• Title/Summary/Keyword: 1/f slope

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Oxidation of Polymers in Nonaqueous Solutions (비수용액 내에서 중합체의 산화)

  • Choi, Chil Nam;Yang, Hyo Kyung
    • Journal of the Korean Chemical Society
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    • v.45 no.2
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    • pp.138-160
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    • 2001
  • In this study we measured oxidation potentials and current densities for poly(vinylcholride) (PVC) and poly(carbonate)(PC) in nonaqueous solutions, in order to find out how corrosion (oxidation) potentials depend on temperature, pH, enzyme, or added salts. The Tafel's slopes were determined from the Tafel plots of polarization curves. The transfer coefficients (${\alpha}$) wre evaluated from the slope(1-${\alpha}$)nF/2.3 RT, and the electrode reactions appeared irreversible under all conditions.

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A Study of the Vegetation in the Deogyusan National Park - Focused on the Forest Vegetation of the Anseong district - (덕유산국립공원의 식생에 관한 연구 - 안성지구의 산림 식생을 중심으로 -)

  • Kim, Hyoun-Sook;Lee, Sang-Myong;Song, Ho-Kyung
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.12 no.6
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    • pp.1-17
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    • 2009
  • This study was carried out to classify vegetation structure of the Anseong district in the Deogyusan National Park from May 2007 to September 2008 using the gradient analyses and phytosociological method. The vegetation communities were classified into Quercus mongolica, Carpinus laxiflara, Q. serrata, Fraxinus mandshurica, Betula davurica, B. costata, Pinus densiflora and Abies koreana. Characteristics of the vegetation such as species composition, layer structure, vegetation ratio, and the distribution of individual trees by DBH were significantly different among communities. The order of important value of the forest community with DBH 2cm above plants was Q. mongolica (40.02), C. laxiflora (25.65), Q. serrata (24.68), F. mandshurica (21.66), P. densiflora (19.12), Acer pseudosieboldianum (16.96), C. cordata (11.87), B. davurica (11.66), B. costata (10.90), Styrax obassia (10.90) and A. koreana (10.41). Distribution of DBH P. densiflora had a formality distribution, suggesting a continuous domination of these species over the other species for the time being. In contrast, F. mandshurica appeared limited to the valley of the sheet and a higher frequency of young individuals, suggesting a continuous domination of these species the development of a climax forest terrain. This study showed the correlation between each community and the environment according to DCCA ordination. The A. koreana community predominated on the northern slope of the park in the high elevation habitats which had many O-M. F. mandshurica community predominated in the highest elevation habitats which had many Moisture, EX-Cation and T-N. The P. densiflora community mainly occurred on the southern slope of the park in the low elevation habitats which had few Moisture, O-M and T-N. The Q. serrata community and C. laxifiora community appeared on the park in the middle habitats.

Developing Suspended Sediment Delivery Ratio in the Lake Imha Watershed (임하호유역 유사유달공식 개발)

  • Jeon, Ji-Hong;Choi, Donghyuk;Kim, Jae-Kwon;Kim, Taedong
    • Journal of Korean Society on Water Environment
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    • v.33 no.6
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    • pp.744-753
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    • 2017
  • The sediment delivery ratio (SDR) is widely used to estimate sediment loads by multiplying soil loss through the Revised Universal Equation (RUSLE). In this study, the SDR equation was developed for the Lake Imha watershed using soil loss calculated by RUSLE and sediment loads by the calibrated Hydrological Simulation. Program Fortran (HSPF). The ratio of watershed relief and channel length ($R_f/L_{ch}$), the ratio of watershed relief and watershed length ($R_f/L_b$), curve number (CN), area (A), and channel slope ($SLP_{ch}$) demonstrated strong correlations with SDR. SDR equations were developed by a combination of subwatershed parameters by referring to the correlation analysis. The area based power functional SDR developed in this study showed significant errors at the point right after entering major tributaries, because SDR was unrealistically reduced when the watershed area increased significantly. The $SLP_{ch}$-based power functional SDR also showed extraordinary values when the channel slope was gradual. The SDR equation that showed the highest value of the coefficient of determination also presented unrealistic changes in the sediment loads within a relatively short river distance. The SDR equation $SDR=0.0003A^{0.198}R_f/L{_w}^{1.167}$ was recommended for application to the Lake Imha watershed. Using this equation, sediment loads at the outlet of the Lake Imha watershed were calculated, and the HSPF parameters related to sediment in the uncalibrated subwatersheds were determined by referring to the sediment loads calculated with the SDR equation.

