• Title/Summary/Keyword: 화학 수축

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Residual Stresses Analysis due to Volumetric Changes in Long-term Autogenous Expansive Concrete (장기팽창성 콘크리트의 체적변화에 의한 잔류응력 해석)

  • Cha, Soo-Won;Jang, Bong-Seok;Oh, Byung-Hyun
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.22 no.6
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    • pp.617-625
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    • 2009
  • This study is devoted to the problems of thermal and autogenous expansion stresses in order to avoid cracking using chemically prestressing method. The chemical prestress can be induced by autogenous expansion characteristics of MgO concrete made in specific burning temperature. The volume change induced cracking has great influence on the long-term durability and serviceability. To evaluate risk of cracking, the computer programs for analysis of thermal and autogenous expansion stresses were developed. In these 3-D finite element procedures, long-term autogenous expansive deformation is modeled and its resultant stress is calculated and then verified by comparison with manual calculation results. In this study, the stress development is related to thermal and autogenous expansive deformation. Using the developed program, residual stresses of MgO concrete were compared and analysed in the example From the numerical results it is found that long-term, and temperature dependent expansive concrete with light-burnt MgO is most effective in controlling the risk of cracking of mass concrete because it has high temperature for long period. The developed analysis program can be efficiently utilized as a useful tool to evaluate the thermal and autogenous expansion stresses in mass concrete structures with lightly burnt MgO.

Effect of Some Essential Oils on Motility of Isolated Rabbit Jejunum Segment (몇가지 정유가 토끼의 적출장관 운동에 미치는 영향)

  • Hong, Chang Ho;Park, Joon Hyoung
    • Current Research on Agriculture and Life Sciences
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    • v.5
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    • pp.173-184
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    • 1987
  • Anethole, eugenol, isoeugenol, safrole and isosafrole are ingredients of refined oils which are obtained from some plants and their chemical structures are very similar. They are mainly used as a flavoring agent, food additive, dental analgesics and for many drugs. But, there is no report about their effect on the intestinal motility. The result of examining the effect, potency and mode of action of anethole, eugenol, isoeugenol, safrole and isosafrole on motility of isolated rabbit jejunum segment, are as follows : 1. Single administration of anethole, eugenol, isoeugenol, safrole and isosafrole showed the inhibition of motility of isolated rabbit jejunum segment, degree of which was various. The $pD_2$ values of isoeugenol, isosafrole, eugenol, safrole and anethole in isolated rabbit jejunum segment were 4.22, 4.18, 4.17, 4.15 and 3.82 (in the descending order of potency). 2. The contracted rabbit jejunum segment : by carbachol, pilocarpine, barium chloride and histarmine were relaxed by five essential oil. 3. The relaxed rabbit jejunum segment by anethole was not recovered by carbachol, pilocarpine, barium chloride and histamine. The relaxed rabbit jejunum segment by eugenol, isoeugenol, safrole and isosafrole were recovered by carbachol, pilocarpine and barium chloride but partially recovered by histamine. 4. Judging from the facts above, it is thought that five essential oil are inhibit the motility of isolated rabbit jejunum segment by neurotropic and musculotropic action.

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Production and evaluation of raw materials for porcelain using clay mineral (점토 광물을 이용한 도자기용 소지 제조 및 물성 평가)

  • Kim, Jong-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.317-328
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    • 2019
  • In this work, we investigated clay and raw materials from China (black clay, red clay, white clay) and Korea (Cheonan clay, Obu clay) used for the manufacture of porcelain products. According to chemical analysis results, feldspar components containing CaO, K2O, Na2O and quartz are found in clay materials besides primary clay such as kaollinte, for the clay materials from Korea, which is found more in clay materials from Korea than from China. For the Fe2O3 content, governing whiteness of porcelain products, more iron oxide (> 5 %) is found in Korean clays (Cheonan clay, obu clay, red clay) compared to those form China (black, white clay). Through X-ray diffraction analysis, kaolinite and Halloysite are found to be main phases for all the raw materials and second phases such as quartz and pyrophyllite are found. Using these clay materials, raw materials for porcelain products were produced, and the physicochemical properties were investigated for sintered samples. Absorption rate is in order of Baekja-A < Baekja-B < Yeonbuncheong < Jinbuncheong < Cheongja, and the sample, sintered at 1250℃ in reductive atmosphere, exhibits the lowest absorption rate. Comparing the color of the sintered samples, the samples sintered in oxidative atmosphere (L* value: 86~95 %) show higher whiteness value than those sintered in reductive atmosphere (L* value: 81~93 %). For the Cheongja and Buncheong, the samples sintered in reductive atmosphre shows higher whiteness, L* values, and low a*/b* value, which is due to reduction of iron oxide (Fe2O3).

