• Title/Summary/Keyword: 흡수 스펙트럼 분석

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The Infrared Absorption Spectra of Molecular Clusters of Acetonitrile and DMF Diluted by Matrices at 80K (매트릭스에 의해 희석된 ACETONITRILE과 DMF 분자클라스터의 80K에서 적외선 흡수 스펙트럼의 분석)

  • Kim, Wan Hee;Jeong, Jong Hak;Jeong, Gi Ho
    • Analytical Science and Technology
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    • v.5 no.3
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    • pp.285-294
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    • 1992
  • Structures of dimers of the acetonitrile and DMF diluted by carbon-tetrachloride and xenon matrices at 80K were studied with infrared absorption spectroscopy. Sample and matrix materials were codeposited onto a KBr cold trapping window. Infrared absorption spectra of pure samples and diluted samples were compared to explain the structures of dimers. The acetonitrile dimer showed the antiparallel shape and the DMF dimer showed the linear shape. After annealing, the infrared spectrum of the diluted sample showed the same shape with that of the pure sample.

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Semiconductor laser-based absorption spectroscopy for monitoring physical vapor deposition process (증기증착 공정 감시를 위한 반도체 레이저 흡수 분광학)

  • 정의창;송규석;차형기
    • Journal of the Korean Vacuum Society
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    • v.13 no.2
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    • pp.59-64
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    • 2004
  • A study on the semiconductor laser-based atomic absorption spectroscopy was performed for monitoring physical vapor deposition process. Gadolinium metal was vaporized with a high evaporation rate by electron beam heating. Real-time atomic absorption spectra were measured by using tunable semiconductor laser beam at 770-794 nm (center wavelength of 780 nm) and its second harmonic at 388-396 nm. Atomic densities of metal vapor can be calculated from the absorption spectra measured. We plot the atomic densities as a function of the electron beam power and compare with the evaporation rates measured by quartz crystal monitor. We demonstrate that the semiconductor laser-based spectroscopic system developed in this study can be applied to monitor the physical vapor deposition process for other metals such as titanium.

Mössbauer and Infrared Absorption Spectroscopy of Tourmaline Minerals (전기석 광물의 뫼스바우어 및 적외선 흡수 분광학)

  • Kim, Hee Jong;Kim, Soo Jin
    • Journal of the Mineralogical Society of Korea
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    • v.6 no.2
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    • pp.105-115
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    • 1993
  • $M{\ddot{o}}ssbauer$ and Infrared absorption spectra of the iron-bearing tourmaline minerals show that the ferrous and ferric ions occupy the Y and Z octahedral sites. The Fe ions are almost ferrous, predominantly partitioning into Y site and partly take in Z site. The $Fe^{2+}$ content of the Z sites in brownish black tourmaline minerals are higher than that in blue/green tourmaline minerals. Therefore, 720 nm peak of brownish black samples is broader than that of blue/green samples in optical spectra. All of the blue/green tourmaline minerals used in experiment have only $Fe^{2+}$ ion. The IR spectra of tourmaline depend on the cation environments around OH groups, as also evidenced by their chemical analyses. There appear no difference in IR spectrum between O(1)H and O(3)H binding characters in the heat-treated samples. But the characteristic $3565cm^{-1}$ peak appears in the ferrous hydroxyl bearing silicates, where dehydroxylation temperature for OH coordinated to $Fe^{2+}$ is $700{\sim}800^{\circ}C$.

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Spectral Analysis for Non-Invasive Total Hemoglobin Measurement in the Region from 400 to 2500nm (총헤모글로빈 농도를 비침습적으로 측정하기 위한 400-2500nm 대역의 흡수 스펙트럼 분석)

  • Jeon, Kye-Jin;Kim, Yoen-Joo;Kim, Su-Jin;Kim, Hong-Sig;Yoon, Gil-Won
    • Journal of Sensor Science and Technology
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    • v.10 no.6
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    • pp.273-278
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    • 2001
  • Absorption spectra of blood components have been measured for the purpose of predicting the total hemoglobin concentration. We obtained absorption spectra of major blood components from the visible to near-infrared of $400{\sim}2500nm$ region. In the near-infrared, water is the main absorbing constituent. The amount of water in the sample cell varies depending on the volume of solute concentration(water displacement). We acquired water-compensated spectra by considering the variation of water volume depending on the variation of analyze concentration. Those spectra show inherent absorption peaks of analyzes and linearity with respect to concentration. We selected wavelengths for non-invasive measurement of hemoglobin concentration considering the scattering effect of tissue and the interference of other blood components.

