• Title/Summary/Keyword: 15-nitrogen

Search Result 2,690, Processing Time 0.03 seconds

Effect of the SBA-15 template and KOH activation method on CO2 adsorption by N-doped polypyrrole-based porous carbons

  • Yuan, Hui;Jin, Biao;Meng, Long-Yue
    • Carbon letters
    • /
    • v.28
    • /
    • pp.116-120
    • /
    • 2018
  • Nitrogen-doped carbons have attracted much attention due to their novel application in relation to gas storage. In this study, nitrogen-doped porous carbons were synthesized using SBA-15 as a template, polypyrrole as the carbon and nitrogen precursor, and KOH as an activating agent. The effect of the activation temperature ($600-850^{\circ}C$) on the $CO_2$ adsorption capacity of the obtained porous carbons was studied. Characterization of the resulting carbons showed that they were micro-/meso-porous carbon materials with a well-developed pore structure that varied with the activation temperature. The highest surface area of $1488m^2g^{-1}$ was achieved at an activation temperature of $800^{\circ}C$ (AC-800). The nitrogen content of the activated carbon decreased from 4.74 to 1.39 wt% with an increase in the activation temperature from 600 to $850^{\circ}C$. This shows that nitrogen is oxidized and more easily removed than carbon during the activation process, which indicates that C-N bonds are more easily ruptured at higher temperatures. Furthermore, $CO_2$ adsorption isotherms showed that AC-800 exhibited the best $CO_2$ adsorption capacity of $110mg\;g^{-1}$ at 298 K and 1 bar.

Effects of Nitrogen Supply Levels on Growth and Nitrogen Substance in Pear (Pyrus pyrifolia cv. Niitaka) Seedlings (질소 시용수준에 따른 배 '신고' 실생묘의 생육과 질소관련물질의 변화)

  • Jin, Song-Nan;Choi, Dong-Geun;Kang, In-Kyu;Han, Kwang-Soo;Choi, Cheol
    • Journal of Bio-Environment Control
    • /
    • v.15 no.1
    • /
    • pp.84-90
    • /
    • 2006
  • This study was conducted to anticipate nitrate reduction state in tree through measurement of nitrate reductase activity (NRA) and investigate the effect of nitrogen concentrations (100, 200, 400, and 600 $mg\;L^{-1}$) on growth, the nitrogen content of various tissue, and NRA of pear (Pyrus pyrifolia cv. Niitaka) seedlings in sand culture. Nutrient solutions used in this experiment were adjusted to pH 6.5 and fixed the ratio of ammonium and nitrate to 1:3 and trickle-irrigated 3 times a day. Tree height and dry weight of various organs in seedlings were higher in low nitrogen concentration (100 and 200 $mg\;L^{-1}$) than in high nitrogen concentration (400 and 600 $mg\;L^{-1}$). The shoot growth in 600 $mg\;L^{-1}$ was extremely poor by nitrogen over supply. Increasing the nitrogen concentration, the concentration of nitrate-N in leaves and roots were insignificantly changed but that of stems increased. The accumulation of total and reduced nitrogen in all organs with increasing concentrations of nitrogen supply were increased at 30 days after treatment but those of all organs at 60 and 90 days after treatment were highest in 600 $mg\;L^{-1}$, whereas there were no significant changes among other nitrogen concentration. The in vivo (${+NO_3}^-$) NRA of all organs did not relate to nitrogen concentration but the in vivo (${-NO_3}^-$) NRA of leaves except roots increased with increasing the nitrogen concentration. Therefore, the proper nitrogen concentration to promote growth and nitrate reduction of pear tree was 200 $mg\;L^{-1}$.

Relation of Conception Rate and Plasma Urea Nitrogen in Dairy Cattle (젖소의 수태율과 혈장 요소태 질소의 관계)

  • 박수봉;김현섭;김창근;정영채;이종완;김천호
    • Korean Journal of Animal Reproduction
    • /
    • v.21 no.2
    • /
    • pp.185-189
    • /
    • 1997
  • The objectives of this study were to relate concentrations of plasma urea nitrogen(PUN) to conception rate in dairy cows. the relationship between PUN concentration and time postcalving was examined for 11 individual cows. Mean concentration of PUN rose for serveral weeks after calving and then was stable from 7 week. As PUN increased, the rate of conception decreased. Cows with PUN<15 and 15∼19.9mg/dl had the likelihood ratios of conception of 1.33 and 1.67. As PUN increased 20∼22.9 and 23mg/dl, the likelihood ratios decreased to 1.00 and 0.90. Thus, low PUN had a favorable association with conception, whereas high PUN had a negative association with conception.

