• Title/Summary/Keyword: 확산농도

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Uncertainty Analysis of the Net Flow Discharge and Diffusion Model in Gyeonggi Bay and Han River Estuary (경기만 및 한강하구의 순유량 및 확산모형의 불확실성 분석)

  • Kim, Jeong-Dae;Jeong, Shin-Taek;Cho, Hong-Yeon;Kim, Tae-Heon
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.22 no.5
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    • pp.344-351
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    • 2010
  • Uncertainty analysis on the net flow discharge (NFD) influencing the long-term material transport and the simulation results of the salinity and COD concentration distribution using the MIKE21 diffusion model in Gyeonggi bay and Han-River estuary is carried out. The NFD flowing the Gyodongdo - Seokmodo channel via the North channel of Ganghwado is estimated about 97% of the total NFD and the NFD of the Yeomha channel is estimated as only $2.5{\sim}3.0%$. On the other hand, the uncertainty defined as the difference by the different time-scale data input is analysed by the comparison of the model simulation result of the salinity and COD concentration distribution. One is computed based on the daily river flow data, and the other is computed based on the monthlymean river flow data. The results show that the salinity and COD concentration differences are about -10~20 psu and ${\pm}1.0\;mg/L$ during the summer season having a high flow discharge in Yeomha channel, respectively. The difference is clearly negligible in the open sea area.

Evaluation of Fine Dust Diffusion and Contamination Degree : Focused on the Operation Status of Donghae Port (항만 인근 미세먼지 노출 영향권 및 오염도 분석 :동해항 운영현황을 중심으로)

  • Hwang, Je-Ho;Kim, Si-Hyun;Kang, Dal-Won
    • Journal of Navigation and Port Research
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    • v.46 no.3
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    • pp.251-258
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    • 2022
  • Donghae Port is adjacently located to a residential area wherein 26,933 generations are creating a living environment. The areas comprise Song-jeong village (5,754 generations) and Bukp-yeong village (21,179 generations). Major cargoes handled in Donghae Port are dusty limestone, cement, anthracite, and bituminous coal, etc. In the process of handling such cargoes, air pollutants including oxide dust and fine dust which adversely impact the living conditions and health of residents are generated, causing air pollution in the vicinity of the port. Currently, Donghae Port is making an effort to improve the operation environment of the infrastructure and equipment in stages, for the purpose of reducing air pollutant emissions caused by the port industries in a long-term perspective. In this study, the sphere of influence of fine dust exposure and the degree of air pollution in the surrounding area were analyzed such as the state of fine dust concentration and diffusion in the vicinity of Donghae Port, fine dust diffusion pattern and spatial distribution of high-concentration considering wind direction and speed characteristics during the day and seasonal cycles. A more effective plan to reduce the concentration of fine dust in nearby areas by combining reduction plan, is being developed in terms of improvement regarding port infrastructure and equipment, and reduction measures considering the characteristics of the atmosphere environment according to the daytime, nighttime and season.

Analysis of Description of Diffusion Phenomena in the 7th Grade Textbook and Diagnosis of Science Teachers' Understanding of the Diffusion Concepts (7학년 교과서의 확산현상 기술에 대한 분석과 과학교사들의 확산개념에 대한 이해도 조사)

  • Koo, Sun-Ah;Chae, Hee-K.
    • Journal of The Korean Association For Science Education
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    • v.28 no.5
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    • pp.383-394
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    • 2008
  • We analyzed the description of diffusion phenomena in a 7th-grade textbook, and investigated teachers' understanding and teaching methods on diffusion concepts. The data were collected from textbook analysis and questionnaires from 46 science teachers and interviews with 5 teachers. Based on texts' analysis by definition, example, and representation of the diffusion, we found that most of the representations were macroscopically explained by observing the movement of ink in water and smelling the fragrance of perfume in the air. The analysis of questionnaire and interviews also revealed that the definition and the explanation of the diffusion were too abstract for teachers to understand and teach the concept without further information about the microscopic concept of collision of the matter with the medium. Such examples and models lead science teachers to form indistinctive concepts such as dissolution, effusion, and evaporation. Furthermore, the analytical data showed that teachers' understanding of the diffusion concept has been heavily dependent upon the textbook and the level of the understanding was very similar with that of textual description.

