• Title/Summary/Keyword: 휘발성 유기 성분

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Stability Study for B.T.X Gas in the Aluminum Cylinder (알루미늄용기에서 BTX 가스에 대한 안정성 연구)

  • 김용두;배현길;김병문;김광섭;허귀석;김진석;우진춘
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.356-357
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    • 2003
  • 대기오염을 유발하는 가스 중 휘발성 유기오염물(VOC)의 가스성분에 대한 관심은 점점 높아지고 있다. 휘발성 유기오염물(VOC)가스 중 가장 대표적인 성분은 벤젠, 톨루엔, 자일렌으로서 주 발생원은 유해한 작업환경의 대기나 공장의 배기 가스, 또는 주변 주거 지역의 대기 등이다. 본 연구는 벤젠, 톨루엔, 자일렌을 측정하는데 있어서 표준가스로 사용하는 벤젠, 톨루엔 및 자일렌 교정용 혼합가스의 인증 값의 정확성 및 신뢰성을 유지하기 위하여 이들 성분을 조성으로 하는 혼합가스를 제조하고 단기 흡착성 정도 및 유효기간 설정을 위하여 안정도 조사를 수행하였다. (중략)

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Measurement of Atmospheric VOC Concentrations at a Roadside in a Large Urban Area (대도시 도로변 대기 중 휘발성 유기화합물의 농도측정)

  • 김미현;백성옥;김성렬;황승만;문영훈;정진욱;신주희
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.383-384
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    • 1999
  • 도시대기 중의 광화학 대기오염의 원인인 동시에 사람의 건강상에 유해한 성분(발암성 혹은 돌연변이성)들이 많이 존재하는 것으로 알려진 대기오염물질 중에서도 탄화수소성분에 대한 관심이 최근들어 고조되고 있다. 메탄을 제외한 탄화수소성분을 총칭하여 비메탄계 탄화수소(NMHC)라고 일컫고 있으며, 비메탄계 탄화수소는 알데히드등의 산소화합물을 함유하고 있지 않지만, 휘발성 유기화합물(Volatile Organic Compounds;이하 VOCs)은 산소함유화합물을 포함한 물질을 말한다.(중략)

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Comparison of Volatile Organic Components in Fresh and Freeze Dried Garlic (생마늘과 동결건조마늘의 휘발성 유기성분 비교)

  • Kim, Youn-Soon;Seoa, Hye-Young;No, Ki-Mi;Shim, Sung-Lye;Yang, Su-Hyeong;Park, Eun-Ryong;Kim, Kyong-Su
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.6
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    • pp.885-891
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    • 2005
  • The study was carried out to find the effect of freeze drying on the volatile organic components in garlic (Allium sativum L.). The volatile organic compounds from fresh and freeze dried garlic were extracted by simultaneous steam distillation and extraction (SDE) method and identified with GC/MS analysis. A total of 42 and 32 compounds were identified in fresh and freeze-dried garlic, respectively. Sulfur containing compounds in the garlic samples were detected as the major compounds, and alcohols, aldehydes and esters were detected as minor compounds. Diallyl disulfide, diallyl trisulfide, allyl methyl disulfide and ally1 methyl trisulfide were the main sulfur compounds in fresh and freeze dried garlic. The amount of sulfur containing compounds were decreased freeze-drying but methyl propyl trisulide, 3- allylthiopropionic acid, cyclopentyl ethyl sulfide etc. were increased. The others, non- sulfur containing compounds such as ethyl acetate, ethanol, 2-propenol, 2- propenal and hexanal were increased in freeze-dried garlic. Consequently, the total amount of volatile organic compounds in garlic became lower during freeze-drying from 853.42 mg/kg to 802.21 /kg, and the composition of major components were nearly same in fresh and freeze-dried garlic.

Effect of $\gamma$-Irradiation of Volatile Organic Compounds of Houttuynia cordata Thunb. (방사선 조사에 의한 어성초의 휘발성 유기성분 변화)

  • Ryu, Keun-Young;Shim, Sung-Lye;Jung, Min-Seok;Jun, Sam-Nyeo;Jo, Cheor-Un;Song, Hyun-Pa;Kim, Kyong-Su;Kim, Youn-Soon
    • Food Science and Preservation
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    • v.15 no.3
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    • pp.411-420
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    • 2008
  • This study was performed to examine the effect of $\gamma$-irradiation on the volatile organic compounds in Houttuynia cordata Thunb.(H. cordata). 1be volatile compounds of non-irradiated and 10 kGy $\gamma$-irradiated H. cordata were isolated using SDE apparatus and analyzed by GC/MS. For each treatment the number of volatile compounds were detected at 83 and 85, respectively, 1be predominant functional groups of volatile organic compounds from H. cordata were identified as alcohols and ketones. H. cordata was mainly composed of hexahydrofarnesyl acetone (12.81 %), phytol, decanoic acid, dodecanoic acid, octadecanol, caryophyllene oxide, 2-undecanone and menthol. Houttuynum which is characteristic compound of H. cordata was found in all samples and there was no significant difference with irradiation doses. Consequently, $\gamma$-irradiation of H. cordata would be an effective process for sanitation and to increase extraction efficiency.

