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Synthesis of Multi-Walled Carbon Nanotube/Polystyrene (MWCNT/PS) Composites by Solution Process and Their Thermal Behavior (용액공정을 이용한 다중벽 탄소 나노튜브/폴리스티렌(MWCNT/PS) 복합체 합성 및 열적 거동)

  • Teng, Dayong;Shin, Young Hwan;Kwon, Younghwan
    • Applied Chemistry for Engineering
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    • v.19 no.4
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    • pp.421-426
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    • 2008
  • Multi-walled carbon nanotube/polystyrene (MWCNT/PS) composites with various MWCNT contents were prepared by using a solution process with an aid of surfactant. Particularly, PS's with 3 different molecular weights (${\bar{M}}_n$ = 101500 g/mole for PS-1, ${\bar{M}}_n$ = 89900 g/mole for PS-2, and ${\bar{M}}_n$ = 85000 g/mole for PS-3) were used in this study. Thermal behavior of these composites was examined by using an oscillator rheometer at $210^{\circ}C$ and $180^{\circ}C$, of above and below the critical flow temperature ($T_{cf}{\sim}195^{\circ}C$) of PS matrix, respectively. The storage and loss modulus, and the complex viscosity of these composites increased with increasing MWCNT content at both temperatures. Largest increases in the frequency-dependent moduli and complex viscosity were observed between 2 wt% and 5 wt% of MWCNTs at $210^{\circ}C$ and $180^{\circ}C$. Only the composite at $210^{\circ}C$ showed the rheological phase transition from a viscous-dominant to an elastic-dominant behavior of the composites at a certain MWCNT content. The MWCNT content at the rheological phase transition of MWCNT/PS composites generally increased with decreasing molecular weight of PS, and was measured to be 3.5 wt% for MWCNT/PS-1, 3.2 wt% for MWCNT/PS-2, and 3.0 wt% for MWCNT/PS-3 composites.

Simulation Model for Estimating Soil Temperature under Mulched Condition (멀칭에 따른 지온변화 모델의 작성 및 토양온도의 추정)

  • Cui RiXian;Lee Byun-Woo
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.1 no.2
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    • pp.119-126
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    • 1999
  • A numerical model using soil surface energy balance and soil heat flow equations to estimate mulched soil temperature was developed. The required inputs data include weather data, such as global solar radiation, air temperature, wind speed, atmospheric water vapor pressure, the optical properties of mulching material, and soil physical properties. The observed average soil temperature at 50 cm depth was used as the initial value of soil temperature at each depth. Soil temperature was simulated starting at 0 hour at an interval of 10 minutes. The model reliably described the variation of soil temperature with time progress and soil depth. The correlation between the estimated and measured temperature yielded coefficient values of 0.961, 0.966 for 5cm and 10cm depth of the bare soil, respectively, 0.969, 0.965 for the paper mulched soil, and 0.915, 0.938 for the black polyethylene film mulched soil. The percentages of absolute differences less than 2$^{\circ}$C between soil temperatures measured and simulated at 10 minute interval were 97.4% and 98.5% for 5 cm and 10cm for the bare soil, respectively, and 95.8% and 97.4% for the paper mulched soil, and 70.1% and 92.5% for the polyethylene film mulched soil. The results indicated that the model was able to predict the soil temperature fairly well under mulched condition. However, in the night time, the model performance was a little poor as compared with day time due to the difficulty of accurate determination of the atmospheric long wave radiation.

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A study on the electrochemical reduction of carbon dioxide (전기화학환원에 의한 이산화탄소의 수소화 반응연구)

  • Sim, Kyu-Sung;Kim, Jong-Won;Kim, Yeon-Soon;Myeong, Kwang-Sik
    • Journal of Hydrogen and New Energy
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    • v.9 no.1
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    • pp.8-15
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    • 1998
  • The catalytic hydrogenation of carbon dioxide has been studied for the fixation of carbon dioxide to mitigate global warming problems, but it needed hydrogen, which the price is still high. Recently, the electrochemical reduction of carbon dioxide has been drawn attractions because carbon dioxide could be converted to the valuable chemicals such as methane, ethane and alcohols electrochemically in the electrolyte solution using a catalytic electrode. This system is simple because the water electrolysis and hydrogenation take place at the same time using the surplus electricity at midnight. In this work, a continuous electrochemical reduction system was fabricated, which was composed of the reduction electrode (copper or perovskite type, $2{\times}2cm^2$), reference electrode(platinum, $2{\times}6cm^2$), standard electrode(Ag/AgCl), and potassium bicarbonate electrolyte solution saturated with carbon dioxide. The quality and quantity of the products and reduction current were analyzed, according to the electrolyte concentration and electrode type.

