• Title/Summary/Keyword: 휘발성 황 화합물

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Volatile Sulfur Components from Fresh Radishes of Korean Origin (한국산 무우의 휘발성 함유황화합물에 관하여)

  • Kim, Mee-Ree;Rhee, Hei-Soo
    • Korean journal of food and cookery science
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    • v.1 no.1
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    • pp.33-39
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    • 1985
  • The volatile sulfur components from two varieties of radishes ('Taeback' and 'Altali'), obtained by steam distillation and solvent ($CCl_4$) extraction, were isolated and charac-terized by GC/MS analysis. The GC profile of the volatile sulfur com-pounds in the steam distillates from two types of radishes was quite similar. 4-Me-thylpentyl, 3-methylthiopropyl, 4-methylthio-3-butenyl, 4-methylthiobutyl and 5-methyl-thiopentyl isothiocyanates, 5-methylthio-4-pentenenitrile, 1-methylthio-3-pentanone, and dimethyl sulfides were commonly identified. In the $CCl_4$ extract, 4-methylsulfinyl-3-bu-tenyl isothiocyanate was obtained as another major constituent. Whereas 4-methylthiobutyl isothiocyanate was found to be a predominent component in the steam distillate, 4-methylthio-3-butenyl isothiocyananate was a major one in the $C1_4$ extract.

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Heat Effects for the Volatile Organic Compounds emitted from Garlic and Kimchee (열처리가 마늘과 김치에서 발생되는 휘발성 유기화합물에 미치는 영향)

  • 김병순;양성봉
    • Journal of Environmental Science International
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    • v.7 no.5
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    • pp.615-622
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    • 1998
  • The volatile organic compounds(VOCs) emitted from raw garlic and Kimchee were analyzed with thermal desorption or purge & trap/gas chromatography/mass selective detection method. Very offensive compounds such as methyl allyl sulfide, dimethyl sulfide, dimethyl disulfide, diallyl sulfide, methyl allyl disulfide, diallyl disulfide and dimethyl trisulfide were detected, and among them, dimethyl disulfide and dimethyl trisulfide were confirmed to be generated during the precocity of Kimchee or emitted from the stuff of Kimchee other than the garlic. Malodorous compounds emitted from the garlic or Kimchee were detected in the breath of a Korean and the refregirator keeping Kimchee. It was confirmed that the disufides emitted from the garlic or Kimchee were major components of offensive odor in the alveolar air and the refregirator. It was clarfied that heat process is very effective to reduce odorous VOCs in garlic or Kimchee.

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Analysis of Volatile Organic Components from Fresh and Decayed Onions (생양파와 부패된 양파의 휘발성 유기성분 분석)

  • 박은령;고춘남;김성호;김경수
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.6
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    • pp.1011-1020
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    • 2001
  • Volatile organic components from onions stored in the different decay conditions were extracted by SDE apparatus and analyzed by GC-FID and GC/MS. Components of 115, 143, 123 and 137 were identified in fresh onions, decayed onions without heating, half-decayed and complete-decayed onions after heating, respectively. These components included esters, aldehydes, ketones, alcohols and sulfur-containing compounds. Dimethyl trisulfide, dimethyl disulfide, dipropyl trisulfide and 3,5-diethyl-1,2,4-trithiolane were the main sulfur-containing components in fresh onions and decayed onions without heating. As spoilage of onions, the concentrations of sulfur-containing components of volatile extracts significantly decreased. Apart from sulfur-containing components, volatile organic components in half-decayed and complete-decayed onions after heating were mainly composed of esters, aldehydes, ketones and alcohols. Ketones of volatiles in complete-decayed onions after heating were high relatively.

