• Journal of the Korean Chemical Society
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• v.18 no.1
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• pp.8-11
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• 1974

The solvolysis of p-substituted benzenesulfonyl chlorides $(substituents:p-H, p-Br, p-NO_2, p-OCH_3)$ in acetonitrile-water mixtures below 50 % of water content has been studied kinetically. Results show that Hammett plots give concaved curves but the mechanism is predominantly $S_N2$ and water acts both as nucleophile and general-base.

• Journal of the Korean Vacuum Society
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• v.21 no.3
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• pp.178-184
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• 2012

Carbon coils could be synthesized on nickel catalyst layer-deposited silicon oxide substrate using $C_2H_2$ and $H_2$ as source gases and $SF_6$ as an additive gas under thermal chemical vapor deposition system. The characteristics (formation density and morphology) of as-grown carbon coils were investigated as functions of additive gas flow rate and the cycling on/off modulation of $C_2H_2/SF_6$ flows. Even in the lowest $SF_6$ flow rate (5 sccm) in this work, the cycling on/off modulation injection of $SF_6$ flow for 2 minutes could give rise to the formation of nanosized carbon coils, whereas the continuous injection of $SF_6$ flow for 5 minutes could not give rise to the carbon coils formation. With increasing $SF_6$ flow rates from 5 to 30 sccm, the cycling on/off modulation injection of $SF_6$ flow confines the geometry for the carbon coils to the nanosized ones. Fluorine's role of $SF_6$ during the reaction was regarded as the main cause for the confinement of carbon coils geometries to the nano-sized ones.

• The Korean Journal of Ecology
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• v.25 no.2
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• pp.119-125
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• 2002

In order to elucidate the budget and cycling of Nitrogen and Sulfur, esential elements and principal constituents of acid rain, their input through precipitation, and their output by streamflow were quantified in coniferous and deciduous forested watersheds, using combination of nutrient concentration and hydrological analysis, in Kwangnung Experimental Forest from July 1991 to Decmeber 1993. Amount of annual mean precipitation was 12.916 ton·ha/sup -1/·yr/sup -1/, annual mean runoff 5,094 ton·ha/sup -1/·yr/sup -1/(39%), 7,647 ton·ha/sup -1/·yr/sup -1/(59%) in coniferous and deciduous forest watersheds, respectively. Amounts of annual input of N(NO₃/sup -/+NH₄/sup +/) and SO/sup 2-/₄ through preciptation were 12.5, 81.7 kg·ha/sup -1/·yr/sup -1/, respectively. Annual output via runoff of N(NO₃/sup -/+NH₄/sup +/) and SO/sup 2-/₄were 0.06, 39.23 ton·ha/sup -1/·yr/sup -1/ in the coniferous forest watershed ecosystem, and 0.15, 55.46 ton·ha/sup -1/·yr/sup -1/ in the deciduous one, respectively. On the basis of annual nutrient input and output, the annual budget of N(NO₃/sup -/+NH₄/sup +/) and SO/sup 2-/₄were +12.46, +42.49 ton·ha/sup -1/·yr/sup -1/ in the coniferous forest watershed, and +11.35, +26.26 ton·ha/sup -1/·yr/sup -1/ in the deciduous one. Thus N(NO₃/sup -/+NH₄/sup +/) and SO/sup 2-/₄were accumulated in both forested watershed ecosystems.

• Journal of Korean Society of Forest Science
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• v.86 no.1
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• pp.98-104
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• 1997

Soil pollution intensity at Mt. Namsan in Seoul city which was expected to show significant soil contamination due to long-term air pollution was evaluated by comparing soil chemical properties at Mt. Kyebangsan in Hongcheon area as a control, and the bacteria participating in nitrogen or sulfur mineralization were assayed simultaneously in order to evaluate the validity of N and/or S mineralization bacteria as an index of soil contamination. The soil of Mt. Namsan showed 10 times higher concentration of hydrogen ion compared to that of Mt. Kyebangsan, which indicated that the soil had relatively been acidified seriously. Especially, large amount of canons were thought to be leached out from the soil, while the amount of extractable Al was getting larger and larger, which result in serious problems in soil ecosystem of the mountain. I could infer from soil chemical properties of the four study sites that the major reason of soil acidification was SOx deposition. However, the sulfur-reducing bacteria were not significantly different between the two regions, which indicated that the microbial dynamics of the soil ecosystem was not controlled by simple factor, but by multiple factors. By the way, the dynamics of bacteria participating in denitrification process was different between the two regions, which was more active at Mt. Kyebangsan than at Mt. Namsan. Thus, the microbial assay for nitrogen mineralization is desirable to be examined as a tool for evaluating soil health or microbial activity in soil ecosystem.

• Economic and Environmental Geology
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• v.42 no.5
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• pp.457-469
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• 2009

Applicability of bioleaching techniques using a sulfur-oxidizing bacteria, Acidithiobacillus thiooxidans, for remediation of shooting range soil contaminated with toxic heavy metals was investigated. The effects of sulfur concentration, the amount of bacterial inoculum and operation temperature on the efficiency of heavy metal solubilization were examined as well. As sulfur concentration and the amount of bacterial inoculum increased, the solubilization efficiency slightly increased; however, significant decrease of heavy metal extraction was observed with no addition of sulfur or bacterial inoculum. Bacteria solubilized the higher amount of heavy metals at $26^{\circ}C$ than $4^{\circ}C$. Lead showed the highest removal amount from the contaminated soil but the lowest removal efficiency when compared with Zn, Cu and Cr. It was likely due to formation of insoluble $PbSO_{4(s)}$ as precipitate or colloidal suspension. Sequential extraction of the microbially treated soil revealed that the proportion of readily extractable phases of Zn, Cu and Cr increased by bacterial leaching, and thus additional treatment or optimization of operation conditions such as leaching time were required for safe reuse of the soil. Bioleaching appeared to be a useful strategy for remediation of shooting range soil contaminated with heavy metals, and various operating conditions including concentration of sulfur input, inoculum volume of bacteria, and operation temperature exerted significant influence on bioleaching efficiency.