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Ferrimagnetic Resonance Studies of Poly-crystalline $Mn_x$ Ferrites (Mn-Zn 훼라이트의 자기공명 특성연구)

  • 김정렬;박명희;박윤창
    • Journal of the Korean Magnetics Society
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    • v.2 no.2
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    • pp.105-113
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    • 1992
  • 조성이 Mn$_{x}$Zn$_{1-x}$ Fe$_{2}$O$_{4}$ 훼라이트(x=0.75, 0.52)를 pusher type 연속 전기로를 이용하여 질소 분위기하에서 1360 .deg. C 로 3시간 동안 소결하여 얻어냈다. 본 연구에서는 스피넬 구조인 Mn-Zn 훼라이트의 FMR(Ferrimagnetic Resonance) 스펙트럼 특징과 초기투자율과의 상관성을 조사하고자 EPR X-band 스펙 트로미터를 이용 9.50 GHz의 microwave frequency에서 FMR 실험을 수행하였다. FMR 공명흡수선은 주 자기공명 흡 수선외에 낮은 자기장에서 약한 subsidiary 공명흡수선을 나타내는데 온도변화에 따른 주 자기공명 흡수선과 sub- sidiary 공명흡수선(제2, 제3 공명흡수선)의 세기, 공명선폭, g값 등의 온도 의존성을 연구함으로써 제2 공명흡수 선이 나타나는 원인을 분석하였으며, 자기공명 흡수선의 g값, 자기공명선 세기, 그리고 공명선폭과 초기투자율의 상관성을 연구하였다. 실험 결과 주 자기공명 흡수선의 g값, 자기공명선 세기, 공명선폭은 초기투자율 값과 밀접 한 관련이 있음을 확인할 수 있었다.었다.

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Variations of superconducting characteristics of $YBa_2Cu_3O_{7-\delta}$ by Ag-doping (은 첨가에 의한 $YBa_2Cu_3O_{7-\delta}$의 초전도 특성 변화)

  • 강형부;김현택;이영철
    • Electrical & Electronic Materials
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    • v.6 no.6
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    • pp.514-522
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    • 1993
  • 본 연구에서는 Ag/ 첨가에 의한 YB $a_{2}$C $u_{3}$ $O_{7-{\delta}}$산화물의 초전도 특성 변화를 조사하였다. Ag가 첨가된 YB $a_{2}$C $u_{3-x}$A $g_{x}$ $O_{7-{\delta}}$ 산화물 시료를 만들고 이 시료들에 대한 X-ray 회절분석, IR흡수 스펙트럼분석, 임계온도(Tc)측정 및 자화(M-H)특성 측정등을 통하여 제조된 시료의 물리적 성질을 조사하였다. X-ray 회절실험 결과로 부터 x.leq.0.03인 경우에는 YB $a_{2}$C $u_{3-x}$A $g_{x}$ $O_{7-{\delta}}$가 단일상의 물질로 존재하고 x가 증가함에 따라 불순물상( $Y_{2}$ $O_{3}$, 순Ag)이 나타남을 알 수 있었다. IR흡수의 실험결과에서 Cu와 치환되어 들어간 Ag의 Ag-O 결합에 의한 흡수 스펙트럼(670$cm^{-1}$ /)이 관측되었다. 실험 결과로 부터 치환된 Ag의 양 x가 증가함에 따라 Tc가 조금씩 낮아지는 경향이 있었으며 자화의 세기 및 임계자장( $H_{C2}$)은 급격히 감소함을 알 수 있었고 또 M-H특성곡선에는 히스테리시스 특성이 나타났다.났다..났다.다.

