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Geochemical Evolution and Deep Environment of the Geothermal Waters in the Bugok Area: Reconsideration on the Origin of Sulfate-type Geothermal Water (부곡 지열수의 심부환경과 지화학적 진화: 유황형 지열수의 생성과정 재해석)

  • 고용권;윤성택;김천수;배대석;박성숙
    • Economic and Environmental Geology
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    • v.34 no.4
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    • pp.329-343
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    • 2001
  • The deep environment and geochemical evolution of the Bugok geothennal waters, located in the Kyeongnam Province, was re-interpreted based on the hydrochemical and isotopic data published by Yun et al. (1998). The geothermal waters of the Bugok area is geochemically divided into three groups; Geothennal water I, II and III groups. Groups I and II are geochemically similar; high temperature (55.2-77.2$^{\circ}$C) and chemically belonging to Na-S04 types. However, pH and Eh values are a little different each other and Group II water is highly enriched in S04 compared to Group I water. Group III water, occurring from peripheral sites of the central part of the geothennal waters, shows temperature range of 29.3 to 47.0$^{\circ}$C and belongs to $Na-HCO_3-S0_4$ types. The deep environment and geochemical evolution of the Bugok geothennal waters, showing the diversity of geochemistry, can be interpreted as follows; I) Descending to great depth of meteoric waters that originated at high elevation and reacting with sediments and/or granites in depth. The $S0_4$ concentration of the waters has been increased by the dissolution of sulfate minerals in sediments. 2) During the continuous descending, the waters has met with the reduction environment, producing the $H_2S$ gas due to sulfate reduction. The waters has been heated up to 130$^{\circ}$C and the extent of water-rock reaction was increased. At this point, pH of waters are increased, S04 concentration decreased and calcite precipitated, therefore, the waters show the $Na-S0_4$ type. 3) Ascending of the geothennal waters along the flow path of fluids and mixing with less-deeply circulated waters. The $S0_4$ concentration is re-increased due to the oxidation of $H_2S$ gas and/or sulfide minerals in sediments. During continuous ascending, these geothennal waters are mixed with shallow groundwater.

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The Effects of Pre-slaughter Stress and Season on the Activity of Plasma Creatine Kinase and Mutton Quality from Different Sheep Breeds Slaughtered at a Smallholder Abattoir

  • Chulayo, A.Y.;Muchenje, V.
    • Asian-Australasian Journal of Animal Sciences
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    • v.26 no.12
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    • pp.1762-1772
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    • 2013
  • The objective of the current study was to determine the effect of pre-slaughter stress, season and breed on the activity of plasma creatine kinase (CK) and the quality of mutton. One hundred and seventy-three (173) castrated sheep from Dormer (DM), South African Mutton Merino (SAMM), Dorper (DP) and Blackhead Persian (BP) sheep breeds were used in the study. The animals were grouped according to age-groups as follows: Group 1 (6 to 8 months), Group 2 (9 to 12 months) and Group 3 (13 to 16 months). Blood samples were collected during exsanguinations using disposable vacutainer tubes for CK analysis. Representative samples of the Muscularis longissimuss thoracis et. lumborum (LTL) were collected from 84 castrated sheep, of different breeds (28 per breed) 24 h after slaughter. The following physico-chemical characteristics of mutton were determined; meat pH ($pH_{24}$), color ($L^*$, $a^*$ and $b^*$), thawing and cooking losses and Warner Braztler Shear Force (WBSF). The activity of plasma CK was significantly higher (p<0.001) in summer ($1,026.3{\pm}105.06$) and lower in winter ($723.3{\pm}77.75$). There were higher values for $L^*$ ($33.7{\pm}0.94$), $b^*$ ($11.5{\pm}0.48$) and WBSF ($29.5{\pm}1.46$) in summer season than in winter season; $L^*$ ($29.4{\pm}0.64$), $b^*$ ($10.2{\pm}0.33$) and WBSF ($21.2{\pm}0.99$). The activity of plasma CK was influenced by the type of breed with Dormer having the highest (p>0.001) levels ($1,358.6{\pm}191.08$) of CK. South African Mutton Merino had higher values for $pH_{24}$ ($5.9{\pm}0.06$), $L^*$ ($34.2{\pm}0.97$), $b^*$ ($12.2{\pm}0.50$) and WBSF ($26.8{\pm}1.51$) and Blackhead Persian had higher values ($35.5{\pm}2.17$) for cooking loss (CL%) than the other breeds. Computed Principal Component Analyses (PCA) on the activity of plasma CK and physico-chemical characteristics of mutton revealed no correlations between these variables. However, positive correlations were observed between $pH_{24}$, $L^*$, $a^*$, $b^*$, CL% and WBSF. Relationships between pre-slaughter stress, CK activity and physico-chemical characteristics of mutton were also observed. It was therefore concluded that although mutton quality and creatine kinase were not related, pre-slaughter stress, season and breed affected the activity of creatine kinase and mutton quality.

