• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 춘계학술대회 논문집 초전도 자성체
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• pp.59-63
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• 2002

The purpose of this paper is to investigate the crystal texture of the 2223 phase and its relationship with PIT processing parameter. Ag-sheathed Bi-2223 multi-filament tapes were prepared by changing rolling reduction ratio. We analysed the degree of texture for 2223 phase after heat-treatment. According to X-ray pole-figure, the texture of the filaments located near surface and center were not so different each other for all rolling conditions. we found a little higher degree of texture for 60% rolling reduction. But its difference is not so high compared with those tapes with a lower rolling reduction ratio. Reaction induced texturing seemed to contribute with a large portion under present condition.

• 한국전기전자재료학회논문지
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• 제18권5호
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• pp.473-477
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• 2005

A Bi-2223 tape has been developed for power applications such as a fault current limiter, a power cable and a superconducting magnetic energy storage system. In such applications, the Bi-2223 tape carries time varying transport current and in addition experiences time varying external magnetic field. It is well known that the external magnetic field not only causes magnetization loss in the Bi-2223 tape, but also drastically increases transport loss due to a so-called 'dynamic resistance' We developed an evaluation setup, which can measure transport loss in external at magnetic fields. Using this equipment, we measured the dynamic resistances for various amplitudes and frequencies of an external at magnetic field perpendicular to the face in the tape. Simultaneously we investigated the effect of an external ac field on transport loss with different experimental conditions. This paper describes test results ana discussions on correlation between the dynamic resistance and the transport loss for the Bi-2223 tape.

• Progress in Superconductivity
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• 제5권2호
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• pp.124-127
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• 2004

Many of research efforts have been focused on the improvement of critical current density (Jc) of silver-sheathed Bi-2223 tapes far practical applications. In this study, the transformation of Bi-2212 phase was investigated, which was transformed to orthorhombic from tetragonal through pre-annealing during powder packing and drawing process. The relationship between hardness of Bi-2212 orthorhombic phase and workability of Bi-2223/Ag tape was investigated. Bi-2223 superconducting wires with 55 filaments were fabricated by stacking and drawing process with different heat-treatment histories. Before rolling process, round wires were pre-annealing at 76$0^{\circ}C$ and in a low oxygen partial pressure. We confirmed that pre-annealing step was to transform to Bi-2212 orthorhombic structure from Bi-2212 tetragonal structure and to reduce the formation of second phases. However the breakages were created at Ag-alloy clad during rolling for pre-annealed Bi-22231Ag tapes. Several pre-annealing scenarios were introduced to reduce the breakages during rolling process. Microstructure and critical current density of pre-annealed Bi-2223 superconducting tapes were investigated. We could achieve proper pre-annealing conditions for Ag-alloy clad Bi-2223 superconducting tapes.

• 한국초전도ㆍ저온공학회논문지
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• 제25권2호
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• pp.5-9
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• 2023

The effect of La_0.7Sr_0.3MnO₃ (LSMO) addition on the superconducting property of Bi_1.6Pb_0.4Sr₂Ca₂Cu₃O_10+δ ((Bi, Pb)-2223) polycrystalline samples was studied. LSMO (0.3 wt.% to 2.0 wt.%) added (Bi, Pb)-2223 samples were prepared by using a solid-state reaction method. The XRD analyses show that as the LSMO addition increases, the volume fraction of the Bi-2223 phase is gradually decreased. The critical temperature (T_c) exhibits a gradual decrease with a single transition as the LSMO amount increases up to 1.0 wt.%, but a further addition of LSMO induces an abrupt decrease of T_c with a dual transition. The analyses on the local structure of the CuO₂ plane from the X-ray absorption fine structure (EXAFS) measurements showed that for the samples with low concentration of LSMO up to 1.0 wt.%, the Cu-O bond length and the CuO₂ plane ordering do not degrade from the values of pure (Bi, Pb)-2223, while they get worsen with a further increase of LSMO addition. These results open up the possibility of LSMO as artificial pinning centers of the (Bi, Pb)-2223 system for power application.

• 한국전기전자재료학회논문지
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• 제11권11호
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• pp.1014-1021
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• 1998

We evaluated the effect of processing variables on microstructural evolution interface irregularity between Ag sheath and superconductor core and resultant critical current density(J$_{c}$) of (Bi,Pb)$_2$Sr$_2$Ca$_2$Cu$_3$O$_{x}$(2223) superconductor tape. The value of J$_{c}$ was significantly influenced by the interface irregularity, degree of texturing and relative 2223 content. The interface became more irregular(sausage effect), while the degree of texturing gradually improved as the dimension of tape decreased during forming process. As the dimension of wire/tape were changed from diameter of 3.25 mm to thickness of 0.20 mm, J$_{c}$ value was observed to be increased by 10 times. In addition, optimum sintering temperature for improved J$_{c}$ was observed to be 835$^{\circ}C$ in a ambient atmosphere probably due to combined effect of both improved texturing and high 2223 content. Microstructural investigation showed the degree of texturing was degraded by the existence of both second phases and interface irregularity. It was observed that larger grain size and better texturing was developed near relatively flat interface compared to those inside superconducting core.ting core.