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Odorous Gas Removal in Biofilter with Powdered Activated Carbon and Zeolite Coated Polyurethane Foam (분말활성탄 및 제올라이트 담지 폴리우레탄 담체를 이용한 바이오필터에서의 악취가스 제거)

  • Lee, Soo-Chul;Kim, Dong-Jin
    • Clean Technology
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    • v.18 no.2
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    • pp.209-215
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    • 2012
  • The performance and removal efficiencies of a pilot scale biofilter were estimated by using ammonia and hydrogen sulfide as the odorous gases. Expanded polyurethane foam coated with powdered activated carbon and zeolite was used as a biofilm supporting medium in the biofilter. Odorous gases from the sludge thickener of a municipal wastewater treatment plant were treated in the biofilter for 10 months and the inlet ammonia and hydrogen sulfide concentrations were 0.1-1.5 and 2-20 ppmv, respectively. The removal efficiencies reached about 100% at the empty bed retention time (EBRT) of 3.6-5 seconds except for the adaptation periods. The pressure drop of the biofilter caused by the gas flow was also low that the maximum attained was 31 mm $H_2O$ during the operation. Its stability was confirmed in the long term due to the fact that the biofilter and the polyurethane medium had a minimum plugging and compression. The microbial community on the medium is critical for the performance of the biofilter especially the distribution of ammonia oxidizing bacteria (AOB) and sulfur oxidizing bacteria (SOB). The distribution of Nitrosomonas sp. (AOB) and Thiobacillus ferroxidans (SOB) was confirmed by FISH (fluorescence in situ hybridization) analysis. The longer the operation time, the more microbial population observed. Also, the medium close to the gas inlet had more microbial population than the medium at the gas outlet of the biofilter.

Effect of Change in Hydrological Environment by Climate Change on River Water Quality in Nam River Watershed (기후변화에 따른 남강유역의 수문환경의 변화가 하천수질에 미치는 영향)

  • Kang, Ji Yoon;Kim, Young Do;Kang, Boo Sik
    • Journal of Korea Water Resources Association
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    • v.46 no.8
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    • pp.873-884
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    • 2013
  • In Korea, the rainfall is concentrated in summer under the influence of monsoon climate. Thus, even a small climate change can be significant problems in water resources. As a result, a lot of attention has been focused on climate changes and a number of researches have been conducted in a manner commensurate with the attention to the climate change. This study is intended to forecast the changes in the flow and water quality of the Nam river resulting from the future climate changes in the Nam river basin using a watershed and water quality model. An SWAT model, as a watershed hydrologic model, was established after estimating a climate scenario using an artificial neural network method, and the established model was verified and adjusted using date from the Ministry of Environment to evaluate the applicability of the model. As a consequence, $R^2$ showed more than 0.7 in the simulation test, which satisfies the minimum required level. Results from the SWAT model and the future Namgang dam discharge calculated by HEC-ResSIM is used as input date for QUALKO. The results showed a huge variation in BOD depending on the annual flow of the river, which recorded a maximum difference of 2 mg/L between a rainy season and a dry season. It can be deduced that because rainfall and the runoff of a basin significantly account for the water quality of a river, higher water concentrations are recorded in a dry season in which the flow is not as much as that in a rainy season. It also can be said that water should be reserved in advance to secure water in the Nam river downstream for a dry season and be controlled in an effective and efficient manner to provide better water quality.

The Method for Evaluating Unsaturated Hydraulic Conductivity of the Bentonite-buffer Using Relative Humidity (상대습도를 이용한 벤토나이트 완충재의 불포화 수리전도도 평가방안)

  • Lee, Hang-Bok;Kim, Jin-Seop;Choi, Young-Chul;Choi, Heui-Joo;Kim, Kyungsu
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.1
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    • pp.69-77
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    • 2014
  • Unsaturated hydraulic conductivity of the bentonite-buffer was evaluated using the relative humidity data. The method for calculating unsaturated hydraulic conductivity was deduced from the general analytical equation representing the movement of water in unsaturated media, which was applied to the experimental results of water infiltration tests for identifying the behavior of unsaturated hydraulic conductivity according to the water saturation. Unlike the saturated condition, the hydraulic gradient and water flux were irregularly changed, and the unsaturated hydraulic conductivity was increased with increasing the experimental time. Swelling of bentonite grains due to the water absorption increased the volume and size of pore within bentonite, resulting in the increase of water velocity and unsaturated hydraulic conductivity. This result suggested the necessity of further investigation on the correlation between the swelling degree of bentonite-buffer and unsaturated hydraulic conductivity. The method used in this study can be useful technique for evaluating long-term hydraulic performance of bentonite-buffer in the radioactive waste disposal system.

