• Title/Summary/Keyword: 회수시간

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A Study on the Recovery of Mn Component from the Spent Manganese Batteries with Ammonium Sulfate (廢 망간電池로부터 黃酸 암모늄에 의한 Mn 성분의 분리 회수에 관한 연구)

  • 박용성;우제원;황영애
    • Resources Recycling
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    • v.9 no.6
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    • pp.3-8
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    • 2000
  • A reaction between the depolarizing mixture in the spent manganese batteries and ($NH_4$)$_2$$SO_4$was carried out to find a new process for the extraction of Mn component from the spent manganese batteries. The optimum conditions were as follows : the reaction temperature $425^{\circ}C$, ($NH_4$)$_2$$SO_4$weight ratio to the depolarizing mixture in the spent manganese batteries 12.0, reaction time 60 min. Under above conditions manganese was extracted 93.5%.

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Development of a Synthetic Process for N-Cyclohexylmaleiamic Acid Isobutyl Ester (N-사이크로헥실말레아민산 이소부틸 에스테르의 제조 공정 개발)

  • Moon, Bu-Hyun;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.51 no.5
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    • pp.545-549
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    • 2013
  • For the purpose of development of effective synthetic process of CHMI, a series of experiments were preformed on the preparation of CHMAIE, the intermediate of CHMI. For the first step, CHMA was synthesized by dropwise mixing of cyclohexylamine with maleic anhydride in toluene and 98.2% of theoretical CHMA was obtained by precipitation at $10^{\circ}C$ for 2 hours. The optimum reaction temperature of the esterfication, preparation reaction of CHAMIE from CHMA, was $68^{\circ}C$, and equilibrium conversion at optimum temperature was 98.5%. Equilibrium reaction time decreased with reaction temperature, and 4 hours was taken to reach equilibrium at optimum reaction temperature. Toluene in the final reaction product could be recovered by vacuum distillation. The recovery of toluene was increased with distillation temperature and 98% of toluene could be recovered at $55^{\circ}C$.

Mechanism improvement of the heat exchanger and the ventilator for the thermal efficiency increment of hot-air heater (온풍난방기의 열이용효율 증대를 위한 열교환부 및 송풍기 구조개선)

  • 이기명;박규식;최성우
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2002.02a
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    • pp.558-563
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    • 2002
  • 시설원예에서 난방장치를 사용하는 겨울철 재배 농산물의 생산비 중 난방 연료비가 30%~37% 정도를 차지하여 비중이 가장 높다. 따라서 시설원예 농가에서는 난방비를 절감하는 것이 농가소득과 직결되므로, 난방장치의 선정이 대단히 중요하다. 본 연구에서는 겨울철 재배 농산물의 생산비 중 30%-37% 정도를 차지하는 연료비를 절감하기 위해 기존의 온풍난방기와 다른 새로운 방식의 열교환기와 원심식 송풍블로워를 사용하는 블로워 송풍방식의 온풍난방기를 개발하고 개발된 온풍난방기의 가동으로 인한 난방 연료비 절감효과와 온실내의 균일한 온도분포를 획득하기 위해 8연동 비닐온실에서의 시험을 실시하였으며 얻어진 결과를 요약하면 다음과 같다. 가. 저 정압용의 전동기 축직결식 송풍팬을 대신하여 고 정압용의 블로워 송풍팬을 장착하고 열교환 면적을 크게 한 지그재그식 환류의 열교환실을 채용한 온풍난방기를 개발하였다. 나. 공시한 온실에서 기존 온풍난방기의 2일 가동시 DH당 연료 사용량이 평균 1.082$\ell$/$^{\circ}C$.hr 이며, 블로워 송풍방식 온풍난방기의 3일 가동시 DH당 연료 사용량은 평균 0.854$\ell$/$^{\circ}C$.hr로써 21%의 난방 연료비 절감효과가 나타났다. 다. 블로워 송풍방식 온풍난방기는 동일시간대 3$^{\circ}C$의 경시적 온도변화가 발생하였고, 기존의 은풍난방기의 동일시간대 온도변화는 최대 6.1$^{\circ}C$로 나타나 개발된 블로워 송풍방식 온풍난방기가 동일시간대 온실내의 온도변화를 크게 줄일 수 있었고 온도분포를 비교적 균일하게 하는 효과가 있음을 확인하였다.도 33$^{\circ}C$를 기준으로 한 열 회수 시간은 유입공기 온도가 52$^{\circ}C$ 및 64$^{\circ}C$ 일 각각 120분 및 140분으로 나타났다. (3) 제 3종 자갈: 축열조로 공급되는 공기의 온도가 52$^{\circ}C$와 64$^{\circ}C$ 일 때, 축열조 출구의 공기온도가 33$^{\circ}C$에 도달될 때까지 가열되는데 소요된 시간은 가열공기의 온도가 52$^{\circ}C$와 64$^{\circ}C$ 일 때 각각 180분과 150분이었고, 방열에 소요된 시간은 각각 240분 및 270분으로 나타났다. 방열과정 동안 축열조 출구의 최고 공기온도는 가열 공급공기의 온도가 52$^{\circ}C$$65^{\circ}C$일 때 각각 35.5$^{\circ}C$ 및 39.5$^{\circ}C$였다. 출구 공기온도 33$^{\circ}C$이상을 기준으로 한 에너지 회수시간은 유입공기 온도가 52$^{\circ}C$ 및 64$^{\circ}C$일 때 각각 140분 및 160분으로 나타났다. 이와 같이 자갈이 작을수록 축열조 출구의 공기온도가 기준온도 33$^{\circ}C$에 도달되는 시간이 길었으며, 이것은 축열조내의 공극이 작고 비중량이 커 자갈층을 가열시키는 축열시간이 길어지기 때문인 것으로 사료된다. 또한 작은 자갈일수록 방열시간도 다소 길어져 회수 가능 열에너지가 큰 것으로 나타났다

