• Title/Summary/Keyword: 화학적 하수처리

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Manufacturing and Characteristics of the Electrodeless UV Lamp for Disinfection of the Sewage Effluent (하수 방류수 살균소독을 위한 무전극 UV 램프의 제조 및 특성)

  • Shin, Dong Ho;Lee, Yong Taek
    • Applied Chemistry for Engineering
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    • v.16 no.4
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    • pp.570-575
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    • 2005
  • In this study, we have manufactured electrodeless ultraviolet lamp which has a long life and a high degree of efficiency than the existing electrode UV lamp used in sewage effluent sterilization disinfection. First, we investigated change of UV intensity and temperature of lamp by activation materials. The best results for the dose response experiments were 250 minutes stabilizing to UV intensity of $300{\mu}W/cm^2$ and surface temperature $200{\sim}250^{\circ}C$ in Hg/Ind's weight ratio 95/5. When electrodeless UV lamp emits light for prolonged hours, surface temperature of lamp increases. therefore, temperature change is studied using a duplex lamp for cooling in actual sewerage process. Also, manufactured electrodeless UV lamp showed sterilization efficiency of more than 99.9% as result that experiment manufactured electrodeless UV lamp by E-coli. for sterilization disinfection of sewage effluent.

A study on the Optimization of Sewage Sludge-based Adsorbent Carbonization Condition for Improving Adsorption Capacity of Hydrogen Sulfide (H2S) (황화수소(H2S) 흡착성능 증진을 위한 하수슬러지 기반 흡착제 탄화조건 최적화 연구)

  • Choi, Sung Yeol;Jang, Young Hee;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.765-771
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    • 2018
  • In this study, the optimization of carbonization conditions in manufacturing processes was performed to improve the absorption performance of sewage sludge based sorbent used for treating $H_2S$ out of all odorous substances generated by various environmental facilities. Adsorbents applied were manufactured from the sewage treatment plant under different carbonization conditions, such as temperature and heating rate, and the correlation between the adsorption performance and physical properties of the adsorbents was verified. As a result, the adsorption performance of sludge at $900^{\circ}C$ with a heating rate of $10^{\circ}C/min$ was the best, and the SEM and BET analysis revealed that specific surface area and characteristics of pore (size, volume) were major parameters for the adsorption. In addition, the effect of K ions used for improving the adsorption performance of the optimum carbonization condition sorbent was insignificant for the sewage sludge based sorbent.

About Fluidized Bed Incinerators (유동층 소각로에 대하여)

  • 박승호
    • Journal of the KSME
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    • v.35 no.7
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    • pp.620-637
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    • 1995
  • 이 글에서는 유동층소각로와 관련된 기술적 사항을 정리하고자 한다. 일부 교과서적인 내용이 서술되어 있으나, 자세한 이론적 고찰보다는 현상적인 이해에 중점을 두고, 실제 유동층 소각로와 관련된 분야에서 연구를 수행하는 연구자들과의 토론 및 설계시 고려하여야 할 사항들을 간략히 포함한다. 일반적으로 유동층은 효울적인 화학반응로로서 주로 이용되고 있으나, 이 글에서는 환경 및 에너지분야와 일정한 관계가 있는 폐기물 소각로 및 석탄연소로로서의 유동층의 응용에 초점을 맞추고 있다. 우선 환경 및 에너지산업의 현황을 이해함으로써 유동층의 핵심적 역할 담당 가능성을 밝힌다. 그리고 소각로의 종류 및 유동층의 역사와 응용에 대하여 각략히 설명 한다. 여타의 소각로와는 다른 특성인 기포유동특성 및 유동화에 대하여 논함으로써 유동층에 대한 기본현상을 파악한다. 유동층 소각로의 중요한 기능인 공해물질의 노내처리에 대하여 논 의하고, 기포유동층보다 효율적인 순환유동층 및 가압유동층의 특성과 역할을 소개한다. 그리고 유동층 소각로의 예로 일본의 폐기물소각로 및 하수슬러지 소각로개발 현황을 소개한다. 최종 적으로는 유동장 소각로의 실제 설계과장에 대하여 간략히 해설한다.

