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Synthesis and Electrochemical Characteristics of Lantanium and Neodynium Metal Complexes (란탄늄 및 네오디늄 금속의 착물합성과 전기화학적 특성)

  • Oh, Je Jik
    • Analytical Science and Technology
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    • v.6 no.1
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    • pp.83-92
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    • 1993
  • The electrochemical behaviors of lanthanide ion(La and Nd) and lanthanide complexes with 2, 2, 6, 6-tetramethyl-3, 5-heptanedione(THD), sym-hydroxydibenzo-16-crown-5(HD16C5) and sym-dibenzo-16-crown-5-oxyacetic acid(D16C5A) ligands in acton solution have been investigated by the use of cyclic voltammetry and direct current polarography. The peak potential and peak current, their dependency on the concentration, temperature, the reversibility of the eleotrode reactions are described. The reduction of the lanthanide ions and complexes in 0.05 M TEAP proceeded one-electron step in first step and one two-electron step in second step. These reduction step was irreversible and the reduction current was diffusion controlled. Macrovcyclic crown ethers, sym-hydroxydibenzo-16-crown-5(HD16C5) and sym-dibenzo-16-crown-5-oxyacetic acid(D16C5A), were prepared from 1, 5-bis-(2-hydroxyphenoxy)-3-oxapentane with epichlorohydrin. The voltammetric behaviors of Ln(III)-HD16C5 and Ln-D16C5A complexes in aceton solution have been investigated by the voltammetric method. The composition and stability constants of lanthanide complexes were determined.

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Carcinogenic Potentials of HPV-16 and NNK in Human in Vitro Model (인체 세포 모델을 이용한 HPV-16과 NNK의 발암 잠재력에 관한 연구)

  • 양재호;이세영
    • Toxicological Research
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    • v.12 no.2
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    • pp.271-275
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    • 1996
  • Carcinogenic potential of HPV-16 DNA and NNK in a human keratinocyte cell line was assessed to study effects of viral-chemical interaction. Human cells were transfected with HPV-16 DNA and 6 clonal cell lines were subsequently obtained. Clonal line-3 and 6 at passage 7 showed characteristics of tumor cells such as increases of saturation density, soft-agar colony formation, cell aggregation and foci appearance. Among cells treated with 1$\mu M$, 10$\mu M$, 100$\mu M$ or 1 mM of NNK for 4 weeks, 100$\mu M$ treatment showed most tumorigenic characteristics at passage 7. These results indicate that either HPV-16 or NNK alone is tumorigenic in this in human in vitro model. When cells transfected with HPV-16 were subsequently exposed by 100 uM NNK for 4 weeks, all the clonal cells except clone-1 showed higher levels of tumor cell characteristics than HPV-16 DNA or NNK exposure alone. Clonal line-6, the most tumorigenic cells, showed higher transcriptional level of fibronectin and lower level of TGF-$\beta_1$, as compared to control cells, suggesting that alteration of growth factor or extracellular matrix may play a role in carcinogenesis process induced by HPV-16 and NNK. Taken together, the present study indicates that viral-chemical interactions between HPV-16 DNA and NNK enhance carcinogenic potentials of human cells and implies that smoking among people infected with human papillomavirus may pose an additional risk of causing cancer.

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아랍의 F-16 구매결정으로 살펴 본 F-16의 과거, 현재, 그리고 미래

  • 한국항공우주산업진흥협회
    • Aerospace Industry
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    • v.61
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    • pp.23-25
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    • 1998
  • 미국의 워싱턴포스트지는 지난 5월 12일 중동의 아랍 에미레이트(UAE)가 차세대 전투기로 F-16 80대를 구매하기로 록히드마틴사와 전격 계약하였으며 사업규모는 60억불이라고 보도하였다. 이번에 결정된 차세대 전투기의 후보기종에는 프랑스의 라팔과 유럽연합의 유로파이터, 보잉의 F-15, 록히드 마틴의 F-16이 경합하였으며, ''''97년 9월에 F-15, 유로파이터는 탈락되고 F-16과 라팔기종중에서 최종적으로 성능, 안전성 및 실전사례 평가 등을 고려 결정된 것으로 알려졌다. 본 고에서는 이번 UAE의 대량 구매를 계기로 우리공군의 주력전투기인 F-16의 과거와 현재 그리고 미래에 대해 살펴보고자 한다.