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Economic Analsys of Cooling-Heating System Using Ground Source Heat in Multi Family Apartment (공동주택에서 지열 냉난방 시스템 적용시 경제성 분석)

  • Park, Yongboo;Park, Jongbae;Lim, Haesik;Baek, Sungkoon
    • Journal of the Korean GEO-environmental Society
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    • v.8 no.3
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    • pp.11-18
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    • 2007
  • This paper studied the economical efficiency of ground source heat pump system under various conditions in apartments which have important effects on the housing market. And this study analysed the initial cost increase, saved managing cost and recovery time of initial cost. Analysis result showed as time of heating-cooling and water heating increases, the amount of saved managing cost increased much than the initial construction cost, so recovery time shortened. And as the net area of apartment increases, the recovery time increased. The study of the relation between the installation type and recovery time of initial construction cost showed when heat-cooling system adapted ground source heat and water heating system adapted waste heat, the initial construction cost was recovered most quickly. When Ground Source Heating system was used for the heating-cooling and water heating system, ground source heating system was used for the heating-cooling and waste heat used for water heating, and ground source heating system was used for the heating-cooling and LNG used for water heating, the construction cost increased 72,000, 66,900 and 62,300 won each per $m^2$ compared to the current system (package air-conditioner, heating and water heating using LNG).

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Recovery of Yttrium from the Sludge Generated in Recycling Process of the Obsolete CRT (폐CRT의 재활용 공정에서 발생한 슬러지로부터 Y의 회수)

  • 전준미;이재천;정진기;김남철
    • Resources Recycling
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    • v.10 no.6
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    • pp.22-28
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    • 2001
  • A study on the recovery of yttrium was conducted using the phosphor sludges generated in the recycling process of obsolete CRTs. Yttrium was leached by HCl and $HNO _3$. The leaching efficiency of yttrium was extensively investigated in terms of acid concentration, leaching temperature and time, and pulp density. Yttrium and lead was recovered from leaching solutions also by precipitation method. The leaching behavior of yttrium was similar in both acids. The leaching efficiency of yttrium for both acids increased with time at the conditions of 3.0M, $90^{\circ}C$, and 280 g/L of pulp density. After 40 minutes, it was saturated to 93% and 90% for HCl and HNO$_3$respectively. Yttrium was recovered from leaching acid solution by the addition of $H_2$$C_2$$O_4$while lead was removed as $PbSO_4$by $Na_2$ $SO_4$.