Surgical Experience of Pathological Stage IIIB Non-Small Cell Lung Cancer (병리학적 병기 IIIB폐암의 외과적 체험)

  • 백희종;이종목
    • Journal of Chest Surgery
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    • v.29 no.5
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    • pp.517-523
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    • 1996
  • From May 1988 to June 1994, )73 patients underwent exploratory thoracotomy for resection of non- small cell lung cancer, and 48 patients staged pathologically as lIIB were analyzed. 74 lesions were involvement of great vessel (n=26), heart (n=5), ipsilateral lung metastasis(n=4), esophagus (n=4), carina(n=3), mediastinum (n=2), trachea(n=1), spine (n=1) and 13lourO seeding(A=15). N3 lesions were involved in 6 patients. Extended pulmonary resection with radical mediastinal node dissection was possible in 25 patients, and exploration only was performed in 23 patients. The most frequent cause of unresectability was pleural seeding. Postoperative morbidity was )2 % (8125) and mortality was 16 % (41 25) in resected group. The adjutant therapy was given to 37 patients. The 1 year and 3 year survival for resected group ncluding operative deaths was 57.2%, and 2).8 % (median 15 months), but 48.4%, and 0 % (median 7 months) for exploration only group (Log-Rank test, p : 0.17). Our results suggest that extended pulmonary resection might be helpful for carefully selected patients with 74 non-small cell lung cancer, but meticulous preoperative work-up for staging, especially to detect pleural seeding and Invasion to the irlediastinal structures is a prerequisite to avoid unnecessary thoracotomy.

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Nucleophilic Substitution at a Carbonyl Carbon Atom (IX). Solvolysis of 2-Furoyl Chloride and 2-Thenoyl Chloride in Binary Mixtures (카르보닐탄소원자의 친핵성 치환반응 (제9보). 이성분 혼합용매에서 2-염화테노일 및 2-염화퓨로일의 가용매분해반응)

  • Son Jin-Eon;Sang-Kee Yoon;Ikchoon Lee
    • Journal of the Korean Chemical Society
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    • v.23 no.6
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    • pp.339-348
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    • 1979
  • The kinetics of the solvolysis of 2-furoyl chloride and 2-thenoyl chloride in $MeOH-H_2O,\;EtOH-H_2O,\;(Me)_2CO-H_2O,\;MeCN-H_2O$ and MeCN-MeOH has been investigated. The rates were faster in protic solvents than in aprotic solvents. This was caused by the bond breaking of leaving group through hydrogen-bonding solvation of protic solvents. In MeCN-M$\'{e}$OH the rate in MeOH rich solvents was faster than in MeCN rich solvents by the specific solvation of alcoholic hydrogen and there was a maximum rate of reaction at MeOH mole fraction of 0.8. The reaction rates of solvolysis were considerably slower than those of benzoyl chloride owing to the electron withdrawing effect of thienyl and furyl groups. It was concluded that solvolytic reaction proceeds via a dissociative $S_N2$ mechanism in which bond-breaking precedes bond-formation at the transition state.