Effects of the Addition of Vegetables on Oxidized Frying oil (항산화 채소류 첨가가 가열 산패된 유지에 미치는 영향)

  • 김업식;최은미;구성자
    • Korean journal of food and cookery science
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    • v.18 no.6
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    • pp.557-561
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    • 2002
  • The changes in some chemical and physical properties of fresh or rancid soybean oil by the treatment with sweet potato, potato, burdock, and carrot were investigated. The results of the study were as follows: The specific gravity of the soybean oil increased by heating and decreased by the addition of sweet potato, burdock and carrot into the oil. The chromaticity of soybean oil increased by heating and treatment with above vegetables having antioxidant activity. To investigate the antioxidant effects of above vegetables during heating, anisidine value (AV) and DPPH (1,1-diphenyl-2-picrylhydrazyl) electron donating ability were measured. The AV of oil decreased by heating with sweet potato in fresh or rancid oil. The DPPH value decreased by heating with sweet potato and carrot, of which the antioxidant activity were similar to that of 0.02 ∼ 0.05 mg of dl-${\alpha}$ -tocopherol.

Study on the Thickness Effect of the Separator for Lithium Secondary Batteries (리튬이차전지용 분리막의 두께에 따른 특성 연구)

  • Kim, Sang Woo;Seok, Ji-Hoo;Kim, Byung-Hyun Daniel;Cho, Hee-Min;Cho, Kuk Young
    • Journal of the Korean Electrochemical Society
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    • v.17 no.1
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    • pp.7-12
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    • 2014
  • There is increasing demand on the reducing the weight and the volume of the major components in lithium secondary battery to improve energy density. Separator not only provides pathway for lithium ion movement but also prevents direct contact between anode and cathode. Herein we fabricated polyethylene separator by varying biaxial stretching ratio to obtain membrane thickness of 16, 12, and $9{\mu}m$. Mechanical and thermal properties of the separator with different thickness were investigated. Also rate capability and charge-discharge cycle property up to 500 cycles were studied using coin type full-cell with $LiCoO_2$ and graphite as a cathode and an anode, respectively. All the cells using separator with different thickness demonstrated excellent capacity retention after 500cycles (around 80%). Considering the rate capability, cell using separator with thickness of $9{\mu}m$ showed best performance. Interestingly, separator thickness of $9{\mu}m$ was more resistant to heat contraction compared to that of $16{\mu}m$ separator.

Interpretation of Material Homogenity and Making Techniques of the Jar Coffins from the Oryangdong Kiln Site and the Ungokdong Tomb Site in Naju, Korea (나주 오량동 가마와 운곡동 분묘 유적 출토 대형전용옹관의 재료학적 동질성과 제작기법 해석)

  • Kim, Ran-Hee;Cho, Mi-Soon;Yeon, Ung;Seo, Jeong-Seog;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.26 no.3
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    • pp.229-245
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    • 2010
  • The pupose of this study was to identify the material characteristics, firing environments and making techniques for the jar coffins from the Oryangdong kiln site and the Ungokdong tomb site in Naju. All jar coffins had very similar physical, mineralogical and geochemical characteristics, although it was excavated from the different sites. The wall thickness of the jar coffins was about 2.3 to 5.3 cm. Under the microscopy, the jar coffins include a large quantity of various quartz with some microcrystalline and showed partly orthoclase and biotite. It is presumed that the mineral sherds added to maintain the thick wall and to control the percentage of contraction during drying and firing of jar coffins and it has contained about 11.4 to 19.8 %. Firing temperature of the jar coffins is estimated as 1,000 to $1,150^{\circ}C$. Also, all jar coffins and soils show similar geochemical behavior of elements and clay-mineralization degree within the site. This indicates making that the soil is probable to be a raw material of the jar coffins. But it shows different characteristics in major elements of soils which is collected at the kiln floor and the trench region of the Oryangdong kiln site because of the lack of quartz and feldspar in the soils. Therefore, it can use of the jar coffins making clay, if it goes through a simple special process such as mixing temper.

