• Journal of the Korean Electrochemical Society
• /
• v.2 no.2
• /
• pp.93-97
• /
• 1999

From the anodic peak currents of cyclic voltammograms for Ag(I)/Ag(II) couple obtained with the variation of nitric acid concentration, Ag(I) concentration and solution temperature at a Pt electrode in concentrated nitric acid solutions, the diffusion coefficients of Ag(I) ion were evaluated to estimate the limiting current density of Ag(II)-mediated electrochemical oxidation (MEO) process, which has been effectively used for the complete destruction of hazardous organic materials. The results showed that, due to the water decomposition reaction which occurred simultaneously with the Ag(I) ion oxidation, background subtractions for the cyclic voltammograms were required to estimate the correct peak currents. The empirical relationship for the diffusion coefficient of Ag(I) was suggested as a function of solution viscosity and temperature.

• Journal of the Korean Chemical Society
• /
• v.60 no.2
• /
• pp.107-110
• /
• 2016

A new series of hydrazino thiazolyl-2-azetidinone 4(a-i) derivatives were synthesized efficiently using benzylidene hydrazinyl thiazole derivatives 3(a-i). The precursors, benzylidene hydrazinyl thiazoles were prepared by reacting 4-fluoro phenacyl bromide with thiosemicarbazones 2(a-i). All the structures of the synthesized compounds were ascertained by IR, NMR and mass spectral analysis.

• Journal of the Korean Chemical Society
• /
• v.56 no.1
• /
• pp.137-143
• /
• 2012

This study analyzed the questions posted on the chemistry Q&A board by students and teachers in a chemistry education homepage, in order to understand the difficulties in learning and teaching chemistry. The different tendencies were found in the contents and the motivations of questions by students and teachers. In Chemistry I, students raised many questions in the 'Water' unit, while teachers raised many ones in the 'Chemical compound in our life' unit. In Chemistry II, students asked many questions in the 'Gas, liquid, solid' unit, while teachers did in 'Chemical reaction and energy' unit. Students' motivations of questioning were 'Explanation of unclear concept', and 'Problem solving', while teachers' motivations were 'Searching information', and 'Question in experiment'. The Q&A board provided a field in exchanging informations needed in learning and teaching chemistry. Educational implications were discussed on the use of Q&A board in chemistry education.

• Journal of the Korean Chemical Society
• /
• v.62 no.3
• /
• pp.214-225
• /
• 2018

In this study, we tried to find out how heat and thermal energy terms are defined and used in Korean science textbooks, and to see if there are any differences in the meaning of these terms used in different areas of science. For this purpose, the contents of 52 science textbooks of elementary, middle and high school published by the 2009 revised curriculum were analyzed. The definition of the term heat is given in the middle school Science(1) and the high school Physics I and II textbooks. Most textbooks define heat as "energy transferred due to a temperature difference (Type I)". Only one textbook of Physics I defines heat as "transfer of energy due to a temperature difference (Type II)". The definition of thermal energy is mostly presented in the middle school Science (2) and the high school Physics I textbooks. Physics I textbooks define the thermal energy as "molecular kinetic energy (Type III)", while Science(2) textbooks define it as Type I or "energy causes temperature change or phase transition of matter (Type IV)". In the texts of textbooks, heat is mainly used as the meaning of Type I or Type III. Thermal energy is mainly used as Type III, but it is also used as Type I in the high school Physics and Chemistry textbooks. The meanings of heat and thermal energy terms used are differed by the area of science. They are mainly used as type I or type III in Physics and Chemistry textbooks, and used as type III in Life Science and Earth Science textbooks.

• Journal of the Korean Chemical Society
• /
• v.54 no.4
• /
• pp.465-470
• /
• 2010

Using interesting video clips corresponding to lesson subjects for students who favour visual representation is one of the good methods to enhance students' preference for science class. There are many moving picture web sites to get video clips easily via internet and 'YouTube' is very popular and one of the largest reservoir. In this study, every student in the 'Chemistry I' class, which is a class for 11th grade, was requested to search a video clip corresponding to lesson subjects and to make a presentation in the class. After 1st semester, students' response about the class using YouTube was examined by survey. As a result, students preferred and were interested in the class using YouTube than class centered on textbook. And students preferred YouTube clips showing unusual experiments that were related with contents of subject. In addition, experiments and watching their real phenomena were an interesting factor and helpful factor of learning chemistry in YouTube video clips, respectively. However, translation of English used in the video clips seemed to be a difficult part for students.

• Journal of Life Science
• /
• v.9 no.2
• /
• pp.207-211
• /
• 1999

Biologically active compounds in Polygonatum sibiricum were extracted using organic solvents as hexane, CHCl$_3$, n-butanol corresponding each component. Compound I was purified from hexane layer and the chemical structure of compound I was characterized using 1H-NMR, 13C-NMR, DEPT135, COSY, HMQC, HMBC spectrum and MS-spectrum. Consequently, the chemical structure of compound I was determined as 9,12-(9E,l2E)-octade cadienoic acid.

• Journal of the Korean Chemical Society
• /
• v.36 no.1
• /
• pp.107-112
• /
• 1992

Electron injection from excited rose bengal into the conduction band of a thin film of $SnO_2$ semiconductor in acetonitrile was investigated in an electrochemical cell, ITO/$SnO_2$/rose bengal, NaI or $I_2$, $NaClO_4$/Pt. It was observed that NaI enhanced the supersensitized photocurrent, followed by the slow reduction, whereas $I_2$ yielded a fast decaying photocurrent. Spectroscopic analyses of the dye solution containing NaI revealed that electron is transferred to the $SnO_2$ electrode from the reduced rose bengal and iodide is responsible for the reduction of the dye in triplet state. However $I_2$ appears to possess neither the reducing ability of the oxidized dye nor the retardation of the dehalogenation of RB.

• Journal of the Korean Chemical Society
• /
• v.14 no.3
• /
• pp.277-279
• /
• 1970

• Journal of the Korean Chemical Society
• /
• v.6 no.1
• /
• pp.61-63
• /
• 1962

The polarographic behaviors of Tl(I) was investigated in EDTA and NTA as supporting electrolytes for determination of Tl(I). A base solution containing 0.005 % gelatine, 0.1 M EDTA, and 0.05 M NTA was used. The halfwave potential of Tl(I) determined is -0.495 V v.s. S.C.E. in 0.1 M EDTA at pH 4.1 and -0.520V v.s. S.C.E. in 0.05 M NTA at pH 6.3. In this paper, the effects of gelatine concentration and pH values was investigated. The half-wave potentials of common elements was determined and compared with the half-wave potential of Tl(I).

• Journal of the Korean Chemical Society
• /
• v.55 no.6
• /
• pp.994-999
• /
• 2011

Some novel heterocyclic derivatives of 1,1-bis(2-phenyl-5-arylidine-1,3-thiadiazolidin-4-one)cyclopropane 4(a-i) have been synthesized from cyclopropane dicarboxylic acid and substituted thiadiazole moieties. All the synthesized compounds have been characterized by elemental and spectral (I.R., $^1H$-NMR, Mass) analysis. Furthermore, above said compounds were screened for their antifungal and antibacterial activities. Compound 4c was found the most potent one which further evaluated for lesser toxicity test.