• Journal of the Korea Organic Resources Recycling Association
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• v.30 no.4
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• pp.41-50
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• 2022

Recently, research on carbon adsorbents has been active as an interest in improving the environment such as indoor and outdoor air quality. Considering that causative substances deteriorate the air quality are basically volatile organic compounds, it is important to improve the hydrophobicity of the carbon materials for better removal efficiency. This study presents a method for improving hydrophobicity of carbon and a measurement of the hydrophobicity. Generally, methods of improving the hydrophobicity of carbon materials are heat treatment, acid/alkali treatment, coating and immersion with hydrophobic materials. However, it collapses the pore structure and reduces the adsorption capacity. Therefore, this study briefly introduce not only the general method for improving carbon materials' hydrophobicity but also the method for converting the precursor of the material is briefly introduced. Futhermore, this study introduces a analytical technique used to determine hydrophobic modification or not, and aims to enhance the understanding of carbon materials.

• Journal of Life Science
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• v.30 no.9
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• pp.743-748
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• 2020

Sulfate is a reductant that competes for electrons and may lower CH₄ production in the rumen. This study was designed to evaluate the beneficial effect of detoxified sulfur powder supplementation on in vitro rumen fermentation and methane mitigation. A ruminally cannulated Holstein Friesian cow was used as a rumen fluid source, and commercial pelleted concentrate was used as a substrate at 1 g dry matter. Treatments included the addition of detoxified sulfur powder at the rate of 0% (Control), 0.2% (T1), 0.4% (T2), 0.6% (T3), 0.8% (T4), and 1.0% (T5) as dry matter (DM) basis. The pH, total gas (TG), methane (CH₄) production, DM digestibility, organic matter (OM) digestibility, and volatile fatty acids (VFA) production were analyzed after 12 hr of incubation. The results showed that CH₄ production was significantly lowest in T1 (13.78 ml) but highest in the control (20.16 ml). Insignificantly higher total VFA was observed in control and T1 (64.99 and 64.28 mM, respectively) compared to other treatments after 12 hr of incubation. After 12 hr of incubation, the significantly lowest acetate:propionate was observed in T1 (1.90) while the highest was observed in T4 (2.44). However, no significant differences were recorded for pH, TG, DM digestibility, OM digestibility, acetate, propionate, and butyrate between the control and T1. Total number of bacterial DNA copies was significantly lower in the treatment group than the control. Therefore, it can be concluded from this study that detoxified sulfur at 0.2% inclusion level is optimal for production performance and ruminal CH₄ mitigation.

• Journal of the Korea Organic Resources Recycling Association
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• v.1 no.1
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• pp.85-102
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• 1993

This study was conducted to achieve develop organic sludge recycling technology as sludge make a prey of earthworm. Therefore sludge treatment and recycling technology is an important field by which this research project to solve landfill site and reduction treatment expense using vermicomposting treatment process on the waste sludge from the biological wastewater treatment plant. In experimental results on the optimum conditions of vermicomposting of nightsoil treatment sludge, survival rates were observed 98.3% in temperature of $10-15^{\circ}C$, 75% in pH 5.8-7.5 and 100% in density of $1/79.8cm^3$, respectively. Liveweight changes of earthworm were increased 266% in temperature of $10-15^{\circ}C$, 227% in pH 5.8-7.5 and 325 % in density $1\;cap./79.8cm^3$, respectively. Casting production rate were generated 0.06 g/cap./day in temperature $20-25^{\circ}C$, 0.065 g/cap./day in pH 5.8-7.5 and 0.1 g/cap./day in density $1\;cap./79.8cm^3$, respectively. Cocoon production numbers were observed 3.8 ea. /cap.in $10-15^{\circ}C$, 2.95 ea./cap.in pH 5.8-7.5 and 3.16 ea./cap. in $1\;cap./79.8cm^3$ during 6 weeks, respectively. pH was droped by 6.2 to 5.7, volatile solids was decreased by 2.9%, $NH_3-N$ were also reduced by $6.984{\mu}g/g$ to $0.991{\mu}g/g$. $NO_3-N$, however, were increased by $3.213{\mu}g/g$ to $7.706{\mu}g/g$. Fecal coliforms and pathogenic bacteria are analyzed by microbiological method to assess public health safety of casting. Number of fecal coliform groups were reduced 88.6-99.1% (Avg. 95.7%) approximately. And pathogenic bacteria such as Salmonella, Shiegella and Vibrio, were not isolated from the earthworm cast.

