• Journal of Environmental Science International
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• v.16 no.5
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• pp.571-581
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• 2007

The mechanism of water pollution in Lake Shihwa, one of highly eutrophicated artificial lakes in Korea, has been studied using a numerical 3D physical-biochemical coupled model. In this study, the model was applied to estimate the contribution of land-based pollutant load to water quality of heavily polluted Lake Shihwa. The chemical oxygen demand(COD) was adopted as an index of the lake water quality, and the spatial distribution of an average COD concentration during the summer from 1999 to 2000 was simulated by the model. The simulated COD showed a good agreement with the observed data. According to reproducibility of COD, the high-est levels between 8 and 9 mg/L were shown at the inner site of the lake with inflow of many rivers and ditches, while the lowest was found to be about 5 mg/L at the southwestern site near to dike gate. In the pre-diction of water quality of Lake Shihwa, COD showed still higher levels than 3 mg/L in case of reduction of 95% for land-based pollutant load. This suggests that the curtailment of land-based pollutant load is not only sufficient but the improvement of sediment quality or the increase of seawater exchange should be considered together to improve a water quality in Lake Shihwa.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.16 no.3
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• pp.291-299
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• 2018

Under a pyro-processing concept, an electrolytic reduction process has been developed to reduce uranium oxide in molten salt by electrochemical means as a part of spent fuel treatment process development. Accordingly, a model based on electrochemical theory is required to design a reactor for the electrolytic reduction process. In this study, a 1D model based on the phase-field theory, which explains phase separation behaviors was developed to simulate electrolytic reduction of uranium oxide. By adopting parameters for diffusion of oxygen elements in a pellet and electrochemical reaction rate at the surface of the pellet, the model described the behavior of inward reduction well and revealed that the current depends on the internal diffusion of the oxygen element. The model for the electrolytic reduction is expected to be used to determine the optimum conditions for large scale reactor design. It is also expected that the model will be applied to simulate the integration of pyro-processing.

• Journal of Life Science
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• v.16 no.1
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• pp.148-155
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• 2006

The diversity of bacterial populations in rivers flowing through Changwon City, was investigated using quinone profiling. The physicochemical properties such as temperature, pH, dissolved oxygen(DO), dissolved organic carbon (DOC) and biochemical oxygen demand (BOD) were also measured in this study. Ubiquinone (UQ)-8, UQ-9 and UQ-10 were observed in all samples for the sites investigated. UQ-8 was the -predominant quinone species in rivers except for Namch'on downstream, T'owolch'on, and Kaumchongch'on in autumn, while UQ-8 was also found as major quinones in the sample except for Hanamch'on, T'owolch'on, Kaumchongch'on, and Namsanch'on in winter. A higher concentration of DOC in rivers yield high concentration of plastoquinone (PQ-9) in autumn and those of total quinones in winter, respectively. Correlation analysis also indicate that BOD is considered to be a major factor controlling the concentration of PQ in rivers.

• Korean Journal of Environmental Biology
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• v.26 no.4
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• pp.279-291
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• 2008

The seasonal distribution pattern of the Bivalvia samples collected from 12 stations in Gamak Bay in April, July, September and November from 2001 to 2006. A total of 28 species (226.72$\pm$196.20 ind. m$^{-2}$) were identified. The COD has decreased from 3.30 mg L$^{-1}$ to 1.89 mg L$^{-1}$ level on average and especially, the COD of sediment has decreased from 21.51 mg g-dry$^{-1}$ to 16.99 mg g-dry$^{-1}$ level on average. Therefore, water quality level of Gamak Bay was improved from level 3 to 2. The dominant species over 1.0 percentages were composed of the total 13 species, and they occupied 96.75% of the total density of the Bivalvia. Major dominant species was Musculista senhousia 100.38 ind. m$^{-2}$ (22.16%), Moerella rutila 69.00 ind. m$^{-2}$ (15.23%), Theorafragilis 49.70 ind. m$^{-2}$ (10.97%), Mytilus edulis 42.18 ind. m$^{-2}$ (9.31 %), and Raphia undulata 40.99 ind. m$^{-2}$ (9.05%). This area could be divided into three groups by the cluster analysis based on the total species composition.

