• Journal of the Korean Ceramic Society
• /
• v.33 no.7
• /
• pp.816-822
• /
• 1996

Dependence of graphitic structure on oxidation of carbon materials was discussed using furan resin-derived carbon with inorganic compounds such as SiC and TiO2 Oxidation of carbon was governed by active site. I. e surface area regardless of the degree of graphitization. When oxidation was considered for not unit weight but unit area graphitization was important factor for oxidation so that the degree of graphitization increased the oxidation rate was delayed. Graphite (tiO2 addition) and turbostratic graphite(SiC addition) were oxidized through the same mechanism. In carbon materials with different structure components more than 2 oxidation of each component was different and amorphous component without the influence of additives on the surface was selectively oxidized in the intial oxidation stage.

• Journal of the Institute of Electronics and Information Engineers
• /
• v.49 no.11
• /
• pp.24-35
• /
• 2012

In this paper, we propose a dynamic lane control scheme with a traffic predictor module and a rate controller for reconciling with commercial optical PHY modules in energy efficient optical Ethernet systems. The commercial high speed optical Ethernet system capable of 40/100Gbps employs 4 or 10 multiple optical transceivers over WDM or multiple optical links. Each of the transceivers is always turned on even if the link is idle. To save energy, we propose the dynamic lane control scheme. It allows that several links may be entirely turned off in a low traffic load and frames are handled on the remaining active links. To preserve the byte order even if the number of active links may be changed, we propose a rate controller to be sat on the reconciliation sublayer. The main role of the controller is to insert null byte streams into the xGMII of inactive lanes. For the PHY module, the null input streams corresponding to inactive lanes will be disregarded on inactive PMDs. It is very handy to implement the rate controller module with MAC in FPGA without any modification of commercial PHYs. It is very crucial to determine the number of active links based on the fluctuated traffic load, we provide a simple traffic predictor based on both the current transmission buffer size and the past one with different weighting factors for adapting to the traffic load fluctuation. Using the OMNET++ simulation framework, we provide several performance results in terms of the energy consumption.

• Journal of the Korean Chemical Society
• /
• v.46 no.3
• /
• pp.187-193
• /
• 2002

The reaction rates of substituted 6-chloroquinoline with p-substituted benzoyichorides $p-CH_3,$ p-H, $p-NO_2$ have been measured by conductometry in acetonitrile, and the constants are determined at various temperatures (10, 15, 20, $25^{\circ}C$) and pressures (1, 200, 500, 1000 bar). From the values of rate constants, the activation parameters (Ea, ${\Delta}V^{\neq}$, ${\Delta}H^{\neq}$, ${\Delta}S^{\neq}$, ${\Delta}G^{\neq}$) and the pressure dependence of Hammett p values were determined. The rate constants increased with increasing temperatures and pressures, and are further increased to introduction to the electron donor substiuents in substrate $(p-NO_2)$ with 6-chloroqinoline. When the activation volume and the activation entropy are all negative And the Hammett p values are positive for the substrate over the pressure and temperature range studied. The results of kinetic studies for pressure and substituent show that thease reactions proceed in typical $S_N2$ reaction mechanism and "associative $S_N2$" in bond formation favored with increasing pressures.

• Electrical & Electronic Materials
• /
• v.3 no.1
• /
• pp.45-51
• /
• 1990

무배향 미연신 폴리에틸렌 테레프탈레이트 필름을 수중에서 일축연신 시킨후 연신된 시료의 열자극전류를 측정하여 검토 고찰하였다. 연신에 따른 측정결과 결정화도가 대체로 증가하는 경향이 있으나 연신비 150% 부근에서는 반대로 결정화도가 감소함을 알수가 있었는데 이는 초기인장에 따른 일시적 분자배향의 불안정한 형태로 인한 자유체적의 증가와 더불어 배위 엔트로피가 증가 하기 때문이라고 생각되며 인장된 시료의 밀도측정 및 적외선 스펙트럼분석으로 부터 확인하였다. 그리고 인장비의 변화에 따른 열자극전류의 피이크를 105(.deg.C)부근에서 얻었으며 인장비에 따른 열자극전류의 활성화 에너지를 구한 결과 150%에서 가장 큰 값을 얻었다.

