• Membrane Journal
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• v.32 no.5
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• pp.336-347
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• 2022

Reverse electrodialysis (RED) is one of the promising eco-friendly renewable energy technologies which can generate electricity from the concentration difference between seawater and freshwater by using ion-exchange membranes as a diaphragm. The ion-exchange membrane is a key component that determines the performance of RED, and must satisfy requirements such as low electrical resistance, high permselectivity, excellent durability, and low manufacturing cost. In this study, pore-filled anion-exchange membranes were fabricated using porous polymer substrates having various thicknesses and porosity, and the effects of ion-exchange polymer composition and membrane thickness on the power generation performance of RED were investigated. When the electrical resistance of the ion-exchange membrane is sufficiently low, it can be confirmed that the RED power generation performance is mainly influenced by the apparent permselectivity of the membrane. In addition, it was confirmed that the apparent permselectivity of the membranes can be improved through IEC, crosslinking degree, membrane thickness, surface modification, etc., and the optimum condition must be found in consideration of the trade-off relationship with electrical resistance.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.310-310
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• 2012

최근 전자산업의 발달에 따른 전자제품의 소형화 및 고기능화 요구에 대응하기 위하여 저항(resistor), 커패시터(capacitor), IC (integrated circuit) 등의 수동소자를 개별 칩(discrete chip) 형태로 형성하여 기판의 표면에 실장하는 기술이 일반화되고 있다. 그러나, 수동 소자의 내장 기술은 기판의 패턴 밀도의 급격한 향상과 더불어 수동소자의 내장 공간도 협소해지는 문제점이 있다. 상기의 문제점을 해결하기 위해 개별 칩 형태의 내장형 저항체를 박막 형태의 내장 저항체를 구현하는 기술의 개발이 최근 주목을 받고 있다. 박막 저항체는 기존의 권선저항 및 후막저항과 비교하여 정밀한 온도저항계수를 가지며 이동통신에 적용시 고주파 영역(GHz)에서의 안정성과 주파수 특성이 좋다는 장점들을 가지고 있다. 박막 저항 물질로는 높은 경도와 우수한 열적 안정성을 가지고 있는 TaN (tantalum nitride)이 주로 사용되고 있다. 일반적으로, TaN 박막은 스퍼터링을 사용하며 제조되며 TaN 박막의 성질은 탄탈륨과 질소의 화학정량비, 박막의 결함 정도, 또는 공정압력 및 증착 온도, 플라즈마 파워 등과 같은 공정조건 등의 변화에 민감하게 변화하므로, TaN 박막의 다양한 연구가 더 필요한 실정이다. 본 연구에서는 반응성 마크네트론 스퍼터링을 사용하여 TaN 박막을 Si 기판 위에 증착하였고 TaN 박막의 원하는 특성을 제어할 수 있도록 질소 분압과 total gas volume을 조절하여 공정을 최적화하는 연구를 진행하였다. 또한 tensile pull-off 방법을 이용하여 TaN 박막의 부착강도를 평가하였고, 온도 사이클 및 고온고습 환경에 노출된 TaN 박막들의 열화 특성들에 대하여 연구하였다.

• Journal of the Korean Geotechnical Society
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• v.19 no.5
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• pp.263-272
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• 2003

Various types of geosynthetics have been manufactured and their applications are rapidly extended disregarding unreliable lifetime, chemical and biological persistence and puncture resistance. Puncture resistance of geosynthetics in earth structures and liner systems has been a critical issue to be improved. In this paper, comparative studies were made on a puncture resistance of various geosynthetics that were used to a liner system. Two types of puncture tools and rubles and gravels were used to generate punctures on geosynthetics. From the results it is shown that types of puncture tools affect puncture resistance of materials significantly and puncture forces were irregular depending upon puncture tools and materials.

• Korean Journal of Materials Research
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• v.1 no.1
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• pp.23-28
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• 1991

The resistivity of polycrystalline silicon film deposited by low pressure chemical vapor deposition and doped by arsenic Implantation has been investigated as a function of dopant concentration and testing temperature ranging from $25^{\circ}C$ to $105^{\circ}C$ . The resistivity vs. doping concentration curve had a peak point with highest activation energy with respect to the dependence of the resistivity on temperature. We showed that $O_2$ plasma anneal followed by heat-treatment in $N_2$ ambient was able to recover the resistivity degraded by the plasma deposited passivation layers.

• Proceedings of the Korean Nuclear Society Conference
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• 1997.05b
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• pp.201-206
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• 1997