• Journal of Environmental Impact Assessment
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• v.22 no.6
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• pp.591-607
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• 2013

The objectives of the study were to evaluate the aquatic environment of an urban stream using various ecological parameters of biological biomarkers, physical habitat quality and chemical water quality and to develop a "Multimetric Eco-Model" ($M_m$-E Model) for the ecosystem evaluations. For the applications of the $M_m$-E model, three zones including the control zone ($C_Z$) of headwaters, transition zone ($T_Z$) of mid-stream and the impacted zone ($I_Z$) of downstream were designated and analyzed the seasonal variations of the model values. The biomarkers of DNA, based on the comet assay approach of single-cell gel electrophoresis (SCGE), were analyzed using the blood samples of Zacco platypus as a target species, and the parameters were used tail moment, tail DNA(%) and tail length (${\mu}m$) in the bioassay. The damages of DNA were evident in the impacted zone, but not in the control zone. The condition factor ($C_F$) as key indicators of the population evaluation indicator was analyzed along with the weight-length relation and individual abnormality. The four metrics of Qualitative Habitat Evaluation Index (QHEI) were added for the evaluations of physical habitat. In addition, the parameters of chemical water quality were used as eutrophic indicators of nitrogen (N) and phosphorus (P), chemical oxygen demand (COD) and conductivity. Overall, our results suggested that attributes of biomarkers and bioindicators in the impacted zone ($I_Z$) had sensitive response largely to the chemical stress (eutrophic indicators) and also partially to physical habitat quality, compared to the those in the control zone.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.6
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• pp.546-552
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• 2020

In this study, optimization research was conducted through statistical analysis with the aim of maximizing the efficiency of organic matter reduction and hydrogen production by applying electrolysis process at sewage treatment plant. Statistical analysis and optimal operating conditions of organic matter removal efficiency and H2 generation, which varied with various conditions in the electrolysis process, were derived using response surface methodology. As a result, 1,268 μS/cm of conductivity, 350 A current, and pH 3.2 was found to be the optimum condition to reach the desired value as 38% of organic matter reduction and 2.58 L/min of H2 production. The experiment also determined that the optimization study was reliable. Base on this study, it was confirmed that the removal of organic matter and hydrogen production could be stably by applying the electrolysis process in the sewage treatment plant.

• Korean Journal of Ecology and Environment
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• v.38 no.3 s.113
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• pp.361-371
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• 2005

The objective of study was to diagnose integrative ecological health of Daejeon Stream, one of the tributaries of Guem River, during May 2004 ${\sim}$ April 2005. The research approach was primarily based on a Qualitative Habitat Evaluation Index (QHEI) and the Index of Biological Integrity (IBI) using fish assemblage. These outcomes were compared with conventional chemical dataset. For the experiment, four sampling sites were chosen from Daejeon Stream and long-term water quality data during 1995 ${\sim}$ 2004 (obtained from the Ministry of Environment) were analyzed in the spatial and temporal aspects. For the biological health assessment, we developed a stream health assessment model (SHA model) far regional applications. We found that current water quality conditions, based on the COD, BOD, TN and TP, were enhanced by 1.6 ${\sim}$ 5.3 fold over the period of 1995 ${\sim}$ 2004 and that the parameters showed a typical longitudinal decline from the upstream to downstream reach. The differences of water quality between the two reaches were more than 4.4 times, indicating a large spatial variations within the stream. The health conditions, based on the SHA model, averaged 23 and varied from 20 to 26 depending on the sampling stations. Values of the QHEI varied from 39 (Poor condition) to 124 (Cood condition)and values of QHEI in the reach of S2 ${\sim}$ S4 had significantly lower than in the headwater site (S1). Also, biological stream health, based on the criteria of US EPA (1993), was judged as 'Poor condition', in the S4 where TN, TP, BOD and COD were highest. In the meantime, maximum value of SHA (26) was found in the upstream reach (S1) where the water quality and QHEI were best. We also found that compositions of sensitive species showed a linear function with water quality conditions and this pattern was evident in the tolerant species. Thus, the biological stream health, based on the SHA model, matched well water chemistry. Overall outcomes suggest that the biological health impact was a function of chemical degradation and physical habitat quality in the stream.