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Ultrastructural Changes on the Cuticular Surface, Excretory and Digestive Organs of Anisakis simplex Larvae Chronologically Recovered from Experimental Cats (실험감염 고양이로부터 경시적으로 회수한 고래회충 유충의 표피, 배설기 및 소화기의 미세구조 변화)

  • Sohn, Woon-Mok
    • Applied Microscopy
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    • v.29 no.2
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    • pp.211-221
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    • 1999
  • The ultrastructural changes of cuticular surface, excretory and digestive organs of Anisakis simplex larvae chronologically recovered from experimental cats were observed with a SEM and TEM. The larva recovered from an experimental cat at 3 days post-infection (PI) retained the cuticular surface with regular transverse striations and a longitudinal groove on the lateral side of body. This finding suggests that the molting of the 3rd stage larva of A. simplex to 4th one occurred from the 3rd day after infection in cats. The excretory organ (renette cell) consisted of a large cell with numerous ductules ramified from the main duct, mitochondria and secretory granules in cytoplasm. Secretory granules in the renette cell of larvae recovered at 24 hours PI were round whereas those of control and larvae recovered at 6 hours PI were amorphous. Muscular esophagus and ventriculus also retained many secretory granules in the cytoplasm. The secretory granules in these organs of larvae recovered at $6\sim24$ hours PI were electron-dense and widely distributed whereas those of control worm were packed in a pocket and retained various electron densities. In the cytoplasm of intestinal epithelial cells, numerous fine glycogen particles and mitochondria were distributed. The chronological changes of secretory granules in renette cell, muscular esophagus and ventriculus seem to be related with the worm penetration into host tissue.

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Analysis of the Recovery Rate of Food-borne Pathogens according to Sample Preparation Methods in Animal Origin Foods (축산식품 중 전처리 방법에 따른 식중독균 회수율 분석)

  • Kim, Jong-Hui;Kim, Hyoun Wook;Ham, Jun-Sang;Kim, Bu-Min;Oh, Mi-Hwa
    • Journal of Food Hygiene and Safety
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    • v.31 no.6
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    • pp.406-413
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    • 2016
  • This study was performed to evaluate and establish a sample preparation method for the detection of food-borne pathogens in animal origin foods. Ham, yogurt, and Korean beef inoculated with Escherichia coli O157:H7, Staphylococcus aureus, and Salmonella Typhimurium, were tested for the effects of diluent composition, processing time, and proportion of diluent to sample. The diluents used were peptone water (PW), Saline solution (SS), Butterfield's phosphate buffered dilution water (BPD), and Buffered peptone water (BPW). The processing time periods considered for the samples were 30, 60, 90, 120, and 300 sec, and the proportions of diluent to samples tested were 1:2, 1:4, 1:9, and 1:19. Yogurt and beef showed the highest number of bacteria when treated with BPW (p < 0.05). However, ham showed no significant difference between the treatments with four different diluents. Optimum proportions of diluent to ham, yogurt, and beef were 1:9, 1:2, and 1:4, respectively. The processing time of 120 sec was chosen as optimum, because it showed the best recovery rate in all sample types. In this manner, detection of food-borne bacteria with the selected optimal conditions was indicated by a recovery rate of more than 85%. These data suggest that an appropriate diluent composition and diluent volume should be used depending on the type of sample, which would thereby increase the accuracy of detecting food-borne bacteria in animal origin foods.