  • PDF

Effects of Dietary Lamb and Beef Meat on the Growth and Protein Utilization in Rats (양고기와 쇠고기의 식이가 흰쥐의 성장과 단백질 이용성에 미치는 영향)

  • 박선희
    • Journal of Nutrition and Health
    • /
    • v.24 no.1
    • /
    • pp.20-29
    • /
    • 1991
  • This study was carried out to compare the protein quality of lamb and beef meat. by feeding to growing rats. Sixty weanling rats, 30 males and 30 females, were blocked into 12 groups(6 gruops of males and 6 groups of females). They were fed casein. beef, or lamb as a protein source at two levels, 6 and 15%, for 5 weeks. The amount of food intake. food efficiency ratio, protein efficiency ratio. body weight gain. and the weights of skeletal muscles and liver were measured. Nitrogen retention, protein content in the liver and skeletal muscles, and the levels of protein and cholesterol in the serum were also assayed. Summarzing the results, there were no significant differences between lamb and beef on the growth and nitrogen utilization in the rats fed same percentage of protein diet. However. rats fed 15% protein diet showed significantly higher growth rate than those fed 6%. Therefore, it can be concluded that lamb is as good a protein food as beef in terms of protein quality.

  • PDF

Dark Hydrogen Production by a Green Microalga, Chlamydomonas reinhardtii UTEX 90

  • SIM SANG JUN;GONG GYEONG TAEK;KIM MI SUN;PARK TAl HYUN
    • Journal of Microbiology and Biotechnology
    • /
    • v.15 no.6
    • /
    • pp.1159-1163
    • /
    • 2005
  • The production of hydrogen by Chlamydomonas reinhardtii UTEX 90, a marine green alga, was performed under dark fermentation. The effects of initial nitrogen and phosphorus concentration on the cell growth and the production of hydrogen and organic substances were investigated. In the growth stage, the maximum dry cell weight (DCW) was 3 g/l when the initial ammonium concentration was 15 mM. In the dark fermentation, the maximum hydrogen production was $3.5\;{\mu}mol/\;mg$ DCW when the initial nitrogen concentration was 7.5 mM. The nitrogen concentration had a greater effect on organic compound and hydrogen production than the phosphorus concentration during the dark fermentation. An investigation of the duration of dark fermentation showed that, at least until three days, dark fermentation should be prolonged for maximum hydrogen production.

Electrical Breakdown Characteristics of LN2 under Simulated Quenching Conditions for Application of HTS Apparatus (고온초전도 기기응용을 위한 모의 \ulcorner치 환경에서 액체질소의 절연파괴 특성)

  • 백승명;정종만;김상현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.15 no.11
    • /
    • pp.985-990
    • /
    • 2002
  • The electrical breakdown characteristics of liquid nitrogen(LN$\sub$2/) were studied under simulated quenching conditions for application of HTS apparatus. The experimental results for various quenching condition revealed that the breakdown voltage of LN$\sub$2/ with bubble flow velocity and gap spacing. In the case, breakdown voltage decreases gradually with the bubble velocity. When it is bubble velocity from 0 to 1 $\ell$ /min, breakdown voltage rapidly decreases but decreases from 2 $\ell$/min to 10 $\ell$/min slowly. The breakdown voltage for vertical electrode arrangement is higher than that for horizontal electrode arrangement. Also, it did a electric field and potential distribution interpreting at the liquid nitrogen when the bubble existed. The plots of equipotential lines for three cases are also shown.

Mechanical Characteristics of Crystalline Carbon Nitride Films Grown by Reactive Sputtering (반응성 스퍼터링으로 성장된 결정성 질화탄소막의 기계적 특성)

  • 이성필;강종봉
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.15 no.2
    • /
    • pp.147-152
    • /
    • 2002
  • Carbon nitride thin films were deposited by reactive sputtering for the hard coating materials on Si wafer and tool steels. When the nitrogen content of carbon nitride film on tool steel is 33.4%, the mean hardness and elastic modulus are 49.34 GPa and 307.2 GPa respectively. The nitrided or carburised surface acts as the diffusion barrier which shows better adhesion of carbon nitride thin film on the steel surface. To prevent nitrogen diffusion from the film, steel substrate can be saturated by nitrogen forming a Fe$_3$N layer. The desirable structure at the surface after carburising is martensite, but sometimes, due to high carbon content an proeutectoid Fe$_3$C structure may form at the grain boundaries, leaving the overall surface brittle and may cause defects.

