• Title/Summary/Keyword: 화학기상안정화

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Characteristics of Mercury Concentration in Vapor Phase from Compact Fluorescent Lamp (소형형광등(Compact Fluorescent Lamp)의 파쇄에 따른 기상에서의 수은농도 특성)

  • Rhee, Seung-Whee
    • Korean Chemical Engineering Research
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    • v.52 no.5
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    • pp.652-656
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    • 2014
  • Mercury amount in vapor phase from 3 types of CFL(compact fluorescent lamp) are estimated by measuring mercury concentration in vapor phase. The mercury concentration in vapor phase from CFL is sharply decreased during initial time and then the change in the mercury concentration is slightly decreased up to 24 hours. The mercury concentration in vapor phase is almost constant after 42 hours, which can be called by stabilized concentration. It can be estimated that the stabilized concentration is caused by the evaporation of mercury in the residues of broken CFL and can be affected by temperature and pressure in crushing apparatus. The mercury concentration for CFL manufactures are in the order of A < B < C as the same results of the initial mercury concentration and the stabilized concentration in vapor phase. As increased air flow rate, the partial pressure of mercury is decreased and the amount of mercury is reduced. Initially, the mercury concentration in vapor phase emitted from CFLs is higher than the regulatory level of $0.1mg/m^3$ in the specific facilities regardless of air flow rate. Hence, it is absolutely necessary that mercury in vapor phase should be controlled at the point of crushing campact fluorescent lamp.

Densification of Cf/SiC Composite Using PIP with Adding of Cyclohexene (Cyclohexene을 첨가한 PIP 공정 사용 Cf/SiC 복합재의 고밀도화)

  • Bae, Jin-Cheol;Cho, Kwang-Youn;Kim, Jun-Il;Im, Dong-Won;Park, Jong-Kyu;Lee, Man-Young;Lee, Jae-Yeol
    • Composites Research
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    • v.26 no.5
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    • pp.322-327
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    • 2013
  • Carbon fiber-reinforced SiC matrix composites have good oxidation resistance and thermal shock resistance. These properties have allowed the composites to be applied to high-temperature structures. In this study, $C_f/SiC$ composites were fabricated via precursor infiltration and pyrolysis (PIP) process, including liquid phase infiltration and chemical vapor curing using cyclohexene. The final $C_f/SiC$ composites, which have gone through the PIP process five times, showed a density of $1.79g/cm^3$, as compared to a density of $0.43g/cm^3$ for pre-densified bare carbon fiber preform. As for the oxidation resistance characteristics, the weight of $C_f/SiC$ composite was maintained at 81% at $1400^{\circ}C$ in air for 6 hours. Chemical vapor curing (CVC) using cyclohexene has shown to be an effective method to achieve high densification, leading to increased oxidation resistance.

지지막의 특성에 의한 복합막의 성능 변화에 대한 연구

  • 곽상효;오종열;신세종;민병렬
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.73-74
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    • 1996
  • 역삼투막은 높은 투과율과 배제율, 기계적 강도, 열적 안정성, 화학적 안정성, 성형성, 경제성 등의 여러 가지 조건을 동시에 만족시켜야 한다. 복합막을 통한 역삼투막의 제조는 위의 조건들을 만족시키는 역삼투막을 제조할 수 있는 훌륭한 제조 방법인데 지지막과 표면의 활성층을 여러 가지로 조합하여 다양한 성능의 막을 개발할 수 있기 때문이다. 지지막은 다공질의 고분자막으로 기계적 강도, 화학적.열적 안정성 등이 있어야 하는데 역삼투막이 가혹한 운전 조건에서 조작되기 때문이다. 그리고 지지막은 활성층과 안정된 결합을 할 수 있는 물리적 및 화학적 성질을 지녀야 한다. 활성층은 분리가 일어나는 곳으로 막의 배제율과 투과특성에 큰 영향을 미친다. 따라서 복합막의 제조에 있어서 고려되어야 할 사항은 지지막과 활성층의 재질의 선택, 지지막의 특성, 지지막 위에 얇고 안정된 활성층의 도포 방법, 성능향상과 활성층의 안정화를 위한 제조된 복합막의 후처리 방법 등이다. 지지막 위에 활성층을 도포시키는 방법은 계면중합법, 박층분산법, 침지코팅법, 기상증착법 등을 들 수 있는데 이 중에서 계면중합법을 이용한 복합막의 제조가 가장 실용적인 방법으로 인정되고 있고 현재 실용화되어 있다.

