• Proceedings of the Membrane Society of Korea Conference
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• 1993.04a
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• pp.12-15
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• 1993

방사선 graft 중합법을 이용하여, microfiltration hollow fiber(MF)에 affinity ligand로서 소수성 아미노산 (tryptophan)을 고정하였다. affinity막에 압력차를 주어 막의 안쪽으로 부터 바깥쪽으로 단백질 용액을 투과시키면서, 단백질의 흡착 성능을 알아보았다. affinity막이 확산이동 저항이 없는 우수한 분리 기능 재료인 것을 나타내었다.

• Journal of Korean Society of Water and Wastewater
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• v.23 no.6
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• pp.855-864
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• 2009

The main object of this work was to determine the influence of periodic chemical backwash on filtration resistance in membrane filtration system. In this work Hermia's models were used to investigate the fouling mechanisms involved in the microfiltration of $0.45{\mu}m$ filtered sewage feed. Batch microfiltration experiments were performed at transmembrane pressure 0.4 bar and different feed SCOD concentration (9~67 mgSCOD/L). The results showed that the best fit to experimental data corresponded to the intermediate blocking model followed by the standard and complete blocking model for all the experimental conditions tested. From the simulation results of filtration performance, it was found that in order to maintain sustainable operation of membrane filtration system, irreversible foulant component accumulated continuously on membrane surface and/or pore must be effectively removed. In addition, it was verified that periodic chemical backwash using NaOCl or NaOH effectively improved filtration performance of membrane.

• Journal of the Korean Ceramic Society
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• v.40 no.1
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• pp.77-80
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• 2003

Adsorption of glycine on$Si_3N_4$powder surface has been investigated, which is supposed to enhance the formation of passive layer inhibiting oxidation in aqueous solution. In the basic solution, multinuclear surface complexing between Si and dissociated ligands was responsible for the saturated adsorption of glycine. In addition, $CeO_2$-based CMP slurry containing glycine was manufactured and then applied to planarize$SiO_2$and$Si_3N_4$thin film. Owing to the passivation by glycine, the removal rates, Rh, were decreased, however, the selectivities, RE(SiO$_2$)/RR($Si_3N_4$), increased and showed maximum at pH=12. The suppressed oxidation and dissolution by adsorbate were correlated with the dissociation behavior of glycine at different pH and subsequent chemical adsorption.

• Membrane Journal
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• v.27 no.1
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• pp.68-76
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• 2017

Flat membrane with $0.4{\mu}m$ pore size was prepared with PVdF (polyvinylidene fluoride) nanofiber, which has the advantages such as excellent strength, chemical resistance, non-toxicity, and incombustibility. The spiral wound module was manufactured with the flat membrane and a woven paper. Hybrid water treatment process was composed of the PVdF nanofibers spiral wound microfiltration and granular activated carbon (GAC) adsorption column. Effect of GAC packing mass was investigated by comparing the case of recycling or discharging the treated water using the synthetic solution of kaolin and humic acid. After each filtration experiment, water back-washing was performed, and recovery rate and filtration resistances were calculated. Also, effect of GAC adsorption was compared by measuring turbidity and $UV_{254}$ absorbance. As a result, there was no effect of GAC packing mass on turbidity treatment rate; however, the treatment rate of $UV_{254}$ absorbance was 0.7~3.6% for recycling the treated water, and increased to 3.2-5.7% for discharging the treated water. In the case of recycling the treated water, reversible filtration resistance ($R_r$) and irreversible filtration resistance ($R_{ir}$) trended to decrease as increasing GAC packing mass; however, total fitration resistance ($R_t$) was almost constant, and recovery rate of water back-washing trended to increase a little.

• Journal of the Korea Institute of Building Construction
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• v.19 no.1
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• pp.31-38
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• 2019

In this study, amine derivatives and ion exchange resins were selected to actively control penetration ions ($SO{_4}^{2-}$, $Cl^-$) as the element technology of repair materials for concrete structures in drainage environments. Ions ($SO{_4}^{2-}$, $Cl^-$) adsorption performance and corrosion resistance of calcium hydroxide solution with amine derivative and ion exchange resin were confirmed by ion chromatography and potentiostat analysis. As a result of the experiment, it was confirmed that the amine derivative is excellent in the adsorption of chlorine ion and the ion exchange resin is excellent in the adsorption of sulfate ion. It has been confirmed that corrosion resistance can be increased by proper combination of two materials in the calcium hydroxide solution containing sulfate ion and chloride ion simulating sewage environment.

