• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2023년도 봄 학술논문 발표대회
• /
• pp.53-54
• /
• 2023

In recent decades, climate change has become an issue of global importance. The calcium sulfoaluminate (CSA) cement emits lower CO₂ than the Portland cements while manufacturing. However, ettringite, which is a main hydration product of CSA cement, starts dehydrating at a temperature above 100℃, hence it may limit the CSA cement for high temperature application. Recently, an early carbonation curing of cement-based material has been extensively studied in terms of carbon neutralization. The carbonation curing of CSA cement has a potential to transform the AFt and AFm phases into calcium carbonate, and the transformation of unstable hydrates to stable hydrates can increase the resistance to elevated temperature. This review study summarizes and discusses the carbonation curing effect of CSA cement and the thermal stability of CSA cement exposed to elevated temperatures.

• Restorative Dentistry and Endodontics
• /
• 제41권3호
• /
• pp.167-175
• /
• 2016

Objectives: Endodontically treated teeth with insufficient tooth structure are often restored with esthetic restorations. This study evaluated the cytotoxicity and biological effects of yttria partially stabilized zirconia (Y-TZP) blocks in combination with several dental cements. Materials and Methods: Pairs of zirconia cylinders with medium alone or cemented with three types of dental cement including RelyX U200 (3M ESPE), FujiCEM 2 (GC), and Panavia F 2.0 (Kuraray) were incubated in medium for 14 days. The cytotoxicity of each supernatant was determined using 3-(4,5-dimethylthiazole- 2-yl)-2,5-diphenyltetrazolium bromide (MTT) assays on L929 fibroblasts and MC3T3-E1 osteoblasts. The levels of interleukin-6 (IL-6) mRNA were evaluated by reverse transcription polymerase chain reaction (RT-PCR), and IL-6 protein was evaluated by enzyme-linked immunosorbent assays (ELISA). The data were analyzed using one-way ANOVA and Tukey post-hoc tests. A p < 0.05 was considered statistically significant. Results: The MTT assays showed that MC3T3-E1 osteoblasts were more susceptible to dental cements than L929 fibroblasts. The resin based dental cements increased IL-6 expression in L929 cells, but reduced IL-6 expression in MC3T3-E1 cells. Conclusions: Zirconia alone or blocks cemented with dental cement showed acceptable biocompatibilities. The results showed resin-modified glass-ionomer based cement less produced inflammatory cytokines than other self-adhesive resin-based cements. Furthermore, osteoblasts were more susceptible than fibroblasts to the biological effects of dental cement.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2023년도 봄 학술논문 발표대회
• /
• pp.305-306
• /
• 2023

Recently, as the radioactive waste disposal facility becomes scarce, the importance of efficient disposal of waste from nuclear power plants is increasing. This study was conducted to utilize radioactive waste concrete powder as solidifying agent for radioactive waste treatment. Paste with an age of more than one year was used with a disk mill to have a particle size of 150㎛ or less, and treated at temperatures of 500℃, 600℃ and 700℃ for 2 hours. In order to simulate the radioactive cement powder, aqueous solutions of Di-water, CsCl 1M, SrCl₂ 1M and CoCl₂ 1M were used as blending water at W/C 0.7 and to improve fluidity, polycarboxylate type superplasticizer was used at 0.4 wt.% based on the weight of recycled cement paste powder. Characterisation was carried out using vicat method, strength and density.

• 한국세라믹학회지
• /
• 제41권10호
• /
• pp.749-755
• /
• 2004

불화규산($H_2SiF_6$)은 인산 혹은 불산 제조공정에서 발생되는 사불화규소($SiF_4$)의 흡수공정에 의해 수용액 상태로 회수된다. 불화규산과 금속염의 반응에 의해 생성된 규불화염을 시멘트에 첨가하면 시멘트와의 특이 수화반응에 의해 독특한 물성을 발휘된다. 본 연구에서는 상기 공정에 의해 회수된 불화규산(농도 : $25\pm2\%$)과 금속염을 반응시켜 3가지 농도($4\%,\;6\%,\;8\%$)의 2성분 규불화염계 혼화제(MZ)를 제조하고, 시멘트 중량의 동일 첨가량($C\times1.0\%$)에서 시멘트 수화반응 및 수밀성에 대해 MZ의 농도변화에 따른 효과를 관찰하였다. MZ가 첨가된 시멘트 수화과정중 $CaF_2$와 같은 난용성 금속불화물과 가수분해에 의한 가용성 실리카가 새로이 생성되었다. MZ가 첨가된 경화시멘트의 총 공극율은 난용성 금속불화물의 충전작용과 가용성 실리카의 포졸란 작용에 의해 감소되었다. 궁극적으로 시멘트와 MZ간의 특이 수화반응에 의해 MZ가 첨가된 시멘트 경화체의 수밀성이 개선되는 것으로 나타났다.

• 한국세라믹학회지
• /
• 제39권2호
• /
• pp.178-183
• /
• 2002

금속염으로 산화아연(ZnO)과 규불화수소산($H_2SiF_6$)을 이용하여 용액법으로 규불화아연($ZnSiF_6$, 농도 15%)을 제조하고 이를 시멘트용 혼화제로 첨가하여 시멘트의 유동성과 수화특성에 미치는 영향을 파악하였다. 규불화아연의 첨가량을 시멘트량 대비 1.0∼4.0%로 증가시켜 첨가한 시멘트 페이스트의 초기 유동성과 유동성의 경시변화를 측정하였다. 초기 유동성은 mini-slump 시험을 통해 평가하였고, 유동성의 경시변화는 slump loss 시험을 통해 평가하였다. 또한 규불화아연을 시멘트에 1.0∼3.0%로 첨가하였을 때 시멘트의 응결시간에 미치는 영향과 시멘트 수화열 변화에 미치는 영향을 파악하였다. 시멘트 페이스트의 유동성은 규불화아연이 2.1% 첨가되었을 때 가장 높게 나타났으나 경시변화는 다소 큰 것으로 나타났다. 시멘트 응결시간은 규불화아연의 첨가량 증가에 따라 지연되는 특성을 보였으며, 시멘트 수화열은 첨가량에 비례하여 감소되는 경향을 보였다.