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A Study on Efficient Network Design Scheme for Link-16 Tactical Networks (네트워크 중심전을 위한 LINK-16 시스템에서의 효율적인 네트워크 설계방안 연구)

  • Jang, Jae-Hyeong;Choe, Hyeong-Uk;Jeong, Seung-Seop;Kim, Yeong-Beom
    • 한국ITS학회:학술대회논문집
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    • 2008.11a
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    • pp.118-121
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    • 2008
  • 본 연구에서는 정보통신기술을 활용한 미래전 개념인 네트워크 중심전 (NCW: Network Centric Warfare) 수행에 있어서 세계적으로 가장 널리 쓰이고 있는 Link-16의 기술적 요소들을 물리계층, 데이터링크 계층, 응용계층(전술메시지교환) 측면에서 검토하고 작전 운용 측면에서 Link-16 만의 장점과 한계점을 도출해 보기로 한다. 특히, 군용 전술 네트워크인 Link-16의 경우 통신 보안 및 견고성에 시스템 설계상의 주안점이 주어지기 때문에 비록 낮은 전송속도이지만 Link-16의 전송용량의 적절한 분배와 활용 방안은 매우 중요한 문제이다. 본 연구에서는 Link-16의 타임슬롯 구조, NPG 개념, 멀티네팅 개념을 기반으로 주요 작전을 수행하는데 있어서 네트워크 참가요소 (지상 및 공중 플랫폼)에 효율적인 전송용량 배분을 하기 방안을 제시한다. 여기에 있어서 고려해야 할 요소들로는 불필요한 통신용량할당의 최소화, 네트워크 설계 과정의 간소화, 작전 목적에 대한 충분한 지원, 보안성 유지 등을 들 수 있다.

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Improved H.264/AVC $16{\times}16$ Intra Prediction Scheme (개선된 H.264/AVC $16{\times}16$ 인트라 예측 기술)

  • Yang, Hee-Chul;Yang, Jung-Youp;Jeon, Byeung-Woo
    • Proceedings of the Korean Society of Broadcast Engineers Conference
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    • 2010.07a
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    • pp.285-286
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    • 2010
  • 최근 HDTV, 블루레이 등 고해상도, 고품질 디지털 멀티미디어 응용 기술의 보급으로 인하여, 고해상도, 고품질 비디오 부호화 기술에 대한 중요성이 증가하고 있다. 현재 고해상도 비디오 부호화에 사용되는 H.264/AVC 표준의 인트라 부호화 기술은 인터 부호화 기술의 복잡도가 크게 증가하는 고해상도 영상에서 인터 부호화 기술에 비해 낮은 복잡도를 가진 부호화기 및 복호화기의 구현이 가능하다는 장점을 가지고 있다. 그러나 인트라 부호화 기술은 인터 부호화 기술에 비하여 압축 효율이 매우 낮다는 문제점이 있다. 본 논문에서는 고해상도 영상을 위한 새로운 $16{\times}16$ 블록의 인트라 예측 기술을 제안한다. 실험을 통하여 제안한 새로운 $16{\times}16$ 인트라 예측 기술을 사용할 경우, HD급 고해상도 영상에 대해 평균 2.8%의 부호화 효율을 증가시킬 수 있음을 보여준다.