The effect of chemicals and chilling treatments on the frequency of metaphase in root tips of some economic crops (화학약품과 저온처리가 작물근단세포의 Metaphase 출현빈도에 미치는 영향)

  • Mun-Hue Heu;Hye-Yong Kim
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.2
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    • pp.3-9
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    • 1964
  • Root tips of wheat, soybean, cotton and barley were treated with cold temperature (12 or 24 hrs in $0^{\circ}C$ or 2$^{\circ}C$), 8-Hyd.exyquinolin (2 or 10 hrs in 0.03 or 0.1%) and colcllicine (2 or 10 hrs in 0.2 or 1, 0%), and the frequency of metaphase were observed. The results were summarized as follow; 1. Chilling the seminal roots before or after sooting from the seed significantly increased tile number of mitotic cells and the rate of metaphase cells to mitotic cells. The optimal duration of chilling seemed to be differ depending on the kinds of plant and 24 hours to be too long except wheat so far examined here. 9. 8-Hydroxyquinolin treatment, about 2 hours in 0.03%, increased the rate of metaphase cells. The higher concentration and the longer treatment of this chemical caused the lower frequency of mitotic cells generally. 3. Colchicine treatment, 2 to 10 hrs in 0.2 to 1.0%, increased the frequency of mitotic cells and the rate of metaphase cells. Colchicine treatment was same or superior than any other treatments on the increase of metaphase cells. 4. All the treatments examined here caused chromosome contraction with most serious in colchicine following by 8-Hydroxyquinolin and chilling. 5. The feasibility of general application of chilling under the check of proper temperature and proper duration depending on the kinds of crops were discussed.

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Growth of Carbon Nanotube by Chemical Vapor Deposition (화학기상증착법에 의한 탄소 나노튜브의 성장)

  • 은광용;이광렬;백영준;이재갑;정민재;박종완
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2001.04a
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    • pp.34-34
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    • 2001
  • 열CVD법에 의하여 아세틸렌 가스를 탄소 원으로 사용한 탄소 나노튜브의 성장거동을 조사하였다. 닉켈 분말의 직경을 15nm 내지 90nm 범위로 조정하여 기판 에 촉매로 배열하였다. 탄소 나노튜브는 질소, 수소, 알곤, 암모니아 등 여러가지의 가스 분위기에서 증착되었으며 이들 가스의 혼합 분위기가 탄소나 노튜브의 성장에 미치는 영향을 조사하였다. 증착은 대기압 압력하에서 85$0^{\circ}C$ 의 온도에서 이루어졌다. 순수한 질소 분위기에서는 탄소 나노튜브의 성장이 이루어지지 않고 두꺼운 탄소 층이 기판 위에 중착되었다. 이 조건에서는 탄소로 뒤덮혀진 닉켈 입자가 탄소 나노튜브 형성의 촉매 역할을 담당하지 못했다. 그러나 질소와 수소의 혼합분위기에서는 수소의 농도가 증가함에 따라 탄소 나노튜브의 성장이 증진되었다. 순수한 수소 분위기에서는 일정한 방향이 없이 꼬여진 탄소 나노튜브가 성장되었다. 탄소 나노튜브의 성장은 분위기 가스로 암모니아를 사용하였을 때 훨씬 더 증진되었다. 수직으로 배열된 탄소 나노튜료를 암모니아 분위기에서는 성장시킬 수 있었으나 암모니아와 같은 비율의 수소와 질소 가스의 혼합 분위기 하에서 는 탄소 나노튜브의 성장을 얻을 수 없었다. 이러한 결과를 여기에서는 닉켈 촉매의 표면에 과도하게 석출된 탄소의 촉매 passivation으로 설명하였다. 탄소 나노튜브의 증착을 위해서는 아세틸렌 가스의 분해율이 너무 과도하지 않게 즉 촉매의 표면이 과도한 탄소의 증착으로 수동태화 되지않도록 조절되어야 한다는 것이다. 이 연구결과는 분위기 가스의 조성이 탄소 나노튜브의 성장에 있어서 그 반웅 kinetics에 큰 영향을 미친다는 것을 잘 보여주고 있다. 또한 암모니아 분위기에서는 촉매 닉켈입자 표면에 질화물층이 형성되어 탄소 나노튜브의 성장에 영향을 미쳤다는 것도 알 수 있었다.며 실제 가공업체에서도 터짐 문제가 발견되지 않았다. 결론적으로 표면층의 인장강도가 패션/구부림에 가장 중요한 변수로 작용하며 어떠 한 형태로 표면층의 인장강도를 향상시킬 경우 침엽수 펄프는 재생펄프로 대체가 가능 할 것으로 판단된다.하는 통계기법 중의 하나인 주성분회귀분석을 실시하였다. 주성분 분석은 여러 개의 반응변수에 대하여 얻어진 다변량 자료의 다차원적인 변 수들을 축소, 요약하는 차원의 단순화와 더불어 서로 상관되어있는 반응변수들 상호간 의 복잡한 구조를 분석하는 기법이다. 본 발표에서는 공정 자료를 활용하여 인공신경망 과 주성분분석을 통해 공정 트러블의 발생에 영향 하는 인자들을 보다 현실적으로 추 정하고, 그 대책을 모색함으로써 이를 최소화할 수 있는 방안을 소개하고자 한다.금 빛 용사 둥과 같은 표면처리를 할 경우임의 소재 표면에 도금 및 용 사에 용이한 재료를 오버레이용접시킨 후 표면처리를 함으로써 보다 고품질의 표면층을 얻기위한 시도가 이루어지고 있다. 따라서 국내, 외의 오버레이 용접기술의 적용현황 및 대표적인 적용사례, 오버레이 용접기술 및 용접재료의 개발현황 둥을 중심으로 살펴봄으로서 아직 국내에서는 널리 알려지지 않은 본 기 술의 활용을 넓이고자 한다. within minimum time from beginning of the shutdown.및 12.36%, $101{\sim}200$일의 경우 12.78% 및 12.44%, 201일 이상의 경우 13.17% 및 11.30%로 201일 이상의 유기의 경우에만 대조구와 삭제 구간에 유의적인(p<0.05) 차이를 나타내었다.는 담수(淡水)에서 10%o의 해수(海水)로 이주된지 14일(日) 이후에 신장(腎臟)에서 수축된 것으로 나타났다. 30%o의 해수(海水)에 적응(適應)된 틸라피아의 평균 신사구체(腎絲球體)의 면적은 담수(淡水)에

