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Heavy Metal Retention by Secondary Minerals in Mine Waste Rocks at the Abandoned Seobo Mine (서보광산 폐광석 내 2차 광물에 의한 중금속 고정화)

  • 이평구;강민주;최상훈;신성천
    • Economic and Environmental Geology
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    • v.36 no.3
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    • pp.177-189
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    • 2003
  • The main purposes of this study are to utilize mineralogical studies such as optical microscope, XRD and SEM/EDS analyses to characterize the oxidation of sulfide minerals and the mechanisms controlling the movement of dissolved metals from waste rocks at the abandoned Seobo mine. Mineralogical research of the waste rocks confirms the presence of anglesite, covellite, goethite, native sulfur and nsutite as secondary minerals, suggesting that these phases control the dissolved concentrations of As, Cu, Fe, Mn, Pb and Zn. The dissolved metals are precipitated, adsorbed and/or coprecipitated with(or within) Fe(Mn)-hydroxides and Mn(Fe)-hydroxides. The main phases of secondary mineral, Fe-hydroxide, can be classified as amorphous or poorly crystalline and more crystallized phases(e.g. goethite) by crystallinity. Amorphous or poorly crystalline Fe-hydroxide has relatively high As contents(9-24 wt.%). This poorly crystalline Fe-hydroxide changes toward more crystallized phase(e.g. goethite) which contains relatively low As(0.6-7.7 wt.%). These results are mainly due to the progressive release of As with the crystallization evolution of the As-trapping poorly crystalline Fe-hydroxides. It is also attributed to the differences of specific surface areas between the poorly crystalline Fe-hydroxides and well crystallized phases. The dissolved metals from waste rocks at Seobo mine area are naturally attenuated by a series of precipitation(as Fe, Mn, Cu, Pb), coprecipitation(Fe, Mn) and adsorption(As, Cu, Pb, An) reactions. The results of mineralogical researches permit to assess the environmental impacts of mine waste rocks in the areas, and can be used as a useful data to lay available mine restoration plan.

Studies on Cure Kinetics and Thermal Stability of Epoxy/Nylon 6 Blend (에폭시/나일론6 블랜드의 경화 동력학 및 열안정성에 관한 연구)

  • Kim, Dong-Kyu;Kim, Kwan-Woo;Han, Woong;Kwac, Lee-Ku;Kim, Byung-Joo
    • Applied Chemistry for Engineering
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    • v.26 no.5
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    • pp.538-542
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    • 2015
  • In this work, effects of the blend composition composed of 0, 10, 20, 30 and 40 wt% of nylon 6 to epoxy (diglycidylether of bisphenol-A, DGEBA) resin were investigated in terms of cure kinetics and thermal stability by differential scanning calorimeter (DSC) and thermogravimetric analysis (TGA). As the content of the nylon 6 increased, the maximum exothermic temperature ($T_{max}$) and the value of cure activation energy ($E_a$) decreased. The maximum exothermic temperature of the blending samples decreased with increasing in nylon 6 content, resulting in the decrease in curing activation energy of them due to the rapid curing reaction with epoxy resin in this system. From TGA analysis results of the DGEBA/nylon 6, the thermal stability based on the thermal stability index ($A^*{\cdot}K^*$) and integral procedure decomposition temperature (IPDT) increased with increase in the nylon 6 content. This was because of the combination of DGEBA and nylon 6 having good heat resistance, resulting in improving thermal stability of the DGEBA/nylon 6.

Synthesis and Infrared Light Reflecting Characteristics of TiO2/Mica Hybrid Composites (이산화 티타늄/마이카 복합 재료의 적외선 광반사 특성)

  • Kil, Hyun Suk;Rhee, Seog Woo
    • Applied Chemistry for Engineering
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    • v.27 no.1
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    • pp.16-20
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    • 2016
  • In this work, we describe the synthesis and infrared light reflecting characteristics of $TiO_2$/mica hybrid composites. $TiO_2$/mica composite materials were obtained by the hydrolysis and condensation reaction of titanium isopropoxide in an aqueous solution of acetic acid in the presence of mica particles. Amorphous phase of $TiO_2$ on the surface of mica was converted to the crystalline rutile phase via anatase phase by heat treatment ($600-1000^{\circ}C$, 1-3 h) of $TiO_2$/mica composite materials, and the size of crystals was controlled by heat treatment conditions. Physicochemical properties of mica and $TiO_2$/mica composites were investigated using FE-SEM, ED-XRF, and PXRD. The solar reflectance of $TiO_2$/mica composites in the near IR region (780~2,500 nm) measured using a diffuse reflectance NIR spectrophotometer was 88.6%, which is rather higher than that of calcined pure mica (86.6%). Therefore, $TiO_2$/mica composites can be used as NIR light reflective pigments.