Recovery of Nitric Acid from Waste Solder Stripper by Diffusion Dialysis (폐솔더 박리액으로부터 확산투석법에 의한 질산의 회수)

  • Ryu, Seong-Hyung;Kim, Tae-Young;Ahn, Nak-Kyoon;Gang, Myeong-Sik;Ahn, Jae-Woo;Ahn, Jong-Gwan
    • Resources Recycling
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    • v.24 no.5
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    • pp.33-39
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    • 2015
  • A basic study was conducted to effectively recover nitric acid from a waste solder stripper by diffusion dialysis using anion exchange membranes. The effects of flow rate, flux ratio, nitrate concentration, and metallic ion types and concentration on the recovery percentage of nitric acid were investigated. The recovery percentage of nitric acid was decreased with the increase of flow velocity. But the recovery percentage of nitric acid was increased as the increase of flux ratio(W/F) and showing a recovery percentage of nitric acid of about 99% at a flux ratio of 1.5 or more. As the increase of nitric acid concentration in feed solution, the recovery percentage of nitric acid was increased up to 3.0M, but in case of greater than 3.0M, the recovery percentage gradually was decreased. Leakage percentage of metallic ions through the membrane were in the order of Pb, Na and Cu but Fe and Sn did not leakaged. As a result of diffusion dialysis using real waste solder stripper at a flow rate of $0.9L/hr-m^2$, W/F = 1.3, a recovery percentage of nitric acid of approximately 94% was gained.

Evaluation of a Diffusive Sampler for the Measurement of Formaldehyde using Colorimetric Method (흡광광도법을 이용한 포름알데히드 확산측정기의 평가)

  • Yim, Bong-Been;Kim, Sun-Kyu;Jung, Eui-Suk;Kim, Sun-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.6
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    • pp.606-613
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    • 2005
  • The badge-type diffusive sampler for the measurement of formaldehyde in indoor air using three types of colorimetric methods such as chromotrophic acid(CTA), 3-methyl-2-benzothiazolinone hydrazone(MBTH), and 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole(AHMT) method. The washing of the collection filter with several cleaning solution was effected with satisfactory results, regardless of the types of cleaning solutions. The concentrations of absorbance solution in each colorimetric method were experimentally determined by considering the sampling rates. The variation blank values in each colorimetric method was below 15%. As compared with CTA and AHMT methods, the reproducibility of MBTH method was excellent and was below 10% relative standard deviation. The collected formaldehyde mass and time-weighted concentration had a good correlation (correlation coefficient > 0.93). The limit of detection and limit of quantitation, and minimum sampling time were closely correlated to the sampling rates for the measurement of formaldehyde in each method.

Numerical Analysis for Impurity Effects on Diffusive-convection Flow Fields by Physical Vapor Transport under Terrestrial and Microgravity Conditions: Applications to Mercurous Chloride (지상 및 미소중력 환경에서 물리적 승화법 공정에 미치는 불순물의 영향 분석: 염화제일수은에 대한 응용성)

  • Kim, Geug Tae;Kwon, Moo Hyun
    • Applied Chemistry for Engineering
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    • v.27 no.3
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    • pp.335-341
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    • 2016
  • In this study, impurity effects on diffusive-convection flow fields by physical vapor transport under terrestrial and microgravity conditions were numerically analyzed for the mixture of $Hg_2Cl_2-I_2$ system. The numerical analysis provides the essence of diffusive-convection flow as well as heat and mass transfer in the vapor phase during the physical vapor transport through velocity vector flow fields, streamlines, temperature, and concentration profiles. The total molar fluxes at the crystal regions were found to be much more sensitive to both the gravitational acceleration and the partial pressure of component $I_2$ as an impurity. Our results showed that the solutal effect tended to stabilize the diffusive-convection flow with increasing the partial pressure of component $I_2$. Under microgravity conditions below $10^{-3}g_0$, the flow fields showed a one-dimensional parabolic flow structure indicating a diffusion-dominant mode. In other words, at the gravitational levels less than $10^{-3}g_0$, the effects of convection would be negligible.

Numerical Study on Soot Formation in Opposed-flow Nonpremixed Flame by Mixing Toluene (톨루엔 혼합에 따른 대향류 확산화염 내 매연 생성에 대한 수치적 연구)

  • Choi, Jae-Hyuk;Yoon, Seok-Hun;Yoon, Doo-Ho
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.2
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    • pp.139-144
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    • 2012
  • A numerical simulation has been performed to investigate effects of toluene mixing on soot formation in pure ethylene opposed-flow nonpremixed flame. Mixture ratios of toluene were 3%, 5%, 10%, and 20%. Senkin code for 0-D simulation and oppdif code for 1-D simulation based on CHEMKIN III were utilized. 0-D results by senkin showed that concentrations of methyl radicals and benzene were increased with increasing toluene mixture ratio. This implied that the mixing of toluene in pure ethylene diffusion flame produces more PAHs and soot than those of pure ethylene flame. 1-D result of 10 % toluene reaction by oppdif code showed that production rate for H radical was a crucial factor for benzene formation. These results imply that methyl radical, benzene and H radical play a important role on soot formation in diffusion flames.

