• Title/Summary/Keyword: 확산오염

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염소계유기용제 및 유류물질에 의한 산업단지 지하수 오염특성

  • Kim Jong-Ho;Kim Rak-Hyeon;Ryu Gwan-Hui;Park Jeong-Gu;Seo Chang-Il;Jeon Gwon-Ho;Jeong Jang-Sik
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.355-359
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    • 2006
  • 토양에 누적된 오염물질은 지하수 유동과 연계하여 점차 주변지역으로 확산된다. 본 조사는 오염의 개연성이 높은 산업단지를 선정하고 그 중에서도 유해화학물질의 사용이 많은 지역을 대상으로 토양과 지하수의 오염도조사를 수행하였다. 토양오염도 조사는 160개 지점에서 토양시료를 채취하여 오염물질을 분석하였으며 분석결과 TPH물질은 최고 23,151mg/kg, BTEX는 최고 1,657mg/kg로 검출되었다. 오염특성은 유류(TPH, BTEX) 물질 이외에도 TCE, PCE◎물질과같은 염소계 유기용제에 의한 오염도 확인할 수 있었으나 중금속 물질에 의한 오염은 우수 방류구와 같은 일부 지역에서 검출되었다. 지하수 수질의 경우 페놀, 비소, 납, BTEX, TCE, PCE 물질들이 복합적으로 오염되어있는 것으로 나타났다.

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Chemical Characteristics and Pollution of Groundwater in the Ponchon Area, Kwangju (광주, 본촌지역의 지하수의 수화학적 특성과 오염)

  • 양해근;김인수;최희철;김정우
    • Journal of Soil and Groundwater Environment
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    • v.6 no.4
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    • pp.83-95
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    • 2001
  • In this study, the contaminated status of groundwater under Ponchon Basin, Kwangju-city was analyzed by hydrogeological survey. Though the distribution of groundwater hydraulic head was similar with the ground elevation, the flow system of groundwater was changed due to overpumping in the industrial area. Paddy field and residential area which were located in the north part of the basin had relatively high concentrations of Cl, N $a^{+}$ and N $O_3$$^{[-10]}$ in the groundwater. Southern part of the basin which most industrial area occupied had relatively high concentrations of HC $O_3$, $Ca^{2+}$, $Mg^{2+}$ and Zn. Groundwater was contaminated by C $l^{[-10]}$ and N $O_3$$^{[-10]}$ due to the infiltration of domestic sewage and factory wastewater. In the Cl case, C $l^{[-10]}$ had a tendency of distribution over the water shed along with the contaminated source. The drawdown of groundwater due to overpumping caused more vertical movement of contaminant than lateral movement. If the overpumping continues in the industrial area, the groundwater flow system will be more affected and the groundwater will be lowered in the north part of basin. It is clear that contamination by C $l^{[-10]}$ and N $O_3$$^{[-10]}$ due to domestic sewage and factory wastewater will spread through the whole basin area.rea.

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Experimental Study on the Hydrodynamic Dispersion of Contaminants in Geologic Media : Adsorption and Diffusion of Sr and Cr-EDTA in Granitic Rocks (수리지질계에서 지질매체에 따른 오염물질의 수리분산에 관한 실험적 연구 : 화강암질암에서 Sr과 Cr-EDTA의 흡착 및 확산에 관한 연구)

