• Title/Summary/Keyword: 화학I

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The Effect of Classes Using the Scratch for Quasi-Microscopic Representation Approaches in Dynamic Equilibrium Learning (동적 평형 학습에서 준미시적 표상 접근을 위한 스크래치 활용 수업의 효과)

  • Seongjae Lee;Sungki Kim;Seoung-Hey Paik
    • Journal of the Korean Chemical Society
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    • v.67 no.4
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    • pp.241-252
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    • 2023
  • This study aims to increase students' understanding of equilibrium, one of the many concepts in chemistry that students find difficult. Dynamic equilibrium must be dealt with at the sub-microscopic level where the real and the representation overlap in order to microscopically understand the constant motion and interaction of particles and to understand the macroscopic characteristics expressed through this. However, as a result of analyzing 9 Chemistry I textbooks, the expression approach for equilibrium had some limitations. As a strategy to understand equilibrium at a sub-microscopic approach, the classes using scratch were consisted of a total of 4 hours, and it was implemented with 56 students. The classes were composed of 6 steps, and it was designed to understand equilibrium step by step. As a result of comparing the pretest and post- test, the number of students who got both the microscopic and macroscopic explanations of chemical equilibrium correct increased largely. Through this, it was possible to get a glimpse of the applicability of classes using scratch as the approach strategy of the sub-microscopic representation.

Effect of Operation Temperature on the Durability of Membrane and Electrodes in PEM Water Electrolysis (PEM 수전해에서 막과 전극의 내구성에 미치는 구동 온도의 영향)

  • Donggeun Yoo;Seongmin Kim;Byungchan Hwang;Sohyeong Oh;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.19-25
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    • 2023
  • Although a lot of research and development has been conducted on the performance improvement of PEM (Proton Exchange Membrane) water electrolysis, the research on durability is still in early stage. This study investigated effect of temperature on the water electrolysis durability when driving temperature of the PEM water electrolysis was increased to improve performance. Voltage change, I-V, CV (Cyclic Voltammetry), LSV (Linear Sweep Voltammetry), Impedance, and FER (Fluoride Emission Rate) were measured while driving under a constant current condition in a temperature range of 50~80 ℃. As the operating temperature increased, the degradation rate increased. At 50~65 ℃, the degradation of the IrO2 electrocatalyst mainly affected the durability of the PEM water electrolysis cell. At 80 ℃, the polymer membrane and electrode degradation proceeded similarly, and the short resistance decreased to 1.0 kΩ·cm2 or less, and the performance decreased to about 1/3 of the initial stage after 144 hours of operation due to the shorting phenomenon.

Petrogenetic Study on the Foliated Granitoids in the Chonju and the Sunchang Area(I) -In the Light of Petrochemical Properties- (전주 및 순창지역에 분포하는 엽리상화강암류의 성인에 대한 연구(I) - 암석지화학적 특성을 중심으로 -)

  • Na, Choon-Ki;Lee, In-Sung;Chung, Jae-Il
    • Journal of the Korean earth science society
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    • v.18 no.6
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    • pp.480-492
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    • 1997
  • In order to understand the processes involved in the petrogenesis and the differentiation of the primary magma spectrum, a petrological and geochemical properties were investigated for the Chonju and the Sunchang foliated granites, which are located in the southwestern part of the Okchon zone and extends up to the northwestern boundary of the Ryongnam massif as two subparallel batholiths. Major element analyses show that the Chonju and Sunchang foliated granites are classified petrologically into a weakly to strongly peraluminous or calc-alkaline, but do not fit neatly into either of the I/S-type or magnetite/ilmenite-series classification schemes for granites, although the I-type and magnetite-series characteristics seem to be predominant based on the major element chemistry. In normative compositions, the Chonju granite is petrographically evolved from granodiorite to granite, whereas the Sunchang granite is from granodiorite to quartz monzodiorite. It seems to suggest a difference of the magmatic evolution processes such as crustal assimilation and/or fractional crystallization in magma. The REE patterns of both batholiths show high similarity and strongly fractionated REE distributions which show high $(Ce/Yb)_N$ ratios and little or no Eu anomalies. These REE patterns correspond broadly to those seen in the pre-Cretaceous granitoids of Korea. Apparently, the evidences obtained from the bulk compositions strongly suggest that the two foliated granitoids were formed by partial meltings of a relatively restricted and similar, may be common, source material which contains a continental crust component having an igneous composition, and have undergone a similar magmatic differentiation processes.