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An Experimental Study on the Ion Reaction and the Electrochemical Rebar-Corrosion in Aqueous Solution Mixed with Sulfate and Chloride Ion-Reactive Material (황산, 염소이온 반응 소재 혼입 수용액에서의 이온반응성 및 전기화학적 철근 부식에 관한 실험적 연구)

  • Ryu, Hwa-Sung;Shin, Sang-Heon;Kang, Tae-Won;Lim, Chang-Gil;Kim, Hong-Tae
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.1
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    • pp.31-38
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    • 2019
  • In this study, amine derivatives and ion exchange resins were selected to actively control penetration ions ($SO{_4}^{2-}$, $Cl^-$) as the element technology of repair materials for concrete structures in drainage environments. Ions ($SO{_4}^{2-}$, $Cl^-$) adsorption performance and corrosion resistance of calcium hydroxide solution with amine derivative and ion exchange resin were confirmed by ion chromatography and potentiostat analysis. As a result of the experiment, it was confirmed that the amine derivative is excellent in the adsorption of chlorine ion and the ion exchange resin is excellent in the adsorption of sulfate ion. It has been confirmed that corrosion resistance can be increased by proper combination of two materials in the calcium hydroxide solution containing sulfate ion and chloride ion simulating sewage environment.

Study on solubilization of sewage sludge with electrolysis (전기분해 활용 하수슬러지 가용화 연구)

  • Lee, Ji-Sun;Chang, In-Soung;Lee, Chul-Ku;Joung, Seun-Young
    • Proceedings of the KAIS Fall Conference
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    • 2010.11a
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    • pp.482-482
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    • 2010
  • 하수처리장에서 발생하는 유기성 슬러지는 대부분 해양투기에 의해 처분되고 나머지는 매립, 소각, 퇴비화 등으로 처분된다. 그러나 런던협약 '96 의정서' 발효에 의해 2012년부터 해양투기가 금지되고, 매립장 및 소각장의 신규건설은 님비(NIMBY) 현상에 의해 제한받기 때문에 효과적인 슬러지 처분 및 가용화 방법이 요구되고 있다. 현재 초음파[1]나 열처리[2], 오존[3,4], 미생물 처리[5,6] 등 물리, 화학, 생물학적 처리방안이 연구되고 있으나 이러한 방법들은 에너지 과소비, 2차 오염물질 발생에 따른 처리비용 증가 등의 단점을 가지고 있다. 따라서 본 연구에서는 기존의 연구 방법을 보안하고자 전기분해를 활용하여 슬러지 가용화를 시도함으로써 슬러지 발생을 저감시킬 수 있는 방법을 연구하였다. 본 실험에서는 전기분해를 위해 제작된 불용성 전극은 Titanium에 Iridium을 코팅하여 제작하였고, 최대 20V까지 전압을 고정시키고 시간에 따라 변화되는 전류와 전기전도도, pH 값을 관찰하였다. 실험에 사용된 활성슬러지는 3개월간 합성폐수로 순응화 시킨 후에 시료로 사용하였다. 전기분해에 의해 처리된 활성슬러지의 여액을 분석한 결과 SCOD, TN, TP 농도가 각각 510%, 9%, 106% 증가하였다. 이는 전기분해에 의해 미생물의 세포벽이 파괴되어 세포 내 물질들이 세포 외부로 용출되어 미생물들의 이용이 가능한 상태로 되었음을 알 수 있었다. 이는 국내 하 폐수의 낮은 C/N비 때문에 무산소조에 메탄올 같은 외부 탄소원을 공급하는 대신에 별도의 탄소원 공급 없이 가용화 된 슬러지를 반송시킴으로써 슬러지 저감에 따른 폐기 비용과 운전비용의 절감을 기대할 수 있어, 근본적인 슬러지 발생을 저감시킬 수 있는 해결책이라 할 수 있다.

