• Title/Summary/Keyword: 15-nitrogen

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Magnetic Properties and Production of Fe-N Phases by Plasma Source Ion Implantation (플라즈마 이온주입 방법에 의한 질화철 제조 및 자기적 성질)

  • 김정기;김곤호;김용현;한승희;김철성
    • Journal of the Korean Magnetics Society
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    • v.8 no.1
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    • pp.6-12
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    • 1998
  • Fe-N(iron-nitrogen) crystal phases were prepared by nitrogen ion implantation into $\alpha$-Fe foil with Plasma Source Ion Implantation (PSII). Ion implantation time of sample is treated 15 minutes(FeN15) and 30 minutes (FeN30). The nitrogen depth profiles measured by Auger electron spectroscopy (AES) were determined to be about 12000 $\AA$ and 4000 $\AA$ for the samples of FeN15 and FeN30, respectively. The results of vibrating sample magnetometer (VSM) show that the saturation magnetization of the samples of as-implanted FeN15 and FeN30 was higher than that of pure $\alpha$-Fe foil, which may be owing to $\alpha$'-$Fe_8N$ or $\alpha$"-$Fe_{16}N_2$ phases. Accordingly this study shows the possibility of the partial formation of $\alpha$' or $\alpha$" phase in iron nitrogen produced by PSII method.II method.

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Effects of Nitrogen Fertilization on Growth of Populus sibirica and Ulmus pumila Seedlings and Soil Properties in a Semi-Arid Area, Mongolia (몽골 반건조지에서 질소 시비가 백양나무와 비술나무 묘목의 생장 및 토양 특성에 미치는 영향)

  • Chang, Hanna;Han, Seung Hyun;Kim, Seongjun;Park, Min Ji;An, Jiae;Kang, Hoduck;Yi, Myong-Jong;Akhmadi, Khaulenbek;Son, Yowhan
    • Journal of Climate Change Research
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    • v.6 no.3
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    • pp.249-256
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    • 2015
  • This study was conducted to investigate the effects of different levels and types of nitrogen fertilizer on seedlings and soil chemical properties in a semi-arid area, Mongolia. 2-year-old Populus sibirica and 4-year-old Ulmus pumila seedlings were planted in May 2014. Six treatments with three levels of nitrogen (low-level: urea $5g\;tree^{-1}$; medium-level: urea $15g\;tree^{-1}$, ammonium sulfate $33g\;tree^{-1}$, urea $15g\;tree^{-1}$ with potassium phosphate $10g\;tree^{-1}$; high-level: urea $30g\;tree^{-1}$) were applied and for the medium-level of nitrogen, different types of fertilizer were treated. Survival rate, root collar diameter (RCD) growth rate, leaf nitrogen concentration of seedlings, and soil chemical properties were determined in August 2014. The seedling survival rate of both species decreased as the level of nitrogen increased. This result can be explained by water stress caused by nitrogen fertilization in arid regions. The RCD growth rate of P. sibirica was significantly decreased by the treatment of high-level of nitrogen due to excessive nitrogen fertilization, and was increased by the treatment of ammonium sulfate due to sulfur which might promote nitrogen uptake. The leaf nitrogen concentration of P. sibirica did not change by the treatment of low-level of nitrogen, and was increased by the treatment of medium-level of nitrogen. There were no significant differences in the RCD growth rate and the leaf nitrogen concentration of U. pumila among the six treatments. None of soil chemical properties was affected by nitrogen fertilization. Overall, the low-level of nitrogen showed no effect on seedlings and soil chemical properties, except on survival rate of U. pumila and the high-level of nitrogen was considered excessive fertilization. Continuous monitoring of medium-level nitrogen fertilization including the ammonium sulfate, which increased early growth of seedlings, would be needed to elucidate the effect of fertilization on seedling growth and soil properties in a semi-arid region.

Effects of Nitrogen Level and Defoliation at Maturing Stage on the Yield Components of Rice (질소시용량(窒素施用量) 및 등숙기(登熟期) 절엽처리(切葉處理)가 수도수량구성요소(水稻收量構成要素)에 미치는 영향(影響))

  • Ahn, Su-Bong;Lee, Jong-Chul
    • Korean Journal of Agricultural Science
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    • v.4 no.1
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    • pp.26-33
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    • 1977
  • We have studied the responce of nitrogen on the newly bred varieties, Yusin and Milyang #23, and the effects of defoliation at maturing stage on the rate of ripened grains under different nitrogen levels. The results obtained are summarized as follows : 1. Milyang #23 as well as Tongil was found to be highly nitrogen responsive variety and showed good grain maturing percentage. The number of grain per unit area affected the total yield under the high levels of nitrogen application. The variety, Yusin, was less responsive to nitrogen and had also less leaf area than other varieties under the high level of nitrogen application. Yusin also seemed to have low maturing percentage due to unbalanced ratio between photosynthetic area and size of storage. 2. The low internodes and leaf blade of Yusin and Milyang #15 were grown too much under high levels of nitrogen and these caused more lodging and less light penetration in pant canopy. 3. The effects of defoliation at maturing stage on yield was high under the high levels of nitrogen application, especially when defoliation was done early stage of maturing. The effects of defoliation appeared to be greates in Tongil than in Milyang #15.