• 한국초전도ㆍ저온공학회논문지
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• 제5권1호
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• pp.40-43
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• 2003

The phase transformation, variation of secondary phase, and critical current density $(J_c) for (Bi,Pb)_2Sr_2Ca_2Cu_3O_10 (2223)$ tapes have been studied through the thermal slide heat treatment (TSHT) process. This process consists of a multiple variations of oxygen partial pressures and temperatures at the initial heat treatment During the initial heat treatment some secondary phase such as $(Ca,Sr)_2CuO_3(2/1 AEC), (Ca,Sr)_{14}Cu_{24}O_{41} (14/24 AEC), and (Bi,Pb)_2Sr_2CuO_y$(2201, amorphous phase) farm in Bi-2223 tapes, especially at the 2223 grain boundaries. These secondary phases are detrimental to the phase transformation and final properties. In order to control the secondary phase in Bi-2223 tapes the amount and size of secondary phases among the TSHT process were observed. The results indicate that the amount and particle size of AEC particles were smaller when the TSHT process was used than when the normal process at the initial heat treatment was used which results in the improved $J_c$ properties after the final process.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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• pp.26-27
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• 2006

The fundamental mechanical characteristics under tensile and bending deformations of hermetically-sealed reinforced Bi-2223 tape and CTOP processed Bi-2223 tape were examined at 77K. Also, the Tensile strain dependence of the critical current, $I_c$, was obtained at 77K and self-field. The reinforced hermetic tape showed higher tensile strength and a better Tensile strain tolerance than the CTOP processed tape. For bending tests, a rho-shaped sample holder was used giving multiple bending strains. in increasing order. In the same case under bending deformation, the hermetic tape showed a higher bending strain tolerance than the CTOP processed tape. This higher strength of the hermetic tape can be attributed to the thick hardened copper reinforcement layer.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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• pp.345-348
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• 2004

For practical applications, the evaluation of reliability or endurance of HTS conductors is necessary. The mechanical properties and the critical current, $I_c$, of multifilamentary Bi-2223 superconducting tapes, externally reinforced with stainless steel foils, subjected to high cycle fatigue loading in the longitudinal direction were investigated at 77K. The S-N curves were obtained and its transport property was evaluated with the increase of repeated cycles at different stress amplitudes. The effect of the stress ratio, R, on the $I_c$ degradation behavior under fatigue loading was also examined considering the practical application situation of HTS tapes. Microstructure observation was conducted in order to understand the L degradation mechanism in fatigued Bi-2223 tapes.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1660-1662
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• 1996

Superconducting current lead is one of the promising applications of the oxide high-Tc superconductors, because they have the advantage of decreasing heat conduction to low temperature region, comparing with a conventional cooper alloy lead. High critical current density is a key factor for the applications such as current lead. $(Bi,Pb)_{2}Sr_{2}Ca_{2}Cu_{3}O_{x}$ high Tc superconductor hase been investigated in terms of critical current density. Bi-2223 superconducting current lead made by CIP and solid state sintering process. Bi-2223 current lead that heat treated at $836\;^{\circ}C$ for 240 h in 1/13 $PO_2$ had over $500\;A/cm^2$ of critical current density at 77K. We knew that the superconducting properties of tube type current leads were better than rods type of them. And we investigated the relation of Bi-2223 formation and heat treatment condition by XRD and SEM analysis.

• Progress in Superconductivity
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• 제3권1호
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• pp.99-103
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• 2001

We have conducted two runs of interlaboratory comparison on Ag-sheathed Bi-2223 tapes to evaluate the level of measurement techniques for the critical current measurement. Two classes of specimens were prepared for parallel and serial routings and sent to four participating laboratories. The critical currents of specimens were measured at 77 K in zero magnetic field. In the first comparison, we used twenty different Bi-2223 tapes as specimens for comparison and participating laboratories measured the specimens using their own instruments and procedures. As a result, the scattering of data on the first comparison showed -3.0% to +l2.2% for the parallel routing and -0.7% to +l5.1% for the serial routing. Major sources of these variations were attributed to different measurement techniques. Thus, the second comparison of measurement was done on the same specimens under specified measurement conditions, particularly in terms of cooling procedure and sweep rate of the test current. The variations for the second comparison were decreased -3.1% to +3.2% far the parallel routing and -1.8% to +7.7% fur the serial routing.