Adsorption Characteristics of Three-components Volatile Organic Compounds on Activated Carbonaceous Adsorbents (탄소흡착제에 의한 삼성분계 휘발성 유기화합물의 흡착특성)

  • Son, Mi Sook;Kim, Sang Do;Woo, Kwang Jae;Park, Hee jae;Seo, Man cheol;Lee, Si hun;Ryu, Seung Kon
    • Korean Chemical Engineering Research
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    • v.44 no.6
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    • pp.669-675
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    • 2006
  • Toluene of aromatic compounds, MEK of ketones and IPA of alcohols were extremely used as VOCs (Volatile Organic Compounds) on the getting into step with industrial process. The adsorption characteristics of three component solvent vapors (Toluene-MEK-IPA) on the activated carbonaceous adsorbents such as AC, ACF and AC+ACF were investigated in a stainless steel fixed bed adsorption experimental apparatus in order to identify those carbons for eliminating and recovering solvent vapors from industrial emission sources. The used activated carbonaceous adsorbents were pelletized commercial activated carbon and activated carbon fiber. The breakthrough curves and adsorption capacity have been obtained at atmospheric pressure in a adsorption fixed bed. It has been found that non-polar and larger molecules have been adsorbed better than polar and smaller molecules. Especially, alcohols and ketones were poorly adsorbed due to competitive adsorbability in ternary mixture system. However, it could be overcome by employment of activated carbonaceous adsorbent which have different porosity distribution appropriately.

Chemical Characterization of Commercial Vinegars (식초의 종류별 화학성분의 특징)

  • Yoon, Hee-Nam
    • Korean Journal of Food Science and Technology
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    • v.31 no.6
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    • pp.1440-1446
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    • 1999
  • Fourty-two commercial vinegars were analyzed for their non-volatile organic acids, free sugars. amino acids, and volatile compounds. A study was made to characterize commercial vinegars chemically into three kinds of vinegars such as spirit, cider, and brown rice vinegars. Sixteen chemical components were significantly effective for the chemical characterization of commercial vinegars by stepwise discriminant analysis. Those were malic, succinic and lactic acids from the non-volatile organic acids; fructose and glucose from the free sugars; lysine, serine, leucine, valine and alanine from the amino acids; 1-hexanol, acetaldehyde, 3-methyl-1-butanol, 2-methylpropanoic acid, isopropyl butanoate and ethanol from the volatile compounds. Six components including malic acid, lysine, succinic acid, glucose, lactic acid and 1-hexanol were the most significant contributors to the differentiation of commercial vinegars into spirit, cider, and brown rice vinegars. In particular, cider vinegars could be characterized to be abundant in amounts of malic acid and 1-hexanol, whereas brown rice vinegars in amounts of lysine and lactic acid compared to spirit vinegars.

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Source apportionment study of ambient volatile organic compounds in Seoul (서울지역 휘발성 유기화합물의 배출원 기여도에 관한 연구)

  • 봉춘근;황인조;윤중섭;김동술
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.191-192
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    • 2002
  • 대기중의 휘발성 유기화합물 (VOCs)은 종류 및 그 성분이 매우 복잡하고 다양할 뿐만 아니라 매우 다양한 배출원을 가지고 있어 이의 관리 및 제어에 많은 어려움을 가지고 있다. 대도시의 경우 대기중으로 배출되는 VOCs는 주로 자동차나 페인트, 용매 등으로부터의 기여가 매우 높은 것으로 알려져 있다. 그렇지만 이들에 대한 국내에서의 연구는 매우 적은 실정이어서 솔벤트나 연료의 사용량 등을 기준으로 한 개략적인 발생원 기여도파악이 전부라 할 수 있다. (중략)

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VOCs Permeation Property of Composite Hollow Fiber Membranes (중공사 복합막을 이용한 다성분계 휘발성 유기 화합물 투과 특성)

  • Choi, Whee Moon;Cho, Soon Haing;Kim, Soon Tae;Lee, Chung Seop;Nam, Sang Yong
    • Membrane Journal
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    • v.23 no.2
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    • pp.176-184
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    • 2013
  • To investigate the performance of VOC separation, composite hollow fiber membrane was prepared which composed of poly (ether imide) support prepared by phase separation method and poly (dimethylsiloxane) coating active layer. The performances of the membranes for the application of recovery process in terms of their morphology, gas permeance test for $N_2$ and $O_2$ gases. Durability against benzene, toluene and xylene was also investigated. And permeation test for multi-component VOCS through the membrane with different feed concentration and stage-cut were investigated. Permeance of PEI supported membrane and the membranes coated with PDMS decreased from 45,000 GPU to 63 GPU and 49,450 to 30 GPU for $N_2$ and $O_2$, respectively. Recovery efficiency and concentration of VOCs in permeate increased with decreasing stage-cut. VOCs concentration in permeate proportionally increased with increasing feed concentration but concentration ratio and recovery efficiency showed any noticeable changes with feed concentration change.

Measurement of Atmospheric VOC Concentrations at a Roadside in a Large Urban Area(II) (대도시 도로변 대기 중 휘발성 유기화합물의 농도측정(II))

  • 백성옥;김미현;황승만;정진욱;박상곤
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.04a
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    • pp.108-109
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    • 2000
  • 도시대기 중에서 질소산화물과 공존시 태양광의 작용을 받아 광화화학 반응을 일으키는 동시에 사람의 건강상에 유해한 성분(발암성 혹은 돌연변이성)들이 많이 존재하는 것으로 알려진 대기오염물질 중에서도 탄화수소성분에 대한 관심이 최근 들어 고조되고 있다. 본 연구에서는 도시 도로변에서 시료를 24시간 연속적으로 채취하여 휘발성유기회합물(Volatile Organic Compounds;이하 VOCs)의 시간별 농도수준 및 거동을 파악하고 나아가 각 VOCs 농도에 영향을 주는 인자에 대해 평가하고자 한다. (중략)

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