• Title/Summary/Keyword: 회분식

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Thermodynamic Correlations for Predicting the Properties of Coal-Tar Fractions and Process Analysys (석탄 유분에 대한 물성예측식 개발 및 공정에 대한 연구)

  • Oh, Jun Sung;Lee, Euy Soo;Park, Sang Jin
    • Korean Chemical Engineering Research
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    • v.43 no.4
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    • pp.458-466
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    • 2005
  • Full-scale utilizations of batch separation process often require knowledge about thermodynamics and correlation techniques of physical properties of complex mixture consisting of a great number of many unknown components. Various empirical correlations have been proposed to predict the physical properties mostly about the pseudocomponent of petroleum. In this study, one parameter correlations are developed for the calculations of the critical physical properties and ideal heat capacity of the pseudo-component of coal tar fractions. Developed model can provide a tool for the design and operations for the batch distillation of coal tar mixture.

Pyrolysis of Polyethylene using Batch Microreactor (회분식 미분반응기를 이용한 폴리에틸렌의 열분해특성 연구)

  • CHa, Wang-Seog;Kim, Sang-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.553-556
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    • 2005
  • Pyrolysis of polyethylene was carried out in the stainless steel reactor of internal volume of $40cm^3$. Pyrolysis reactions were performed at temperature $390-450^{\circ}C$ and the pyrolysis product were collected separately as reaction products and gas products. The molecular weight distributions(MWDs) of each liquid product were determined by GC-SIMDIS. Molecular weight of each product were decreased wi th increase of react ion temperature and time.

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니트로화합물의 혼합위험 특성연구

  • 김관응
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2003.05a
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    • pp.297-302
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    • 2003
  • 국내 화학공업에 있어서 두드러진 특징중의 하나는 의약품, 염·안료 등과 같은 부가가치가 매우 큰 제품을 제조하는 정밀화학공업이 대부분을 차지하고 있으며, 반응기는 회분식으로 대상이 되는 공정의 반응조건 등을 제조자 스스로 결정해야 하는 것이 많아 오조작이나 열분해반응이나 폭주반응과 같은 이상반응 발생 시 조기 제어 미흡 등으로 인한 화재 폭발 등 중대사고가 발생할 위험성이 매우 크다. 실제로 회분식 반응기에 의한 사고가 빈번히 발생하였고 사고에 의한 피해도 심각하다.(중략)

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Volatile Organic Compounds Production from Aerobic Biotreatment of Dairy Wastewater by a Sequencing Batch Reactor (연속회분식반응기(SBR)에 의한 낙농폐수의 호기성처리에서 휘발성유기물질 발생)

  • Hong, Ji-Hyung
    • Journal of Animal Environmental Science
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    • v.11 no.1
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    • pp.17-24
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    • 2005
  • Aerobic sequencing batch reactor (SBR) was used to treat screened dairy wastewaters. The study examined the production of volatile organic compounds (VOCs) and volatile fatty acids (VFAs) in the aerobic SBR and raw manure effluent storage over 35 days. The reduction of total VFAs in the aerobic SBR was over $59\%$ removal than that of the raw manure. Acetic acid production in the aerobic SBR and the raw manure effluent storage were kept 138 and 286 mg/L. The propionic acid in the aerobic SBR was 1.9 mg/L, while the raw manure effluent storage was 68 mg/L, respectively. The concentrations of VOCs in the aerobic SBR reactor and effluent fill down remarkably than the raw manure storage. The results confirmed that the aerobic biological treatment is an essential requirement for minimizing odor problems.

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The Kinetics of Protease Production by Bacillus licheniformis (Bacillus licheniformis에 의한 단백질분해효소 생산 Kinetics)

  • 김진현;유영제
    • KSBB Journal
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    • v.4 no.2
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    • pp.128-133
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    • 1989
  • Carbon sources and nitrogen sources are known to be very important in protease production by microorganisms. The effects of carbon source and nitrogen source on protease biosynthesis by Bacillus licheniformis were investigated using batch cultures. As initial carbon and nitrogen concentrations of culture medium increased, the specific growth rate of Bacillus licheniformis was increased, while the specific protease production rate was decreased. From the results of batch cultures, a mathematical model which considers the effects of carbon source and cnitrogen source was proposed and the methods to increase the productivity of protease were discussed.

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Characteristics of $\beta$-Glucosidase Immobilized on the Modified Chitin in Bioresctors (수식 Chitin에 고정된 $\beta$-Glucosidase의 동특성)

  • 이경희;김종덕김병우송승구
    • KSBB Journal
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    • v.5 no.3
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    • pp.279-291
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    • 1990
  • Partial hydrolysed and deacetylated chitin, CHITA and CHITB as supports of immobilized enzyme were obtained by treatment of acid and base respectively. Glutaraldehyde, bifunctional reagent, was employed for crosslinking between $\beta$-glucosidase and support. Immobilized enzyme activities of CHITA-Gase and CHITB-Gase were determined with the reaction of p-nitrophenol-$\beta$-D-glucopyranoside(PNG) in batch reactor, CSTR and PFR. Their optimum temperature, pH and enzymatic characteristics including Km and Vmax values were observed with variation of the flow rates. Mass transfer coefficient(h), effectiveness factor(η), deactivation rate(kd ) of two immobilized enzymes were also examined to compare efficiency of reactors.

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Enhancement of ${\beta}$-1,3-Glucan Functionality by Batch and Semi-continuous Typed Specific Carboxylation (회분식 및 반연속식 특이적 카르복실화 반응에 의한 ${\beta}$-1,3-glucan의 기능성 향상)

  • Jeong, Suk-Yun;Kim, Sang-Woo;Lee, Yong-Hwan;Lee, Jae-Hwan;Chang, Pahn-Shick
    • Korean Journal of Food Science and Technology
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    • v.40 no.2
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    • pp.146-151
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    • 2008
  • In this study, batch or semi-continuous reactions, introducing site-specific carboxylic acids in ${\beta}$-1,3-glucan structures, were performed to increase water solubility and gel forming ability, using TEMPO/hypobromite with or without NaBr as catalysts. Regio-selective carboxylic acid formations were determined with infrared (IR) and $^{13}C$ nuclear magnetic resonance (NMR) spectroscopic analyses. The regio-selective reactions with and without NaBr gave oxidation yields of 92.5 and 85.6%, respectively, in the batch type, and yields of 93.9 and 86.4%, respectively, in the semi-continuous type. The reaction times in the batch and semi-continuous reactions without NaBr were delayed by 100 and 150%, respectively, as compared to those with NaBr. A combination of IR and $^{13}C$ NMR analyses were used to confirm the formation of carboxylic acids in ${\beta}$-1,3-glucan. From the batch reactions with and without NaBr, the water solubilities of oxidized products were 50.0 and 55.6%, respectively, and in the semi-continuous reactions they were 52.6 and 53.5%, respectively; while the water solubility of the native ${\beta}$-1,3-glucan was less than 1.0%. Finally, as compared to the native ${\beta}$-1,3-glucan, the gel forming ability of the reaction products was greatly increased irrespective of the presence of NaBr or the reaction type.