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Source apportionment study of ambient volatile organic compounds in Seoul (서울지역 휘발성 유기화합물의 배출원 기여도에 관한 연구)

  • 봉춘근;황인조;윤중섭;김동술
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.191-192
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    • 2002
  • 대기중의 휘발성 유기화합물 (VOCs)은 종류 및 그 성분이 매우 복잡하고 다양할 뿐만 아니라 매우 다양한 배출원을 가지고 있어 이의 관리 및 제어에 많은 어려움을 가지고 있다. 대도시의 경우 대기중으로 배출되는 VOCs는 주로 자동차나 페인트, 용매 등으로부터의 기여가 매우 높은 것으로 알려져 있다. 그렇지만 이들에 대한 국내에서의 연구는 매우 적은 실정이어서 솔벤트나 연료의 사용량 등을 기준으로 한 개략적인 발생원 기여도파악이 전부라 할 수 있다. (중략)

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Comparison of Volatile Organic Components in Fresh and Freeze Dried Garlic (생마늘과 동결건조마늘의 휘발성 유기성분 비교)

  • Kim, Youn-Soon;Seoa, Hye-Young;No, Ki-Mi;Shim, Sung-Lye;Yang, Su-Hyeong;Park, Eun-Ryong;Kim, Kyong-Su
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.6
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    • pp.885-891
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    • 2005
  • The study was carried out to find the effect of freeze drying on the volatile organic components in garlic (Allium sativum L.). The volatile organic compounds from fresh and freeze dried garlic were extracted by simultaneous steam distillation and extraction (SDE) method and identified with GC/MS analysis. A total of 42 and 32 compounds were identified in fresh and freeze-dried garlic, respectively. Sulfur containing compounds in the garlic samples were detected as the major compounds, and alcohols, aldehydes and esters were detected as minor compounds. Diallyl disulfide, diallyl trisulfide, allyl methyl disulfide and ally1 methyl trisulfide were the main sulfur compounds in fresh and freeze dried garlic. The amount of sulfur containing compounds were decreased freeze-drying but methyl propyl trisulide, 3- allylthiopropionic acid, cyclopentyl ethyl sulfide etc. were increased. The others, non- sulfur containing compounds such as ethyl acetate, ethanol, 2-propenol, 2- propenal and hexanal were increased in freeze-dried garlic. Consequently, the total amount of volatile organic compounds in garlic became lower during freeze-drying from 853.42 mg/kg to 802.21 /kg, and the composition of major components were nearly same in fresh and freeze-dried garlic.

An Experimental Study on the Photodegradation of Volatile Organic Compounds(VOCs) using $TiO_2$ Nano Particles ($TiO_2$ 나노 입자를 이용한 휘발성 유기 화합물의 광분해에 관한 실험적 연구)

  • Lee, Ju-Yong;Kim, Seong-Chan;Ahn, Young-Chull;Hwang, Eu-Gene;Lee, Jae-Keun;Hwang, Jung-Sung;Kim, Tae-Ho
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1881-1884
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    • 2003
  • In this experiment, the oxidations of p-Xylene (140-180 ppmv), one of the air pollutants as a VOC, using $UV/TiO_2$ photocatalyst is studied. In order to increase the specific surface area, the filter is coated by nano $TiO_2$ particles. The photodegradation system consists of a VOCs generator, a photocatalyst filter and a measuring equipment. Illumination is generally provided by two of 20 W black light lamps with 380 nm of wavelength. The filter coated by nano $TiO_2$ particles has a passing efficiency over 80% but a pressure drop of 9.0 $mmH_2O$ at 0.45 cm/s. The filter endurance is better than activated carbon at the same pressure drop.

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Flavor Characteristics of Omija (Schisandra chinensis Baillion) Added Onion Fermented Beverage (오미자첨가 양파 발효 음료의 향미 특성)

  • Eun-Jeong Jeong
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.3
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    • pp.371-380
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    • 2023
  • This study aimed to present data for the industrialization of Omija added onion fermented beverage (OOFB) development by analyzing the volatile flavor components. A total of 55 compounds, including 4 terpene derivatives, 9 esters, 5 aromatic compounds, 6 alcohols, 7 ketones, 3 aldehydes, 11 acids, 1 sulfur-containing compound, 8 furans and 1 other, were identified in OOFB. The content of fragrance components was high with 37.8% of acids and 29.0% of furans. 2,5-dimethyl thiophene, a sulfur compound, is a compound produced during the acetic acid fermentation of onion, and is thought to affect the onion flavor of OOFB.