Molecular Theory of Plastic Deformation (Ⅲ)$^*$

  • Kim, Jae-Hyun;Ree, Tai-Kyue;Kim, Chang-Hong
    • Bulletin of the Korean Chemical Society
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    • v.2 no.3
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    • pp.96-104
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    • 1981
  • (1) The flow data of f (stress) and ${\dot{s}$ (strain rate) for Fe and Ti alloys were plotted in the form of f vs. -ln ${\dot{s}$ by using the literature values. (2) The plot showed two distinct patterns A and B; Pattern A is a straight line with a negative slope, and Pattern B is a curve of concave upward. (3) According to Kim and Ree's generalized theory of plastic deformation, pattern A & B belong to Case 1 and 2, respectively; in Case 1, only one kind of flow units acts in the deformation, and in Case 2, two kinds flow units act, and stress is expressed by $f={X_1f_1}+{X_2f_2}$where $f_1\;and\;f_2$ are the stresses acting on the flow units of kind 1 and 2, respectively, and $X_1,\;X_2$ are the fractions of the surface area occupied by the two kinds of flow units; $f_j=(1/{\alpha}_j) sinh^{-1}\;{\beta}_j{{\dot{s}}\;(j=1\;or\;2)$, where $1/{\alpha}_j\;and\;{\beta}_j$ are proportional to the shear modulus and relaxation time, respectively. (4) We found that grain-boundary flow units only act in the deformation of Fe and Ti alloys whereas dislocation flow units do not show any appreciable contribution. (5) The deformations of Fe and Ti alloys belong generally to pattern A (Case 1) and B (Case 2), respectively. (6) By applying the equations, f=$(1/{\alpha}_{g1}) sinh^-1({\beta}_{g1}{\dot{s}}$) and $f=(X_{g1}/{\alpha}_{g1})sinh^{-1}({\beta}_{g1}{\dot{s}})+ (X_{g2}/{\alpha}_{g2})\;shih^{-1}({\beta}_{g2}{\dot{s}})$ to the flow data of Fe and Ti alloys, the parametric values of $x_{gj}/{\alpha}_{gj}\;and\;{\beta}_{gs}(j=1\;or\;2)$ were determined, here the subscript g signifies a grain-boundary flow unit. (7) From the values of ($({\beta}_gj)^{-1}$) at different temperatures, the activation enthalpy ${\Delta}H_{gj}^{\neq}$ of deformation due to flow unit gj was determined, ($({\beta}_gj)^{-1}$) being proportional to , the jumping frequency (the rate constant) of flow unit gj. The ${\Delta}H_{gj}\;^{\neq}$ agreed very well with ${\Delta}H_{gj}\;^{\neq}$ (self-diff) of the element j whose diffusion in the sample is a critical step for the deformation as proposed by Kim-Ree's theory (Refer to Tables 3 and 4). (8) The fact, ${\Delta}H_{gj}\;^{\neq}={\Delta}H_{j}\;^{\neq}$ (self-diff), justifies the Kim-Ree theory and their method for determining activation enthalpies for deformation. (9) A linear relation between ${\beta}^{-1}$ and carbon content [C] in hot-rolled steel was observed, i.e., In ${\beta}^{-1}$ = -50.2 [C] - 40.3. This equation explains very well the experimental facts observed with regard to the deformation of hot-rolled steel..