• 대한토목학회논문집
• /
• 제31권3A호
• /
• pp.251-260
• /
• 2011

본 연구는 천연마섬유보강 시멘트 경화체와 폴리올레핀계 매크로섬유의 부착강도, 계면인성, 미세구조 분석을 포함한 부착 특성에 미치는 천연마섬유의 효과를 제시하였다. 다양한 조건에서의 폴리올레핀계 매크로섬유 인발시험의 실험적 결과를 보고하였다. 천연마섬유의 혼입률은 0.1%에서 0.2%까지를 배합설계에 적용하였다. 부착시험은 천연마섬유보강 시멘트 경화체에서 폴리올레핀계 매크로섬유의 부착특성을 측정하기 위하여 실시하였다. 시험결과 천연마섬유의 혼입은 폴리올레핀계 매크로섬유와 시멘트 경화체의 계면강화에 효과적이었다. 폴리올레핀계 매크로섬유와 천연마섬유보강 시멘트 경화체의 부착강도 및 계면인성은 섬유의 혼입률이 증가할수록 증가하였다. 미세구조분석은 섬유의 인발시험결과로부터 획득한 부착 메커니즘을 확인할 수 있었다.

• Computers and Concrete
• /
• 제19권1호
• /
• pp.19-31
• /
• 2017

This paper uses modelling and experiment to perform a quantitative analysis for the gypsum and ettringite formations in cement pastes subjected to sulfate attack. Firstly, based on Fick's law and chemical reaction kinetics, a diffusion model of sulfate ions in cement pastes is proposed, and then the model of the gypsum and ettringite formations is established to analyze its contents in cement pastes with corrosion time. Secondly, the corrosion experiment of the specimens with cement pastes immersed into 2.5%, 5.0% and 10.0% $Na_2SO_4$ solutions are carried out, and by using XRD-Rietveld method, the phases of powder samples from the specimens are quantitatively analyzed to obtain the contents of gypsum and ettringite in different surface depth, solution concentration and corrosion time. Finally, the contents of gypsum and ettringite calculated by the models are compared with the results from the XRD experiments, and then the effects of surface depth, corrosion time and solution concentration on the gypsum and ettringite formations in cement pastes are discussed.

• 한국농공학회논문집
• /
• 제54권1호
• /
• pp.83-91
• /
• 2012

In this study, the compressive strength characteristics of lime-cement-soil mixtures, composed of lime, soil, and a small amount of cement, were investigated by performing the unconfined compression tests, the freezing and thawing tests, the wetting and drying tests and the permeability tests. The specimens were made by mixing soils with cement and lime. The cement contents were 0, 6, 8 and 10 %, and the lime contents were 2, 4, 5, 10, 15 and 20 % in weight. Each specimen was cured at constant temperature in a humidity room for 3, 7 and 28 days. The compressive strength characteristics of the lime-cement-soil mixtures were then investigated using the unconfined compression tests, freezing and thawing tests and the wetting and drying tests. Based on the test results, a discussion was made on the applicability of the lime-cement-soil mixtures as a construction material.

• 한국세라믹학회지
• /
• 제47권3호
• /
• pp.216-222
• /
• 2010

Portland cement has been restricted in applications to ecological area because of its environmental harmfulness and the $CO_2$ emission during a production process. Geopolymer materials attract some attention as an inorganic binder due to their superior mechanical and eco-friendly properties. In this study, geopolymer-based cement was prepared by using aluminosilicate minerals (flyash, meta-kaolin) with alkaline-activators and its compressive strength with concentration of alkaline-activators was investigated. Aluminosilicate-based geopolymers were obtained by mixing aluminosilicate minerals, alkaline solution (NaOH or KOH with different concentration) and water-glass under the vigorous stirring for 20 min. Compressive strength after curing at $30^{\circ}C$ for 3 days increased with the concentration of alkaline-activator due to the enhanced polymerization of the aluminosilicate materials and dense microstructure. Aluminosilicate-based geopolymer cement using KOH as an alkaline-activator showed high compressive strength compared with NaOH activator. In addition, geopolymer cement using fly-ash as a raw material showed higher compressive strength than that of meta-kaolin.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
• /
• pp.333-338
• /
• 2001

Fractal geometry is a non-Euclidean geometry which has been developed to quantitative analysis irregular or fractional shapes. Fractal dimension of irregular surface has fractal values ranging from 2 to 3 and of irregular line profile has fractal values ranging from 1 to 2. In this paper, quantitative analysis of crack growth patterns during the fracture processing of fiber-reinforced cement composites based on fractal geometry. The fracture behaviors of fiber reinforced mortar beams subjected to three-point loading in flexure. The beams all had a single notch depth, but varing volume fractions of polypropylene, cellulose fibers. The crack growth behaviors, as observed through the image processing system, and the box counting method was used to determine the fractal dimension, Df. The results showed that the linear correlation exists between fractal dimension and fracture energy of the fiber reinforced cement mortar.