• 한국표면공학회지
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• 제51권3호
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• pp.149-156
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• 2018

The corrosion and strength degradation characteristics of 1.25Cr-0.5Mo steels were studied under $650^{\circ}C$ in $76%N_2+6%O_2+16%CO_2+2%SO_2$ gas condition up to 500 hrs. Corroded specimens were characterized by weight gain, scanning electron microscope(SEM), energy dispersive X-ray spectroscopy(EDS), and X-ray diffraction(XRD). The tensile test was conducted to evaluate the mechanical strength and fracture mode with corrosion at high temperature. As the results of the experiments, thick Fe-rich oxide layers over $200{\mu}m$ were formed on the surface within 500 hrs. The thick oxide layers are formed with reduction of the cross-sectional area of the specimens. Thus, the strength tended to decrease with reduction of the cross-sectional area.

• 한국표면공학회지
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• 제51권6호
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• pp.354-359
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• 2018

NaCl-induced hot corrosion behavior of ASTM T22 (Fe-2.25Cr-1Mo), T91 (Fe-9Cr-1Mo), T92 (Fe-9Cr-1.8W-0.5Mo), 347HFG (Fe-18-Cr-11Ni), and 310H (Fe-25Cr-19Ni) steels was studied after spraying NaCl on the surface. During corrosion at $600-800^{\circ}C$ for 50-100 h, thick, non-adherent, fragile, somewhat porous oxide scales formed. All the alloys corroded fast with large weight gains owing to fast scaling and destruction of protective oxide scales. Corrosion rates increased progressively as the corrosion temperature and time increased. Corrosion resistance increased in the order of T22, T91, T92, 347HFG, and 310H, suggesting that the alloying elements of Cr, Ni, and W beneficially improved the corrosion resistance of steels. Basically, Fe oxidized to $Fe_2O_3$, and Cr oxidized to $Cr_2O_3$, some of which further reacted with FeO to form $FeCr_2O_4$ or with NiO to form $NiCr_2O_4$.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 추계학술대회논문집A
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• pp.210-215
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• 2001

The ferritic 2.25CrMo steel has been used for high temperature structure applications such as turbine rotors, boilers and pressure vessels in fossil plant and petroleum chemical facilities. However, this steel is known to result in aging degradation due to temper embrittlement, carbide induced brittleness and softening of matrix after long time exposure to high temperature. This research investigated the microstructural and mechanical changes after artificial degradation treatment and evaluated the degree of degradation by several nondestructive methods. The decrease of electrical resistivity and increase of magnetic Barkhausen noise(RMS voltage) with increasing aging time were observed. The change of electrical resistivity and Barkhausen noise showed a good correlation with the ductile-brittle transition temperature.

• 열처리공학회지
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• 제30권2호
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• pp.43-52
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• 2017

Heat treatment condition for dissolution of the M23C6 carbides in 2.25Cr-1Mo-V-Ti material for thermal power plant tube was investigated using a dilatometer method. 2.25Cr-1Mo-V-Ti material was heat-treated at $900{\sim}1,100^{\circ}C$ for 0, 10, 30 min to find the proper dissolution condition of M23C6 carbides. The phase identification and volume fraction of the carbide were measured by using OM, SEM, EBSD and TEM analysis. Optimal heat treatment condition of M23C6 carbide dissolution was selected by predicting dissolution temperature of carbide using Bs points appeared at dilatometer curve. Experimental results showed that the conditions of carbide dissolution was 900, 1,000, $1,100^{\circ}C$ for 30 min. Eventually, the optimal heat treatment condition for dissolution was 30 min at $1,000^{\circ}C$ considering the minimum coarsening of Austenite grain size.