Long Term Average Spectral Analysis for Acoustical Discrimination of Korean Nasal Consonants (한국어 비음의 음향학적 구분을 위한 장구간 스펙트럼(LTAS) 분석)

  • Choi, Soon-Ai;Seong, Cheol-Jae
    • MALSORI
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    • no.60
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    • pp.67-84
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    • 2006
  • The purpose of this study is to find some acoustic parameters on frequency domain to distinguish the Korean nasals, $/m,\;n,\;{\eta}/$ from each other. The new parameters are devised on the basis of LTAS (Long Term Average Spectrum). The maximum peak amplitude and the relevant formant frequency are measured in low and high frequency range, respectively. The frequency of spectral valley and its energy level are also obtained in the specific frequency range of the spectrum. Spectral slope, total energy value in specific frequency range, statistical distribution of spectral energy like centroid, skewness, and kurtosis are suggested as new parameters as well. The parameters that show statistically significant differences across nasals are summerized as follows. 1) in syllable initial positions: the total energy value from 1,500 to 2,200 Hz(zeroENG); 2) in syllable final positions: the peak amplitude of the first formant(peak1_a), the formant frequency with maximum peak amplitude from 4,000 to 8,000 Hz(peak2_f), the maximum peak amplitude of the formant frequency from 4,000 to 8,000 Hz(peak2_a), and the total energy value from 1,500 to 2,200 Hz(zeroENG).

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Enthalpy Changes of Adsorption of Tetrafluorocarbon (CF4) and Hexafluoroethane (C2F6) on Activated Carbon

  • Shin, Jiyoung;Suh, Sung-Sup;Choi, Moon Kyu
    • Clean Technology
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    • v.20 no.1
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    • pp.22-27
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    • 2014
  • Under low pressures of $CF_4$ and $C_2F_6$ up to 20.7 kPa, the equilibrium adsorbed quantity on activated carbon was experimentally examined using the volumetric method at various temperatures between 293.15 K and 333.15 K. To give the best fit to the experimental data curve, the two step model (i.e., Langmuir model for the first layer adsorption and then Freundlich physisorption) is suggested. The method of initial slope yielded the enthalpy of adsorption for the first step while we could apply the Clausius-Clapeyron equation to find the heat of adsorption of the second step. They are 25.9 kJ/mol and 11.8 kJ/mol, respectively, with $CF_4$, and 38.7 and 38.2 kJ/mol with $C_2F_6$.

Fabrication of Perchlorate Ion Selective PVC Membrane Electrode (과염소산 이온선택성 PVC막전극 제작)

  • 우인성;안형환;강안수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.4
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    • pp.298-305
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    • 1998
  • The PVC membrane electrode for measuring perchlorate ion was developed by incorporating various quaternary ammonium sallts. The effect of chemical structure, the content of active material, the kind of plasticizers, and the membrane thickness on the electrode characteristic such as the linear response range and Nernstian slope of the electrode were studied. It was obtained that the effect of the chemical structure of an active material on the electrode characteristics was improved with increasing the alkyl chain length of the quarternary ammonium salts in the ascending order of Aliquat 336P, TOAP, TDAP, and TDDAP. The optimum membrane composition was 9.09wt% of TDDAP, 30.3wt% of PVC, and 60.6wt% of plasticizer(DBP). And the optimum membrane thickness was 0.45mm at this composition. Under the above condition, the linear response range was $10^{-1}~1.2\times10^{-6}$M, and the detection limit was $5.1\times10^{-7}$M with the Nernstian slope of 57mV/decade of activity of perchlorate ion. The electrode potential was stable within the pH range from 4 to 11. The selectivity coefficient was as shown below: $SCN^->I^-NO_3^->Br^->ClO_3^->F^->Cl^->SO_4^{2-}$

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The fundamental frequency (f0) distribution of Korean speakers in a dialogue corpus using Praat and R (Praat과 R로 분석한 한국인 대화 음성 말뭉치의 fundamental frequency(f0)값 분포)