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Stabilizing Properties of SiOF Film with Low Dielectric Constant by $N_2O$ Plasma Annealing ($N_2O$ 플라즈마 열처리에 의한 저유전율 SiOF 박막의 물성 안정화)

  • Kim, Yoon-Hae;Lee, Seok-Kiu;Kim, Sun-Oo;Kim, Hyeong-Joon
    • Korean Journal of Materials Research
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    • v.8 no.4
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    • pp.317-322
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    • 1998
  • The stabilization of low dielectric constant SiOF films prepared by conventional PECVD using TEOS and $C_2F_6$ was evaluated by the $N_2O$-plasma post-deposition annealing. Properties of SiOF film became unstable when it was air-exposed or heat-treated. Water absorption of SiOF films was increased as F content was increased due to the for¬mation of F -Si- F bonds. Also F content of SiOF films decreased after heat treatment. $N_2O$-plasma post-deposition annealing was proved to be effective on stabilizing SiOF films. which was mainly due to the formation of thin SiON layer near the top surface of films. However. the value of dielectric constant was greatly increased again when $N_2O$-plasma post-deposition annealing was done for a long time. To stabilize the SiOF films without an increase of dielec¬tric constant by $N_2O$- plasma post-deposition annealing. the annealing time should be kept the minimum value. to which stabilizing effects against air environment and heat treatment were preserved.

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Changes to the pH and Chemical Composition of the Precipitation inside the Pinus densiflora and Pinus rigida Stands (산림을 통과한 강우의 pH 및 화학적 조성의 변화)

  • 주영특;김홍률;이상덕
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.5 no.1
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    • pp.24-29
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    • 2003
  • This study was conducted to investigate vertical movement properties of precipitation passing forest stands (Pinus densiflora and Pinus rigida stands) in Chunchon, Kangwon-do. The results were as follows: The pH range of precipitation was 4.08∼7.08, and the average pH showed 6.2$\pm$0.7. The average pH of the Pinus densiflora stand showed that the stemflow was 5.9$\pm$0.9, and the throughfall was 6.0$\pm$0.8. The pH value of stemflow and throughfall in the Pinus rigida stand was lower than for the Pinus densiflora stand. Changes of the cation concentrations in two different stands, $Ca^{2+}$, increased more than the $Mg^{2+}$, $K^{+}$, and N $a^{+}$ions. Anions, S $O_{4}$$^{2-}$ and N $O_{3}$$^{[-10]}$ increased more than C $l^{[-10]}$ . Leaching and washout for each species differed by precipitation and influence of tree organs (crown, branch, stem, etc.).etc.).

The Behavior of Leachate on The Transient Condition in The Nanji Waste Landfill (부정류 상태에서의 난지도 매립지 침출수 거동 예측)

  • 강동희;조원철;이재영
    • Journal of Soil and Groundwater Environment
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    • v.6 no.2
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    • pp.57-67
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    • 2001
  • The purpose of this study is to predict appropriate leachate rates and leachate transport velocity through weathered zone and basement rock on the transient condition at Nanji waste landfill. The leachate transport in the Nanji waste landfill is analyzed using MODFLOW(A Modular 3-D Finite Different Groundwater Flow Model) model which simulates three dimension groundwater flow and MT3D(A Modular Three Dimentional Transport Model) model which describes three dimensional transport for advection, dispersion and chemical reaction of dissolved constituents in groundwater system on the transient condition. Leachate production rates are estimated by HELP(Hydraulical Evaluation of Landfill Performance) model and used weather records for recent 10 years. Leachate transport is predicted by a change of leachate level to after/before established HDPE, established slurry wall and wells.

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