• Journal of the Korean Chemical Society
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• v.38 no.3
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• pp.186-196
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• 1994

Three fully dehydrated partially $Ag^+$-exchanged zeolite A(Ag_4Na_8-A, Ag_6Na_6-A, and Ag_8Na_4-A) were treated at $250^{\circ}C$ with 0.1 torr Rb vapor at 4 h. Their structures were determined by singlecrystal X-ray diffraction methods in the cubic space group $Pm{\bar3}m$ (a = 12.264(4) $\AA$, a = 12.269(1) $\AA$, and a= 12.332(3) $\AA$, respectively) at $22(1)^{\circ}C$, and were refined to the final error indices, R(weighed), of 0.056 with 131 reflections, 0.068 with 108 reflections, and 0.070 with 94 reflections, respectively, for which I > $3\sigma(I).$ In these structures, Rb species are found at three different crystallographic sites; three $Rb^+$ ions per unit cell are located at 8-ring centers, ca. 6.0∼6.8 $Rb^+$ ions are found opposite 6-rings on threefold axes in the large cavity, and ca. 2.5 $Rb^+$ ions are found on three fold axes in the sodalite unit. Also, Ag species are found at two different crystallographic sites; ca. 0.6∼1.0 $Ag^+$ ion lies opposite 4-rings and about 1.8∼4.2 Ag atoms are located near the center of the large cavity. In these structures, the numbers of Ag atoms per unit cell are 1.8, 3.0, and 4.2, respectively, and these are likely to form hexasilver clusters at the centers of the large cavities. The $Rb^+$ ions, by blocking 8-rings, may have prevented silver atoms from migrating out of the structure. Each hexasilver cluster is stabilized by coordination to 6-ring, 8-ring $Rb^+$ ions, and also by coordination to a 4-ring $Ag^+$ ion.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.7
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• pp.929-935
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• 2014

This paper is study on the pressure monitoring system(PMS) for ship's engine performance analysis( SEPA) based on web, with high speed and accuracy. This system is composed of pressure sensor, monitoring module with multi channel A/D converter, TCP/IP and satellite internet communication system. Existing domestic products measure cylinder pressure when piston of first explosive cylinder reached TDC(the top dead center) point and then measure next cylinder pressure manually each angle divided by a constant rotating interval. But presented system monitors in the local and web computer, using pressure information transmitted from pressure sensor installed on each engine. In this system, it is possible to increase the accuracy of the engine performance analysis because not only each TDC points but cylinder pressures synchronized with the TDC points could be measured in real time, accurately. And therefore, it may be used in a various diagnosis of main engines, such as deviations of each cylinder maximum pressures(Pmax) and the TDC firing positions and combustion conditions.

• Journal of the Korean Chemical Society
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• v.38 no.4
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• pp.283-287
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• 1994

The crystal stucture of bithional surfoxide, $C_{12}H_6Cl_4O_3S$, has been determined from 2295 independent reflections collected on an automated CAD-4 diffractometer with a graphite-monochromated $Mo-K\alpha$ radiation. The crystal belongs to the monoclinic, space group P2$_1$/n, with a unit cell dimensions a = 12.448(4), b = 9.740(1), c = $11.815(2)\AA$, $\beta$ = $100.06^{\circ}$, $\mu$ = 9.02 cm$^{-1}$, Dm = 1.76 g/cm$^3$, Dc = 1.75 g/cm$^3$, F(000) = 744, and Z = 4. The structure was solved by the direct method and refined by the least-squares method. The final R values was 0.037 for 2295 independent reflections. Overall conformation of the molecule is folded with respect to central surfur atom. Comparing with the molecular conformation of bithional, one of phenyl rings was swinged with about $180^{\circ}.$ This conformational change in the molecule results in the existance of intramolecular-hydrogen bond of S-O(3)---H-O(1) type and its steric hindrance between this moiety and the other phenyl ring. The two best planes of the phenyl rings have a maximum deviation of 0.009 $\AA$ for C(1) atom. The dihedral angle between two phenyl rings is $99.22^{\circ}.$ In the crystal structure, the molecules are packed with intermolecular-hydrogen bond of O(3)---H-O(2).

