• Title/Summary/Keyword: 휘발성 유기물

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A Study on the PM2.5 Concentration in the Car in Jeonju Downtown (전주시 중심가를 주행중인 승용차내 초미세먼지(PM2.5) 농도 변화에 대한 연구)

  • Moon, Hyung Suk;Kim, Jong Soo;Kim, In Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.10
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    • pp.717-723
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    • 2013
  • The Korea Ministry of Environment prepares some paticulate matter eliminate measures for national health protection, as the Paticulate Matter ($PM_{2.5}$) exceeds the standard at more than half of the monitoring posts installed in the nation's big cities. At the center of JeonJu, when measuring the ultrafine particles of inner car at the different driving conditions, at the condition of the Actuator of inner recirculation mode and the Blower of 2-speed, the reduction speed of the ultrafine particles is most fast and the concentration stays low. When the windows are opened during driving, outer pollutants enter the car and also inner paticulate matter flies in all direction, and the increase of passengers causes the scattering of the ultrafine paticles. As the filter for air cleaning, the using of polypropylene non-woven fabric (used commonly now) is most excellent, but for the removal of volatile organic substance as well as the paticulate matter, it is thought that the using of activated carbon fiber filter, carbon adsorbent, is even more excellent.

A Study on Combustion Characteristics for Dry Food Waste (음식폐기물의 고형연료화를 위한 연소특성 연구)

  • Sang, Byoungchan;Lee, Seungjeong;Lee, Doyeon;Ohm, Taein
    • Journal of the Korea Organic Resources Recycling Association
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    • v.30 no.4
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    • pp.101-108
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    • 2022
  • This study analyzed the physicochemical properties and combustion characteristics of dry food waste to evaluate the possibility of using food waste as a solid refuse fuel (SRF). The characteristics of dry food waste as a fuel were analyzed by comparing the difference in properties with SRF, and the combustion characteristics after conversion into fuel were identified. Ultimate analysis, proximate analysis, calorific value analysis, and TGA analysis were conducted using two types of food waste and two types of SRF, and the following results were obtained. The moisture content and ash content of dry food waste were 1.7~10.0 wt.% and 7.8~11.7 wt.%, respectively, which satisfied the quality standards for SRF. The low calorific value of dry food waste was 4,000 ~ 4,720 kcal/kg, which was higher than the quality standard of 3,500 kcal/kg for SRF. As a result of TGA analysis of dry food waste, the combustion reaction started at about 200 ℃ and the highest burning rate was at about 500 ℃. After moisture evaporation between 100 and 200 ℃, initial volatile matter, carbon and residual volatile matter were released and burned between 200 and 500 ℃. Based on the high calorific value and low moisture and ash content of dry food waste, it is considered that it is possible to convert dry food waste into SRF through the application of efficient drying technology and strict quality standard inspection in the future.

Heavy Metals in Road Deposited Sediments and Control of Them in Urban Areas: A Review (문헌고찰에 의한 도시 지역 도로퇴적물의 중금속 특성 및 적정 관리방안)

  • Kim, Do Gun
    • Land and Housing Review
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    • v.13 no.3
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    • pp.125-140
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    • 2022
  • Road Deposited Sediment (RDS) is the solids formed from the wear of road, wear of vehicles, exhausts, and the input of the emissions from various sources out of the roads. RDS is seriously polluted by organic matter, nutrients, and metals. RDS plays an important role as the sink and the transport medium of the associated pollutants because RDS can be carried to the adjacent water system via stormwater runoff. In this regard, the heavy metals in RDS were investigated based on the publications. The contents of the metals in RDS were highly variable. The concentration of Cr, Ni, Cu, Fe, Zn, As, Cd, and Pb in urban RDS in various regions was in a range of 3.16-3,410, 1.15-1,382, 20.2-9,069, 2,980-124,853, 81-2,550, 2.3-214, 0.19-21.3, and 15.21-1,125 mg/kg, respectively. The anthropogenic enrichment of the metals in RDS was confirmed by the high concentration of Cu, Zn, Cd, and Pb. The contents of the metals were higher in industrial and traffic areas than in residential areas, while they were generally increased with decreasing particle size. It is believed that this study's results would contribute to quantifying the metals' load via RDS and establishing control strategies.

Occurrence and Variation of Oxygen Deficient Water Mass in the Namdae Stream Estuary, Yangyang, Korea (양양 남대천 하구의 빈산소 수괴 출현과 변동)

  • Kwon, Kee-Young;Lee, Yong-Hwa;Shim, Jeong-Min;Lee, Pil-Yong
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.15 no.3
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    • pp.115-123
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    • 2010
  • The occurrence and variation of oxygen deficient water mass (ODW) in Namdae stream estuary, Yangyang were studied. Field observations for water properties and sediment environments were conducted at 5 stations of the estuary from April 2008 to November 2008. The coastal sandbar is developed at the estuary mouth, and there is a pool between the estuary mouth and about 2.3 km upstream of the estuary. The pool is relatively deep and narrow compared to riverbed of the estuary. The ODW was observed continuously in the pool from May to October. The ODW extends vertically up to 2 m depth in August, and maximum length of the ODW were about 2.3 km. Mean concentration of ignition loss (IL) and acid volatile sulfide (AVS) of sediment was 7.5~9.0%, $0.282{\sim}1.106\;mg/g{\cdot}dry$ wt, respectively. Ammonium concentration in the bottom layer during formation period of the halocline and the ODW was 4~23 times higher than that of surface layer. ODW was initiated by the introduction of seawater into bottom of the estuary pool to make a strong halocline, and then decomposition of organic matter within sediment accelerated the formation of the ODW.