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The Mechanism of the Photocyclization of N-(2-Haloarylmethyl)Pyridinium and N-(arylmethyl)-2-Halopyridinium Salts

  • Yong-Tae Park;Chang-Han Joo;Chung-Do Choi;Kum-Soo Park
    • Bulletin of the Korean Chemical Society
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    • v.12 no.2
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    • pp.163-169
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    • 1991
  • The photochemical and photophysical properties of N-(2-haloarylmethyl)pyridinium, N-(arylmethyl)-2-halopyridinium, N-(2-haloarylmethyl)-2-halopyridinium salts and N-(2-halobenzyl)-isoquinolinium salt are studied. The pyridinium salts photocyclize to afford isoindolium salts, while the isoquinolium salts do not. In the photocyclization of N-(2-chlorobenzyl)-2-chloropyridinium salts, pyrido[2,1-a]-4-chloroisoindolium salt is formed by the cleavage of chlorine of pyridinium ring. This indicates that the excited moiety is not the phenyl ring, but the pyridinium ring. The triplet states of the pyridinium salts are believed to be largely involved in the photocyclization, since oxygen retards most of the reaction. Some assistance of a ${\pi}$-complex between the excited chlorine moiety of the salt and phenyl plane of the same molecule is required to explain the reactivity of the salts. N-(Benzyl)-2-chloropyridinium salt is two times more reactive than N-(2-chlorobenzyl)pyridinium salt. N-(Benzyl)-2-chloropyridinium salt can form ${\pi}-complex$ effectively because of the electron-rich phenyl group. The ${\pi}$-complex affords an intermediate, phenyl radical by cleaving the chlorine atom. The photocyclized product, isoindolium salt is obtained by losing the hydrogen atom from the phenyl radical. The reactive pyridinium salts 1a, 2a and 3a have a low fluorescence quantum yield (${\Phi}F$ < 0.01) and a higher triplet energy (ET > 68 kcal/mole) than the unreactive quinolinium salt. The unreactivity of isoquinolinium salt can be understood in relation to its high fluorescence quantum yield and its low triplet energy $(E_T = 61 kcal/mole).$.

A Study on the Effect of Moisture Content of Wood upon the Absorption on Zinc Chloride Solution (침지처리법에(浸漬處理法)있어서 목재함수량(木材含水量)이 염화아연 흡수율(吸收率)에 미치는 영향(影響))

  • Shim, Chong-Supp;Shin, Dong-So
    • Journal of the Korean Wood Science and Technology
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    • v.10 no.3
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    • pp.133-134
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    • 1982
  • This experiment has been made to investigate the absorption of watersoluble zinc chloride by Pinus densiflora S. et Z. at different moisture content, under soaking process, to decide the optimum content condition for the maximum absorption of zinc chloride by the wood tested and to investigate the concentration of zinc chloride affecting each moisture content of wood. Material was cut in the Dept. of Forest, College of Agr. S.N.U. Suwon, Korea. Sample was divided into sap and heartwood group and cut $2{\times}2{\times}2\;cm$ in size, having exact three dimensions, using the part of D.B.H. The numbers of sample were 20 pieces for each moisture content condition for both sap and heartwood. Especially, the samples were protected from exposure to keep moisture content in green condition. The ranges of moisture content tested were as the table 3 and 4. The conclusions were as follows: 1. With 3% zinc chloride solution, the rate of absorption decreased with the time increased, if the air seasoned Korean red pine (Pinus densiflora S. et Z.) was treated in steeping process. Initial absorption for 30 minutes was more than 50% of total absorpon for 24 hours. 2. Rate of absorption was same under the green condition, while rate of absorption under the moisture content 7 to 30% varied. 3. Although it was not quite proportional change in the absorption with the difference of moisture content, the great change in the absorption occured by seasoning. With exception sap green condition, sapwood twice more permeable than the heartwood in the oven dried condition and it has been observed the nearly same amount of absorption at the moisture content of 7%, 10% and 15% respectively in heartwood. 4. It was better from water in wood from view-point of absorption of zinc chloride solution, but it was difficult practically to obtain the smallest moisture content, and then it was decided that values of allowable moisture content, on the basis of mean absorption, were 15% to 20% in the sapwood, and in the heartwood, 10% to 15%. The mean absorption for each moisture content in the sap and the heartwood were as following. 5. In general, the concentration of zinc chloride after steeping was nearly same between moisture content and sap and heartwood respectively.