• Korean Journal of Crystallography
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• v.4 no.2
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• pp.54-62
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• 1993

The crystal shnture of dehydrated fully Cd2+-exchanged zeolite A evacuated at 2 × 10-6 Torr and 650℃ (a:12.189(2) A) and of its iodine sorption corrplex (a:12.168(2)A) have been netsmlmn by single uystal x-ray diffraction techliques in the cubic space group hkTn at 21(1)℃. The strutures were refined to final error indices, Ri:0.057 and R2 =0.063 with 186 reflections and Rl:0.082 and R2:0.085 with 181 reflections, respectively, for which 1>3σ(In both structure, six lie at two distinguished threefold axes of unit cell ten the crystal structure of an iodine sorption complex of Cd6-A four Cd2+ ions are recessed 0.69(1) A into the large cavity to complex each with from the (111) plane of 0(3), whereas two Cd2+ ions recessed 0.68(1) A into the sodalite unit Awximately 4.0 l3ions per nit cell are sorbed. Each bridge between a Cd2+ ion and 8-ring oxygens ((I-I-I)= 117(1) ˚ and 0(1)-I(1)-I(2)=172(1)). The near linear I-I-0 angle and its interatomic distance (I-0=3.57(3) A) are indicative of a weak charge transfer interacticn between the frarrework oxygen and iodine. The existence of In3 inside the large cavity indicates that the If ions and H ions may be produced by reaction of In vapor with water molecules which maybe associated with Cd2+ ions in partially dehydrated Cd6-A In3- ions may be produced by the combination of I- and I2.

• Journal of the Korean Chemical Society
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• v.37 no.1
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• pp.76-82
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• 1993

Two crystal structures of fully dehydrated Ca(II) and Tl(I) exchanged zeolite A, $Ca_{5.6}Tl_{0.8}-A (a = 12.242(2){\AA})\;and\;Ca_{1.4}Tl_{9.2}-A (a = 12.191(1){\AA})$, have been determined by single-crystal X-ray diffraction methods in the cubic space group Pm3m at 21(1)$^{\circ}C$. All crystals were ion exchanged in flowing streams of mixed $Ca(NO_3)_2\;and\;TINO_3$ aqueous solution with total concentration of 0.05M. All crystals were dehydrated at 360$^{\circ}C$ under $2{\times}10^{-6}\;torr$ for two days. The structures of the dehydrated $Ca_{5.6}Tl_{0.8}-A$ and $Ca_{1.4}Tl_{9.2}-A$ were refined to the final error indicies, $R_1$ = 0.072 and $R_2$ = 0.076 with 179 reflections for I > 3$\sigma$(I), and $R_1$ = 0.048 and $R_2$ = 0.043 with 226 reflections for I > 3$\sigma$(I), respectively. In each structure, Ca(II) ions are located on threefold axes associated with three 6-ring oxygens. $Ca^{2+}$ ions prefer to 6-ring sites and $Tl^+$ ions prefer to 8-ring sites when total number of exchanged cations per unit cell is more than 8.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2017.04a
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• pp.19-19
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• 2017

자율주행 트랙터를 위한 트랙터 조향제어는 일반적으로 전자모터를 이용한 EPS(Electric Power Steering) 시스템을 스티어링 휠에 연결하여 회전변위를 변경하고 그 결과 오비트롤(Orbitrol) 밸브의 토출유량을 바꾸고 호스로 연결된 조향실린더의 변위를 조절하여 최종적으로 전방 타이어의 방향각을 변경하면서 이루어진다. 이러한 조향방식은 시스템 구조상 조향실린더와 오비트롤 밸브가 상대적으로 멀리 떨어져 있으며, 밸브 특성상 약 ${\pm}5^{\circ}$의 오버랩이 포함되어 있다. 또한, EPS의 전자모터는 관성력, 마찰, 백래시 등의 영향을 가진다. 이와 같은 복합적인 영향은 조향 응답을 느리게 만들어 상대적으로 빠른 속도에서 주행에서 추종성능이 떨어지는 문제가 발생한다. 본 연구에서는 자율주행 트랙터의 조향성능 개선 연구의 일환으로 조향 HILS 시뮬레이터를 설계제작하여 조향 성능의 요인을 실험적으로 구명하고자 하였으며 이를 바탕으로 조향 시스템의 설계개선 방안을 수립하고자 하였다. 시뮬레이터는 동양물산 80 마력급 TX803 트랙터에 사용되는 오픈센터방식의 오비트롤 유압회로 시스템을 기어펌프가 장착된 AC모터로 구동되게 구성하였으며, 유량은 모터의 주파수를 조절 회전속도를 조절 변경하였다. 추가적으로 EPS와 오비트롤 조합의 조향성능을 비교 및 개선하기 위해 비례제어밸브(PVG 32, Danfoss)를 추가 장착하였다. 실제 트랙터 조향 시 나타나는 마찰저항을 모사하기 위해 부하 실린더를 구성하였으며, 조향 실린더의 부하의 크기는 부하 실린더를 폐회로를 구성하고 유량비례제어밸브를 이용한 유로의 개구량 조절을 통해 부하의 크기를 약 4000 N 까지 증가시킬 수 있도록 하였다. EPS와 비례제어밸브를 제어하기 위해 CANoe 8.0 소프트웨어를 이용하여 CAN통신 기반 가상 조향ECU를 구성하였으며 오비트롤의 기본 성능을 확인하기 위해 조향휠에 따른 실린더 동특성 및 계단 추종성능을 비례제어밸브와 비교하였다. 오비트롤 밸브는 약 ${\pm}5^{\circ}$이상 동작 시 실린더 압력이 상승하기 시작하였으며, 이후 약 ${\pm}10^{\circ}$이상 동작 시 조향실린더가 동작하기 시작하였다. 계단 추종성능실험에서는 비례제어밸브가 약 2배 이상의 응답개선을 나타냈다. 자율주행 경로추종 성능을 향상시키기 위해서는 순간적인 출력밀도가 높은 비례제어밸브를 통해 응답개선이 필요한 것으로 나타났다.

