• Journal of the Korean Chemical Society
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• v.32 no.3
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• pp.163-170
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• 1988

The MNDO calculations were performed on the various rotamers of N-methyl formamide, N,N-dimethyl formamide, N-methyl acetamide, and N,N-dimethylacetamide in order to investigate the contribution of the one-electron and the steric effect on their rotational barriers about the C-N bond. Results show that while the conformational stabilities of formamides depend mainly on the one-electron factor, those of acetamides depend mainly on the steric factor. According to results obtained by calculations on the rotational barriers about C-N bond, for N-monosubstituted amides the steric effect is larger in the rotational ground state than in the transition state and for N,N-disubstituted amides the steric effect is larger in the rotational transition state.

• Journal of the Korean Chemical Society
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• v.26 no.3
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• pp.117-127
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• 1982

In order to analyze the role of axial carbon atoms in rotational barrier of ethane, we take the carbonless ethane, as a model, which is made of six hydrogens in coordinates of ethane. The energy of the system is calculated by McWeeny's open-shell restricted Hartree-Foch selfconsistent-field (RHF-SCF) method, and the transition density on the staggered-to-eclipsed rotation is examined. As being expected, the eclipsed form of the model is more stable than the staggered one. Through the transition density comparison of this model and real ethane, it is found that the existence of the axial carbon atoms induces the electronic density to be diluted in the vicinity of protonic sites and to be attracted to the region of carbon atoms or further to C-C bond region as the barrier is traversed. This migration of electronic charge tell us that the barrier to the internal rotation of ethane originates from the fact that the magnitude of electronic energy depression is not large enough to offset the increased nuclear-nuclear repulsion on the staggered-to-eclipsed rotation.

• Journal of the Korean Chemical Society
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• v.50 no.4
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• pp.291-297
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• 2006

The equilibrium structures, relative energies and NBO analyses for the possible conformations and transition states which can exist on the internal rotation of CPDFB and CPCFB molecules have been investigated using DFT and ab initio methods with various basis sets. The interaction between bonding orbital ((C1-C3, C2-C3)) and antibonding orbital (n*(B9) and *(B9-Cl11)) was the main characteristic hyperconjugation in both molecules. In addition, the stabilization energy of CPDFB was 6.63kcal/mol and that of CPCFB was 6.97(E-form)/6.79(Z-form) kcal/mol for each conformation. The rotational barriers by internal rotation of BF2- and BFCl- functional groups were evaluated to be 5.3~6.7kcal/mol and 5.7~6.5kcal/mol respectively, which showed good agreement with the experimental values reported by previous dynamic NMR study. Finally, Z-form was more stable than E-form by 0.2 kcal/mol in CPCFB molecule and therefore Z-form was confirmed as global minimum.

• Proceedings of the KIEE Conference
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• 2011.07a
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• pp.928-929
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• 2011

본 논문에서는 IPMSM(Interior Permanent Magnet Synchronous Motor)의 회전자에 보조 슬롯인 노치(Notch)와 자속 장벽인 베리어(Barrier)를 설치하여 전반적인 구동 특성을 향상 시켰으며, 각 형상에 따른 d, q축 인덕턴스의 변화를 고찰하였다. 인덕턴스의 계산은 IPMSM의 등가회로 및 벡터도를 이용하였으며 계산되어진 인덕턴스로 전류위상각에 따른 토크를 계산하고 FEM(Finite Element Method)결과와 비교하였다.

• Proceedings of the KIEE Conference
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• 2015.07a
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• pp.728-729
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• 2015

본 논문은 100kW급 차량 구동용 매입형 영구자석 동기전 동기의 회전자 형상에 따른 특성을 비교 분석하였다. 영구자석 사용량을 동일하게 유지하고, 자속장벽 길이와 자석의 각도를 설계변수로 하여 해석 모델을 선정하였다. 유한요소 해석을 통해 선정된 해석 모델의 평균 토크, 토크리플 특성을 비교, 분석하여 개선된 모델을 제시하였다.