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Sugar Content and Protein Fractionation in Human Pleural Fluid (늑막액의 당 및 단백분획상)

  • Kim, W.J.;Ahn, Y.S.;Kim, H.Y.;Lee, W.Y.
    • The Korean Journal of Pharmacology
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    • v.15 no.1_2 s.25
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    • pp.1-5
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    • 1979
  • Previous studies concerning the usefulness of pleural fluid glucose levels in differentiating causes of pleural effusions have been conflicting. Gelenger and Wiggers (1949), Calnan et al(1951) and Barber et al(1957) concluded that the lower the level of pleural fluid glucose, the more likely was tuberculosis, and that tuberculosis was unlikely if the pleural fluid glucose level was more than 80 mg/100 ml. Light and Ball(1973), however, reported that in the great majority of tuberculous pleural fluids the glucose concentration was high rather than low, concluded that the pleural fluid glucose levels were not useful in the differential diagnosis of pleural effusion. In this study, pleural fluid glucose was determined in 46 pleural effusions from various causes to evaluate the usefulness in the differential diagnosis of pleural effusion. In addition, the protein concentration and the electrophoretic patterns of protein and amylases in pleural fluid was compared with that of serum. And the results were as follows. 1. The mean glucose concentration of pleural fluid was 80.8 mg/100 ml in 22 tuberculous origin, 92.5 mg/100 ml in 12 cancer patient and 70.4 mg/100 ml in 10 undiagnosed cases. In 2 cases of paragonimiasis the pleural fliud glucose levels were low (mean, 32.0 mg/100 ml). The percentage of pleural fluid protein to serum is about 75% in all disease groups and the protein level of tuberculous pleural fluid was significantly correlated with that of serum. 2. The disc eletrophoretic patterns of pleural fluid were almost similar with that of serum in all disease groups but the prealbumin fraction was not observed in pleural fluid. 3. With the isoelectric focusing, 4 to 7 isoamylase was observed in serum and the isoelectric point was ranged from pH 5.8 to 7.8 and isoelectic point of main fracticn is pH 7.2. The isoelectic focusing patterns of amylase of pleural fluid were identical to that of serum in all disease group. With the above results it is concluded that the pleural fluid is exudate of serum and that the glucose levels of pleural fluid are not useful in the differential diagnosis of pieural effusions.

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Effects of Leukocyte Depleted Priming Solution on Cardiopulmonary Edema by Extracorporeal Circulation (백혈구제거 혈액성 충진액이 체외순환 후 심폐부종에 미치는 영향)