Removal of Heavy Metals from Aqueous Solution by a Column Packed with Peat-Humin (Peat-Humin 충전 칼럼을 이용한 수용액 중의 중금속 제거)

  • Shin, Hyun-Snag;Lee, Chang-Hoon;Lee, Yo-Snag;Kang, Ki-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.5
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    • pp.535-541
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    • 2005
  • Peat humin(p-Humin) extracted from Canadian Sphagnum peat moss was packed in a column and removal of heavy metal ions such as Cd, Cu and Pb from aqueous solution under flow conditions was studied. The metal ions were removed not only from single-element solutions but also from a multi-metal solution. Column kinetics for metal removal were described by the Thomas model. For single-component metal solutions, the maximum adsorption capacities of the p-Humin for Pb, Cu and Cd were 138.8, 44.66 and 41.61 mg/g, respectively. The results of multi-component competitive adsorption showed that adsorption affinity was in the order of Pb $\gg$ Cu > Cd. The adsorbed metal ions were easily deserted from the p-Humin with 0.05 N $HNO_3$ solution. It is apparent that 95% of the heavy metal ions were recovered from the saturated column. This investigation provides possibility to clean up heavy-metal contaminated waste waters by using the natural biomass, p-Humin as an environmentally friendly and cost-effective new biosorbents.

The Dynamic Split Policy of the KDB-Tree in Moving Objects Databases (이동 객체 데이타베이스에서 KDB-tree의 동적 분할 정책)

  • Lim Duk-Sung;Lee Chang-Heun;Hong Bong-Hee
    • Journal of KIISE:Databases
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    • v.33 no.4
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    • pp.396-408
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    • 2006
  • Moving object databases manage a large amount of past location data which are accumulated as the time goes. To retrieve fast the past location of moving objects, we need index structures which consider features of moving objects. The KDB-tree has a good performance in processing range queries. Although we use the KDB-tree as an index structure for moving object databases, there has an over-split problem in the spatial domain since the feature of moving object databases is to increase the time domain. Because the over-split problem reduces spatial regions in the MBR of nodes inverse proportion to the number of splits, there has a problem that the cost for processing spatial-temporal range queries is increased. In this paper, we propose the dynamic split strategy of the KDB-tree to process efficiently the spatial-temporal range queries. The dynamic split strategy uses the space priority splitting method for choosing the split domain, the recent time splitting policy for splitting a point page to maximize the space utilization, and the last division policy for splitting a region page. We compare the performance of proposed dynamic split strategy with the 3DR-tree, the MV3R-tree, and the KDB-tree. In our performance study for range queries, the number of node access in the MKDB-tree is average 30% less than compared index structures.

Low-Power Motion Estimator Architecture for Deep Sub-Micron Multimedia SoC (Deep Submicron 공정의 멀티미디어 SoC를 위한 저전력 움직임 추정기 아키텍쳐)

  • 연규성;전치훈;황태진;이성수;위재경
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.41 no.10
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    • pp.95-104
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    • 2004
  • This paper propose a motion estimator architecture to reduce the power consumption of the most-power-consuming motion estimation method when designing multimedia SoC with deep submicron technologies below 0.13${\mu}{\textrm}{m}$. The proposed architecture considers both dynamic and static power consumption so that it is suitable for large leakage process technologies, while conventional architectures consider only dynamic power consumption. Consequently, it is suitable for mobile information terminals such as mobile videophone where efficient power management is essential. It exploits full search method for simple hardware implementation. It also exploits early break-off method to reduce dynamic power consumption. To reduce static power consumption, megablock shutdown method considering power line noise is also employed. To evaluate the proposed architecture when applied multimedia SoC, system-level control flow and low-power control algorithm are developed and the power consumption was calculated based on thor From the simulation results, power consumption was reduced to about 60%. Considering the line width reduction and increased leakage current due to heat dissipation in chip core, the proposed architecture shows steady power reduction while it goes worse in conventional architectures.

Hexagon-shape Line Search Algorithm for Fast Motion Estimation on Media Processor (미디어프로세서 상의 고속 움직임 탐색을 위한 Hexagon 모양 라인 탐색 알고리즘)

  • Jung Bong-Soo;Jeon Byeung-Woo
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.43 no.4 s.310
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    • pp.55-65
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    • 2006
  • Most of fast block motion estimation algorithms reported so far in literatures aim to reduce the computation in terms of the number of search points, thus do not fit well with multimedia processors due to their irregular data flow. For multimedia processors, proper reuse of data is more important than reducing number of absolute difference operations because the execution cycle performance strongly depends on the number of off-chip memory access. Therefore, in this paper, we propose a Hexagon-shape line search (HEXSLS) algorithm using line search pattern which can increase data reuse from on-chip local buffer, and check sub-sampling points in line search pattern to reduce unnecessary SAD operation. Our experimental results show that the prediction error (MAE) performance of the proposed HEXSLS is similar to that of the full search block matching algorithm (FSBMA), while compared with the hexagon-based search (HEXBS), the HEXSLS outperforms. Also the proposed HEXSLS requires much lesser off-chip memory access than the conventional fast motion estimation algorithm such as the hexagon-based search (HEXBS) and the predictive line search (PLS). As a result, the proposed HEXSLS algorithm requires smaller number of execution cycles on media processor.