• Bulletin of the Korean Chemical Society
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• 제11권5호
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• pp.422-426
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• 1990

Fully optimized MNDO molecular orbital calculations are described for N-nitroso-aziridine (I), -oxaziridine (II), and -dioxaziridine (III). The ground state geometries show the nonplanar configuration around the imino nitrogen. The nitroso group rotational energy barriers are 3.25, 0.43 and 1.18 kcal/mol for I, II and III, respectively. Also the calculated aziridine ring inversion barriers are 3.98, 15.61 and 27.46 kcal/mol for I, II and III, respectively.

• 월간양계
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• 제11권11호통권121호
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• pp.62-65
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• 1979

• 월간양계
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• 제11권11호통권121호
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• pp.66-69
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• 1979

• BMB Reports
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• 제42권3호
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• pp.160-165
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• 2009

The temperate Staphylococcus aureus phage ${\Phi}11$ harbors cI and cro repressor genes similar to those of lambdoid phages. Using extremely pure ${\Phi}11$ Cro (the product of the ${\Phi}11$ cro gene) we demonstrated that this protein possesses a single domain structure, forms dimers in solution at micromolar concentrations and maintains a largely $\alpha$-helical structure even at $45^{\circ}C$. ${\Phi}11$ Cro was sensitive to thermolysin at temperatures ranging from $55-75^{\circ}C$ and began to aggregate at ${\sim}63^{\circ}C$, suggesting that the protein is moderately thermostable. Of the three homologous 15-bp operators (O1, O2, and O3) in the ${\Phi}11$ cI-cro intergenic region, ${\Phi}11$ Cro only binds efficiently to O3, which is located upstream of the cI gene. Our comparative analyses indicate that the DNA binding capacity, secondary structure and dimerization efficiency of thermostable ${\Phi}11$ Cro are distinct from those of P22 Cro and $\lambda$ Cro, the best characterized representatives of the two structurally different Cro families.

• 한국정보과학회논문지:정보통신
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• 제35권4호
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• pp.311-317
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• 2008

본 논문에서는 VANET 환경에서 차량과 인프라간의 신뢰성 있는 통신을 제공하기 위한 V2I간의 세션 키 교환 기법을 제안한다. 기존의 VANET에서는 V2I간의 안전한 통신을 위해 IEEE 802.11i와 PKI 기반의 보안 메커니즘을 사용하고 있다. 그러나 차량의 고속 이동과 네트워크 환경이 자주 변하는 특성을 가진 VANET에서 짧은 시간에 IEEE 802.11i 또는 PKI 방식을 이용한 V2I 세션 키 교환은 어려움이 있다. 제안하는 기법에서는 빠르게 움직이는 차량과 인프라간의 세션키 교환을 위해 LR (Local Router)을 새롭게 정의하였으며, LR과 OBU 사이의 랜덤 값에 기반 한 XOR 연산을 통해 새로운 세션키를 빠르게 생성하고 교환할 수 있게 하였다. 때문에 제안하는 기법은 VANET 환경에서 AAA 서버 도움 없이도 빠르게 세션키를 교환할 수 있는 이점이 있다.

• 정보보호학회논문지
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• 제19권1호
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• pp.81-92
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• 2009

최근 들어 IEEE 802.11 WLAN(Wireless Local Area Network) 서비스에 대한 수요의 증가와 함께 WLAN 환경에서 실시간 멀티미디어 서비스를 이용하려는 사용자의 관심이 날로 증가하고 있다. 그러나 IEEE 802.11i의 보안 정책은 MS(Mobile Station)의 이동이 빈번하게 발생하는 WLAN 환경에서 끊김 없는 실시간 멀티미디어 서비스를 제공하기에는 핸드오프 지연 시간이 너무 길어 이를 보완하기 위한 기법들이 제안되고 있다. 또한 IEEE 802.11i에서 제시하고 있는 세션 키 도출 과정 및 핸드오프 메커니즘에는 DoS(Denial-of Service) 공격 가능성이 내포되어 있다. 본 논문은 이러한 문제점을 해결하기 위해 중앙집중식 WLAN 환경을 기반으로 안전하고 효율적인 핸드오프 메커니즘을 소개한다. 상호인증 및 세션키 도출로 사용되는 802.11i의 4-way Handshake 과정이 2-way Reassociation 과정으로 대체된다.