  • Kim, Si-Hoon;Kim, Young-Du;Jin, Ung;Jo, Keon-Hyun
    • Journal of Chest Surgery
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    • v.34 no.9
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    • pp.704-710
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    • 2001
  • Background: Extracorporeal circulation using pump-oxygenator is an inevitable process to keep vital sign during cardiac arrest for open heart surgery. However, the diversion of blood through nonendothelialized channels appears to stimulate inflammatory response, and leukocyte activation may lead to cardiopulmonary edema. Our study evaluated the effect of leukocyte-induced cardiopulmonary edema using three different pump-oxygenator priming solutions; non-hemic crystalloid solution ; leukocyte-depleted homologous blood; non leukocyte-depleted homologous blood in priming solutions. Material and Method: Each different priming solution was used on five dogs, and the effect of leukocyte-induced cardiopulmonary edema during cardiopulmonary bypass(CPB) was evaluated. For each dog after 2 hours of exracorporeal circulation and another 4 hours of post-pump period, the dog was sacrificed and its heart and lung tissues were obtained for measuring Wet/Dry ratio. Arterial $O_2$partial pressure(PaO$_2$) and $CO_2$partial pressure(Pa$CO_2$) were checked. For the evaluation of ventilatory function, $CO_2$partial pressure difference between arterial blood (Pa$CO_2$) and exhaled air(Et$CO_2$) was measured. Result: 1. No significant difference was seen in arterial PaO$_2$and Pa$CO_2$among groups. 2. Ventilatory function evaluated by Pa$CO_2$and Et$CO_2$showed no significant difference between non-hemic and blood-mixed priming solution (P<0.05). 3. Cardiac and lung Wet/Dry ratios were remarkedly lower in the leukocyte-depleted group. There was no significant difference between the non-hemic and blood-mixed groups. Conclusion: Based upon this result, we concluded that the leukocyte depletion from homologous blood of CPB priming solution has a beneficial effect in reducing cardiopulmonary edema compared with non leukocyte-depleted or crystalloid priming solutions.

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A Study on the space organization of the CDI in $Lyc\acute{e}es$ (학교도서관 공간계획 방향에 대한 연구 - 프랑스 고등학교의 지식정보센터(CDI)를 중심으로 -)

  • Kim, Kyung-Ho;Yeom, Dae-Bong;Kim, Jong-Seok
    • Journal of the Korean Institute of Educational Facilities
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    • v.13 no.2
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    • pp.42-49
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    • 2006
  • We have analysed the use and organization of space in the Centres des Documentations et de Informations(CDI) in lycees in France with the equivalent information centres. The majority of CDI are located in close proximity to the Academic staff and provide easy student access. The CDI provide not only books but also reviews, magazines and CD-Rom. This information is very important to pupils both in the pursuit of their higher studies and also with their future professional life as there is also careers information available to be discussed regularly with the careers advisor. The function of the CDI is not only to provide information. As part of the curriculum there are classes on how to access the information available in the CDI as well as Seminars and Audio-Visual courses. This management makes it possible for the CDI to operate, not only as a school library but also as a multi-function centre of documentation and information; a variety of spaces are also available: a room for private/small group study. A computer room (as well as a research corner), a reading room, monthly review room, photocopy room, rest room, exhibition room, careers information room, audio visual room etc. The results of this study can be used as essential information during the space planning of Korean school libraries in the future.

Environmental Dependence of Galactic conformity in the Virgo Cluster

  • Lee, Hye-Ran;Lee, Joon Hyeop;Jeong, Hyunjin;Park, Byeong-Gon
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.1
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    • pp.77.3-78
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    • 2015
  • It is known that the galaxy evolution by direct interaction between galaxies is most active in a galaxy group. As a result, the satellite galaxies are closely related to their central galaxy in properties such as morphology, color and star formation rate (so-called 'galactic conformity'). However, it is not clear yet whether such conformity between galaxies is found in a galaxy cluster. Recently, Lee et al. (2014) have found a measurable correlation between the colors of bright galaxies and the mean colors of their faint companions in a cluster WHL J085910.0+294957 at z = 0.3, using the photometrically-selected cluster members. They suggest that such correlation may be the vestige of infallen groups in the cluster as one possibility. In order to confirm the small-scale conformity in galaxy clusters with higher reliability, we study the Virgo cluster using the Extended Virgo Cluster Catalog (EVCC). The cluster members are selected spectroscopically unlike in WHL J085910.0+294957. We examine the galactic conformity in two distinct areas of the Virgo cluster: the inner X-ray emission region and its outer region. We find a marginal conformity in color (> $2{\sigma}$ significance to bootstrap uncertainty) in the outer region, while no meaningful signal of small-scale conformity is detected in the X-ray emission region. We discuss the implication of this result, focusing on cluster mass assembly and cluster environmental effects on galaxy evolution.

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