end-of-life care (r=-212, P=0.003) and positively correlated with terminal care performance (r=0.383, P<0.001). There was no correlation between terminal care stress and terminal care performance. Conclusion: Appropriate programs are needed to improve job satisfaction for high quality terminal care performance.

Characteristics of Long-term Care Patients at a Tertiary Referral Hospital and Factors Influencing the Decision of prolonged Care-giving (일 상급종합병원 장기재원환자의 특성과 전원 결정 여부에 영향을 미치는 요인)

  • Lee, MiJin
    • Journal of Home Health Care Nursing
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    • v.31 no.1
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    • pp.56-65
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    • 2024
  • Purpose: This study aimed to explore the association between demographic characteristics, hospitalization-related characteristics, and the severity of long-term hospitalization in a high-level general hospital, and to analyze the factors influencing decisions of all patients. Methods: General and clinical characteristics of the participants were analyzed using frequency, percentage, mean, and standard deviation. Differences in these characteristics, contingent upon whether a power source was requested, were analyzed using independent t-Test and Chi-squared tests. Logistic regression analysis was used to identify the factors related to the presence or absence of power requests. Results: The factors impacting the decision to refer a dependent variable include medical treatment (neurosurgery) (B=2.118, SE=0.960, p-value=.027, OR=8.314, 95% CI=1.267-54.551), infection isolation (CRE) (B=1.336, SE=0.666, p-value=.045, OR=3.804, 95% CI=1.032-14.021), and the utilization of tertiary antibiotics (B=3.076, SE=1.362, p-value= .024, OR=21.663, 95% CI=1.502-312.530). Conclusion: This study found a significant association between medical treatment (neurosurgery), infection isolation (CRE), and the use of tertiary antibiotics as dependent variables. These findings indicate that continuous monitoring can contribute to a reduction in long-term financial burdens.