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Preparation and characterization of nearly stoichiometric $LiNbO_3$ crystals by VTE method (VTE법에 의한 nearly stoichiometric $LiNbO_3$의 성장 및 특성)

  • 김상수;유동선
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.6-17
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    • 1997
  • Lithium niobate single crystals with various [Li]/[Nb] ratios were grown by the Czochralski method from melts having compositions varing between 48.6 ~ 58.0 mol % $Li_2O$. A vapor transport equilibration technique has been used to improve the homogeneity and adjust the [Li]/[Nb] ratio in small $LiNbO_3$ single crystals grown by the Czochralski method. When equilibrated with a Li-rich powder (65 mol%$Li_2O$), containing a mixture of $LiNbO_3$ and $Li_3NbO_4$, crystals of nearly stoichiometric composition can be obtained. This was established by studying the composition dependence of the following properties; lineshape, intensity and linewidth for the electron paramagnetic resonance (EPR) of $Fe^{3+}$ energy of the fundamental absorption edge and $OH^-$ absorption spectra.

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A Study of Infrared Emitter with High Efficiency for Curing Car Paints (자동차 도료 경화용 고효율 적외선 방사체에 관한 연구)

  • Gang, Byeong-Cheol;Choe, Jeong-Jin;Hwang, Seon;Kim, Gi-Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2008.11a
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    • pp.114-114
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    • 2008
  • 자동차 보수도료 경화는 주로 열풍방식을 사용하고 있지만 적외선 가열방식을 사용하면 품질이 향상 되고 에너지 절약 등의 이점이 있다. 따라서 자동차 보수도료의 경화용으로 사용할 적외선 방사체를 개발하였다. 자동차 보수도료의 적외선 흡수 스펙트럼과 적외선 방사체 방사 스펙트럼이 일치해야 도료의 경화효율이 우수해짐을 알 수 있었고 열풍방식과 비교하여 경화된 도막의 품질 및 경화시간에 대한 실험데이터를 분석하였다.

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Intersubband absorption in strained Si(110)/SiGe multiple quantum wells (Si(110)/SiGe 다중 양자 우물에서 수직 입사광에 의한 적외선 흡수)

    • Korean Journal of Optics and Photonics
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    • v.10 no.4
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    • pp.306-310
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    • 1999
  • Electron intersubband absorption in Sb $\delta$-doped Si(110)/SiGe multiple quantum well structures is observed. Normally incident light can excite electrons in Si(110) quantum wells, which is not possible for Si(001) or GaAs quantum wells. The influence of Ge composition in SiGe barries is investigated. As the Ge composition in SiGe barriers increases, the absorption strength is decreased and the transition energy is increased. It is verifired by comparing the calculated and experimental results obtained at various incident and polarization angles that normally incident light and parallel incident light are absorbed in different processes.

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Analysis of Motor-Current Spectrum for Fault Diagnosis of Induction Motor Bearing in Desulfurization Absorber (탈황 흡수탑 유도전동기 베어링 결함 진단을 위한 전류 스펙트럼 해석)

  • Bak, Jeong-Hyeon;Moon, Seung-Jae
    • Plant Journal
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    • v.11 no.2
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    • pp.39-44
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    • 2015
  • According to a research that is based on a previous study, But in a different way, This study shows fault diagnosis of Induction motor bearing which runs in coal-fired power plant industries on Desulfurization absorber agitator using Spectrum analysis of Stator Current and visual inspection. As a result of harmonic content analysis of stator current spectrum, It was possible to detect ball and outer race fault frequency. The comparison in the context of this experiment proves that the amplitude of faulty frequency is increased in three times at a fault in ball and in outer race. Spectrum analysis of stator current can be used to detect the presence of a fault condition as well as experiment in faulty bearings, besides early fault detection in bearings can prevent unexpected power generation loss and emergency maintenance cost.

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