• Journal of Korean Society on Water Environment
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• v.26 no.3
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• pp.420-431
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• 2010

Simple material budget models were developed to predict the dry season water quality for a river-type reservoir in Paldang, Republic of Korea. Of specific interest were the total phosphorus (TP), chlorophyll ${\alpha}$ (Chl. ${\alpha}$), 5-day biochemical oxygen demand (BOD), and chemical oxygen demand (COD). The models fit quite well with field data collected for 20 years and have enabled the identification of the origins of organic materials in the reservoir. The critical hydraulic load that determines the usability of phosphorus for algal production appeared to be about $1.5m\;d^{-1}$. When a hydraulic load was smaller than the critical value, the concentrations of $Chl.{\alpha}$, COD, and BOD in the reservoir water became sensitive to internal algal reactions such as growth, degradation, and settling. In spite of the recent intensive efforts for organic pollutant removal from major point sources by central and local governments, the water quality in the reservoir had not been improved. Instead, the concentration of COD increased. The model analysis indicated that this finding could be attributed to the continuing increase of the algal production in the reservoir and the allochthonous load from non-point sources. In particular, the concentrations of COD and BOD of algal origin during 2000~2007, each of which is comprised of approximately one half of the total, were approximately 2.5 times higher than those observed during 1988~1994 and approximately 1.3 times higher than those between 1995~1999. The results of this study suggested that it is necessary to reduce the algal bloom so as to improve the water quality of the reservoir.

• Proceedings of KOSOMES biannual meeting
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• 2006.11a
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• pp.271-275
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• 2006

여수 하수처리장 하수처리 방류수가 배출구 인근해역에 미칠 수 있는 영향정도를 파악하기 위하여 해양수질 및 저질 환경을 조사하였다. 조사는 총 30개 지점에서 수질과 저질의 일반항목과 영양염류에 대하여 실시하였다. 조사시기는 2005년 9월 3일 (하계), 2005년 11월 20일(추계), 2006년 2월 13일 (동계), 2006년 5월 28일 (춘계) 에 4 계절에 걸쳐 밀물시와 썰물시에 현장 조사를 실시하였다. 배출수는 해양수질환경의 특성을 통해 추정한 결과 직접영향권은 0.5km, 간접 영향권은 반경 약 2km까지로 추정되었다. 저질의 결과를 보면 산 휘발성 황화물의 농도가 많은 해역에서 저질의 오염기준을 초과하는 동 오염된 저질의 특성을 보였으며, 산 휘발성 황화물과 화학적 산소요구량의 분포는 니질 퇴적상이 두드러지게 나타나는 배출구 동측과 돌산도 남동쪽, 돌산도 서측과 대경도 동측사이에 위치한 해역에서는 대체적으로 높은 값들을 보이고 있으며, 조립질 퇴적상이 주로 분포하고 있는 배출구와 국동항사이의 수로에서는 대체적으로 낮은 분포를 나타내었다.

• Journal of the Korean Society for Marine Environment & Energy
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• v.6 no.4
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• pp.24-36
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• 2003

In this study, we estimated the seasonal fluctuations of water quality and effect of small tide embankment in coastal water around the Muan Peninsula, which is located in the northern part of Mokpo city, and layer farming ground is spread around there. Some physical and chemical factors were analyzed to characterize water quality from Jan. to Oct. in 1994. The results were as follows: Dissolved oxygen was slightly under saturation in the almost areas of July, and in some bottom layer at ebb tide of October. Distribution of COD showed high values that over 2㎎/L in October and flood tide of April by the discharge of freshwater and resuspension of benthic sediment, which exceeded water quality criteria II. Maximum values of dissolved inorganic nitrogen ware appeared in surface layer during the flood tide of October, while minimum of that showed in surface layer in April. Concentration of dissolved inorganic phosphorus was higher at July than the others, which ranged from 0.24 to 2.08㎍-at/L. Mostly mean values of N/P ratio were lower than 16, it mean that nitrogen is more limiting nutrient than phosphorus for the growth of phytoplankton. The values of eutrophication index were in the range of 0.07~0.81. However, very high values due to increase of COD were estimated near the tide embankment and southern part in relation to tidal current in October. Water quality around tide embankment was suddenly changed worse within a short period after opening the water gate during the rainfall.