Estimation of Service Life for Expressway Bridge Subjected to Chloride Ingress from De-icer (동절기 제설제 사용에 대한 고속도로 교량의 내구수명 평가)

  • Lee, Honam;Jeon, Chanki;Kim, Juho;Shim, Jaeyeong;Jeon, Inkyu
    • Journal of the Society of Disaster Information
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    • v.11 no.4
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    • pp.548-555
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    • 2015
  • This paper aims to estimate the service life of the target bridge structures subjected to chloride ingress from de-icer, which is used for safety of vehicles in winter, by investigating the chloride ingress into concrete. In this study, the 10-year-old bridge structures were investigated by measuring the chloride along the depth from the exposed surface to derive the surface chloride concentration and the diffusion coefficient for the prediction of service life. The service life of each measured point on the structures were estimated with the surface chloride concentration and the diffusion coefficient by using Life-365 software. As a result, it was estimated for all measured points to have over 100-year service life. Furthermore, the diffusion coefficient and the service life from the measured data were compared to another method calculated with the concrete mix, considering the time dependency of diffusion coefficient.

Fuelcell GDL used in the high conductance of the carbon fiber surface treatment (연료전지 기체확산층용 고전도성 탄소섬유 표면처리 연구)

  • Baek, Sunghwan;Kim, Taejin;Kim, Jingu;Lee, Yohan
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.131.1-131.1
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    • 2010
  • 고분자연료전지(PEMFC)에서 기체확산층(GDL)은 다공성의 카본 종이/천 위에 마이크로한 다공층을 가치는 구조로 촉매층을 지지하고 촉매층과 분리판 사이의 전류전도체 역할을 한다. 또한 촉매층에 연료와 공기 확산 및 생성된 물의 통로 역할을 하며 소수성인 전기전도성 물질로 이루어져 있다. 현재 연료전지에 쓰이는 가스확산층은 대부분 국외 회사에서 제조 수입 사용하는 현황이고 국내에서는 협진 I&C가 연구하고 있으나 상용화는 아직 이루어지지 않고 있다. 본 연구는 탄소섬유의 전도성을 개선하고자 탄소섬유 표면에 금속코팅 시 최적의 접촉계면유지를 위한 표면처리 방법 및 공정을 조사 분석 후 최적 개선방법(농도/온도/압력/시간)을 설정하고자 하였다. 또한 선정된 공정인자별 수준별 시험 후 샘플링 된 시료를 토대로 금속물질이 탄소섬유 표면에 코팅(도금)된 금속-탄소섬유를 대하여 평가하여 최적화시키고자 탄소섬유로부터 carbon paper GDL의 모재를 개발할 계획이다. 앞에서 설명한 바와 같이 탄소섬유를 이용하여 paper making, resin impregnation, molding, carbonization/graphitization의 제조공정을 거쳐 paper형태의 GDL을 생산 및 평가하고자 하였다.

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The Solution of Upward Salt Diffusion in Floodeol Soil using Laplace Transformation (침수상태(湛水狀態)에서 토양(土壤) 염분(鹽分) 확산(擴散) 상승(上昇) 해석(解析)에 Laplace변환 이용)

  • Oh, Yong-Taeg;van der Molen, W.H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.28 no.3
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    • pp.233-240
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    • 1995
  • Fick's diffusion equation was transformed into algebraic subsidiary equation with its initial and boundary conditions through Laplace transformation, and the subsidiary equation was transformed back on the basis of Burington's table of inverse transformations so that it became the solution of Fick's equation. The initial and boundary condition was for upward diffusion of salts into flooding water of constant depth from uniform polder soil of infinite depth containing constant concentration of salt. The derived solution was tested through comparison for its conformability with other solutions of simpler initial and boundary conditions. The importance of shallow transplanting of rice seedlings and salt removing by growing rice was mentioned on the basis of very slow desalting rate by diffusion calculated from the derived solutions.

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