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An Evaluation on Electrochemical Polarization Characteristics and Material Degradation for Cr-Mo-V Steel (Cr-Mo-V강의 전기화학적 분극 특성과 재질열화 평가)

  • Kwon, Il-Hyun;Lee, Song-In;Ha, Jeong-Soo;Yu, Hyo-Sun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.3
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    • pp.267-274
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    • 2002
  • This research is described on the applicability of a electrochemical techniques for evaluating nondestructive material degradation with various polarization characteristics for Cr-Mo-V steel. The applied electrochemical technique is anodic polarization test which are widely used to evaluate the corrosion rate and/or sensitization at depleted zone of strengthening elements mainly caused by thermal experience for stainless steels. The evaluation of material degradation is performed by small punch test which has been well known as micromechanics test method using specimen size of $10{\times}10{\times}0.5mm$. The 1,000hrs aged material at $630^{\circ}C$ shows the highest material degradation$({\Delta}[DBTT]_{SP})$, but the 2,000hrs and 3,000hrs aged materials show the decrease of ${\Delta}[DBTT]_{SP}$ as aging time increases. It is observed that the difference of current density $({\Delta}I_{FP}\;and\;{\Delta}I_{SP})$.

Electrochemical properties of heat-treated multi-walled carbon nanotubes (열처리된 탄소나노튜브 상대전극의 전기화학적 특성 연구)

  • Lee, S.K.;Moon, J.H.;Hwang, S.H.;Kim, G.C.;Lee, D.Y.;Kim, D.H.;Jeon, M.H.
    • Journal of the Korean Vacuum Society
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    • v.17 no.1
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    • pp.67-72
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    • 2008
  • We have studied the effect of heat treatment of multi-walled carbon nanotubes (MWNTs) as a counter electrode on the electro-chemical properties of dye-snsitized solar cells. MWNTs on the p-type Si substrate were synthesized by thermal chemical vapor deposition (CVD) using Fe catalysts. We prepared the two types of MWNTs samples with the different diameters. The rapid thermal annealing (RTA) treatment for the MWNTs was carried out at the growth temperature ($900^{\circ}C$) for 1 minute with $N_2$ gas atmosphere. The structural, electrical and electrochemical properties of MWNTs were investigated by field-emission scanning electron microscopy (FE-SEM), Raman spectroscopy, 2-point probe station and electrochemical impedance spectroscopy (EIS). The I(D)/I(G) ratio of heat-treated MWNTs in Raman spectra was considerably decreased. It was also found that the heat-treated MWNTs showed better redox reaction of iodide at the interface between MWNTs surface and electrolyte than that of as-grown MWNTs. The redox resistance value of heat-treated electrodes was measured to be much lower than that of as-grown electrode at the interface. As a result, the counter electrode using the heat-treated MWNTs showed better electrochemical properties.

Analysis of the Inquiry Tendency of the Higher-level Middle School 1 Chemistry Textbooks of Kim Jong-Un Era in North Korea (북한 김정은 시대의 고급중학교 1 화학 교과서의 탐구 경향성 분석)

  • Park, HyunJu;Kwon, JiYoon
    • Journal of the Korean Chemical Society
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    • v.63 no.4
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    • pp.266-279
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    • 2019
  • The purpose of this study was to investigate the inquiry tendency of North Korean chemistry textbook by Romey's method. We analyzed the inquiry tendencies of texts, figures, questions, activities, and summaries by Romey's method. And the following results were compared with those of previous South Korean studies, which method was the same. The 20,017 texts, 541 figures, 140 questions, 243 activities, and 25 summaries in 5 chapters of chemistry textbook of the Higher-level middle school 1 in the Kim Jong-Un Era were analyzed. Results were as follows: texts were authoritarian tendency, figures were authoritarian tendency, questions were excessive inquiry tendency, activities were inquiry tendency, and chapter summaries were drastic authoritarian tendency. The inquiry tendency of North Korean chemistry textbook in higherlevel middle school showed similar tendencies as the textbooks of South Korean chemistry I textbook in the 6th National Science Curriculum. The results of this study are expected to be utilized as basic information and data to understand the inquiry teaching that North Korea science education is aiming at.