• 월간산업보건
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• s.49
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• pp.4-10
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• 1992

• Analytical Science and Technology
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• v.10 no.5
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• pp.1105-1114
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• 1997

• Electrical & Electronic Materials
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• v.12 no.6
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• pp.1-10
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• 1999

• Proceedings of the Optical Society of Korea Conference
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• 2002.11a
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• pp.78-79
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• 2002

• Korean Journal of Optics and Photonics
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• v.12 no.3
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• pp.158-164
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• 2001

We observed a velocity-selective saturated absorption spectrum when the pump beam intersects the probe beam at a finite angle with a saturated absorption spectroscopic configuration in the cesium vapor cell. And we also observed a dispersion-like signal by measuring the difference between two velocity-selective absorption spectra produced by two parallel probe beams intersected by one pump beam. The dispersion-like signal was changed with the crossing angle and the crossing position of the pump and probe beams and compared with the calculated result. The dispersion-like signal was used as a frequency discriminator, and the laser could be frequency-stabilized without any frequency modulation. As a result, the square root of Allan variance was $\sigma_y(\tau=1s)=7$\times10^{-12}$, for the sampling time of 1 s.of 1 s.

• The Bulletin of The Korean Astronomical Society
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• v.39 no.1
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• pp.82.2-82.2
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• 2014

지상에서 천체 분광관측을 하면 천체 스펙트럼에 대기 흡수선이 겹쳐 나타나기 때문에 이를 제거해주어야 한다. 대기 흡수선은 주로 적외선 영역에 많이 나타나고, 주로 H2O, O2, CO2, O3, CH4 등의 분자에 의하여 생긴다. 대기 흡수선을 제거하기 위하여 조기형 별을 관측하여 그 스펙트럼으로 천체스펙트럼을 나누어주는 방법이 널리 이용된다. 본 연구에서는 인공 흡수선 스펙트럼을 계산하여 대기 흡수선을 제거하는 방법을 소개하기로 한다. 인공 흡수선 스펙트럼 계산은 LBLRTM 코드를 이용하였으며 대기모델은 MIPAS를 채택하였다. 이렇게 계산한 인공 스펙트럼을 실제 관측된 대기 흡수선에 맞추기 위하여 가우시안 라인 프로파일을 이용하고 파장 눈금을 조정해 준다. 이 과정에서 대기 흡수선을 정밀 시선속도 측정을 위한 파장 표준으로 이용할 수 있다.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.49 no.11
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• pp.893-900
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• 2021

In this study, air density in a narrow test section is measured using a laser absorption spectroscopy system that detects oxygen absorption lines. An absorption line pair at 13156.28 and 13156.62 cm^-1 are detected. A gas chamber with a height of 40 mm is used as a narrow test section. A triangular spiral-shaped laser path is applied in the gas chamber to amplify absorption strength by extending laser beam path length. A well-known logarithm amplifier and a secondary amplifier are used to electrically amplify absorption signal. An AC-coupling is applied after the logarithm amplifier for signal saturation prevention and noise suppression. Procedure of calculating spectral absorbance from output signal is introduced considering the logarithm amplifier circuit configuration. Air density is determined by fitting the theoretically calculated spectral absorbance to the measured spectral absorbance. Test conditions with room temperature and a pressure range of 10~100 kPa are made in a gas chamber using a Bourdon pressure gauge. It is confirmed that air density in a narrow test section can be measured within a 16 % error through absorption signal amplification using a triangular spiral-shaped beam path and a logarithm amplifier.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.2
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• pp.121-131
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• 2021

Magnesium (Mg) present in carbonate minerals as impurities has been used as a geochemical proxy to infer the environmental conditions where the minerals precipitated. The reliability of Mg geochemical proxies requires fundamental understanding of Mg incorporation into minerals based on accurate speciation of Mg ²⁺ in the crystal structure, which is determined mainly by application of X-ray absorption spectroscopy (XAS). However, high uncertainties are involved in interpreting the XAS spectra of minerals containing trace amount of Mg ²⁺. Because density function theory (DFT) can predict an XAS spectrum for a crystal structure, DFT calculations can reduce the uncertainties in the interpretation of the XAS spectrum. In this study, we calculated ab initio Mg K-edge absorption spectra of Mg silicates and (hydr)oxides based on DFT and analyzed the correlation between the calculated spectra and Mg structural parameters. Our ab initio Mg K-edge absorption spectra well reproduced the key features of the experimental spectra. The absorption-edge positions of the calculated spectra showed the weak positive correlation with the average Mg-O bond distance or Mg effective coordination number. The current study shows that DFT-based core-level spectroscopy method is a powerful tool in providing standard Mg K-edge spectra of diverse Mg minerals and determining the Mg chemical species within carbonate minerals.

• The Bulletin of The Korean Astronomical Society
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• v.36 no.1
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• pp.44-44
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• 2011

상대적으로 온도가 낮은 태양계 천체의 적외선 분광관측 자료는 행성대기의 구성성분, 온도 분포와 haze및 구름을 포함한 대기의 수직구조에 대한 연구를 수행하는 기본이 된다. 외국 망원경의 관측자료에 의존했던 거대 행성 및 타이탄의 적외선 분광자료를 IGRINS를 통해 자체적으로 획득한 자료는 행성대기 연구를 주도적으로 진행할 수 있다는 점에서 큰 의미가 있다. 특히 목성, 토성, 타이탄 대기의K-band(2.0-2.45mm), H-band(1.45-1.80mm) 고분산 분광자료는 기존의 저분산 분광 관측 결과 또는 다른 파장대의 관측 결과와의 비교도 의미가 있을 것으로 기대한다. 그리고 IGRINS의 고 분해능을 이용하면 지구대기에 의해 지상관측이 쉽지 않은 $2.4-2.45{\mu}m$ 파장대에서 지구 흡수선 사이로 도플러 이동되어 들어오는 행성의 분광 자료를 얻을 수 있을 것으로 예상된다. 이에 따라 우리는 IGRINS를 이용한 태양계 행성관측의 시나리오를 마련하고자 한다.

• Clean Technology
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• v.26 no.4
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• pp.293-303
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• 2020

According to the World Health Organization (WHO), air pollution is a typical health hazard, resulting in about 7 million premature deaths each year. Sulfur dioxide (SO2) is one of the major air pollutants, and the combustion process with sulfur-containing fuels generates it. Measuring SO2 generation in large combustion environments in real time and optimizing reduction facilities based on measured values are necessary to reduce the compound's presence. This paper describes the concentration measurement for SO2, a particulate matter precursor, using a wavelength modulation spectroscopy (WMS) of tunable diode laser absorption spectroscopy (TDLAS). This study employed a quantum cascade laser operating at 7.6 ㎛ as a light source. It demonstrated concentration measurement possibility using 64 multi-absorption lines between 7623.7 and 7626.0 nm. The experiments were conducted in a multi-pass cell with a total path length of 28 and 76 m at 1 atm, 296 K. The SO2 concentration was tested in two types: high concentration (1000 to 5000 ppm) and low concentration (10 ppm or less). Additionally, the effect of H2O interference in the atmosphere on the measurement of SO2 was confirmed by N2 purging the laser's path. The detection limit for SO2 was 3 ppm, and results were compared with the electronic chemical sensor and nondispersive infrared (NDIR) sensor.