• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2000.11a
• /
• pp.108-111
• /
• 2000

Bi2212 and Bi2223 thin films are fabricated by ion beam sputtering method. Three phases of Bi2201, Bi2212 and Bi2223 appear as stable ones in spite of the condition for thin film fabrication of Bi2212 and bi2223 compositions, depending on substrate temperature(T$\sub$sub/) and ozone pressure (PO$_3$). It is found out that these phases show similar T$\sub$sub/ and PO$_3$ dependence, and that the stable regions of these phases are limited within very narrow temperature.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2007.06a
• /
• pp.484-485
• /
• 2007

BiSrCaCuO superconducting thin films have been fabricated by co-deposition using the faraday cup. Despite setting the composition of thin film Bi2212, Bi(2201, 2212, 2223) phase were appeared. It was confirmed the obtained field of stabilizing phase was represented in the diagonal direction of the right below end in the Arrhenius plot of temperature of the substrate and $PO_3$, and it was distributed in the rezone.

• Progress in Superconductivity and Cryogenics
• /
• v.8 no.3
• /
• pp.1-4
• /
• 2006

The characteristics of Bi2212 round wire was systematically studied depending on different heat treatment conditions. Initial wire was drawn after routine PIT (Powder In Tube) process. The wire was divided into 3 pieces with 10 cm in length and 2.5 mm in diameter. 3 wires were pre-heat treated separately by different heat treatment schedules, heated in air and nitrogen atmosphere and centrifugally melted. Pre-heated wires were annealed at $845^{\circ}C$ for 40 hours in oxygen atmosphere. SEM results indicate that all pre-heated wires showed highly oriented microstructure. However the wire by centrifugally melted process showed higher density and better electric properties as compared with 2 other wires pre-heated in air and nitrogen atmosphere. The critical current of a centrifugally melted wire was about 18 A in 77 K.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
• /
• 2007.06a
• /
• pp.536-539
• /
• 2007

BSCCO am films fabricated by using the evaporation method at various substrate temperatures, Tsub and ozone gas pressures $PO_3$. Despite setting the composition of thin film Bi2223, Bi2201, Bi2212 and Bi2223 phase were appeared. It was confirmed the obtained field of stabilizing phase was represented in the diagonal direction of the right below end in the Arrhenius plot of temperature of the substrate and $PO_3$, and it was distributed in the rezone. The XRD peak of the generated film continuously changed according to the substrate temperature. This demonstrates the existence of mixed crystal composition where the phases of Bi2201, Bi2212 and Bi2223 are mixed in the crystal structure; and the single-phase film of each phase exist in a very rezone of temperature and gas pressure.

• Progress in Superconductivity
• /
• v.8 no.1
• /
• pp.108-112
• /
• 2006

We fabricated Bi-2212/$SrSO_4$ bulk superconductors by the casting process and evaluated the effects of the powder mixing method and annealing temperature on the texture, microstructure, and critical current. In the process, the Bi-2212 powders were mixed with $SrSO_4$ by hand-mixing(HM) and planetary ball milling(PBM) method and then the powder mixtures were melted at $1100^{\circ}C{\sim}1200^{\circ}C$, solidified, and annealed. We observed that the rod made by the PBM had a more homogeneous microstructure and smaller $SrSO_4$ and second phases than that of the rod made by the HM, resulting in increased $I_c$. The $I_c$ of the rod also depended on the annealing temperature and the highest $I_c$ was obtained to be 200 A when prepared by HM at $1200^{\circ}C$ and annealed at $810^{\circ}C$ which is probably due to the moderate density and 2212 texture and the smaller and less second phase compared to that at higher temperature. The possible causes of the variations of $I_c$ with the powder mixing method and annealing temperature were related to the microstructural evolution based on the SEM, EPMA, and DTA analyses.