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Effects of QZ-16 on blood glucose and lipids in Streptozotocin induced diabetic rats

  • Najmi, Abul K.;Pillai, K.K.;Ahmad, Aftab;Aqil, M.
    • Advances in Traditional Medicine
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    • v.5 no.2
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    • pp.144-149
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    • 2005
  • The present study was designed to investigate the hypoglycaemic and hypolipidaemic activities of Qurs-e-Ziabetus 16 (QZ-16) in Streptozotocin (STZ) induced diabetic rats. QZ-16, a polypharmaceutical herbomineral formulation developed on the principles of Unani medicine is used for non-insulin dependent diabetes mellitus (NIDDM). The elevated levels of fasting blood glucose, serum levels of cholesterol, triglycerides and urea observed in rats treated with STZ (55 mg/kg body wt.) were significantly reduced by the treatment of QZ-16 (240 mg/kg, p.o.) and gliclazide (30 mg/kg, p.o.). The reduced HDL cholesterol levels were also increased by the QZ-16 and gliclazide treatments in the STZ induced diabetic rats. These data show that QZ-16 has hypoglycaemic, hypolipidaemic properties in STZ induced diabetic rats.

Effect of Nursery Period on Seedling Growth and Yield in Transplant Rice with Infant Seedling (벼 어린모 육묘일수 연장에 따른 모소질, 본답 생육 및 수량성)

  • 김덕수;김정곤;김제규;한희석;강양순
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.46 no.3
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    • pp.184-188
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    • 2001
  • This study was conducted to find out the basic informations related to the rice cultivation using the infant seedlings. Infant seedlings with different nursery Periods were compared for the growth and grain yield of rice at the National Crop Experiment Station in 1997. The highest sound seedling ratio of 93.9% was observed in 8-day old seedling, followed by 88.9% of 12-day, 82.0% of 16-day, and 80.8% of 20-day, The endosperm remained 52.5% in the 8-day old seedling at transplanting and decreasingly with increasing nursery period. Missing hills at transplanting were more in 16-day and 20-day old seedling than in 8-day and 12-day old seedlings, 5.1-5.2% in 8-day and 12-day growing seedling, 6.7% in 16-day and 7.8% in 20-day old seedling. Rooting ability was observed highest in 8-day, followed by 12-day, 16-day and 20-day old seedling. The milled rice was lower by 5-16% in 12-day, 16-day and 20-day old seedling than in 8-day old seedling of 6.18 t/ha. It was found that the 8-day and 12-day old seedling provided more advantage for sound seedling ratio, endosperm remaining, missing hill during transplanting, rooting ability and grain yields than 16-day and 20-day old seedlings.

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STUDIES ON THE LIPID OF AQUATIC PRODUCTS (PART 3) Fatty Acid Composition the Lipid in Dried Purple Laver Marketable Products (수산물의 지질에 관한 연구(제3보) -산지별 건해태 지질의 지방산조성에 대하여-)

  • HA Bong Seuk
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.11 no.4
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    • pp.219-225
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    • 1978
  • Several samples of tile dried purple laver grown and processed at the major laver producing districts, i. e Mokpo, Wando, Hadong and Jangrim, along the southern coast of Korea were Quantitatively investigated to determine composing patterns of the fatty acids by gas-liquid chromatography. The total lipid contents in dried purple laver of Hadong were $1.8\%$ being the highest value. Upon analyzing fatty acid composition, some differences were observed in their quantitative distribution at different growing places. Dried purple laver of Wando contained mainly $C_{16:0},\;C_{18:1},\;C_{16:1}\;and\;C_{17:0}$ fatty acids, that of Mokpo contained $C_{16:0},\;C_{20:5},\;C_{18:1}\;and\;C_{16:1}$ fatty acids, and that of Hadong $C_{16:0},\;C_{20:5},\;C_{18:0}\;and\;C_{20:1}$ fatty acids, and that of Jangrim $C_{20:5},\;C_{16:0},\;C_{18:1}\;and\;C_{18:0}$ fatty acids, each in order of acid quantity. In regard to the composing pattern of carbon number of fatty acids, the dried purple laver o Mokpo, Hadong, and Jangrim contained $C_{16},\;C_{18}\;and\;C_{20}$ fatty acids with the identical distributional pattern, while that of Jangrim contained $C_{16},\;C_{18}\;and\;C_{17}$ fatty acids as major components. Dried Purple laver of Jangrim contained especially high amount of $C_{20:5}$ fatty acids.