• International Journal of Advanced Culture Technology
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• 제11권4호
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• pp.263-272
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• 2023

We investigated and analyzed students' perceptions of their choice of science subjects in the high school credit system and the reasons for their choice. To achieve this, the selection of science subjects was investigated for the second year of S high school over the past three years. Students selected an average of 1.54 science subjects, and it was found that the rate of selection of science subjects was gradually increasing by year. Students chose high in the order of life science I, earth science I, chemistry I, physics I, etc. in the science subject group. Students who wish to enter the natural and engineering fields chose life science I, chemistry I, physics I, etc., while, students who wish to enter the humanities society chose society and culture, life science I, ethics and thought, etc. On the other hand, the reason for choosing science subjects was 'related to college admission', followed by 'aptitude and interest', 'career and real life help', etc. physics I, chemistry I, etc., were high in the subjects selected according to the 'related to college admission'. The subjects selected according to 'aptitude and interest' were high in life science I, earth science I, etc. Physics I, chemistry I, etc. are recognized as subjects necessary for college entrance, and life science I, earth science I, etc., are found to be related to their interests and aptitudes.

• Journal of Welding and Joining
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• 제18권2호
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• pp.11-13
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• 2000

• 한국식품영양과학회지
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• 제22권3호
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• pp.273-279
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• 1993

박테리아 Bacillus sp. K-295G-7이 생산하는 두유응고효소 I 및 II에 의한 11S globulin (glycinin)의 가수분해 패턴을 조사하였다. 효소 I 과 II에 의한 acidic subunit의 응고시간은 약 4-5 분이었다. 전기 영동의 결과, acidic subunit (A$_3$, M.W=45,000)는 효소반응 2분 이내에 완전히 가수분해되어 분자량 16,000, 20,000의 새로운 band를 형성하였다. 한편 효소 II의 작용으로 약 30,000의 분자량을 가진 분해산물을 생성하였고 효소 I 과 II의 basic subunit 에 대한 가수분해 패턴은 유사하였다.

• 생약학회지
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• 제17권2호
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• pp.178-183
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• 1986

It was our working hypothesis that introduction of 11-keto groups to 12-oleanene/ursene series of triterpenoids should endow them with corticoid-like activities, since pharmacological actions of glycyrrhetinic acid (GA) are known to be caused by inhibition on $corticoid-{\delta}^4-reductase$. 11-Keto-triterpenoids derived artificially in these studies, such as 11, 19-diketo-18, 19-secoursolic acid methyl ester(I), $11-keto-{\beta}-boswellic$ acid derivatives (IIa-IIc), 11-Keto-presenegenin dimethyl ester (III), II-keto-oleanolic acid derivatives (IVa-IVd) and 11-keto-hederagenin (V) possess the fundamental functions of ${\alpha},\;{\beta}-unsaturated$ ketone on C-11 and hydroxyl group on C-3, as like GA (VI). Additionally, they involve the carboxyl groups on rings A (II, III), D (I, III, IV, V) and E (VI), and the hydroxyl groups on rings A (III, V) and C (III). All the compounds competitively inhibited $corticoid-5{\beta}-reductase$, and the highest inhibitory potency appeared in I. All of them except $3,\;11-diketo-{\beta}-boswellic$ acid methyl ester (IIc) were more effective about five times to twice than GA. On carrageenin-induced edema test, compounds I and IVa-IVd showed anti-inflammatory activities, but III enhanced rather edema. Structure-activity relations were found in the aspects of hydrophilicity of ring A and hydrophobicity of rings C/D. The more they were hydrophilic in ring A and hydrophobic in rings C/D, the more they inhibited the enzyme. And the more they were hydrophobic in rings C/D, the more they exhibited antiiflammatory activities. However, the increased hydrophilicity in ring A resulted in increasing edema, probably due to a nonspecific inhibition on $aldosterone-5{\beta}-reductase$.