• Nuclear Engineering and Technology
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• v.16 no.2
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• pp.80-88
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• 1984

The removal mechanism of air borne methyl iodide by triethylenediamine (TEDA) impregnated charcoal bed was investigated. The analysis of experimental data indicates that pore diffusion is the rate controlling step when the air velocity is over 20cm/sec, and both fore diffusion resistance and external mass transfer resistance are contributed to the overall resistance when the air velocity is 10cm/sec. The adsorption model to describe the performance of impregnated charcoal bed under dry condition where water vapors do not exist in air, is proposed. The calculated values and experimental results are well matched.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.84.1-84.1
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• 2018

현재 사용되고 있는 화석 연료는 고갈되고 있으며 지구온난화와 같은 환경오염을 일으키는 주원인으로 이를 대체하는 에너지원으로서 수소가 주목받고 있다. 그러나 수소는 상온 및 대기압에서 4 %의 낮은 LEL (lower explosive limit)을 가지므로 높은 인화성과 폭발성을 가진다. 또한 무색, 무취한 성질을 가지고 있어 사람에 의해 검출되지 않는다. 그러므로 상온에서의 수소 농도를 정량화하고 검출하기 위한 방법이 필요하다. 수소를 검출하기 위한 수소센서에는 저항, 촉매, 광학, 일함수 등을 이용한 센서들이 있으며 그 중 저항을 이용한 귀금속 기반 수소센서가 널리 알려져 있다. 팔라듐(Pd), 백금 (Pt)와 같은 귀금속 기반 수소센서는 높은 수소 용해도 및 확산으로 인해 수소에 우수한 선택성을 가진다. 특히 Pd는 흡착에 대한 친화성이 매우 우수하다. 팔라듐에 수소가 노출되면, 수소가 Pd 격자로 확산되어 Pd-hydride를 형성시켜 부피가 팽창되고 저항이 변한다. 이러한 특성을 바탕으로 팔라듐의 저항 변화를 기반으로 한 수소센서의 개발이 진행되고 있다. 본 연구에서는 물리기상증착 (PVD)을 이용하여 다양한 다공성 나노 Pd 박막을 가지는 수소센서를 제작하였으며, 수소 농도에 따른 실온에서의 수소 검출 특성을 관찰하였다. 제작된 다공성 나노 Pd 박막의 특성은 SEM, TEM 및 XRD를 통하여 확인하였다. 다공성 나노 Pd 박막이 수소에 노출 되었을 때 전자 산란 및 접촉 면적의 증가에 따른 저항의 변화를 확인하였다.

• Applied Chemistry for Engineering
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• v.33 no.6
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• pp.630-635
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• 2022

Copper(II) oxide (CuO), electroless plated on a nitrogen-containing carbon sponge prepared by a melamine sponge thermal treatment, was developed as a nitric oxide (NO) gas sensor that operates without a wafer. The CuO content on the surface of the carbon sponge increased as the plating time increased, but the content of nitrogen known to induce NO gas adsorption decreased. The untreated carbon sponge showed a maximum resistance change (5.0%) at 18 min. On the other hand, the CuO plated sample (CuO30s-CS) showed a maximum resistance change of 18.3% in 8 min. It is considered that the improvement of the NO gas sensing capability was caused by the increase in hole carriers of the carbon sponge and improved movement of electrons due to CuO. However, the NO gas detection resistance of the CuO electroless plated carbon sponge for 60 s decreased to 1.9%. It is considered that the surface of the carbon sponge was completely plated with CuO, resulting in a decrease in the NO gas adsorption capacity and resistance change. Thus, CuO-plated carbon sponge can be used as an effective NO gas sensor because it has fast and excellent resistance change properties, but CuO should not be completely plated on the surface of the carbon sponge.

• Journal of Soil and Groundwater Environment
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• v.10 no.5
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• pp.45-51
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• 2005

The sorption/desorption characteristics of phenanthrene on the natural manganese oxide (NMD) were investigated in the presence of phenolic compounds. 4-chlorophenol (4-CP) was effectively oxidized by NMD catalyzed reaction and transformed into humic-like macromolecular compound through inter-or cross-coupling reaction between byproducts. As 4-CP was degraded with time, sorbed amount of phenanthrene on NMD was significantly increased, resulting from the formation of oxidative coupling products. These results imply that NMD can be used for simultaneous treatment of phenolic contaminants and polycyclic aromatic hydrocarbons (PAHs) in soils, sediments, or water. Also, sorbed phenanthrene on NMD in the presence of 4-CP showed high degree of desorption resistance, indicating that sequestration process of phenanthrene was ongoing with time.

• Applied Chemistry for Engineering
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• v.27 no.1
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• pp.74-79
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• 2016

The effects of scale formation of hardness material caused by electrode reactions on the desalination performance of the membrane capacitive deionization (MCDI) were investigated. During the repeated adsorption and desorption process for the influent containing $Ca^{2+}$ ion, changes in effluent concentration and cell potential with respect to the number of adsorption were analyzed. It was found that $OH^-$ generation at the cathode was initiated at about 0.8 V or more of cell potential. In addition, the scale of $Ca(OH)_2$ was formed on the surface of cathode carbon electrode by combining adsorbed $Ca^{2+}$ ions and $OH^-$ ions generated from electrode reaction. As the scale was forming, the electrical resistance of carbon electrode was increasing, which resulted in the decrease of the adsorption amount. In the case of the operation at 1.5 V cell potential, the adsorption was reduced to 58% of the initial adsorption amount due to the scale formation.