• 제목/요약/키워드: 1,4-Addition

검색결과 20,025건 처리시간 0.05초

오디 추출물 첨가가 요구르트 스타터 생육에 미치는 영향 (Effect of Mulberry Extract on the Growth of Yogurt Starter Cultures)

  • 서형주;김영순;김진만;이호
    • 한국축산식품학회지
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    • 제26권1호
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    • pp.144-147
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    • 2006
  • 발효 유제품 제조에 오디 추출물을 첨가할 때 유산균 생육에 미치는 오디 추출물의 효과를 측정하여 오디의 이용성을 넓히고자 한다. 오디 추출물은 에탄올 함량이 60%일 때 가장 높은 추출 수율을 보였다. L. casei와 L. acidophilus의 생육에 대한 영향을 측정하기 위해 오디 추출물을 1%, 5%, 10% 첨가시킨 후 MRS 배지에 유산균을 접종하여 24시간 배양후 pH, 총산도 및 생균수를 측정한 결과, 첨가량이 1%일 때 가장 낮은 pH 4.19와 4.11를 보였으며, 생균수 측정시 오디 추출물 무첨가시 $2.3{\times}10^9{\sim}4.2{\times}10^{10}\;CFU/mL$의 생균수를 보인 반면 오디 추출물 첨가시 $1.8{\times}10^9{\sim}7.8{\times}10^{10}\;CFU/mL$의 생균수를 보임에 따라 다소 높은 생균수를 보였다. 또한 총산도 역시 오디 추출물 첨가시 증가하는 경향을 보였다. L. casei와 L. acidophilus을 이용한 발효 유제품 제조시 오디 추출물을 각각 1% 첨가시 발효 유제품에 미치는 영향을 측정한 결과, 오디 추출물을 첨가한 발효 유제품의 산도 및 생균수가 첨가하지 않은 발효 유제품에 비해 높은 경향을 보였다. 오디 추출물 1% 첨가시 산도를 측정한 결과 L. acidophilus을 이용한 발효 유제품의 산도가 가장 낮은 것으로 나타났으며, 생균수 역시 $6.9{\times}10^{10}\;CFU/mL$로 가장 많은 생균수를 보였다.

Kinetics and Mechanism of the Addition of Benzylamines to Benzylidene Meldrum's Acids in Acetonitrile

  • Oh, Hyuck-Keun;Kim, Tae-Soo;Lee, Hai-Whang;Lee, Ik-Choon
    • Bulletin of the Korean Chemical Society
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    • 제24권2호
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    • pp.193-196
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    • 2003
  • Nucleophilic addition reactions of benzylamines $(XC_6H_4CH_2NH_2)$ to benzylidene Meldrum's acids (BMA; $YC_6H_4CH=C(COO)_2C(CH_3)_2$) have been investigated in acetonitrile at 20.0 ℃. The rates of addition are greatly enhanced due to the abnormally high acidity of Meldrum's acid. The magnitudes of the Hammett $({\rho}_X\;and\;{\rho}_Y)$ and Bronsted $({\rho}_X$)$ coefficients are rather small suggesting an early transition state. The sign and magnitude of the cross-interaction constant, ${\rho}_{XY}$ (= -0.33), and kinetic isotope effects $(k_H/k_D\;{\stackrel}{~}{=}\;1.5-1.7)$ involving deuterated benzylamine nucleophilies $(XC_6H_4CH_2ND_2)$ are indicative of hydrogen-bonded cyclic transition state. The activation parameters, ${\Delta}H^{\neq}\;{\stackrel}{~}{=}\;4\;kcal\;mol^{-1}\;and\;{\Delta}S^{\neq}\;{\stackrel}{~}{=}\;-37\;e.u.$, are also in line with the proposed mechanism.