• Proceedings of the KIEE Conference
• /
• 2006.07b
• /
• pp.639-640
• /
• 2006

We investigated fault current limitation characteristics of the resistive superconducting fault current limiter(SFCL) which consisted of a Bi-2212 bulk coil and a shunt coil. The Bi-2212 bulk coil and the shunt coil were connected in parallel. The Bi-2212 bulk coil was placed inside the shunt coil to induce field-assisted quench. The fault test was conducted at an input voltage of 200 $V_{rms}$ and fault current of 12 $kA_{rms}$ and 25 $kA_{rms}$. The fault conditions were asymmetric and symmetric, and the fault period was 5 cycles. The test results show that the SFCL successfully limited the fault current of 12 $kA_{rms}$ and 25 $kA_{rms}$ to below $5.5{\sim}6.9kA_{peak}$ within $0.64{\sim}2.17$ msec after the fault occurred. Limitation was faster under symmetric fault test condition due to the larger change rate of current. We concluded that the speed of fault current limitation was determined by the speed of current rise rather than the amplitude of a short circuit current. These results show that the Bi-2212 bulk coil is suitable for distribution-class SFCLs.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2006.06a
• /
• pp.267-267
• /
• 2006

전력에 큰 손실을 초래하는 고장전류를 차단하기 위한 한류기(FCL) 소재로서 고온 초전도체인 BSCCO 2212가 사용된다. 고온에서 용융된 BSCCO 2212 분말은 원심성형법에 의해 한류기용 튜브로 제조되었다. BSCCO 튜브의 기계적 특성을 높이고 용융온도를 낮추기 위해 $SrSO_4$(10wt-%)를 첨가하였다. 용탕은 $1200^{\circ}C$에서 완전히 용융되어 금속 몰드로 주입되었고 원심성형에 사용되는 금속 몰드는 $550^{\circ}C$ 온도로 2시간 예열 후 1020 ~ 2520 RPM으로 회전시켰다. 원심력에 의해 성형된 BSCCO 튜브는 약 48시간 동안 로에서 서냉 후 금속 몰드로부터 분리하였다. 튜브의 용이한 분리를 위해 이형제로서 BSCCO 2212 powder를 사용하였고 임계전류측정을 고려하여 Ag tape 단자를 튜브 끝단에 부착하였다. BSCCO 제조 공정에 있어서 몰드의 예열온도, 용융온도, 몰드 회전속도 등의 변수를 조절하여 최적의 조건을 확립하였다. 제조한 BSCCO 튜브의 임계전류($I_c$)와 임계전류밀도($J_c$)는 77K에서 536A와 $205A/cm^2$ 이었다. 본 연구에서는 BSCCO 2212 튜브를 제조하는 공정조건 변화와 각 조건에서 제조된 BSCCO 2212 튜브의 전기적 특성 및 그에 따른 분석에 대해 기술하였다.

• Journal of the Korean institute of surface engineering
• /
• v.46 no.5
• /
• pp.181-186
• /
• 2013

We performed plasma spraying for 2001 (Bi:Cu = 2:1), 0212 (Sr:Ca:Cu = 2:1:2) oxide powders. $Bi_2Sr_2CaCu_2Ox$ (2212) superconductor has been prepared by PMP-AT (partial melting process-annealing treatment). The 2212 phase is synthesized between Sr-Ca-Cu oxide coating layer (0212) and Bi-Cu oxide coating layer (2001) by movement of partial melted Bi on 2001 layer and the diffusion reaction (Cu, Sr, Ca) after PMP-AT. There are two different coating layers on joining process. The one is ABAB coating layers and the other is BAAB coating layers by arrangement of 2001 (A), 0212 (B) layers. We performed heat treatment these two different coating layers processes under same PMP-AT conditions. We obtained Bi-2212 superconducting layers at each experimental condition, and the result of MPMS, the critical temperature was showed about 78 K. But the microstructure images and result of EDS as each experimental variable were showed about the qualitatively different Bi-2212 superconducting phases. We also deduced the generation mechanism of Bi-2212 superconducting layer as a result of these experimental data, microstruc ture images, EDS data and phase diagram.

• 한국초전도학회:학술대회논문집
• /
• v.16
• /
• pp.70-70
• /
• 2006

• 한국초전도학회:학술대회논문집
• /
• v.16
• /
• pp.92-92
• /
• 2006