• Applied Chemistry for Engineering
• /
• v.5 no.5
• /
• pp.904-909
• /
• 1994

Cure kinetics of DGEBA(diglycidyl ether of bisphenol A)/MDA(4,4'-methylene dianiline)/GN(glutaronitrile) system with and without HQ(hydroquinone) as a catalyst was studied by Kissinger equation and Fractional life method. The activation energy of the system with HQ was somewhat lower and the pre-exponential factor of that was higher by about 30% than those of the system without HQ. As 1.25phr of HQ was added, reaction rates increased about 1.8 times.

• Fire Science and Engineering
• /
• v.18 no.4
• /
• pp.52-56
• /
• 2004

An experiment to examine the characteristics of pyrolysis of Methyl Ethyl Ketone Peroxide was conducted in an air-present environment, using TG-DTA. Decomposition starting temperature was decreased as the increase of 98% concentrated H₂SO₄ to the MEKPO and the maximum decomposition temperature of MEKPO was 116.8℃. The activated energy calculated from differential method of pure MEKPO, MEKPO with 1 wt%, 3wt%, and 5wt% of H₂SO₄ were 0.576㎉/mo1, 0.355㎉/㏖, 0.284㎉/㏖ and 0.258㎉/㏖ respectively.

• Journal of the Korean Vacuum Society
• /
• v.3 no.1
• /
• pp.51-58
• /
• 1994

확산 현상은 박막성장 과정 및 박막의 기계, 전기, 자기적 성질 이해에 중요한 역할을 한다. 열 처리에 의한 상호확산 때문에 생긴 Pd/Cu 다층박막의 조성변화를 AES depth-profiling 방법을 이용해 서 조사하였다. 열처리전 시료에서의 각형의 초기 조성분포가 여러온도에서의 열처리에 의해 정현파 모 양의조성분포로 변화되었다. 조성의존성을 고려하지 않은 상호확산 계수를 정현파 분포의 진폭으로부터 구하였으며, 1.66 eV의 값을 갖는 활성화에너지는 Arrhenius plot으로부터 산출하였다. 또한 Boltzmann-Matano 방법을 사용해서 15$0^{\circ}C$에서의 조성의존 상호확산계수도 구하였다. 열처리에 의해 조 성균일화가 되는 것으로만 알려졌던 본물질계에서도 상분리가 생성됨을 관찰하였고, 그 열처리 조건은 $180^{\circ}C$에서 150분 보다 짧아야함을 밝혔다.

• Electrical & Electronic Materials
• /
• v.6 no.2
• /
• pp.161-167
• /
• 1993

ZnO 바리스터의 비선형 전도특성은 입자의 구조로부터 설명할 수 있다. 본 논문에서는 ZnO 바리스터의 입자구조에 트랩된 캐리어를 분석하기 위해서 TSC 측정 기법을 사용하였다. 측정 결과로 부터 네개의 TSC피크를 얻었다. 고온으로 부터 첫번째 두번째와 세번째 TSC피크의 기원은 각각 트랩, 도너 밀도 및 입계층의 트랩으로 나타나고 네번째 피크의 기원은 공핍층에 있는 도너 이온의 탈분극에 의해서 기인하는 것으로 사료된다. .alpha.$_{1}$피크의 활성화 에너지는 약 0.33-1.42eV였다. 또한 바리스터의 예비동작 영역에서의 전도특성은 .alpha.$_{1}$과 .alpha.$_{2}$피크의 값에 지배된다는 것을 확인하였다.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2010.05a
• /
• pp.331-332
• /
• 2010

This paper present a method to estimate the setting time of cement mortar incorporating admixtures under various curing temperature conditions by appling maturity based on equivalent age. It is indicated that equivalent age using setting time can be a proper method to predict setting time and it also exhibited comparable relativity between prediction value and measurement value.

• Journal of Nutrition and Health
• /
• v.14 no.3
• /
• pp.146-150
• /
• 1981

Some enzymatic properties of the lipase extracted from rice bran were studied. The rate of free fatty acid formation as a function of incubation time was maximum after 30 min. at $35^{\circ}C$. The activation energy of the enzyme was 1.83 Kcal/mol and using a olive oil emulsion as substrate, the Km value was $0.8{\times}10^{-3}M$. The enzyme activity was more stimulated by calcium ion. Application of these enzymatic properties onto the effective utilization of rice bran and preservation of rice were discussed.