향신료 첨가에 의한 닭고기 분쇄육에서의 미생물 증식 억제 효과 (Effects of Spice Addition on the Inhibition of Bacterial Growth in Ground Chicken Meat)

  • 정세윤;김용석
    • 한국식품위생안전성학회지
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    • 제38권1호
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    • pp.19-25
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    • 2023
  • 비가열 닭고기 분쇄육의 제조 시 향신료의 첨가에 의한 세균의 증식 억제 효과에 대하여 연구하였다. 닭가슴살 분쇄육의 일반성분은 수분 72.98±0.15%, 조단백질 23.37±0.46%, 조지방 1.00±0.03%, 조회분 1.90±0.03%였다. 향신료 첨가에 의한 미생물 증식 억제 효과는 로즈마리 > 마늘 > 겨자 순이었으며, 첨가량이 증가할수록 억제 효과가 커졌다. 닭고기 분쇄육의 일반세균 및 대장균 증식 억제를 나타내는 향신료의 최적 첨가 농도는 로즈마리 2%, 마늘 4%, 겨자 1.2%였다. 일반세균 및 대장균에 대한 증식 억제 효과는 단독 및 혼합 첨가 시 저장기간 동안 기간별로 차이가 있었고, 저장 9일째 억제 효과는 MixA(97.4%) > 로즈마리(96.9%) > MixB(96.3%) > 마늘(53.7%) > 겨자(33.3%) 순이었다. 닭고기 분쇄육에 살균마늘과 비살균마늘을 첨가하여 비교했을 때 일반세균 수는 살균마늘 처리구가 비살균마늘 처리구에 비해 초기 2.6-3.0 log CFU/g, 9일째 2.4-3.2 log CFU/g 정도 낮았고, 저장기간이 경과할수록 그 수가 감소하였다. 비살균마늘 처리구는 대조구보다 높은 일반세균 수를 나타냈으며, 저장기간이 경과할수록 증가하는 경향을 나타냈다. 대장균 수의 경우 살균마늘 처리구가 비살균마늘 처리구에 비해 저장 0일째 0.4-1.0 log CFU/g, 9일째 0.5-1.5 log CFU/g 정도 낮았으며, 저장기간의 경과에 따른 변화는 일반세균 수와 비슷한 경향을 나타냈다. 결론적으로 로즈마리, 마늘, 겨자의 다양한 혼합적용에 의해 닭고기 분쇄육 제품의 미생물적 안전성이 향상되었다.

Pb[(Sb1/2 Nb1/2)0.08 Zr0.49 Ti0.48]O3에서의 MnO2 첨가에 따른 미세구조와 전기적 물성변화에 대한 연구 (The Microstructure and Electrical Properties in the Pb(Sb1/2 Nb1/2)O3-PbTiO3-PbZrO3 System with MnO2 Addition)

  • 강원호;박원규;김호기
    • 한국세라믹학회지
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    • 제24권6호
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    • pp.537-542
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    • 1987
  • The microstructure and electrical properties of Pb[(Sb1/2 Nb1/2)0.08 Zr0.49 Ti0.48]O3 with MnO2 addition have been investigated in this work. The amount of MnO2 addition was 0, 0.4, 0.8, 1.2, 2.0 wt%, respectively. The soild solution range of MnO2 that assumed in this composition according to thevariations of micro-structure and electrical properties was 0.4-0.8 wt%.

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$CaO-TiO_2-P_2O_5$계 다공질 결정화 유리의 물성에 미치는 알카리 금속 산화물의 첨가효과 (Addition Effects of Alkali Metal Oxide on Some Properties of Porous Glass-Ceramics in the $CaO-TiO_2-P_2O_5$ System)

  • 장순규;최세영
    • 한국세라믹학회지
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    • 제31권11호
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    • pp.1337-1345
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    • 1994
  • Glasses in the system of 45CaO-25TiO2-30P2O5 containing 1 mole% of M2O(M=Li, Na, K) were melted and crystallized. And their crystal phases were Ca3(PO4)2, CaTi4(PO4)6, and TiO2. Porous glass-ceramics with skeleton of two crystal phase CaTi4(PO4)6 and TiO2 were prepared by selective leaching of Ca3(PO4)2 with 0.1 N-HCl. Glass transition temperature(Tg) and crystallization temperature(Tc) were decreased by addition of 1 mole% alkali metal oxide. Pore size of porous glass-ceramics was increased with increasing heat treatment temperature and its dependence on heat treatment temperature was decreased with addition of Na2O and K2O. It was found that porous glass-ceramics of parent glass and containing 1mole% M2O(M=Li, Na, K) composition had maximum specific surface area, porosity and maximum of crystallzed phase by heat treatment at 80$0^{\circ}C$, 76$0^{\circ}C$, 78$0^{\circ}C$, 80$0^{\circ}C$ respectively.