Volatile Flavor Components in Watermelon(Citrullus vulgaris S.) and Oriental Melon(Cucumis melo L.) (국내산 수박(Citrullus vulgaris S.) 과 참외(Cucumis melo L.) 의 휘발성 향기성분)

  • Kim, Kyong-Su;Lee, Hae-Jung;Kim, Sun-Min
    • Korean Journal of Food Science and Technology
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    • v.31 no.2
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    • pp.322-328
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    • 1999
  • Volatile flavor components of watermelon (Citrullus vulgaris S.) and oriental melon (Cucumis melo L.) obtained by simultaneous steam distillation and extraction apparatus were separated by gas chromatography (GC) and gas chromatography-mass spectrometry (GC/MS). Thirty seven and fifty five volatile flavor components were identified in watermelon and oriental melon, respectively. (Z)-3-Nonen-1-ol, (Z,Z)-3,6-nonadien-1-ol, (E,Z)-2,6-nonadienal and (E)-2-nonenal containing unsaturated nine carbon atoms were the characteristic flavor components of watermelon. $C_{9}-Unsaturated$ esters including (Z)-3-nonenyl acetate, (Z)-6-nonenyl acetate, (Z,Z)-3,6-nonadienyl acetate and thioester were important components in the flavor profile of oriental melon.

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Analysis of Volatile Organosulfur Compounds in Korean Allium Species (국내산 Allium속(마늘, 양파, 대파)의 휘발성 함유황 유기화합물 분석)

  • Song, Hyun-Pa;Shim, Sung-Lye;Jung, In-Sun;Kim, Jun-Hyeong;No, Gi-Mi;Seo, Hye-Yeong;Kim, Dong-Ho;Kim, Kyong-Su
    • Food Science and Preservation
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    • v.16 no.6
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    • pp.929-937
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    • 2009
  • We identified volatile organic compounds in Korean Allium species. Volatile organic components in three Korean Allium species, dried garlic, dried onion, and dried Welsh onion, were extracted using a simultaneous distillation and extraction (SDE) method and identified by GC/MS analysis. The numbers of volatile compounds were 48, 32, and 33 in the three species, respectively. In dried onion, the major compounds were dipropyl trisulfide, methyl propyl trisulfide, and propanethiol. (Z), (E)-propenyl propyl trisulfide, methyl propyl trisulfide, and dipropyl trisulfide were detected at high levels in Welsh onion. In dried garlic, presence of the allyl group identified characteristic volatile organosulfur compounds including diallyl disulfide and diallyl trisulfide. Qualitative and quantitative analysis of volatile compounds in three Korean Allium species showed that sulfur-containing compounds were dominant, and allyl groups derived from (+)-S-(2-propenyl)-L-cysteine sulfoxide (ALLYL CSO, alliin) were more abundant in dried garlic, than in other materials.

Removal of Benzene and Toluene by UV Photooxidation and Photocatalytic oxidation (UV 광산화ㆍ광촉매 산화 반응을 이용한 Benzene과 Toluene의 처리)

  • 황철원;김찬훈;정창훈;최금찬
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.225-226
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    • 2001
  • 휘발성 유기화합물(VOCs)은 광화학적 오존 형성으로 인한 간접 오염뿐만 아니라 그 자체가 독성을 지니고 있어 직접적으로도 인체에 유해한 영향을 줄 수 있으며, 유류 및 유기 용제를 사용하는 작업장에서뿐만 아니라 연소 관련 오염원이 없는 실내 환경에서도 일부 VOCs는 높은 농도를 나타낼 수 있으므로 작업장 및 실내 환경에서의 VOCs 처리에 대한 중요성이 증대되고 있다. (중략)

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