• Resources Recycling
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• v.17 no.1
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• pp.51-58
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• 2008

Artificial mattes were prepared with adding pyrite or chalcopyrite as sulfur sources with Cu-Ni-Co-Fe alloy. The major phases identified by X-ray diffraction pattern were $(FeSi)_9S_8$, $CuFeS_2$, FeS, $Co_4S_3$, $Ni_3S_2$ and $Cu_2S$ for both mattes, and the matte prepared by adding chalcopyrite showed the higher peak of $Cu_2S$ due to high content of copper. Under optimum conditions, more than 95% copper, 90% nickel and 90% cobalt were extracted into leaching solution and sulfur concentration in the mattes did not much affect the leaching efficiency of the metals. The increase of the amount of pyrite or chalcopyrite added decreased pH in leaching solution and increased the concentration of iron ion dissolved in the leaching solution and the amount of residue.

• The Korean Journal of Malacology
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• v.30 no.2
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• pp.165-168
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• 2014

Shell of oyster has a function of shelter from predator as well as growth potential. We investigated the physicochemical characteristics of oyster shells from three difference oyster farms. The shells from Wando waters characterized high stability of nanostructure, ticker nacreous layer, high thermal decomposition temperature and low content of sulphur as well. These results represent that Wando coast is pristine water for oyster farming.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.126.2-126.2
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• 2015

대표적인 금속 칼코지나이드 2차원 물질인 이황화 몰리브덴($MoS_2$)의 대면적 합성을 위해 화학적 기상 증착 (Chemical Vapor Deposition) 방법을 이용하였다. 몰리브덴을 포함한 $Mo(CO)_6$ 전구체와 황이 포함된 $H_2S$ 가스를 적절한 비율로 반응시켰고, 증착 속도를 조절하여 한 층부터 다섯 층까지의 얇은 $MoS_2$ 박막을 제작할 수 있었다. $MoS_2$ 박막들이 층별로 균일 하게 증착 되었는지 확인하기 위해 라만 분광법을 이용 하였고, x-선 분광법을 통해 몰리브덴과 황의 정확한 정량비를 알 수 있었다. 뿐만 아니라, 우리는 두께 의존성을 갖는 이차원 물질인 $MoS_2$ 각 층마다 나타나는 전자 구조적 특성 분석을 위해 자외선 분광법, 역광전자 분광법, 전자 에너지 손실 분광법을 사용하였다. 그 결과, $MoS_2$ 박막의 두께 별 일함수, 가전자대 최대값, 전도대 최소값, 밴드갭의 변화를 관찰할 수 있었다. 이는 기존 계산 결과와 비교하여 잘 일치함을 알 수 있다.

• Journal of the Korean Society of Tobacco Science
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• v.26 no.2 s.52
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• pp.79-84
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• 2004

During the screening of antiviral substances having inhibitory effects on tobacco mosaic virus (TMV) infection to tobacco plants, we found a bacterial isolate KTGBP10, which was identified as a Stenotrophomonas sp., strongly inhibited the infection of TMV. When the culture filtrate from KTGBP10 was applied on the upper surface of leaves of Xanthi-nc tobacco plants at the same time or 24 hours before TMV inoculation, almost complete inhibition of TMV infection was achieved. And $40\%$ inhibition was shown with application of the culture filtrate to the under surface of leaves. In field trials, transmission of TMV from diseased seedlings to the healthy ones during transplanting work was reduced by $87.1\~92.6\%$ when the culture filtrate or cell suspension was sprayed onto the tobacco seedlings, cv. NC82, 24 hours before transplanting. No toxic effect was observed on the tobacco plants. When the broth filtrate of KTGBP10 was supplied by soaking through the cut-leaves before and/or after virus inoculation, the TMV infection was also inhibited by $50.4\~65.3\%$.

• Journal of the Korean Society of Tobacco Science
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• v.35 no.1
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• pp.13-19
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• 2013

The natural ingredient has been utilized variety of the food and medicine. The aromatherapy well known prevent disease and healthy promotion using the essential oil derived extracted plants. In this work, natural ingredient include herb granulated for application of tobacco filter. That used by granulation using fluidized bed granulator(top-spray, bottom-spray and tangential-spray) and wet granule method. According to ingredient can used granulating method selectivity. So, we used fluid-bed granulator and wet granule method. Grapefruit extract coated sugar particle using the bottom-spray method and red ginseng granule granulated red ginseng powder using the tangential-spray method in a fluidized bed. Then, these granules applied the tobacco filter after due consideration add amount and operation efficiency. As a result, wet granule was loaded dual filter because that similarity carbon granule. And it was fitted in added 3mg/mm, per tip in the tobacco end part. Another type, fuidized bed granules was filled cavity filter because it has high hardness, sphere shape.