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$Ni_{0.5}Cu_{0.1}Zn_{0.4}Fe_2O_4$ Ferrite-Rubber Composite의 전파흡수특성에 미치는 열처리 온도의 영향 및 Carbon 첨가효과 (Effect of Carbon Addition and Influence of Heat-treatment Temperature on Electromagnetic Wave Absorbing Properties of $Ni_{0.5}Cu_{0.1}Zn_{0.4}Fe_2O_4$-Rubber Composite)

  • 윤국태;이찬규;박연준
    • 한국자기학회지
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    • 제11권1호
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    • pp.14-20
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    • 2001
  • The structure, shape, size, and magnetic properties of Ni$_{0.5}$Cu$_{0.1}$Zn$_{0.4}$Fe$_2$O$_4$ have been investigated as a function of annealing temperatures. In order to control the microwave absorbing properties of ferrite-rubber composite and the complex losses (magnetic loss and conduction loss), the effect of carbon addition was also studied. It was found that the coercive force decreased with increasing heat-treatment temperatures. Relative complex permeability and reflection loss were measured by the network analyzer. As a result, the natural resonance occurred in the low frequency tinge, and the matching frequency of the ferrite-rubber composite prepared at 130$0^{\circ}C$ was found to be lower. As heat-treatment temperatures were increased, the magnetic loss ($\mu$$_{r}$", $\mu$$_{r}$′) and the dielectric loss ($\varepsilon$$_{r}$"/$\varepsilon$$_{r}$′) were increased. It was caused that the absorption characteristics of the absorber were improved. The conduction loss and magnetic loss were expected to be occurred together because two matching frequencies were shown with carbon addition. It was confirmed that the matching frequency of the microwave absorber could be controlled by controlling heat-treatment temperatures and carbon additions.ons.tions.

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야초 사일리지의 품질향상에 관한 연구 III. 칡 사일리지에 있어서 전분첨가효과 (Studies on Quality of Silage form Domestic Herbage III. Effects of starch addition on the quality of Kudzu silage)

  • 김종쾌;황태기;김대진
    • 한국초지조사료학회지
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    • 제10권1호
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    • pp.48-54
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    • 1990
  • In order to investigate effects of starch addition on the fermentative quality and dry matter digestibility (DMD) of Kudzu, Puerarie thunbergii Bentham plants were ensiled by the conventional method in small experimental plastic silo of 7.5 liter with different levels of starch addition. The fermentative quality, neutral detergent fiber (NDF), acid detergent fiber (ADF), and acid detergent lignin (ADL) of silage were determined by chemical analysis, and in vitro dry matter digestibility (DMD) by pepsin-cellulase technique. Total digestibile nutrients (TDN), digestible energy (DE) and metabolizable energy (ME) were calculated with DMD. The results obtained were as follows; 1. Acetate, butyrate, PH, NDF, ADF, and ADL of Kudzu silage were reduced with increasing of starch addition but the contents of lactate and total acid were increased. 2. The DMD was marked 47.5, 49.5, 51.2, 57.9 and 62.0 % under starch addition with a rate of 0, 2, 4, 6 and 8 %, respectively. 3. TDN, DF and ME were increased with high rate of starch addition. 4. The regression equation and correlation of Kudzu silage between level of starch (X) and DMD (Y) were Y= 41.6 + 1.86 X (I= 0.96, P < 0.01), of silage between Flieg's score (X) and DMD (Y) were Y= 41.6 + 0.23 X (I= 0.96, P < 0.01) and of silage between level of starch (X) and Flieg's score (Y) were Y= 21.3 + 7.97 X (I= 0.97, P < 0.01), respectively.

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Blocking of Zeolite Pore by Loading Ni-Pt Nanoparticles for Maximization of Isomerization Selectivity