Multi-View Video System using Single Encoder and Decoder (단일 엔코더 및 디코더를 이용하는 다시점 비디오 시스템)

  • Kim Hak-Soo;Kim Yoon;Kim Man-Bae
    • Journal of Broadcast Engineering
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    • v.11 no.1 s.30
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    • pp.116-129
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    • 2006
  • The progress of data transmission technology through the Internet has spread a variety of realistic contents. One of such contents is multi-view video that is acquired from multiple camera sensors. In general, the multi-view video processing requires encoders and decoders as many as the number of cameras, and thus the processing complexity results in difficulties of practical implementation. To solve for this problem, this paper considers a simple multi-view system utilizing a single encoder and a single decoder. In the encoder side, input multi-view YUV sequences are combined on GOP units by a video mixer. Then, the mixed sequence is compressed by a single H.264/AVC encoder. The decoding is composed of a single decoder and a scheduler controling the decoding process. The goal of the scheduler is to assign approximately identical number of decoded frames to each view sequence by estimating the decoder utilization of a Gap and subsequently applying frame skip algorithms. Furthermore, in the frame skip, efficient frame selection algorithms are studied for H.264/AVC baseline and main profiles based upon a cost function that is related to perceived video quality. Our proposed method has been performed on various multi-view test sequences adopted by MPEG 3DAV. Experimental results show that approximately identical decoder utilization is achieved for each view sequence so that each view sequence is fairly displayed. As well, the performance of the proposed method is examined in terms of bit-rate and PSNR using a rate-distortion curve.

Bactericidal Efficacy of a Disinfectant Solution Composed to Povidine-iodine Against Salmonella typhimurium and Brucella ovis

  • Park, Eun-Kee;Cho, Youyoung;Lee, Hu-Jang
    • Journal of Food Hygiene and Safety
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    • v.29 no.3
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    • pp.165-169
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    • 2014
  • Salmonella spp. and Brucella spp. are associated with considerable diseases of both humans and animals. In addition, these microorganisms cause the economic loss in animal farming and food industry. In this study, the disinfection efficacy of a commercial disinfectant, composed to povidone-iodine was evaluated against S. typhimurium and B. ovis. A bactericidal efficacy test by broth dilution method was used to determine the lowest effective dilution of the disinfectant following exposure to test bacteria for 30 min at $4^{\circ}C$. The disinfectant and test bacteria were diluted with hard water (HW) or organic matter suspension (OM) according to treatment condition. On HW condition, the bactericidal activity of the disinfectant against S. typhimurium and B. ovis was 400 and 150 fold dilutions, respectively. On OM condition, the bactericidal activity of the disinfectant was 5 and 20 fold dilutions against S. typhimurium and B. ovis, respectively. As the disinfectant composed to povidine-iodine possesses bactericidal efficacy against animal pathogenic bacteria such as S. typhimurium and B. ovis, the disinfectant solution can be used to control the spread of bacterial diseases.

Reduction of Hydraulic Conductivity in the Subsurface by the Formation of Aerobic Biobarrier (토양 내 호기성 생물벽체(Biobarrier)의 형성에 의한 투수계수의 제어)

  • Bae, Bum-Han;Oh, Je-Ill
    • Journal of Soil and Groundwater Environment
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    • v.12 no.2
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    • pp.1-8
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    • 2007
  • A series of batch and column experiments were conducted for the development of biobarrier technology which can be applied to containment and reduction of contaminants in soil and ground waters. The growth kinetic constants of Pseudomonas fluorescens on glucose or molasses were determined using batch experiments. The maximum specific growth rate (Vmax) of P. fluorescens at $23^{\circ}C$ on glucose or molasses were $0.246\;hr^{-1}$ and $0.073\;hr^{-1}$, respectively. However, molasses was selected as carbon source due largely to the absence of lag phase of P. fluorescens growth on molasses and economic reason. In constant head column experiments, the hydraulic conductivity of the column soil reduced by $6.8{\times}10^{-3}$ times from $4.1{\times}10^{-2}cm/sec$ to $2.8{\times}10^{-4}cm/sec$ after the inoculation of P. fluorescens and administration of carbon source and nutrients. The biomass concentration was observed highest in the column inlet. Measurements of carbon source and electron accepter (dissolved oxygen) concentration showed that the growth of P. fluorescence, which is the main reason for hydraulic conductivity reduction, was limited not by the concentration of carbon source but by the concentration of electron acceptor.

The Development of Dynamic Model for Long-Term Simulation in Water Distribution Systems (상수관망시스템에서의 장기간 모의를 위한 동역학적 모형의 개발)

  • Park, Jae-Hong
    • Journal of Korea Water Resources Association
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    • v.40 no.4
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    • pp.325-334
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    • 2007
  • In this study, a long-term unsteady simulation model has been developed using rigid water column theory which is more accurate than Extended-period model and more efficient comparing with water-hammer simulation model. The developed model is applied to 24-hours unsteady simulation considering daily water-demand and water-hammer analysis caused by closing a valve. For the case of 24-hours daily simulation, the pressure of each node decreases as the water demand increase, and when the water demand decrease, the pressure increases. During the simulation, the amplitudes of flow and pressure variation are different in each node and the pattern of flow variation as well as water demand is quite different than that of KYPIPE2. Such discrepancy necessitates the development of unsteady flow analysis model in water distribution network system. When the model is applied to water-hammer analysis, the pressure and flow variation occurred simultaneously through the entire network system by neglecting the compressibility of water. Although water-hammer model shows the lag of travel time due to fluid elasticity, in the aspect of pressure and flow fluctuation, the trend of overall variation and quantity of the result are similar to that of water-hammer model. This model is expected for the analysis of gradual long-term unsteady flow variations providing computational accuracy and efficiency as well as identifying pollutant dispersion, pressure control, leakage reduction corresponding to flow-demand pattern, and management of long-term pipeline net work systems related with flowrate and pressure variation in pipeline network systems