Hydrate Production Performance Analysis with Multi-Well, Plate-Type Apparatus Using Depressurization and Thermal Methods (다중공 평판형 장비를 이용한 감압법과 열자극법에 의한 하이드레이트 가스 생산성 분석)

  • Lee, Youngsoo;Wang, Jihoon;Park, Jungkyoon;Sung, Wonmo
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.133-140
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    • 2009
  • This paper presents the experimental study to analyze the pressure and production behavior using depressurization and thermal methods in order to evaluate the hydrate productivity in the 2-D multi-well, plate-type apparatus which has 80 md permeability and 30% hydrate saturation. Injecting methane gas through multi-well allowed to set up the highly saturated hydrate system and combining two different sorts of sands made possible to build up the low permeability system. In this system, both depressurization and electric stimulation methods were applied. When operating pressure was low, according to the depressurization experiments results, the gas recovery was high, however strong pulses which appeared at initial stage of production would damage the operation system. Moreover, cases that hydrate reformed have occurred by endothermic reaction. We have conducted experiments four and six times for the depressurization magnitudes of 140 psi and 320 psi, respectively, to analyze production behavior for the method more in detail. For the cases that the depressurization magnitude was set as 140 psi, the unstable period appears in the results, but stabilized soon. In the experiment results for 320 psi the discontinuous and intermittent behavior has been observed. Thermal stimulation experiments was conducted with depressurizing 80 psi which is the case that shows stable behavior and low recovery. In the results, the gas recovery was high and the energy efficiency was low for long stimulating time. The energy efficiency and gas recovery increased for the soaking time of 1 minute after 2 minute-preheating. In the cases of which the soaking time exceeds 1 minute, energy loss by long soaking time caused low gas recovery and poor energy efficiency.

Effect of Attrition Scrubbing on the Recovery of Platinum Group Metals from Spent Automobile Catalytic Converters (자동차(自動車) 폐촉매(廢觸媒)로부터 백금족(白金族) 회수(回收)를 위한 어트리션 스크러빙의 효과(效果))

  • Kim, Wan-Tae;Kim, Hyung-Seok;Cho, Sung-Baek;Lee, Jae-Chun;Kim, Sang-Bae
    • Resources Recycling
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    • v.17 no.5
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    • pp.28-36
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    • 2008
  • The effect of attrition scrubbing on the recovery of platinum group metals (PGMs) from automobile catalytic converters has been investigated. Catalytic converters were first crushed into particles less than 2 mm and attrition scrubbed in the range of 60 min, and then they were sieved with several screens. The catalyst layer, $\gamma$-alumina, was dislodged from the surface of the supporting matrix into fine particles less than $45{\mu}m$ by attrition scrubbing. The fraction of fine particles less than $45{\mu}m$ increased as the residence time for attrition scrubbing increased. The composition of the fine fraction obtained at a residence time of 40 min was $CeO_2$ 19.3%, $ZrO_2$ 1.9% and PGMs 419 ppm. In the fine fraction, the recovery of y-alumina increased proportionally to the residence time. Simultaneously, the recovery rates of $CeO_2$, $ZrO_2$ and PGMs increased to 82.9%, 78.7% and 78.9%, respectively. The production of the fine fraction less than $45{\mu}m$ and the recovery of $\gamma$-alumina increased when the solid concentration and initial feed size increased. Therefore, the attrition scrubbing as the comminution and separation process was concerned to be effective for the recovery of catalyst layer from ceramic supporting matrix by physical impact and shearing action between particles in the scrubbing vessel.

Development of a Sow Voice Analysis System for Forecasting Parturition Time (임신돈의 분만시기 예측을 위한 음성 분석 시스템 개발)

  • 장동일;임정택;임영일;한원석;박창식
    • Journal of Animal Environmental Science
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    • v.6 no.2
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    • pp.121-130
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    • 2000
  • Pure voice characteristics of sow were analyzed to predict parturition time. These were analyzed by using oscilloscope and Sound Forge and the results showed that the voice frequency and amplitude of sow were in the range of 30∼2,500Hz and -35∼-75dB. According to the sound analysis results, the frequencies of sound appearance from farrowing sow in the farrowing pen for three days prior to delivery day and eight hours of prior to delivery day and eight hours of prior to time were around 85% and 46%, respectively of the total appearance during eight days to delivery. Forecasting of delivery time of farrowing sow using the number of sound occurrences showed a promising result such that those have been increased whenever the delivery time was approached. The forecasting success rates were 100% for both of one day and six hours prior to the actual delivery.

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