• 한국공작기계학회논문집
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• 제10권3호
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• pp.61-67
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• 2001

The remaining life estimation for the aged component is very important because mechanical properties of the compo-nents are degraded with time of service exposure in high temperature etc. The destructive method is widely used for the estimation of material degradation, but it has a difficulty in preparing specimens from in-service industrial facilities. In order to evaluate the feasibility of ultrasonic evaluation method for properties of high temperature materials, 2.25Cr-1Mo steel specimens which were prepared by the isothermal aging heat treatment at 63$0^{\circ}C$ were evaluated by ultra-sonic measurements investigating the change of velocities and attenuation coefficient. In this results, attenuation coefficient was found to be sensitive to material degradation mainly attributed to the change of grain size and the precipitation of impurities in grain boundaries, but velocity was not for all specimens.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집A
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• pp.517-522
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• 2001

The purpose of this study is to investigate the thermal embrittlement and the mechanical properties of 2.25Cr-1Mo steel aged at high temperature and stress for 250 hours. Original, aged artificially material were tested to obtain the hardness and impact absorbed energy. Hardness and impact absorbed energy decreased with the increasing aging time. The carbide morphology with the thermal embrittlement was found to contribute to the mechanical property change by X-Ray diffraction method.

• 대한기계학회논문집A
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• 제24권7호
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• pp.1771-1778
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• 2000

The purpose of this study is to investigate the thermal embrittlement and the mechanical properties of 2.25Cr-1Mo steel aged at high temperature for the extended periods. Original, aged artificiall y and used material were tested to obtain the tensile strength, hardness and impact absorbed energy. Tensile strength, hardness and impact absorbed energy decreased with the increasing aging time. The carbide morphology with the thermal embrittlement was found to contribute to the mechanical property change by X-Ray diffraction method.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집A
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• pp.280-285
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• 2000

It is very important to evaluate the surface or subsurface microstructure because of their influences on mechanical properties of materials. Surface SH-wave which is horizontally polarized shear wave traveling along near surface and subsurface layer is an attractive technique for material evaluation. The destructive method is widely used for the estimation of material degradation but it has a great difficulty in preparing specimens from in-service industrial facilities. In this study, nondestructive evaluation for degraded structural materials used at high temperature though surface SH-wave method is discussed. 2.25Cr-1Mo steel specimens which were prepared by the isothermal aging heat treatment at $650^{\circ}$ were evaluated though ultrasonic nondestructive evaluation techniques investigating the change of sound velocity, attenuation coefficient and amplitude spectra. In addition, it has verified experimentally the frequency-dependence of attenuation coefficient though wavelet analysis method.

• 대한기계학회논문집A
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• 제20권5호
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• pp.1372-1381
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• 1996

As recieved boiler tuve steel was aged artificially at $650^{\circ}C$ and$690^{\circ}C$ for various time duration to simulate the material deterioration which could be occurred during the operation of fossiol power plants. And the tensile tests, the microhardness tests and the characterization of carbides formed in the aging process were performed to asses the relationship between the mechanical properties and the effect of thermal aging. Furthernore, the amout of Mo-rich carbide were investigated by ondestructive method by noticing the fact that formation of Mo-rich carbide were investigated by ondestructive melthod by noticing the fact that formation of Mo-rich carbides($Mo_6C$) which stabilizes lastly affects the mechanical properties. It was known that the microhardness results of service exposed materials were similar to the ones which are aged at $650^{\circ}C$. The room temperature measurement showed small variation in the yield points and ultimate strength in materials aged at $650^{\circ}C$. Those properties at $540^{\circ}C$ showed the abrupt decrease compared with as received material even if short aging time. And it was found that $650^{\circ}C$ $690^{\circ}C$ aging cause different effects on mechanical properties, although the temperature time parameters(LMP;Larson-Miller parameter) are same. And it was concluded that the aigng at $650^{\circ}C$ is more appropriate to simulate the service exposed condition. Finally, the relationship between high temperature tensile properties and Ip values were established, which offers a potential way of reliability tests onthe power plant components.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2005년도 추계학술발표대회 개요집
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• pp.65-66
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• 2005

In order to evaluate disbonding properties caused by hydrogen on the Electro Slag Strip Welding for 1.25Cr-0.5Mo steel, two kinds of welding consumables were selected and tested under the disbonding condition of $97.2kgf/cm^{2}$ at $425^{\circ}C$. Chemical composition of the welds showed that they have similar chemical compositions. The microsturucture investigation, however, indicated that 'A' weld has high ratio of coarse grain area, while B weld has low. Disbonding results showed that high ratio coarse grain welds showed unacceptable, while low ratio coarse grain welds showed acceptable.