  • Chang, Ho-Wan;Lee, Kwang-Sik
    • Journal of the Korean Society of Groundwater Environment
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    • v.1 no.2
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    • pp.105-112
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    • 1994
  • To investigate the migration behavior of contaminants in rocks. adsorption and diffusion experiments for Sr as a sorbing contaminant and for Cr-EDTA as a non-sorbing contaminant were carried out on granitic rocks. The Sr adsorption on separated minerals and crushed rocks tends to slightly increase with increasing pH. It also greatly decreases with the increase of ionic strength in NaCl solution. Among separated minerals, biotite and sericite have adsorbed much more amount of Sr than other rock-forming minerals, such as quartz, plagioclase, and potassic feldspar, because the specific surfaces and cation exchange capacities of phyllosilicates are generally much greater than those of the other rock-forming minerals. The intrinsic diffusion coefficients of Cr-EBTA for granitic rocks differ little from those of Sr. This indicates that they are independent of water-rock interactions. Experimental data show that the intrinsic diffusion coefficients are positively correlated with the porosities of the rocks. They are close to the theoretically predicted values, especially in pre-steady state diffusion region, with the increase of rock sample thickness.

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Estimation of Cadmium, Copper, Lead Mobility in Column Packed with Furnace Slag (제강슬래그로 충전된 컬럼에서의 카드뮴, 구리, 납의 이동성 평가)

  • Lee, Gwang-Hun;Chung, Jae-Shik;Nam, Kyoung-Phile;Park, Jun-Boum
    • Journal of Soil and Groundwater Environment
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    • v.13 no.4
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    • pp.54-61
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    • 2008
  • Permeable reactive barriers (PRBs) technology has been focused in contaminated groundwater remediation. It is necessary to select adequate reactive material according to characteristics of contaminant in groundwater. In this research, the reaction between reactive material and heavy metal contaminants was estimated through column test. Reactive material was slag, which has been produced in Gwangyang power plant, and heavy metal contaminants were cadmium, lead and copper. Column test was performed in the condition of 1) single and multi contaminated solution and 2) different initial concentration of cadmium. Retardation factor of cadmium is 3.94 in multi contamination. But that of copper is 40.3 in single and 25 in multi. The difference of retardation between cadmium and copper is due to affinity, resulted from the difference of electronegativity. In multi-contamination, copper effluent concentration was above initial copper concentration and at the same time lead effluent concentration was decreased. This phenomenon was considered that lead extract copper sorbed in slag and then lead was sorbed to the vacant sorption site instead. And as the initial concentration was increased, the retardation factor of cadmium became decreased.

Diffusion Characteristics of Heavy Metal Pollution depend on Distance from Abandoned Mines (폐광산으로부터의 이격거리에 따른 중금속오염 확산특성)

  • Kang, Mee-A;Park, Ji-Min;Kim, Kwang-Tae
    • The Journal of Engineering Geology
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    • v.18 no.3
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    • pp.257-262
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    • 2008
  • In the study it was investigated the diffusion characteristics of heavy metal pollutions such as Cu, Pb, Hg and As which was the main pollution sources of soils from abandoned mines. The pollution of Cu and Pb was caused by Mine A, that of Hg was caused by Mine 3, that of Pb was caused by Mine C and that of Cu, Pb, As was caused by Mine D. Though the high concentration was detected within 100m from abandoned mines, the low concentration was detected over than 100m from abandoned mines in all heavy metals investigated except As. It means that it was very difficult to estimate the pollution level of As caused abandoned mines. The results were discussed in the concentrations of Cu, Pb and distances showed a good relationship with 0.71 and 0.68 as the coefficient of correlation, respectively. In particular the relativity of Cu to Pb as very strong with 0.84 as the coefficient of correlation. It was consistent with the chemical behavior in soils in the case of Cu and Pb. Therefore it will be a promising approach to remove Cu and Pb with estimated values in the study.