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Relationship between Leaf Chlorophyll Reading Value and Soil N-supplying Capability for Tomato in Green House (시설재배 토마토 잎의 엽록소 측정치와 토양 질소공급능력의 상호관계)

  • Hong, Soon-Dal;Kim, Ki-In;Park, Hyo-Taek;Kang, Seong-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.2
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    • pp.85-91
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    • 2001
  • To find diagnosing method of nitrogen status in tomato plant for determining optimum application rate of side dress, chlorophyll reading values were measured by portable chlorophyll meter(SPAD 502, Minolta), and compared with nitrogen supplying capability of soils. Regression between dry weight, amount of nitrogen uptake, and chlorophyll reading at stalk positions of tomato grown on the condition of no fertilization were evaluated For 6 green house soils with different nitrate concentrations ranged from $55mg\;kg^{-1}$ to $306mg\;kg^{-1}$. The chlorophyll reading of tomato leave was significantly correlated with amount of nitrogen per unit area of leave suggesting that chlorophyll content is useful for nitrogen diagnosis of tomato plant. The chlorophyll reading showed peak at the 15th leaf of stalk position on the 45th days after transplanting and this suggested that below or near the 15th leaf and before or near the 45th days after transplanting is the critical stalk position and time for diagnosing nitrogen status of tomato by chlorophyll test. The chlorophyll reading at the 14th leaf on the 40th days after transplanting was significantly correlated with soil nitrate status, dry weight and amount of nitrogen uptake by tomato grown with no fertilization. From the above correlation, the chlorophyll reading value of 57.1 at the 14th leaf of tomato was estimated as the critical level for maximum dry weight and amount of nitrogen uptake by tomato grown with no fertilization. Consequently, chlorophyll reading of tomato leaves measured by portable chlorophyll meter was thought to be available as a rapid plant test for predicting the nitrogen supplying capability of green house soils.

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A Study on Nitrogen and Phosphorus Removal in FNR Process (FNR process를 이용한 하수처리장의 질소.인의 제거에 관한 연구)

  • Cho Il-Hyoung;Lee Nae-Hyun;Lee Seung-Mok;Kim Young-Kyu
    • Journal of Environmental Science International
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    • v.15 no.6
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    • pp.571-577
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    • 2006
  • This study make a comparison between the phosphorus removal performance of FNR(Ferrous Nutrient Removal) process and A/O process by the laboratory experiments. For simultaneous removal of phosphorus, iron electrolysis was combined with oxic tank. Iron precipitation reactor on the electrochemical behaviors of phosphorus in the iron bed. The phosphorus removal in FNR process was more than A/O process. Iron salts produced by iron electrolysis might help to remove COD and nitrogen. And the demanded longer SRT is the more removes the removes COD, nitrogen, and phosphorus. Also, FNR process of sludge quantity more reduce than A/O process to input cohesive agents.

Effects of Different Nitrogen Levels and Planting Densities on the Quality and Yield of the Black Rice Cultivar 'Shinnongheugchal' (재식밀도 및 시비량 차이가 신농흑찰 품질 및 수량에 미치는 영향)

  • Lee, In-Sok;Lee, Deok-Ryeol;Cho, Seung-Hyun;Lee, Song-Yi;Kim, Kab-Cheol;Lee, Ki-Kwon;Song, Young-Ju
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.61 no.2
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    • pp.79-86
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    • 2016
  • The late-maturing black rice cultivar Shinnongheugchal from Jeollabuk-do Agricultural Research and Extension Service was used as the plant material for estimating growth characters, quality and yield from the vegetation period to harvest age. This study was performed to select an optimum combination of nitrogen level and planting density for the maximum yield of Shinnongheugchal. The plant height, number of tillers, and SPAD index were higher when the combination of 70 hills per $3.3m^2$ and 13 kg/10 a nitrogen level was used at 30 days after transplanting. The heading date for the combination of 70 hills per $3.3m^2$ and 15 kg/10 a nitrogen level, and 80 hills per $3.3m^2$ and 15 kg/10 a nitrogen level was August 22. The heading date for the other combinations was August 21. The combination of 70 hills per $3.3m^2$ and 13 kg/10 a nitrogen level yielded the highest number of tillers at 40 days after flowering. Even though the lodging index was increased with increasing nitrogen levels, field lodging did not occur until harvest time. Seed nitrogen concentration in the combination of 70 hills per $3.3m^2$ and 13 kg/10 a nitrogen level showed a significant difference when compared with the other combinations. The black rice yield varied significantly, and the highest yield was observed in the combination of 70 hills per $3.3m^2$ and 13 kg/10 a nitrogen level. The yield was significantly correlated with seed nitrogen concentration. The maximum yield was estimated to be 14.67 kg/10 a nitrogen level by using the regression equation. On average, the coloring degree of the black rice was higher at planting density of 70 hills per $3.3m^2$ than at 80 hills per $3.3m^2$. The highest yield of perfect black rice was obtained using the combination of 70 hills per $3.3m^2$ and 13 kg/10 a nitrogen level. Our findings demonstrate that a nitrogen level of 13-14 kg/10 a can be used to obtain the maximum yield from Shinnongheugchal with yield, cyanidin 3-glucoside content, and perfect black rice yield as the standard.