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Biological Activity of Female Sex Pheromone of the Oriental Tobacco Budworm, Helicoverpa assulta (Guenee)(Lepidoptera: Noctuidae): Electroantennography, Wind Tunnel Observation and Field Trapping (담배나방 성페르몬의 생물학적 활성 : 촉가전도, 풍동 및 애외 트랩시험)

  • 박계청;알란콕;부경생;데이빗홀
    • Korean journal of applied entomology
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    • v.33 no.1
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    • pp.26-32
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    • 1994
  • Electroantennography, wind tunnel observation, and field trapping experiments were carried out to investigate the biological activity of synthetic sex pheromone in the onental tobacco budworm. Heli-couerpa assulta. Two major sex pheromone components of H. assulta, Z9-16' Ald and Z11-16: Ald. elicited a big EAG response in male, but not in female Their mIXture ratios did not give much influence on EAG size Fema]e H assulta showed a great EAG response only to its host plant e extract. EAG size also increased with the amount of mixture from 001 to 10 [lg but rather decreased w when the amount was 1 00 $\mug$. H. assulta always revealed a series of stereotyped behavior in a wind tunnel. The behavioral response was different when the males were stimulated with the sex pheromone containing some minor components, 16: AId and Z9.16: Ac, or being different in mixing ratios of the two major components. The best ratio of the sex phemmone components for a attracting H assulta male adults was 20-25: 1 between Z9-16: Aid and Z11-16: Ald in net house a and red pepper field experiments in Korea When the lure contamed Z9-16: OH, attracting power rapidly decreased. The synthetic sex pheromone showed a strong attraction when compared to virgin females

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Identification of Tumor Suppressor Loci on the Short Arm of Chromosome 16 in Primary Small Cell Lung Cancers (원발성 소세포폐암에서 염색체 16번의 단완에 위치한 종양억제유전자좌의 확인)

  • Kee, Hyun Jung;Shin, Ju Hye;Chang, Joon;Chung, Kyung Young;Shin, Dong Hwan;Kim, Young Sam;Chang, Yoon Soo;Kim, Sung Kyu;Kwak, Seung Min;Kim, Se kyu
    • Tuberculosis and Respiratory Diseases
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    • v.55 no.6
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    • pp.597-611
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    • 2003
  • Background : Loss of the short arm of chromosome 16 is a frequent event in various cancers, which suggests the presence of tumor suppressor gene(s) there. To map precise tumor suppressor loci on the chromosome arm for further positional cloning efforts, we tested 23 primary small cell lung cancers. Method : The DNAs extracted from paraffin embedded tissue blocks with primary tumor and corresponding control tissue were investigated. Twenty polymorphic microsatellite markers located in the short arm of chromosome 16 were used in the microsatellite analysis. Results : We found that six (26.1%) of 23 tumors exhibited LOH in at least one of tested microsatellite markers. Two (8.7%) of 6 tumors exhibiting LOH lost a larger area in chromosome 16p. LOH was observed in five common deleted regions at 16p. Among those areas, LOH between D16S668 and D16S749 was most frequent (21.1%). LOH was also observed at four other regions, between D16S3024 and D16S748, D16S405, D16S420, and D16S753. Six of 23 tumors exhibited shifted bands in at least one of the tested microsatellite markers. Shifted bands occurred in 3.3% (15 of 460) of the loci tested. Conclusion : Our data demonstrated that at least five tumor suppressor loci might exist in the short arm of chromosome 16 and that they may play an important role in small cell lung cancer tumorigenesis.