  • Bhavani, A. Geetha;Reddy, N. Subba
    • Korean Chemical Engineering Research
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    • 제58권4호
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    • pp.658-664
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    • 2020
  • Zeolite HY is wet impregnated with Ni (0.1, 0.3, 0.4, 0.5 wt%), Pt (0.1 wt%) and reduced in presence of hydrogen to form nanosized particles of Ni and Pt. All the catalysts were characterized by XRD, TEM, ESCA, NH3-TPD, Pyridine adsorbed FT-IR and BET. Characterization results confirm that the Ni and Pt fractions effectively rehabilitated the physio-chemical properties of the zeolite HY catalysts. Further, all the reduced catalyst were screened with hydroisomerization of m-xylene at LHSV = 2.0 h-1 in the temperature range 250-400 ℃ in steps of 50 ℃ in hydrogen atmosphere (20 ml/g). The addition of Ni to Pt catalyst increases hydroisomerization conversion, as well as maximizes p-xylene selectivity by restricting the pore size. The increasing trend in activity continues up to 0.3 wt% of Ni and 0.1 wt% Pt addition over zeolite HY. The increasing addition of Ni increases the total number of active metallic sites to exposed, which increases the metallic sites/acid sites ratio towards the optimum value for these reactions by better balance of synergic effect for stable activity. The rate of deactivation is pronounced on monometallic catalysts. The results confirm the threshold Ni addition is highly suitable for hydroisomerization reaction for product selectivity over Ni-Pt bimetallic/support catalysts.

미강유의 광산화와 항산화제의 방어작용 (Photo oxidation of Rice Bran Oil and Protective Action of Antioxidants)

  • 백태홍;이용국
    • 한국응용과학기술학회지
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    • 제4권1호
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    • pp.19-22
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    • 1987
  • To investigate the protective action of various antioxidants on the photooxidation of rice bran oil, it was irradiated with red and visible light in presence and absence antioxidants with or without sensitizer (methylene blue). 1. Rice bran oil with and without sensitizer in chloroform-ethanol (4:1, v/v) media was largely oxidized under visible light irradiation. on the other hand, rice bran oil without sensitizer was hardly oxidized under red light irradiation. 2. Rice bran oil with sensitizer was oxidized much faster than that without. And the absorbance of it irradiated with visible was increased more than that with red light. 3. The effectiveness of antioxidants on the rice bran oil photooxidation was same order as follows: Irradiation with visible light, no addition of sensitizer ${\beta}$-carotene > dl-{$\alpha}$-tocopherol > BHT > BHA Irradiation with visible light, addition of sensitizer ${\beta}$-carotene > BHT > dl-${\alpha}$tocopherol > BHA Irradiation with red light, addition of sensitizer ${\beta}$-carotene > BHA > BHT > dl-${\alpha}$-tocopherol From these results, we concluded that rice bran oil was largely oxidized under visible light irradiation, therefore it must be protected from photooxidative deterioration by the addition of antioxidants.

상수리나무림 임상에 공급한 무기질소가 토양호흡에 미치는 영향 (Effects of Nitrogen Addition on Soil Respiration)

  • 최주섭;문형태
    • The Korean Journal of Ecology
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    • 제27권3호
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    • pp.155-159
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    • 2004
  • In order to gain a better understanding of how forests participate in the cycling of carbon, effects of nitrogen addition on soil respiration were investigated on the oak forest in Kongju, Korea. Study site was divided into control, treatment f and treatment 2 plots, with 5 replication in each plot. In each replicate of treatment 1 and treatment 2 were fertilized with ammonium nitrate (NH$_4$NO$_3$), 30 g/$m^2$ and 60 g/$m^2$, respectively. Soil respiration, soil temperature, ammonium-N and nitrate-N were measured during the experimental period. Ammonium-N and nitrate-N in Ta were higher than those in control and T$_1$. Ammonium-N and nitrate-N in top-soil and sub-soil decreased sharply in August after bi9 rainfall in July in T$_1$ and T$_2$, however, those in control plot increased. Soil respiration in T$_2$ Plot showed consistently higher than those in control and T$_1$ until the end of July. However, soil respiration was similar among the control, T$_1$ and T$_2$ in mid-August and September The amount of Co$_2$ released from soil respiration in control, T$_1$ and T$_2$ in mid-August was 8.0$\pm$0.4, 9.3$\pm$0.6 and 10.2$\pm$0.5 $\mu$mol$^{-1}$ ㆍm$^{-2}$ ㆍs$^{-1}$ , respectively. However, those in control, T$_1$ and T$_2$in mid-August was 13.0$\pm$0.4, 13.5$\pm$0.5, 13.3$\pm$0.6 $\mu$mol$^{-1}$ ㆍm$^{-2}$$^{-1}$ , respectively. The results suggest that nitrogen addition in this oak forest has a positive effect on soil respiration.