Evaluation of Extraction Mode for SVE Process by On-Line Monitoring System (온라인 모니터링에 의한 디젤오염토양의 토양증기추출 공정시 추출모드 평가)

  • Park, Joon-Seok;Kim, Seung-Ho;Park, Young-Goo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.11 no.4
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    • pp.90-96
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    • 2003
  • This study was performed to evaluate effect of extraction mode on SVE efficiency for fuel-contaminated soil. A gas station was selected for this study. As a result of pressure test in well head, soil texture of contaminated site under the gas station was very different from site to site. SVE system was operated in intermittent mode (1hr extraction / 3hr rest) or continuous mode. Capacity of air blower was $1m^3/min$. Extration mode test was conducted in two severe contaminated sites. In both two sites, cumulative TPHgas mass of intermittent extraction mode was higher than that of continuous mode. Considering long term operation of SVE in a field, in general, it was thought that intermittent extraction mode was effective in view of vaporized TPHgas mass and electrical cost.

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$SnO_2$ 나노 입자가 분산된 Poly(methylmethacrylate) 박막 층을 사용하여 제작한 유기 쌍안정성 소자의 전기적 성질

  • Gwak, Jin-Gu;Yun, Dong-Yeol;Jeong, Jae-Hun;Lee, Dae-Uk;Son, Dong-Ik;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.210-210
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    • 2010
  • 저항 구조를 가진 유기 쌍안정성 소자는 비휘발성 기억 소자 중에서 구조가 간단하고 제작비용이 저렴하며 플렉시블이 용이한 장점 때문에 많은 연구가 진행되고 있다. 유기물/무기물 복합재료를 사용한 유기 쌍안정성 소자 제작에 대한 연구는 많이 진행되어 왔지만, 넓은 에너지 밴드 갭을 가진 $SnO_2$ 나노 입자가 삽입된 고분자 박막을 기반으로 제작한 유기 쌍안정성 소자에 대한 연구는 상대적으로 미흡하다. 본 연구에서는 Poly(methyl methacrylate) (PMMA) 박막 안에 분산된 $SnO_2$ 나노 입자를 사용하여 제작한 유기 쌍안정성 소자의 전기적인 특성을 관찰하였다. 소자를 제작하기 위해 나노 입자의 전구체인 Tin 2-ethylhexanoate (95%) 2.4 mmol을 dibutyl ether (99.3%) 10 ml에 용해시킨 후, 용매열 화학적 방법을 사용하여 용매 안에서 $SnO_2$ 나노 입자를 합성하였다. 용매 안에 들어있는 1 wt%의 $SnO_2$ 나노 입자와 100 mg의 PMMA를 2 ml의 클로로벤젠에 용해하여 고분자 용액을 제작하였다. 하부 전극 역할을 하는 indium tin oxide가 증착된 유리 기판 위에 고분자 용액을 스핀 코팅하고, 열을 가해 용매를 제거하여 $SnO_2$ 나노 입자가 분산되어 있는 PMMA 박막을 형성하였다. 그 위에 Al 전극을 증착하여 기억 소자를 완성하였다. 제작된 유기 쌍안정성 소자의 전류-전압 (I-V) 측정 결과에서는 동일한 전압에서 서로 크기가 다른 전류가 흐르는 I-V 곡선의 히스테리시스 특성이 나타났다. 그러나 $SnO_2$ 나노 입자가 없는 PMMA 박막으로 형성된 유기 쌍안정성 소자에서는 I-V 곡선의 히스테리시스 특성이 나타나지 않았다. 따라서 PMMA 박막 안에 삽입된 $SnO_2$ 나노 입자가 유기 쌍안정성 소자의 메모리 효과에 결정적인 영향을 준 것을 알 수 있었다. 전류-시간 측정 결과에서는 소자의 ON/OFF 비율이 시간에 따라 큰 변화 이 없이 1000 사이클 이상 지속적으로 유지 하고 있음을 보여 줌으로써 유기 쌍안정성 소자를 장시간 사용할 수 있음을 나타내 주었다.