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Difference in Contents of Chemical Components in Radix of Paeonia lactiflora Pall. with Root Diameters (작약(芍藥)의 뿌리굵기에 따른 성분함량(成分含量) 차이(差異))

  • Kang, Kwang-Hee;Choung, Myoung-Gun
    • Korean Journal of Medicinal Crop Science
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    • v.2 no.2
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    • pp.149-153
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    • 1994
  • This experiment was conducted to know the relationship between root diameter and the contents of paeoniflorin and some Chemical components in Paeoniae radix. Paeoniae radix of Euisung cultivar was harvested on 17 June, 1993 and divided into four gorups according to root diameter such as $30{\pm}2mm,\;17{\pm}1mm,\;12{\pm}1mm\;and\;7{\pm}1mm$. Paeoniflorin, total sugars, starch, crude protein, crude fat and crude ash of them were analyzed after dryed them for 30 days in room temperature. The ratio of shrinkage with different root diameter were not different significantly, and the average ratio of them was about 30%. Contents of paeoniflorin of $17{\pm}1mm$ root diameter was lower than that of $7{\pm}1mm$. but contents of total sugar and starch of $17{\pm}1mm$ were higher than those of $7{\pm}1mm$. Paeoniflorin contents was positively correlated with crude protein and crude fiber, and crude protein contents was negatively correlated with total sugars and starch.

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The Experimental Study on The Compressive Strength of Concrete Using High Quality Recycled Fine Aggregate Produced by Sulphuric Water and Low Speed Wet Abrasional (황산수와 저속습식마쇄기로 생산된 고품질 순환 잔골재의 콘크리트 압축강도에 관한 실험적 연구)

  • Choi, Duck-Jin;Lee, Dae-Guen;Kim, Ha-Suk;Kawk, Eun-Gu;Kang, Chul;Kim, Jin-Man
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.385-388
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    • 2008
  • Recycled fine aggregate has low quality because it contains large amount of old mortar. So, its usage is limited to a lower value-add, such as the roadbed material etc. Also, alkaline water occurred from treatment process of the waste concrete is becoming the cause of environmental problem. Accordingly, this study is to develop on the high quality recycled fine aggregate produced by low speed wet abraser using sulphuric. We investigated the properties of compressive strength of the mortar which was manufactured using recycled fine aggregate containing calcined gypsum produced by earlier mentioned process. Test results indicate that concrete using recycled fine aggregate containing calcined gypsum is higher compressive strength than concrete using other sands.

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