  • Byunggon Yang
    • Phonetics and Speech Sciences
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    • v.15 no.3
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    • pp.17-25
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    • 2023
  • This study examines the fundamental frequency(f0) distribution of 2,740 Korean speakers in a dialogue speech corpus. Praat and R were used for the collection and analysis of acoustical f0 data after removing extreme values considering the interquartile f0 range of the intonational phrases produced by each individual speaker. Results showed that the average f0 value of all speakers was 185 Hz and the median value was 187 Hz. The f0 data showed a positively skewed distribution of 0.11, and the kurtosis was -0.09, which is close to the normal distribution. The pitch values of daily conversations varied in the range of 238 Hz. Further examination of the male and female groups showed distinct median f0 values: 114 Hz for males and 199 Hz for females. A t-test between the two groups yielded a significant difference. The skewness representing the distribution shape was 1.24 for the male group and 0.58 for the female group. The kurtosis was 5.21 and 3.88 for the male and female groups, and the male group values appeared leptokurtic. A regression analysis between the median f0 and age yielded a slope of 0.15 for the male group and -0.586 for the female group, which indicated a divergent relationship. In conclusion, a normative f0 distribution of different Korean age and sex groups can be examined in the conversational speech corpus recorded by a massive number of participants. However, more rigorous data might be required to define a relation between age and f0 values.

The Characteristics of Adult Male Shoulder Types by according to The Slope (국내 성인 남성의 어깨기울기에 따른 유형 분류)

  • Choi, Eun-Hee;Do, Wol-Hee
    • Fashion & Textile Research Journal
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    • v.17 no.1
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    • pp.82-92
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    • 2015
  • This study classified the types of adult male shoulders through criteria which represent the characteristic of male shoulders important to jacket patterns. We selected 39 measurement items to provide information about Size Korea (2010) 3D bodice measurements. Collected data were processed with SPSS 20 for windows. Participants in the study were 1055 adult males, aged 20-60 divided into three age groups of 20-30, 40-50 and 60. Statistical tests (such as descriptive analysis and F-test) analyzed the data and ascertained the differences in ages. In a factor analysis and cluster analysis were conducted for the classification of shoulder type's adult males. The factor analysis indicates 6 factors with 82.4% of total variance. The shoulder types for adult male were divided into 3 groups, flat shoulder (14.1%), normal shoulder (72%), and slope shoulder (13.8%). A total of 19.9% of 20-30 was included in the slope shoulder type, 15.8% of 40-50 was included in the flat shoulder type and 16.1% of 60 was included in the flat shoulder type. This study classified the type of male shoulder through criteria that represent the characteristics of elderly male shoulder to neck base circumference, shoulder angle and shoulder type. The follow-up study will proceed with elderly male neck and various measurement items around the shoulder.

Probabilistic Analysis of Failure of Soil Slopes during Earthquakes (지진시 사면파괴의 확률론적 해석)

  • 김영수;정성관
    • Geotechnical Engineering
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    • v.5 no.1
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    • pp.27-34
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    • 1989
  • This study presents a probabilistic analysis of the stability of homogeneous soil slopes during earthquakes. The stability of the slope is measured through its probability of failure rather than the customary factor of safety. The maximum horizontal ground acceleration is deterimined with Donovan and McGuire equation. The earthquake magnitude (m) is a random variable the Probability density function f(m) has been obtained with a use of Richter law. The potential failure surfaces are taken to be of an exponential shape (log-spiral) , Uncertainties of the shear strength parameters along potential failure surface are expressed by one-dimensional random field model. From a first order analysis the mean and variance of safety margin is osculated. The dependence on significant seismic parameters of the probability of failure of the slope is examined and the results are presented in a number of graphs and tables. On the base of the results obtained in this study, it is concluled that (1) the present model is useful in assessing the reliability of soil slopes under both static and seismic conditions: and (2) the probability of failure of a soil slope is greatly affected by the values of the seismic parameters that are associated with it.

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