• The Transactions of the Korean Institute of Power Electronics
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• v.13 no.4
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• pp.295-302
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• 2008

This paper examines the design and the performance of a PMA-RSM(permanent-magnet assisted reluctance synchronous motor) for washing machine. A FEM(finite element method) is used to analyze performance and maximum torque characteristic of the proposed PMA-RSM. The designed motor is a combination of salient poles, which is making reluctance torque, and permanent magnet which are located on the air-gap of rotor to get a enough torque during low speed resign. Typical flux barrier type reluctance synchronous motor and the effects of adding magnet into the flux barrier of the rotor of a PMA-RSM are compared and examined. Also the maximum torque point of the reluctance torque by reluctance and reaction torque by magnetic alignment torque, which is in barrier, of the proposed PMS-RSM are derived through simulation. Using this results, the characteristics analysis of a performance, an average torque and a torque ripple of flux barrier RSM and the proposed PMA-RSM are performed through FEM under the saturation effect respectively.

• Proceedings of the KIEE Conference
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• 2015.07a
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• pp.902-903
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• 2015

현재 세계는 각종 에너지에 대한 연구가 치열하게 진행되고 있는 가운데 각 기계들의 에너지 효율등급이 엄격하게 규제되고 있다. 전동기 분야에서는 사용 용도에 따라서는 영구자석을 쓰지 않는 유도기가 주목을 받았다. 하지만 유도전동기는 가공이 쉽지 않고 동일 사이즈에서 출력이 동기 릴럭턴스 전동기(Synchronous Reluctance Motor; SynRM)보다 낮기 때문에 현재 국내외 전동기 시장에서는 SynRM이 주목받고 있으며 현재 많은 연구가 진행되고 있다. 본 논문은 30kW급 팬 부하용 SynRM 설계에 관해 논문이다. 기존에 사용되었던 유도 전동기를 대체하기 위해 전동기의 자속장벽의 형상에 따라서 어떠한 효과가 있는지에 대해 연구하고 앞으로의 SynRM의 회전자 형상 설계 방법을 제시한다.

• The Transactions of the Korean Institute of Electrical Engineers B
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• v.55 no.10
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• pp.491-497
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• 2006

For high efficiency and easy speed control of brushless DC (BLDC) motor, the demand of BLDC motor is increasing. Especially demand of interior permanent magnet (IPM) BLDC with high efficiency and high power in electric motion vehicle is increasing. However, IPM BLDC basically has a high cogging torque that results from the interaction of permanent magnet magnetomotive force (MMF) harmonics and air-gap permeance harmonics due to slotting. This cogging torque generates vibration and acoustic noises during the driving of motor. Thus reduction of the cogging torque has to be considered in IPM BLDC motor design by analytical methods. This paper proposes the cogging torque reduction method for IPM BLDC motor. For reduction of cogging torque of IPM BLDC motor, this paper describes new technique of the flux barriers design. The proposed method uses sinusoidal form of flux density to reduce the cogging torque. To make the sinusoidal air-gap flux density, flux barriers are applied in the rotor and flux barriers that installed in the rotor produce the sinusoidal form of flux density. Changing the number of flux barrier, the cogging torque is analyzed by finite element method. Also characteristics of designed model by the proposed method are analyzed by finite element method.

• Proceedings of the KIEE Conference
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• 2004.10a
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• pp.64-66
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• 2004

Several techniques have been adopted in motor design of interior permanent magnet (IPM) type brushless DC (BLDC) motor to minimize cogging torque. IPM type motor has better ability in the centralization of flux than surface-mounted permanent magnet (SPM) type BLDC motor. So, the structure of IPM type BLDC motor has high saliency ratios that produce additional torque. However, this structure has a significant cogging torque that generates both vibration and noise. This paper describes new technique of the flux barriers design for reduction of cogging torque of IPM type BLDC motor. To reduce the cogging torque, flux barriers are applied in the rotor. Changing the number of barrier, the cogging torque is analyzed by finite clement method(FEM).

• Proceedings of the KIEE Conference
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• 2000.07b
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• pp.660-662
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• 2000

It is demonstrated that the torque performance of the flux barrier type synchronous reluctance motor(SynRM) can be improved in terms of geometric parameters. Torque ana power factor are related to the difference of inductances and the saliency ratio. And these inductance characteristics are determined by the geometric parameters of rotor: the number of layers. the width of iron to the width of flux barrier($K_w$). slot number and shape, airgap, bridge, etc. The relationship between geometric parameters. especially, $K_w$ and motor performance will be studied. This paper shows that torque and power factor are improved through redesign with considering geometric parameters. Performance comparisons of proto type SynRM and improved SynRM are given by FEA(Finite Element Analysis).