The Study of Cyclophosphamide Metabolite $^{15}N-Isophosphamide$ Mustard (항암제인 Cyclophosphamide의 중간체인 $^{15}N-Isophosphoramide$ Mustard에 관한 연구)

  • Koo, Kyo-Im;Ryem, Kon
    • YAKHAK HOEJI
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    • v.38 no.6
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    • pp.673-676
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    • 1994
  • The each nitrogen site of ifosfamide metabolite isophosphoramide mustard was synthesized with isotope enriched nitrogen. $Gylcine-^{15}N$ was converted to $2-chloroethylamine-^{15}N$ hydrochloride which was then reacted with phenyl dichlorophosphate to provide $N,N'-bis(2-chloroethyl)phosphordiamidic-^{15}N_2$ acid phenylester(50%, $PhO(O)^{15}N(CH_2CH_2Cl_2)$. Catalytic hydrogenation of this phenyl ester followed by the addition of cyclohexylamine (CHA) provided $IPM-^{15}N$ as the CHA salt(70%).

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The Importance of Nitrogen Release and Denitrification in Sediment to the Nitrogen Budget in Hiroshima Bay

  • KIM Do-Hee;MATSUDA Osamu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.29 no.6
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    • pp.779-786
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    • 1996
  • The main purpose of this study was to estimate the role of dissolved inorganic nitrogen (DIN) released from sediment and denitrification process in sediment on the nitrogen budget of Hiroshima Bay by means of collecting data on distributions and budgets of nitrogen and phosphorus in the bay, DIN fluxes across sediment-water interface and denitrification rates in the sediments of the same area. The TN : TP and DIN:DIP atomic ratios of the discharged freshwater were about 26 and 21, respectively. The standing stocks in the seawater of the TN : TP atomic ratio varied from 8 to 14 with an annual mean value of 11, while the DIN : DIP atomic ratio varied from 10 to 15 with an annual mean value of 12 in the bay. The residence time of nitrogen and phosphorus were estimated to be about 109 days and 200 days in the bay, respectively. The proportion of DIN released from sediment and denitrification rate to the loading of total nitrogen into Hiroshima Bay were $45\%\;(37\~82\%)\;and\;13\%(0.0\~37\%)$, respectively, and the amount of nitrogen through denitrification process was 6.5 times larger than the outflow of nitrogen from the bay. The results show that DIN released from sediment and denitrification process in sediment play important roles on the nitrogen budget in Hiroshima Bay.

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Effect of Nitrogen Fertilizer, Planting Density and Seeding Date on the Yield of OKra(Abelmoschus esculentus (L) MOENCH) (질소시비량, 재식밀도 및 파종기가 오크라의 수량에 미치는 영향)

  • 이경희;조재연;윤성탁;박석근
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.35 no.3
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    • pp.179-183
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    • 1990
  • In order to find out the effects of nitrogen fertilizer, planting density and seeding date of Okra (Abelmoschus esculentus (L) MOENCH), three nitrogen fertilizer level (4, 8 and 10kg N/10a), three planting densities (45${\times}$30cm, 60${\times}$30cm and 90${\times}$30cm) and five seeding date (April 15, May 1, May 15, June 1 and June 15) were treated. Treatment of 8kg N/10a among nitrogen fertilizer level and 45${\times}$30cm among planting densities showed higher green and yield than the other treatments. The plot of 45${\times}$30cm with 8kg N/10a showed the highest yield. Among planting date, May 1 planting date obtained the highest yield.

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Advanced Dual Refrigerant Expansion Cycle for LNG Liquefaction (천연가스 액화용 이중 냉매 팽창 사이클)

  • Kim, Minki;Kim, Mungyu;Lee, Kihwan;Kim, Hyobin;Lee, Donghun;Min, Joonho;Kim, Jinmo
    • Plant Journal
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    • v.15 no.2
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    • pp.46-55
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    • 2019
  • This paper presents a LNG Liquefaction cycle configuration using two stages of methane expansion (i.e. spliting into two stages as warm & cold to generate an additional inflection point within a cold composite curve) and a single stage of nitrogen expansion to improve the efficiency of the conventional Methane & Nitrogen Expansion Cycle. In comparison with Double Nitrogen Expansion Cycel and Methane & Nitrogen Expansion Cycle, the cycle efficiency has increased approximately from 13.92 and 13.13 to 12.08 kW/ton/day (8~15% efficiency increase). A Life Cycle Cost (LCC) analysis based on Net Present Value (NPV) also show an improvement in therms of project NPV, against a minor increment of a CAPEX.