• Journal of the Korean Society for Nondestructive Testing
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• v.23 no.5
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• pp.464-474
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• 2003

Ultrasonic imaging of 3-D structures for nondestructive evaluation must provide readily recognizable images with enough details to clearly show various flaws that may or may not be present. Typical flaws that need to be detected are miniature cracks, for instance, in metal pipes having aged over years of operation in nuclear power plants; and these sub-millimeter cracks or flaws must be depicted in the final 3-D image for a meaningful evaluation. As a step towards improving conspicuity and thus detection of flaws, we propose a pulse-echo ultrasonic imaging technique to generate various 3-D views of the 3-D object under evaluation through strategic scanning and processing of the pulse-echo data. We employ a 2-D Wiener filter that filters the pulse-echo data along the plane orthogonal to the beam propagation so that ultrasonic beams can be sharpened. This three-dimensional processing and display coupled with 3-D manipulation capabilities by which users are able to pan and rotate the 3-D structure improve conspicuity of flaws. Providing such manipulation operations allow a clear depiction of the size and the location of various flaws in 3-D.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.5
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• pp.491-499
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• 2008

It is really urgent to develop wastewater treatment system which is economically efficient, occupies small area for buildup, can be easily operated, discharges small amount of sludge due to the more strict water quality standard, the expensive water and energy cost and so on. This study on treatment of wastewater including nonbiodegadable materials using white-rot fungus biofilm were designed to investigate the submerged type of biofilm, hydraulic retention times, recycle rates, and module turning times. Removal efficiencies of fully exposed biofilm type in atmosphere are similar to submerged biofilm of aeration type. The optimum conditions of white-rot fungus biofilm of fully exposed type in atmosphere are HRT 3$\sim$4 hr, recycle rate 6$\sim$10 Q, module turning times 0.5$\sim$2 times/min. At this time, removal efficiencies of organics were COD$_{Cr}$ 65.0$\sim$69.9%, NBDCOD 70.4$\sim$72.7%, BOD$_5$ 88.8$\sim$90.1%, SS 84.2$\sim$90.4%. Moreover average effluent concentration of BOD$_5$(8.9 mg/L) satisfied water quality standard of heavy water(BOD$_5$ less than 10 mg/L) but concentration of NBDCOD(29.6 mg/L) was higher than water quality standard of heavy water(NBDCOD less than 20 mg/L).

• Transactions of the Korean Society of Mechanical Engineers A
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• v.41 no.7
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• pp.635-643
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• 2017

The purpose of this study is to investigate the influence of the cold reduction rate and an ultrasonic fatigue test (UFT) on the fatigue behaviors of STS 304L. The tensile strength, yield strength, hardness value and fatigue limit in the UFT fatigue test linearly increased as thickness decreased from 1.5 mm to 1.1 mm, as the cold reduction rate of STS 304L increased. As a result of the UFT fatigue test (R = -1) of four specimens, the fatigue limit of the S-N curve formed a knee point in the region of $10^6$, and the 2nd fatigue limit caused by giga cycle fatigue did not appeared. In the case of t = 1.1 mm, the highest fatigue limit was 345 MPa, which was 64.3% higher than the original material (t = 1.5 mm). As a result of the UFT fatigue test of STS 304L, many small surface cracks occurred, grown, coalesced while tearing.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.6
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• pp.703-709
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• 2017

Korea Utility Helicopter(KUH) is a project to replace the aging helicopter presently being operated by the military with a domestic helicopter. The auxiliary power unit is a device that supplies emergency power to the system by an alternator installed when the main generator fails and the start motor converts the electrical energy of the battery into mechanical rotational energy to rotate the auxiliary power unit engine. With continuing power and operation, defects of the starting motor were found and improvements were carried out to solve it. In the failure mode analysis, the causes of possible defects were classified into 5 categories. Analysis of the 5 factors revealed that the main cause of defects is mechanical wear, which was found to be related to spring pressure. 250 tests were conducted through the theoretically determined pressure and regression analysis was performed with 4 sampling.The results showed that pressure was related to wear rate. In conclusion, early wear and breakage due to wear can be controlled through spring force and test showed the prediction of wear and the validity of the result were confirmed.