Development of Graphene Nanocomposite Membrane Using Layer-by-layer Technique for Desalination (다층박막적층법을 이용한 담수화용 그래핀 나노복합체 분리막 개발)

  • Yu, Hye-Weon;Song, Jun-Ho;Kim, Chang-Min;Yang, Euntae;Kim, In S.
    • Membrane Journal
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    • v.28 no.1
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    • pp.75-82
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    • 2018
  • Forward osmosis (FO) desalination system has been highlighted to improve the energy efficiency and drive down the carbon footprint of current reverse osmosis (RO) desalination technology. To improve the trade-off between water flux and salt rejection of thin film composite (TFC) desalination membrane, thin film nanocomposite membranes (TFN), in which nanomaterials as a filler are embeded within a polymeric matrix, are being explored to tailor the separation performance and add new functionality to membranes for water purification applications. The objective of this article is to develop a graphene nanocomposite membrane with high performance of water selective permeability (high water flux, high salt rejection, and low reverse solute diffusion) as a next-generation FO desalination membrane. For advances in fabrication of graphene oxide (GO) membranes, layer-by-layer (LBL) technique was used to control the desirable structure, alignment, and chemical functionality that can lead to ultrahigh-permeability membranes due to highly selective transport of water molecules. In this study, the GO nanocomposite membrane fabricated by LBL dip coating method showed high water flux ($J_w/{\Delta}{\pi}=2.51LMH/bar$), water selectivity ($J_w/J_s=8.3L/g$), and salt rejection (99.5%) as well as high stability in aqueous solution and under FO operation condition.

Extraction of Valuable Metals from Spent Desulfurizing Catalyst (탈황(脫黃) 폐촉매(廢觸媒)로부터 유가금속(有價金屬) 추출(抽出))

  • Pradhan, Debabrata;Kim, Dong-Jin;Baik, Seung-Bai;Lee, Seoung-Won
    • Resources Recycling
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    • v.20 no.3
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    • pp.48-54
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    • 2011
  • Sulphuric acid leaching was conducted to extract the metal values from spent refinery catalyst. More than 95% of Ni and V and 30% of Mo could be leached out in 1 M sulphuric acid and 1 hr of leaching time. The decrease in Mo leaching was due to typical characteristic of Mo matrix. The activation energies of the leaching reactions showed the dissolution process follows a diffusion control mechanism. In order to leach out all Mo, further the leaching experiments were conducted with sulfur free spent refinery catalyst. For sulfur free spent refinery catalyst, a two step process of leaching with 1 M sulphuric acid followed by sodium carbonate washing showed better leaching than a two step leaching process with sodium carbonate followed by sulphuric acid washing, with almost 99% leaching of Ni, Mo and V. Solvent extraction using LIX 841 were conducted for a leach liquor containing Ni, 2 g/L; V, 9 g/L, Mo, 0.6 g/L. More than 98% of Mo was extracted from the leach liquor at A:O ratio of 5:2 in a 2 stage process. Similarly V was extracted at A:O ratio of 5:3 in a 2 stage process with 82% of total V extraction.

Microarchitectural Defense and Recovery Against Buffer Overflow Attacks (버퍼 오버플로우 공격에 대한 마이크로구조적 방어 및 복구 기법)

  • Choi, Lynn;Shin, Yong;Lee, Sang-Hoon
    • Journal of KIISE:Computer Systems and Theory
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    • v.33 no.3
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    • pp.178-192
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    • 2006
  • The buffer overflow attack is the single most dominant and lethal form of security exploits as evidenced by recent worm outbreaks such as Code Red and SQL Stammer. In this paper, we propose microarchitectural techniques that can detect and recover from such malicious code attacks. The idea is that the buffer overflow attacks usually exhibit abnormal behaviors in the system. This kind of unusual signs can be easily detected by checking the safety of memory references at runtime, avoiding the potential data or control corruptions made by such attacks. Both the hardware cost and the performance penalty of enforcing the safety guards are negligible. In addition, we propose a more aggressive technique called corruption recovery buffer (CRB), which can further increase the level of security. Combined with the safety guards, the CRB can be used to save suspicious writes made by an attack and can restore the original architecture state before the attack. By performing detailed execution-driven simulations on the programs selected from SPEC CPU2000 benchmark, we evaluate the effectiveness of the proposed microarchitectural techniques. Experimental data shows that enforcing a single safety guard can reduce the number of system failures substantially by protecting the stack against return address corruptions made by the attacks. Furthermore, a small 1KB CRB can nullify additional data corruptions made by stack smashing attacks with only less than 2% performance penalty.