• Composites Research
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• v.26 no.2
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• pp.123-128
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• 2013

The PVDF (polyvinylidene fluoride) fibers were prepared using the wet spinning processing. To improve ${\beta}$-phase crystalline which closely related piezoelectric property PVDF wet spun fibers conducted post treatment. Post treatment is consisted of heat stretching and annealing process. The heat stretching and annealing conditions were controlled by changing temperature between glass transition temperature and melting temperature. From these experimental data, the resulting crystal structure of the ${\beta}$-phase crystalline was confirmed by FT-IR and XRD experiments. From these analysis results, optimum stretching and annealing conditions of the wet spun PVDF fibers were founded to increase high ${\beta}$-phase crystalline. Furthermore results showed that thermal processing had a direct effect on modifying the crystalline microstructure and also confirmed that heat stretching and annealing could increase the degree of crystallinity and ${\beta}$-phase crystalline. Finally, piezoelectric constant ($d_{11}$) of the post heat treated PVDF fibers reinforced composite were measured to investigate the feasibility for the sensing materials.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.11a
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• pp.180-180
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• 2009

나노 형광체 합성에 있어서 입자 형상 및 입자 크기의 변화를 알아보기 위해 녹색 발광하는 ZnS:Cu 형광체를 액상반응법으로 합성하였다. X선 회절 분석기로 결정성을 확인하였으며, 전계 방사 주사 전자 현미경 (FE-SEM)을 통해 각각 30~80 nm 이하 크기임을 확인하였다. 녹색발광을 하며, 450 $^{\circ}C$부터 900 $^{\circ}C$ 까지 온도 상승함에 따라 결정성이 증가 하였으며, hexagonal구조에서 가장 효율이 높은 PL 값을 보였다.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.03a
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• pp.176-176
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• 2003

강자성 반도체(DMS)는 반도체에 전이금속을 doping함으로써 반도체의 전자 수송 특성과 전이 금속 이온에 의한 자기적 특성을 동시에 발현할 수 있도록 설계된 물질로서 '스핀 전자공학'의 구현을 위해 현재 활발히 연구되고 있는 분야이다. 특히 높은 전기 전도도와 투명 광 특성을 가지는 ZnO계는 전이금속을 첨가 할 경우 상온에서도 강자성 특성을 보일 것이라는 연구가 발표 된 이후 큰 주목을 받고 있으며, 실제로 Tc가 상온 이상인 결과들이 최근 발표되고 있다. 그러나 PLD에 의해 증착 된 Co-doped ZnO 경우 강자성 물성의 재현성이 아주 낮은 것으로 알려져 있는 둥 강자성 발현의 기원이 아직도 명확히 규명되지 못한 상태이다. 이에 본 연구에서는 Co-doped ZnO 계의 강자성 발현의 기원을 밝히고자 고상 반응법을 이용하여 다결정계를 제조한 후 X-선 회절 분석과 Raman 분광법을 이용하여 제2차상의 존재 유무 및 Co 이온의 치환 정도를 분석하였다. 다음으로 방사광 EXAFS 분석을 행하여 ZnO내에서의 Co 이온의 원자가 상태를 분석하고, PPMS를 사용 M-T curve를 측정/분석함으로써 강자성 발현의 기원을 규명하고자 하였다.

• Journal of the KSME
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• v.35 no.10
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• pp.896-902
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• 1995

소음의 저감 대책은 소음원의 소음 감쇠, 소음 전달 경로의 소음 저감 및 수음자에 대한 대책 으로 나눌 수 있다. 여기에서 소음원의 소음 저감 대책을 세우기 위해서는 소음원의 주파수 특 성을 정확하게 분속해야 하고 이를 위해서는 자유음장이라는 공간이 필요하게 된다. 음향학적 으로 자유음장이란 점음원으로부터 무지향적으로 방사되는 음의 음압레벨(sound pressure level )을 따르는 음장으로 정의된다. 이는 음원으로부터 거리가 두 배 증가함에 따라 음압레벨이 6dB 감소함을 의미한다. 즉, 주변 소음으로부터 발생한 음이 다른 물체나 벽으로부터 반사된 반사음 이나 회절음의 영향을 받지 않는 음장을 말한다. 자유음장은 자연계에서 극히 제한적으로 존재 하지만 인간이 측정장비 및 측정 대상물을 이동시켜 이용할 수 없으므로 인공적인 시설로서 무 항실을 만들어 자유음장 환경을 조성한다. 이 글에서는 무항실의 특성 및 국내에서 시공되는 무향실의 설계 및 제작 과정을 간단히 소개하고 현재의 국내 무항실의 수준과 앞으로 나아갈 방항을 제시하고자 한다.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.116.1-116.1
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• 2013

포항가속기연구소 저장링에는 Dipole Magnet, Wiggler, Undulator 등 다양한 방사광발생장치를 설치하여 각종 실험에 사용하고 있다. 그중 ADC사에서 제작한 In- vacuum Undulator (이하, ADC-IVU)는 고휘도의 X-선 빔을 생성하여 생체고분자(단백질, DNA 등) 단결정의 X-선 회절 데이터를 획득하는 실험을 수행한다. 현재, ADC-IVU의 Rf finger 등 일부장치의 성능개선을 위한 장치 해체, 교체 작업과 재조립 및 정렬작업, 구동시험을 거치고 최종 초고진공 진공 달성을 위한 탈가스처리, NEG 활성화작업등을 마무리 하였다. 본 발표에서는 ADC-IVU의 성능개선 작업에 대한 전반적인 사항과 진공작업 및 그 결과를 내용으로 한다.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.11 no.4
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• pp.259-269
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• 2013