Dispersion of Maritime Air Pollutants from Harbor Area into Major Port Cities Considering Characteristics of Local Wind Circulation in Korea -A Case Study of Sea and Land Breezes during Summer- (지역 순환풍 발생 특성 이해를 통한 국내 주요항만 발생 대기오염물질의 항구도시 영향 범위 분석 -여름철 해륙풍 모사를 중심으로-)

  • Kwon, Yongbum;Cho, Inhee
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.6
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    • pp.721-730
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    • 2021
  • Maritime air pollutants around port cities have gained a great deal of attention due to their direct impacts on regional air quality. This study aims to determine the geographical properties of sea/land breezes in different areas to discover overall ranges of maritime emission dispersion. The HOTMAC-RAPTAD modeling program was used to simulate regional-scale air dispersion considering non-linear and unsteady states during the general summer period for the target areas of the Yellow Sea (Incheon Port and Pyeongtaek·Dangjin Ports), archipelago region (Mokpo Port), South and East Sea (Busan and Masan Ports) and East Sea with mountainous area (Donghae·Mukho Ports). The resulting dispersion lengths of vessel emissions into the onshore regions around the target ports shed light on portal air quality management, because vessel emissions from the Incheon, Mokpo, Busan, and Donghae·Mukho ports were transported 27-31km (Western Seoul), 21-24km (Southern Muan), 20-26km (Gimhae and Yangsan), and 22-25km (Taebeak Mountains), respectively. Therefore, the results of this study provide useful data for regional air quality management and marine air pollution mitigation to improve the sustainability of port cities.

Comparative Study for Pollutant Transport and Diffusion Model (오염물 이송 및 확산 거동 해석모형의 특성비교연구)

  • Jung, Sung-Tae;Lyu, Si-Wan;Kim, Young-Do;Seo, Il-Won
    • Proceedings of the Korea Water Resources Association Conference
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    • 2007.05a
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    • pp.1407-1411
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    • 2007
  • 현재까지 우리나라에서 주로 사용되고 있는 2차원 흐름 해석모형은 미연방 도로국(U.S. Federal Highway Administration)과 연계하여 Brigham Young University에서 개발된 SMS(Surface-Water Modeling System) 모형이다. SMS모형 중 이송 확산 모형으로는 RMA-4가 포함되나 이 모형은 최신 수치기법을 반영하지 못하는 등의 문제점들로 인해 실제 물리적 현상 모의에 있어서 한계를 가지고 있다. 따라서 물리적 현상에 대한 적절한 모의를 위한 개선과정을 통하여 RAM4가 개발되었다. 본 연구에서는 현장실측 자료를 바탕으로 RMA-4와의 모의결과 비교를 통하여 오염 확산 해석모형인 RAM4의 적용성을 검증하고자 하였다. RAM4와 RMA-4 모의에 있어서 격자구성과 경계조건은 동일하게 설정하였으며, 유량조건은 평수량과 갈수량으로 선정하였다. 각각의 유량시 수위조건이 틀려지므로 각 유량조건에 대한 격자구성을 달리하였다. 모의구간은 낙동강 본류의 수산대교에서 삼랑진 철교까지의 약 13km 구간을 대상으로 하였다. 모의 구간내에는 밀양-하남 하수처리장이 상류 좌안측에 위치하고 있고, 만곡, 단면의 축소 및 확대, 하중도, 합류 등의 지형학적 특징들이 비교적 짧은 구간에 나타나고 있어 모형의 검증에 적합하다고 판단된다.

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A Study on Fine Dust Modeling for Air Quality Prediction (미세먼지 확산 모델링을 이용한 대기질 예측 시스템에 대한 연구)

  • Yoo, Ji-Hyun
    • Journal of IKEEE
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    • v.24 no.4
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    • pp.1136-1140
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    • 2020
  • As air pollution caused by fine dust becomes serious, interest in the spread of fine dust and prediction of air quality is increasing. The causes of fine dust are very diverse, and some fine dust naturally occurs through forest fires and yellow dust, but most of them are known to be caused by air pollutants from burning fossil fuels such as petroleum and coal or from automobile exhaust gas. In this paper, the CALPUFF model recommended by the US EPA is used, and CALPUFF diffusion modeling is performed by generating a wind field through the CALMET model as a meteorological preprocessing program that generates a three-dimensional wind field, which is a meteorological element required by CALPUFF. Through this, we propose a fine dust diffusion modeling and air quality prediction system that reflects complex topography.