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Evaluation of Environmental and Economic Impacts of Advanced Wastewater Treatment Plants with Life Cycle Assessment (고도 하수처리장의 전과정평가에 따른 환경성 및 경제성 평가)

  • Pyo, SeHee;Kim, MinJeong;Lee, SeungChul;Yoo, ChangKyoo
    • Korean Chemical Engineering Research
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    • v.52 no.4
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    • pp.503-515
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    • 2014
  • A lot of existing wastewater treatment plants (WWTPs) are rebuilt or retrofitted for advanced wastewater treatment processes to cope with reinforced effluent criteria of nitrogen and phosphorous. Moreover, how to treat the wasted sludge from WWTPs has been also issued since the discharge of the wasted sludge into ocean is impossible from 2011 due to the London Convention 97 protocol. These trend changes of WWTPs get a motivation to assess environmental and economic impacts from the construction stage to the waste stage in WWTPs. Therefore, this study focuses on evaluation of environmental and economic impacts of the advanced wastewater treatment processes and waste sludge treatment process by using life cycle assessment. Four advanced wastewater treatment processes of Anaerobic/Anoxic/Oxic ($A_2O$), 5 stages-Bamard Denitrification Phosphate (Bardenpho), Virginia Initiative Plant (VIP), and Modified University of Cape Town (MUCT) are chosen to compare the conventional activated sludge (CAS) and three waste sludge treatment methods of land fill, incineration, and composting are used. To evaluate environmental and economic impacts of each advanced wastewater treatment processes, life cycle assessment (LCA) and life cycle cost (LCC) are conducted based on International organization for standardization (ISO) guidelines. The results clearly represent that the $A_2O$ process with composting shows 52% reduction in the environmental impact than the CAS process with landfill. On the other hand, the MUCT process with composting is able to save 62% of the life cycle cost comparing with the CAS process with landfill. This result suggested the qualitative and quantitative criteria for evaluating eco-environmental and economic technologies of advanced treatment processes and also sludge treatment method, where their main influence factors on environmental and economic impacts are analyzed, respectively. The proposed method could be useful for selecting the most efficient and eco-friendly wastewater treatment process and sludge treatment method when retrofitting the existing WWTPs to advanced treatments.

Optimal Condition of TOC Removal Parameter for Sewage Effluent using Electrolysis Process (하수방류수 내 TOC 제거를 위한 전기분해공정의 최적 조건)

  • An, Sang-Woo;Jung, Hyuk-Sang;Lee, Hui-Kyung;Ko, Jun-Geol;Myoung, Dae-Won
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.4
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    • pp.23-29
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    • 2017
  • As the Enforcement Ordinance of Environmental Policy Act was revised in 2013, Total Organic Carbon (TOC) was added as an indicative parameter for organic matter in Water and Aquatic Ecosystem Environmental Criteria. Under these imminent circumstances, a regulatory standard is needed to achieve the proposed TOC limitation control water quality from the STP (Sewage Treatment Plant). In this study, a electrolysis utilizing the electrochemical reaction was investigated in lab-scale experiments for the treatment of TOC in sewage effluent. TOC reduction by a electrolysis was investigated response surface methodology using the Box-Begnken methods were applied to the experimental results. A central composite design was used to investigate the effects of the independent variables of electrode space ($x_1$), current density ($x_2$) and electrolyte concentration ($x_3$) on the dependent variables removal efficiency of TOC (y). The optimal conditions for electrolysis were determined: electrode space, current density and electrolyte concentration were 50 mm, $10.3mA/cm^2$ and 0.1M, respectively. Statistical results showed the order of significance of the independent variables to be electrode space > current density > electrolyte concentration.