Effect of Annealing on Carbon Nitride Films Prepared by High Voltage Discharge Plasma (고전압 방전 플라즈마에 의해 합성한 질화탄소 박막의 열처리 효과)

  • 김종일
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.15 no.5
    • /
    • pp.455-459
    • /
    • 2002
  • I have investigated the effects of annealing on a polymeric $\alpha-C_3N_{4.2}$ at high pressure and temperature in the presence of seeds of crystalline carbon nitride films prepared by a high voltage discharge plasma. The samples were evaluated by x-ray photoelectron spectroscopy (XPS), infrared spectroscopy, Auger electron spectroscopy and x-ray diffraction(XRD). Notably, XPS studies of the film composition before and after annealing demonstrate that the nitrogen composition in $\alpha-C_3N_{4.2}$ material initially containing more than 58% nitrogen decreases during the annealing process and reaches a common, stable composition of ~43%. XPS analysis also shows that the nitrogen composition in the annealed films without polymeric $\alpha-C_3N_{4.2}$ was reduced from 35% to 17%. Furthermore the concentration of the sp$^3$bonded phase increased with the increment of the annealing temperature.

Effect of Split Nitrogen Application Times on Turf Vegetation of Creeping Bentgrass (질소 분시횟수가 Creeping Bentgrass 잔디초지의 식생에 미치는 영향)

  • Park, Sung-Jun;Cho, Nam-Ki;Kang, Young-Kil;Song, Chang-Khil;Cho, Young-Il
    • Journal of The Korean Society of Grassland and Forage Science
    • /
    • v.25 no.2
    • /
    • pp.119-124
    • /
    • 2005
  • This study was conducted from March 21 to July 8 in 2004 at JeJu Island to investigate the influences of split nitrogen application times on creeping bentgrass vegetation. Nitrogen rate was 20 kg/10a and it was applied from once to 5 times. The result obtained were summarized as follows; plant height was getting longer as nitrogen was split applied from once to 5 times. So it was longest at 5 times split nitrogen application, but it was no significance from 4 to 5 times. Root length, Minolta SPAD-502 chlorophyll meter reading value, leave and root weight n[e directly proportional plant height response. Degree of land cover Iud density of creeping bentgrass increased as nitrogen was split applied from once to 5 times. But degree of land cover md density of reed decreased. The number of reed species on decreased as nitrogen was split applied from once to 5 times. Then ranking of the dominant weeds were Portulaca oleracea Polygonum hydropiper and Stellaria media (at once split time nitrogen application), Portulaca oleracea, Polygonum hydropiper and Digitaria adscendens (at 2 split times nitrogen application), Digitaria adscendens and Portulaca oleracea Polygonum hydropiper, (at 3 split times nitrogen application), Portulaca oleracea, Poa annua and Polygonum hydropiper (at 4 md 5 split times nitrogen application). These results indicate that the optimum frequency of split N applications is four times for growth of creeping bentgrass in volcanic ash soils of Jeju island.

Studies on Nitrogen Fixation of Forage Legumes with 15N-Ammonium Sulfate (중질소(重質素)를 사용(使用)한 두과사료작물(豆科飼料作物)의 질소(窒素) 고정량(固定量) 측정(測定)에 관(関)한 연구(硏究))

  • Kim, Moo-Sung
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.16 no.1
    • /
    • pp.50-55
    • /
    • 1983
  • Effects of nitrogen applied to grown alone and in mixture with grass and legumes of forage crops on the yield of dry matter, absorptivity, and the amount of nitrogen fixation were studied using $^{15}N$ ammonium sulfate. 1. The amount of nitrogen fixation in legume was decreased in order of alfalfa > red clover > birdsfoot trefoil, and red clover gave highest soil-nitrogen dependency. 2. Fertilizer nitrogen for the yield of dry matter was highly effective only in orchardgrass, and effective at the early stages of alfalfa and birdsfoot trefoil in case of a mixed sowing. 3. Alone and mixed sewings showed the yield of dry matter in decreasing order of alfalfa > red clover > orchardgrass > birdsfoot trefoil and orchardgrass + alfalfa > orchardgrass + red clover > orchardgrass + birdsfoot trefoil, respectively. 4. The plot of with nitrogen showed greater nitrogen uptake than the plot of without-nitrogen throughout the plots. In case of grown alone, however, difference in the absorptivity of various forage crops was decreased in order of alfalfa > red clover > orchardgrass > birdsfoot trefoil. 5. Regardless of nitrogen application, nitrogen uptake amount of orchardgrass was higher in the plot of mixture then in the plot grown alone, except the with nitrogen plot of red clover grown in mixture at the ratio of 3 : 7.

  • PDF