본 연구에서는 Ni-기 합금인 합금 600과 합금 690, Fe-기 합금인 합금 800 및 초내식성 오스테나이트계 스테인리스강인 SR-50A에 대하여 부식 환경의 변화에 따른 특성 평가를 행하였다. 전기화학적 부식 평가는 양극 분극 시험을 통하여 행하였으며 부식 환경은 NaCl, HCI, NaOH(+$Na_2$SO$_4$) 액이었다. 응력 부식 균열 시험으로는 CERT(Constant Extension Rate Test)를 행하였으며 부식환경은 40%NaOH, 40%OH+12%$Na_2$SO$_4$ 용액이었다. CERT시험 후 그 파면을 SEM관찰하여 파괴 양상을 관찰하였다. 각 합금의 양극 분극 특성을 부식 환경에 따라 평가한 결과, 부식 용액의 증류에 따라 서로 다른 분극 거동을 보이고 있는데 산성과 중성 용액에서는 SR-50A가 가장 큰 저항성을 보이는 반면, 강 알카리용액인 NaOH용액에서는 Ni-기 합금의 저항성이 Fe-기 합금의 저항성보다 우수하게 나타났다. 응력 부식 균열 저항성은 전반적으로 Fe-기 합금보다 Ni-기 합금이 우수하게 나타났다. 파단면을 SEM관찰한 결과 합금 800과 SR-50A(tube)는 용액에 관계없이 입내 파괴 모드를 나타내고 있으며, 합금 600과 SR-50A판재는 입계 파괴 양상을 보이고 있다. 또한 가성 용액 중에 $Na_2$SO$_4$를 첨가할 경우, 부식 속도를 가속화시키고 응력 부식 균열 저항성을 감소시키고 있다.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.5
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• pp.148-155
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• 2017

In this study, by using the international standards ISO TS 16774, Part 2 Test method for chemical resistance as a quality control method of injection type repair material used for leakage crack of underground concrete structure, the performance requirement against of chemical environment of underground concrete structures for repair materials was tested. For this testing 3 types for each of the 2 classes of repair materials(synthetic rubber, cement), with a total of 9 types repair materials, were selected and examined. As a result, the test results showed that the smallest performance deterioration by the change in the mass was with the synthetic rubber(RG) type as opposed to the cement type system, showing that the synthetic rubber type had the strongest relative resistance to chemical exposure. Furthermore, it is necessary to investigate the material with high resistance to chemical substances and to examine the material which can increase resistance to sodium hydroxide and sodium chloride in cement system. These results can be used as a basic index for the selection of repair materials with the strongest resistance to chemical environment found in concrete structures. In addition, it is expected that the test results derived in this study can be used as reference data that can be reflected in the quality improvement of the maintenance material to be developed later.

• Korean Chemical Engineering Research
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• v.45 no.5
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• pp.500-505
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• 2007

The objectives of this research were to (1) identify the membrane fouling potential due to different fractions of NOM (2) correlate the physicochemical properties of NOM and membranes with the adsorption of humic substances on membrane (4) find out the effect of membrane physical and chemical washing according to membrane material. The static adsorption test and adsorption test showed that hydrophobic organics adsorbed much more quickly than hydrophilic organics. In case of the effect of membrane properties on the adsorption of organic fractions, the adsorption rate ratio(a) of hydrophobic membrane (0.016, 0.077) was greater than that of hydrophilic membrane (0.010, 0.033) regardless of the kind of organic fractions. This suggests that the UF membrane fouling were occurred mainly by internal pore size decreasing due to adsorption of organic into pore surface for hydrophobic membrane, and by sieving of organics and forming a gel layer on the membrane surface for hydrophilic membrane. In conclusion, the decrease in the pore volume, which was caused by the organic adsorption into the internal pore, was greater with the hydrophobic membrane than with the hydrophilic membrane. In case of the effect of membrane properties on permeate flux, the rate of flux decline for the hydrophobic membrane was significantly greater than that for the hydrophilic membrane.

• Journal of the Korea Institute of Building Construction
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• v.19 no.5
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• pp.411-419
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• 2019

Underground concrete structures are constructed under a geographical environment called underground and exposed to various environments that promote deterioration. Among them, groundwater promotes deterioration of underground concrete structures due to contaminated water from the ground. In this study, the chemical resistance performance test evaluation of five different receptors for a total of 15-type leakage repair materials of five series was conducted to determine the chemical stability of the leakage repair material used in the crack area. The results show a general increase and decrease in most chemical receptors, but the biggest increase and decrease was shown in acrylic systems, which were found in sodium chloride and sodium hydroxide, and epoxy was found in hydrochloric acid. The cement system is showing a lot of increase and decrease in sodium chloride. It is expected that the results of these studies will be used as a basis for chemical stabilization in the development of new materials.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2004.05a
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• pp.74-80
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• 2004

Among inorganic materials, it is grounding resistance lower agent of new form that use being strata style clay and makes using water soluble polymer by main material to organic substance. Water soluble polymer chains are dispertion in water because water soluble polymer reacts with water if is done and these discrete polymer chains are inserted to floor of being strata style clay with water. This material that moisture content is very excellent and rate of expansion, electrical conductivity that measure after supplies water of 300wt % as well as is excellent. Can prevent corrosion or electrolytic corrosion of grounding bar securing very environmentally, chemically and pollution of soil. When applied to general grounding rod worker $7{\sim}8$ times ground resistance reduction effect of not application.

• Journal of the Korean Geosynthetics Society
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• v.2 no.3
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• pp.19-24
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• 2003

Long-term performance of smooth and textured type HDPE geomembranes which were used to the liner and slope systems of waste landfills was examined. Artificial surface defects were added to the surface of geomembranes by scratch addition apparatus specially designed. The mechanical and frictional properties, chemical and ultra violet light resistances and oxidative induction time(OIT) of geomembranes were examined for the cases of defective/non-defective surfaces. Frictional properties of textured type geomembranes showed more excellent than those of smooth type geomembranes. Finally, it was known that the long-term performance of non-defective and textured geomembranes was better than that of defective geomembranes through chemical and UV resistance and OIT tests etc.