• Journal of the Korea Organic Resources Recycling Association
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• v.25 no.1
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• pp.103-110
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• 2017

In Concentrated Animal Feeding Operations(CAFOs), emission of ammonia from stored manure contributes negatively on the wellness of livestock. In CAFOs facilities, indoor aerial ammonia concentration oftentime surpasses the critical level potentially harmful to livestock's immune system. Understandably, numerous researches to control aerial ammonia have been conducted in countries where CAFOs were practiced for many decades. Some innovative technologies, such as scrubber, bio-filter, and additives emerged, as a result. Among them, microbial additives became popular in Korea, due to an easiness of use and affordability. However, microbial additives still have some weaknesses. Their price is still high enough to discourage farmers who run a small scale farm and their effectiveness are still questioned by many users and researchers. In the present study, we found soluble carbohydrates, such as sugar, glucose, and molasses, when supplemented to pig slurry manure, can mitigate ammonia emission. To be more specific, pig manure slurry(120kg), stored in container(200L), was supplemented with sugar at 0.1%(w/w) and was, subsequently, monitored for pH and aerial ammonia for next 10 days. From this experiment, it was found that the sugar supplementation was effective in mitigating the aerial ammonia concentration (33% in average) when monitored daily. Also, the pH of manure slurry was maintained at relatively low level(8.2) in sugar-supplemented manure slurry while it was elevated to 8.5 in untreated slurry. Conclusively, the obtained data suggest that soluble carbohydrate can mitigate ammonia emission by acidifying manure slurry. Additionally, it can be suggested that soluble carbohydrates, such as sugar, glucose, and molasses, can be reasonable choices for animal farmers who have been looking for an alternative choice to replace expensive microbial additives.

• Journal of the Korea Organic Resources Recycling Association
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• v.22 no.1
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• pp.11-19
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• 2014

A study on combustion characteristic and evaluation of cost benefit were carried out using dried sewage sludge to evaluate co-combustion with coal in a coal-fired power plant. In the result of proximate analysis, sewage sludge has 78.09%, 79.65% of moisture content in A STP(Sewage Treatment Plant) and B STP, respectively. The dried sewage sludges show 0.12, 0.14 of fuel ratio value, respectively and over 30,000kcal/kg of combustible index. It means that the dried sewage sludges needs to reform from the results of fuel ratio and combustible index. As a results of the economical benefit evaluation of dried sewage sludge, about 73.4 million won through using the dried sewage sludges instead of coal and 56.4 million won through REC(Renewable Energy Certificate) cost were saved, respectively. On the other hand, it occurs 4.2 million won of additional cost related to ash disposal and 2.6 million won of investment/operation cost for co-combustion facility. In conclusion, co-combustion of dried sewage sludges with coal in a coal-fired power plant saves about 123 million won. However, it needs to consider for power supply to produce dried sewage sludges and opportunity cost for environmental pollution and so on to evaluate more reasonable benefit of co-combustion.

• Journal of the Korea Organic Resources Recycling Association
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• v.28 no.1
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• pp.15-25
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• 2020

Biogas production potential was experimentally estimated for mono- and co-digestion of cow manure and waste grass. The two organic wastes were mixed at five different ratios (100:0, 75:25, 50:50, 25:75, 0:100) on the volatile solids basis, and were assessed using biochemical methane potential (BMP) test. Thee reaction temperatures, 25℃, 30℃ and 35℃, were applied as well, resulting in 15 different combinations for the test. The results showed that both higher temperature and waste grass mixing ratio resulted in higher methane yield and maximum methane production rate. Based on the experimental results, a theoretical farm- or community-scale (240 or 2400 ㎥) anaerobic digester was designed to evaluate the energy balance associated with mono- and co-digestion of the wastes at different temperatures. Although the energy production increased as the temperature and the waste grass mixing ratio increased, the net energy gain, energy production subtracted by energy consumption for heating and maintenance, was estimated to be the highest at 30℃, followed by at 35℃ and 25℃. Therefore, it is advised that both the experimental methane production and the detailed design parameters must be considered for the optimization of the net energy gain from these wastes.