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Characteristics of Siloxane Concentrations in Bio Gas from Anaerobic Digestion of Food Wastewater (음식물류폐기물폐수의 혐기성 소화에서 바이오가스의 실록산 농도 특성)

  • Lee, Chae-Young;Lee, Se-Wook;Park, Su-Hee;Hur, Kwang-Beom;Kim, Hae-Ryong;Lee, Nam-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.4
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    • pp.60-65
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    • 2011
  • Siloxane is an organic silicon compound and is volatilized into the bio gas from anaerobic digestion. It causes failure of gas combustion engines using the bio gas. Siloxane emission characteristics should be identified to provide a proper siloxane control. This study focuses on characterizing siloxane emission in bio gas from an anaerobic digester of food wastewater operating from January to March. The concentrations of total average siloxane and cycle-siloxane D4 were detected to be 9.5 and $4.0mg\;siloxane/m^3$, respectively. The concentrations of cycle-siloxane and linear-siloxane were resulted in D4>D5>D6 and L4>L3>L5>L2, respectively. The total siloxane concentration was the lowest in January and the highest in March.

Solid Fuel Carbonization Characteristics through Hydrothermal Carbonization of Sewage Sludge (하수슬러지의 수열탄화를 통한 고형연료 탄화 특성)

  • Seong Kuk Han;Moonil Kim
    • Journal of the Korea Organic Resources Recycling Association
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    • v.31 no.2
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    • pp.53-61
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    • 2023
  • Most of the sewage sludge is organic waste containing a large amount of organic substances decomposable by microorganisms by biological treatment. As for existing sewage sludge treatment methods, reduction and fuel conversion are being carried out using technologies such as drying, incineration, torrefaction, carbonization. However, the disadvantage of high energy consumption has been pointed out as latent heat of 539 kcal/kg is consumed based on drying. Therefore, in this study, we intend to produce solid fuel through hydrothermal carbonization(HTC), which is a thermochemical treatment. To evaluate the value of solid fuel, the characteristics of carbonization and fuel ratio were analyzed. As a result, as the hydrothermal carbonization reaction temperature increased, the lower heating value also increased by about 500 kcal/kg due to the increase in the degree of carbonization. H/C, O/C, ratio showed a decreasing trend from 1.78, 0.46 to 1.57, 0.32. When the ratio of ash to combustible content (fixed carbon + volatile) of dry sludge was 0.25 or more, it was derived that the degree of carbonization and calorific value did not increase even when hydrothermal carbonization was performed.

Effects of Sewage Treatment on Characteristics of Sludge as a Composting Material (하수처리가 퇴비화를 위한 하수 슬러지 특성에 미치는 영향)

  • Kim, Jae-Koo;Kim, Jong-Soo
    • Applied Biological Chemistry
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    • v.41 no.2
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    • pp.181-186
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    • 1998
  • The effects of sewage treatment on characteristics of sludge as a composting material were investigated for a year during the initial operation at the full-scale Chunan sewage treatment plant. Due to the shortage of design capacity of belt press, a sludge dewatering unit, non-volatile solids were recirculating and concentrating in the treatment plant, resulting in an increase of MLSS and a decrease in F/M ratio at the activated sludge system. Special attention is required for long term operations since the increase of non-volatile solids in the plant would deteriorates the treatment efficiency. The sewage sludge of the Chunan sewage treatment plant showed 79.5% of water content, 11.6% of organic content, and C/N ratio of 6.1, and contained As 1.8 mg/kg, Cd 27 mg/kg, Hg <0.1 mg/kg, Pb 54 mg/kg, T-Cr 370 mg/kg, and Cu 1,100mg/kg of heavy metals. In order to be used as raw material for optimum composting, the sewage sludge requires bulking agents for moistrure/porosity control and a carbon source for adjusting C/N ratio. However, the sewage sludge is not adequate as a soil conditioner after composing due to a high content of heavy metals. If the sewage sludge has to he used as a soil conditioner after composting, it as required to identify and remove tire industrial wastewater portions in tire influent of the plant since heavy metals in the influent were mostly concentrated in dewatered sludge.

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Effect of the Applied Biostimulant Depth on the Bioremediation of Contaminated Coastal Sediment (연안오염퇴적물에 주입한 생물활성촉진제의 깊이가 생물정화효율에 미치는 영향)

  • Woo, Jung-Hui;Subha, Bakthavachallam;Song, Young-Chae
    • Journal of Navigation and Port Research
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    • v.39 no.4
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    • pp.345-351
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    • 2015
  • This study investigated the optimum depth for the application of bioremediation in contaminated coastal sediment using a lab scale column experiment. The biostimulants were placed in the top surface of the sediment facing seawater, 3cm, 6cm and 10cm of the depth from the surface, respectibely. During the experiment, the changes of organic pollutants and heavy metal fractions in the sediment were monitored in 1 month and 3month time intervals. The organic pollutants found during various analysis such as chemical oxygen demand, total solids and volatile solids, significantly reduced when the depth of the biostimulant was 3cm or less. In contrast, at a depth of over 6cm, the reduction of organic pollutants decreased, and the results were similar to the control. Heavy metals fractions in the sediment also changed with the depth of the biostimulants. The exchangeable fraction of the metals was quite reduced at the sediment surface in the column, but the organic bound and residual fractions considerably increased at a depth of 3cm. Based on this study, the optimum biostimulants depth for in-situ bioremediation of contaminant coastal sediment is 3cm from the sediment surface.