Applicability of ammonium molybdophosphate/iron oxides-polyacrylonitrile (AMP/IO-PAN) composites on the removal of radionuclides in the radioactive wastewater generated from nuclear power plants was investigated. The composites were characterized using the following analytical techniques: X-ray diffraction (XRD), Fourior transform-infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), particle size analyzer (PSA), nitrogen adsorption-desorption and magnetic property measurement system (MPMS). 10wt% of AMP/IO-PAN composite has a saturation magnetization of 2.038 emu/g. Single-solute sorptions of Co, Sr and Cs onto 10wt% of AMP/IO-PAN composite were investigated. The maximum sorption capacities ($Q^0$) predicted by the Langmuir model on 10wt% of AMP/IO-PAN composite were 0.097, 0.086 and 0.66 mmol/g for Co, Sr and Cs, respectively. The maximum sorption capacities ($Q^0$) of Cs predicted by Langmuir model on 0, 10, 20 and 30wt% of AMP/IO-PAN composites were 0.702, 0.655, 0.602 and 0.559 mmol/g, respectively. The maximum sorption capacities ($Q^0$) of Cs decreased with increasing the iron oxide content in the AMP/IO-PAN composites.

• Journal of the Mineralogical Society of Korea
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• v.31 no.4
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• pp.277-285
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• 2018

Azurite ($Cu_3(CO_3)_2(OH)_2$) was compressed up to 21.52 GPa for its behaviors at ambient temperature. High pressure experiment was performed using the symmetrical diamond anvil cell employed in the angle dispersive X-ray diffraction method. Pressure was determined by ruby fluorescence calibration method. No phase transitions were observed within the present pressure limit and bulk modulus was determined to be 54.4 GPa when ${K_0}^{\prime}$ is fixed to be 4. Applying the normalized pressure-strain analysis, reliability of the azurite compression pattern was checked.

• Journal of the Korean Society for Nondestructive Testing
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• v.20 no.6
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• pp.538-544
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• 2000

A phased array ultrasonic nondestructive inspection system is being developed to obtain images of the interior of steel structures by modifying a medical ultrasound imaging system. The medical system consists of 64 individual transceiver channels that can drive 128 array elements. Several modifications of the system were required mainly due to the change of sound speed. It was necessary to fabricate array transducers for steel structure and to obtain A-scan signal that is necessary for the nondestructive testing. Boundary diffraction wave model was used for the prediction of radiation beam field from array transducers, which provided guidelines to design array transducers. And a RF data acquisition board was fabricated for the A-scan signal acquisition along a selected un line within an image. For the proper beam forming in the transmission and reception for steel structure, delay time was controlled. To demonstrate the performance of the developed system and fabricated transducers, images of artificial specimens and A-scan signals for selected scan lines were obtained in a real time fashion.

• Economic and Environmental Geology
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• v.42 no.5
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• pp.509-512
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• 2009

Powder diffraction patterns of the zeolite mesolite ($Na_{5.33}Ca_{5.33}Al_{16}Si_{24}O_{80}{\cdot}21.33H_2O$), with a natrolite framework topology were measured as a function of pressure up to 5.0 GPa using a diamond-anvil cell and a $200{\mu}m$-focused monochromatic synchrotron X-ray. Under the hydrostatic conditions mediated by pore-penetrating alcohol and water mixture, the elastic behavior of mesolite is characterized by continuous volume expansion between ca. 0.5 and 1.5 GPa, which results from expansion in the ab-plane and contraction along the c-axis. Subsequent to this anomalous behavior, changes in the powder diffraction patterns suggest possible reentrant order-disorder transition. The ordered layers of sodium- and calcium-containing channels in a 1:2 ratio along the b-axis attribute to the $3b_{natrolite}$ cell below 1.5 GPa. When the volume expansion is completed above 1.5 GPa, such characteristic ordering reflections disappear and the $b_{natrolite}$ cell persists with marginal volume contraction up to ca. 2.5 GPa. Further increase in pressure leads to progressive volume contraction and appears to generate another set of superlattice reflections in the $3c_{natrolite}$ cell. This suggests that mesolite in the pressure-induced hydration state experiences order-disorder-order transition involving the motions of sodium and calcium cations either through cross-channel diffusion or within the respective channels.

• Journal of the Mineralogical Society of Korea
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• v.15 no.3
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• pp.161-169
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• 2002

high pressure and temperature conditions. However, those results are not consistent with one another, and phase boundary between ilmenite and perovskite phases determined only from the quenching method may be not so reliable at all. Therefore, in-situ high pressure-temperature (hP-T) X-ray diffraction measurements were performed up to 19 GPa and $700^{\circ}C$ in a large volume press apparatus using synchrotron radiation. Experimental results show that perovskite phase is stable at pressures above 16 GPa, and transforms back to $LiNbO_3$phase near 15 CPa at room temperature, and that the perovskite-ilmenite transition is back and forth near 15 CPa at $500^{\circ}C$. LiNbO$_3$phase transforms to ilmenite at 13 CPa and $300^{\circ}C$ and at 10.8 CPa and $400^{\circ}C$, respectively. These data indicate that $LiNbO_3$phase may have a stability region in the hP-T phase diagram and that the perovskite-ilmenite phase boundary would be quite different from that previously reported.