Initial Operating Condition of Membrane Bioreactor with PVDF Hollow Fiber and Permeate Reuse (PVDF 중공사막을 이용한 막생물반응기의 초기 운전조건 설정 및 여과수 재활용)

  • Shin, Choon-Hwan;Kang, Dong-Hyo;Park, Hae-Sik;Cho, Hyun-Kil
    • Clean Technology
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    • v.16 no.1
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    • pp.39-45
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    • 2010
  • In this paper, 4 bundle modules of PVDF hollow fiber membrane from Woori Tech company (Korea) were manufactured in a treatment capacity of 10 ton/day. A membrane bioreactor (MBR) pilot plant was installed at Sooyoung Wastewater Treatment Plant in Busan. An alternating aeration process was selected to avoid the concentration profile of suspended solid (SS) in the MBR. For stable operation, raw wastewater with mixed liquor suspended solid (MLSS) of about 1,000 ppm, which was in-flowed from the aeration tank of the wastewater treatment plant, was fed and filtered through the pilot plant. Subsequently the pilot plant were washed three times with washing water: once with ethanol solution, once with a solution of 5% NaOCl, and finally with washing water. After the chemical washing, the remaining water in the MBR was fed into the pilot plant. As a result, the SS removal efficiency was found to be more than 99.9%. The amount of filtrate with the aeration tank influent decreased by 16%, compared with that from the initial conditions, giving rise to 30% increase in the suction pressure. These results were used to set up continuous operation conditions. The results from the continuous operation with influent MLSS of 1,900 mg/L showed that the SS removal efficiency was about 99.99% and that the amount of filtrate and the suction pressure were $42{\sim}52L/m^2$ and 16~20 cmHg, respectively, indicating stable operation of the pilot plant. However, for the reuse of wastewater, methods need to be sought to avoid growth of algae which affects the SS removal efficiency at inlet and outlet of the permeate tank.

미생물을 이용한 다용도 고형 탈취제의 개발

  • Kim, Yu-Jin;Lee, Eun-Jeong;Jeon, Mi-Uk;Kim, Cho-Hui;Park, Seong-Hun;Lee, Eun-Yeol
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.513-516
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    • 2001
  • This study was to develop of efficient microbial agent for malodor removal. Total ten strains of beneficial bacteria Bacillus sp., Pseudomonas sp., and photosynthetic bacteria were isolated and identified on the basis of their morphological and biochemical characteristics. The enzyme activities such as amylase, protease, lipase and cellulase of bacteria cells were measured. Furthennore, effective formulation procedure 、 ,vas developed with nutrient additive, stabilizing agent and mineral materix. For preparation of microbial agent, developing of formulation technique was very helpful for incresing the cell survival rate.

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Study on the Design of Attached Revolution Body Horizontal Rotary Kiln Dryer and the Optimum Operational Conditions (회전체를 부착한 수평형 로타리킬른 건조로의 설계 및 최적 운전조건 연구)

  • Jung, Dong Hyun;Chun, Young Nam
    • Applied Chemistry for Engineering
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    • v.18 no.6
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    • pp.575-579
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    • 2007
  • Sludge disposal technology has been studied with many researchers since disposal of sewage sludge has been a social problem. The current technologies include incineration, carbonization, pyrolysis, landfilling and fertilization. However, all of these processes require a dry process, because sewage sludge with more than 80% high water content is difficult to be used as a raw material. This study has the purpose to establish the optimal operation conditions and the technology as changing the variables: kiln residence time, sludge load, dryer temperature, by using the previous study that is rotary kiln type dryer designed as a numerical simulation study. As the results, optimum conditions are determined as follows: kiln residence time, sludge load, dryer temperature are $62.5kg/m^3{\cdot}hr$, 26.2 min, $330^{\circ}C$, respectively. Content of water, drying efficiency, weight loss, volume loss show that the results are $10{\pm}2$, 88, 80, 60%, and the dried sludge is released by a dryer below 10 mm.