• Korean Journal of Environmental Agriculture
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• v.26 no.2
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• pp.179-185
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• 2007

A new technology that utilizes a microbial fuel cell (MFC) has been developed to generate electricity directly from the oxidation of organic matters such as carbohydrates or complex organics in wastewater. Fermentation of these organic matters results in production of volatile fatty acids (VFAs), alcohols, $CO_2$ and $H_2$. We investigated the electricity-producing potential of the VFAs and actual food processing wastewater using a two-chambered MFC. The electrons produced by acetate degradation were proportional to acetate concentration in the medium. Acetate concentration and generated power were linearly correlated at a low range or acetate concentration (< 8 mg/L), but at above 8 mg/L of acetate the power produced was maintained at 0.1 mW. When butyrate was added to the anode acclimated to acetate, there was a lag period of 30 hr for electricity generation. However, when propionate was added to the same anode bottle, lag periods were not existed. The wastewater from baby food processing generated the maximum power density of $81{\pm}7\;mW/m^2$ of electricity and exhibited the Coulombic efficiencies of 27.1% and 40.5% based on TCOD and SCOD, respectively. Sugars in the food processing wastewater were reduced within 50 h from 230 mg/L < 30 mg/L.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.7
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• pp.469-475
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• 2014

The study investigated the physicochemical characteristics and the ecological risk of the Northport sediment in B city and the releasing properties of heavy metals into seawater during the resuspension also studied. The major components of the sediment are fine silt and clay which contains high organic matter and AVS (Acid volatile sulfide) and the ecological risk of the heavy metals in sediment also very high. The release rate of heavy metals into seawater was in order of Pb>>Cu>Cr>>Zn>Cd during the resuspension in a batch experiment, and the heavy metal release mainly attributed to the oxidation of metal sulfides. Heavy metals which came from easily oxidisable metal sulfides rapidly contaminated seawater within about 1.0 h of the sediment resuspension. The sulfide oxidation during the resuspension increased the residual fraction of heavy metals in the sediment, decreased the organic bound fraction, and changed the other fractions of heavy metals in the sediment. The release of heavy metals from the sediment during resuspension was affected by the resuspension time, the oxidation rate of metal sulfides and resuspended concentration of the sediment particle.

• Korean Journal of Environmental Agriculture
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• v.10 no.2
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• pp.149-157
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• 1991

In order to elucidate the possible change in the non-extractable bound residue of TCAB(3,3' 4,4' - tetrachloroazobenzene) in soil as a function of aging period, uniformly ring-labelled $^{14}C-TCAB$ was treated to soil(organic matter : 1.8%), and aged for 3, 6, 9, 12 and 15 months at $21{\pm}1^{\circ}C$, respectively. $^{14}CO_2$ evolution and volatilization loss during the aging were negligible. The amounts of non-extractable bound residue of TCAB increased gradually from 7.55% in 3-month aging to 19.32% in 15-month aging. Partition data suggested no formation of polar groups in the chemical structure of TCAB. Most of $^{14}C-radioactivity$ of bound residues was present in humin in the range of 50.52 to 58.93%. The fact that the number of microorganisms in soil decreased relative to the control suggested no chance of their involvement in the formation of non-extractable bound residues. Accordingly, the increase in the non-extractable bound residue of TCAB in soil with aging period is believed to be due to the transformation of the trans isomer to the cis one which is more polar and more adsorptive than the former.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.5
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• pp.895-902
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• 2011

Objective of this research was to investigate the characteristics of biogas production in anaerobic digestion reactor with different mixing ratio of food waste and swine manure. It was observed that the highest removal efficiency of organic material was 80% at 60 : 40 of mixing ratio (livestock manure : food waste). And also biogas yield was varied due to different mixing ratio of them. The cumulative biogas yield was highest at 60 : 40 of mixing rate (livestock manure : food waste). For use of the liquefied fertilizer as effluent from anaerobic digester, it was the limited ratio for 30% of co-digested food waste based on its salt content.